BR112015013359A2 - peneira molecular sapo-34 utilizando diglicolamina como agente modelo e método de preparação da mesma - Google Patents
peneira molecular sapo-34 utilizando diglicolamina como agente modelo e método de preparação da mesmaInfo
- Publication number
- BR112015013359A2 BR112015013359A2 BR112015013359A BR112015013359A BR112015013359A2 BR 112015013359 A2 BR112015013359 A2 BR 112015013359A2 BR 112015013359 A BR112015013359 A BR 112015013359A BR 112015013359 A BR112015013359 A BR 112015013359A BR 112015013359 A2 BR112015013359 A2 BR 112015013359A2
- Authority
- BR
- Brazil
- Prior art keywords
- molecular sieve
- sapo
- diglycolamine
- preparation
- model agent
- Prior art date
Links
- 239000002808 molecular sieve Substances 0.000 title abstract 6
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title abstract 6
- GIAFURWZWWWBQT-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanol Chemical compound NCCOCCO GIAFURWZWWWBQT-UHFFFAOYSA-N 0.000 title abstract 4
- 239000003795 chemical substances by application Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006555 catalytic reaction Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000007809 chemical reaction catalyst Substances 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/54—Phosphates, e.g. APO or SAPO compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3071—Washing or leaching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates (SAPO compounds)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/06—Washing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
- C01B37/08—Silicoaluminophosphates (SAPO compounds), e.g. CoSAPO
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- B01J35/40—
Abstract
resumo peneira molecular sapo-34 utilizando diglicolamina como agente modelo e método de preparação da mesma a presente invenção é de uma peneira molecular sapo-34, cuja composição química no estado anidro é expressada como: mdga?(sixalypz)o2; é diglicolamina, distribuindo nas estruturas e poros desta peneira molecular; m é o número molar da diglicolamina por um mol de (sixalypz)o2, sendo que m é de 0,03 para 0,25; x, y, z representam, respectivamente, o número molar do si, al, p, sendo que x é de 0,01 para 0,30, y é de 0,40 para 0,60, e z é de 0,25 para 0,49, sendo que x + y + z =1. a peneira molecular sapo-34 pode ser utilizada em um catalisador da reação catalisada por ácido, como um catalisador da reação de metanol para olefinas. a presente invenção também se trata da aplicação da peneira molecular sapo-34 na separação por adsorção de ch4 e co2. 1/1
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2012/086280 WO2014089740A1 (zh) | 2012-12-10 | 2012-12-10 | 一种以二甘醇胺为模板剂的sapo-34分子筛及其合成方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112015013359A2 true BR112015013359A2 (pt) | 2017-07-11 |
| BR112015013359B1 BR112015013359B1 (pt) | 2020-11-24 |
Family
ID=50933665
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112015013359-2A BR112015013359B1 (pt) | 2012-12-10 | 2012-12-10 | Peneira molecular sapo-34, metodo para preparar a peneira molecular sapo-34, catalisador para reaqao catalisada por acido, catalisador para oxigenados para reaqao de olefinas, e material utilizado para separaqao por adsorqao de ch4/co2 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US9611150B2 (pt) |
| EP (1) | EP2930148B1 (pt) |
| JP (1) | JP6076496B2 (pt) |
