EA201591081A1 - Молекулярное сито sapo-34 с использованием дигликольамина в качестве матричного агента и способ его получения - Google Patents

Молекулярное сито sapo-34 с использованием дигликольамина в качестве матричного агента и способ его получения

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Publication number
EA201591081A1
EA201591081A1 EA201591081A EA201591081A EA201591081A1 EA 201591081 A1 EA201591081 A1 EA 201591081A1 EA 201591081 A EA201591081 A EA 201591081A EA 201591081 A EA201591081 A EA 201591081A EA 201591081 A1 EA201591081 A1 EA 201591081A1
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EA
Eurasian Patent Office
Prior art keywords
sapo
diglycolamine
molecular sieve
molecular
sito
Prior art date
Application number
EA201591081A
Other languages
English (en)
Other versions
EA025394B1 (ru
Inventor
Дэхуа Вон
Пэн Тянь
Чжунминь Лю
Дун Фань
Ин Чжан
Сюн Су
Original Assignee
Далянь Инститьют Оф Кемикал Физикс, Чайниз Академи Оф Сайэнс
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Далянь Инститьют Оф Кемикал Физикс, Чайниз Академи Оф Сайэнс filed Critical Далянь Инститьют Оф Кемикал Физикс, Чайниз Академи Оф Сайэнс
Publication of EA201591081A1 publication Critical patent/EA201591081A1/ru
Publication of EA025394B1 publication Critical patent/EA025394B1/ru

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/54—Phosphates, e.g. APO or SAPO compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3071—Washing or leaching
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

Настоящее изобретение относится к молекулярному ситу SAPO-34, химический состав которого в безводном состоянии выражается в виде mDGA∙(SiAlP)O; отличающемуся тем, что DGA представляет собой дигликольамин, распределяющийся в каркасах и порах указанного молекулярного сита; m является молярным количеством дигликольамина-матричного агента на один моль (SiAlP)Oи m составляет от 0,03 до 0,25; х, у, z соответственно представляют молярное количество Si, Al, P, и х составляет от 0,01 до 0,30, у составляет от 0,40 до 0,60, a z от 0,25 до 0,49, и х+у+Z=1. Указанное молекулярное сито SAPO-34 может использоваться в качестве катализатора в катализируемой кислотой реакции, например катализатор в реакции метанол-в-олефины. Настоящее изобретение также касается применения указанного молекулярного сита SAPO-43 в адсорбционном разделении СНи СО.
EA201591081A 2012-12-10 2012-12-10 Молекулярное сито sapo-34 с использованием дигликольамина в качестве матричного агента и способ его получения EA025394B1 (ru)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2012/086280 WO2014089740A1 (zh) 2012-12-10 2012-12-10 一种以二甘醇胺为模板剂的sapo-34分子筛及其合成方法

Publications (2)

Publication Number Publication Date
EA201591081A1 true EA201591081A1 (ru) 2015-10-30
EA025394B1 EA025394B1 (ru) 2016-12-30

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EA201591081A EA025394B1 (ru) 2012-12-10 2012-12-10 Молекулярное сито sapo-34 с использованием дигликольамина в качестве матричного агента и способ его получения

Country Status (11)

Country Link
US (1) US9611150B2 (ru)
EP (1) EP2930148B1 (ru)
JP (1) JP6076496B2 (ru)
KR (1) KR101920959B1 (ru)
AU (1) AU2012396750B2 (ru)
BR (1) BR112015013359B1 (ru)
DK (1) DK2930148T3 (ru)
EA (1) EA025394B1 (ru)
SG (1) SG11201504127XA (ru)
WO (1) WO2014089740A1 (ru)
ZA (1) ZA201504518B (ru)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2380663A4 (en) * 2009-01-22 2017-05-10 Mitsubishi Plastics, Inc. Catalyst for removing nitrogen oxides and method for producing same
EP3183214B1 (en) 2014-08-22 2019-10-09 W.R. Grace & CO. - CONN. Method for synthesizing silicoaluminophosphate-34 molecular sieves using monoisopropanolamine
CN109205637B (zh) * 2017-07-05 2021-10-08 中国石油化工股份有限公司 Sapo-35分子筛及其制备方法和应用
KR102224614B1 (ko) * 2018-12-31 2021-03-05 포항공과대학교 산학협력단 무기 금속 성분을 포함하는 cha형 sapo 및 그 제조 방법
CN115520877B (zh) * 2021-06-25 2024-05-28 中国石油化工股份有限公司 一种sapo-34分子筛及其制备方法和应用
CN114890437B (zh) * 2022-06-22 2023-08-25 中国石油大学(华东) 一种利用mto废催化剂快速合成的小粒度sapo-34分子筛及其制备方法
CN117023604B (zh) * 2023-10-09 2024-01-02 中汽研汽车检验中心（天津）有限公司 一种菱沸石结构分子筛、催化剂及其合成方法与应用

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4440871A (en) * 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US4499327A (en) 1982-10-04 1985-02-12 Union Carbide Corporation Production of light olefins
JP3144432B2 (ja) * 1991-11-02 2001-03-12 株式会社コスモ総合研究所 ゼオライトの合成方法
CN1037334C (zh) * 1992-12-19 1998-02-11 中国科学院大连化学物理研究所 一种以三乙胺为模板剂的合成硅磷铝分子筛及其制备
CN1038125C (zh) * 1993-06-18 1998-04-22 中国科学院大连化学物理研究所 以二乙胺为模板剂合成磷酸硅铝分子筛
JP3785815B2 (ja) * 1997-06-27 2006-06-14 東レ株式会社 芳香族炭化水素の転化方法
CN1314587C (zh) * 2005-04-14 2007-05-09 南京工业大学 一种sapo－34分子筛的制备方法
CN102336413B (zh) * 2010-11-29 2013-04-17 中国科学院大连化学物理研究所 一种低硅sapo-34分子筛的合成方法

Also Published As

Publication number Publication date
AU2012396750A1 (en) 2015-06-11
US20150315031A1 (en) 2015-11-05
EA025394B1 (ru) 2016-12-30
SG11201504127XA (en) 2015-07-30
BR112015013359A2 (pt) 2017-07-11
WO2014089740A1 (zh) 2014-06-19
JP6076496B2 (ja) 2017-02-08
AU2012396750B2 (en) 2015-08-27
EP2930148A1 (en) 2015-10-14
JP2016505492A (ja) 2016-02-25
KR101920959B1 (ko) 2018-11-21
EP2930148B1 (en) 2017-07-05
DK2930148T3 (da) 2017-08-14
ZA201504518B (en) 2016-11-30
BR112015013359B1 (pt) 2020-11-24
EP2930148A4 (en) 2016-04-27
US9611150B2 (en) 2017-04-04
KR20150082596A (ko) 2015-07-15

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