| KR (1) | KR101920959B1 (pt) |
| AU (1) | AU2012396750B2 (pt) |
| BR (1) | BR112015013359B1 (pt) |
| DK (1) | DK2930148T3 (pt) |
| EA (1) | EA025394B1 (pt) |
| SG (1) | SG11201504127XA (pt) |
| WO (1) | WO2014089740A1 (pt) |
| ZA (1) | ZA201504518B (pt) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010084930A1 (ja) * | 2009-01-22 | 2010-07-29 | 三菱化学株式会社 | 窒素酸化物浄化用触媒及びその製造方法 |
| CN107074571B (zh) | 2014-08-22 | 2022-09-27 | 格雷斯公司 | 使用一异丙醇胺合成磷酸硅铝-34分子筛的方法 |
| CN109205637B (zh) * | 2017-07-05 | 2021-10-08 | 中国石油化工股份有限公司 | Sapo-35分子筛及其制备方法和应用 |
| KR102224614B1 (ko) * | 2018-12-31 | 2021-03-05 | 포항공과대학교 산학협력단 | 무기 금속 성분을 포함하는 cha형 sapo 및 그 제조 방법 |
| CN115520877A (zh) * | 2021-06-25 | 2022-12-27 | 中国石油化工股份有限公司 | 一种sapo-34分子筛及其制备方法和应用 |
| CN114890437B (zh) * | 2022-06-22 | 2023-08-25 | 中国石油大学(华东) | 一种利用mto废催化剂快速合成的小粒度sapo-34分子筛及其制备方法 |
| CN117023604B (zh) * | 2023-10-09 | 2024-01-02 | 中汽研汽车检验中心（天津）有限公司 | 一种菱沸石结构分子筛、催化剂及其合成方法与应用 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4440871A (en) | 1982-07-26 | 1984-04-03 | Union Carbide Corporation | Crystalline silicoaluminophosphates |
| US4499327A (en) | 1982-10-04 | 1985-02-12 | Union Carbide Corporation | Production of light olefins |
| JP3144432B2 (ja) * | 1991-11-02 | 2001-03-12 | 株式会社コスモ総合研究所 | ゼオライトの合成方法 |
| CN1037334C (zh) * | 1992-12-19 | 1998-02-11 | 中国科学院大连化学物理研究所 | 一种以三乙胺为模板剂的合成硅磷铝分子筛及其制备 |
| CN1038125C (zh) * | 1993-06-18 | 1998-04-22 | 中国科学院大连化学物理研究所 | 以二乙胺为模板剂合成磷酸硅铝分子筛 |
| JP3785815B2 (ja) * | 1997-06-27 | 2006-06-14 | 東レ株式会社 | 芳香族炭化水素の転化方法 |
| CN1314587C (zh) * | 2005-04-14 | 2007-05-09 | 南京工业大学 | 一种sapo－34分子筛的制备方法 |
| CN102336413B (zh) * | 2010-11-29 | 2013-04-17 | 中国科学院大连化学物理研究所 | 一种低硅sapo-34分子筛的合成方法 |
-
2012
- 2012-12-10 SG SG11201504127XA patent/SG11201504127XA/en unknown
- 2012-12-10 JP JP2015546792A patent/JP6076496B2/ja active Active
- 2012-12-10 KR KR1020157015304A patent/KR101920959B1/ko active IP Right Grant
- 2012-12-10 AU AU2012396750A patent/AU2012396750B2/en active Active
- 2012-12-10 WO PCT/CN2012/086280 patent/WO2014089740A1/zh active Application Filing
- 2012-12-10 EP EP12890022.2A patent/EP2930148B1/en active Active
- 2012-12-10 BR BR112015013359-2A patent/BR112015013359B1/pt active IP Right Grant
- 2012-12-10 US US14/647,973 patent/US9611150B2/en active Active
- 2012-12-10 DK DK12890022.2T patent/DK2930148T3/da active
- 2012-12-10 EA EA201591081A patent/EA025394B1/ru unknown
-
2015
- 2015-06-23 ZA ZA2015/04518A patent/ZA201504518B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR101920959B1 (ko) | 2018-11-21 |
| EA201591081A1 (ru) | 2015-10-30 |
| JP2016505492A (ja) | 2016-02-25 |
| SG11201504127XA (en) | 2015-07-30 |
| WO2014089740A1 (zh) | 2014-06-19 |
| JP6076496B2 (ja) | 2017-02-08 |
| ZA201504518B (en) | 2016-11-30 |
| EA025394B1 (ru) | 2016-12-30 |
| US20150315031A1 (en) | 2015-11-05 |
| EP2930148B1 (en) | 2017-07-05 |
| EP2930148A1 (en) | 2015-10-14 |
| DK2930148T3 (da) | 2017-08-14 |
| AU2012396750B2 (en) | 2015-08-27 |
| KR20150082596A (ko) | 2015-07-15 |
| US9611150B2 (en) | 2017-04-04 |
| BR112015013359B1 (pt) | 2020-11-24 |
| AU2012396750A1 (en) | 2015-06-11 |
| EP2930148A4 (en) | 2016-04-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06F | Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette] | ||
| B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 10/12/2012, OBSERVADAS AS CONDICOES LEGAIS. |