EA200800708A1 - Способ получения линейных альфа-олефинов и катализатор для его осуществления - Google Patents

Способ получения линейных альфа-олефинов и катализатор для его осуществления

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Publication number
EA200800708A1
EA200800708A1 EA200800708A EA200800708A EA200800708A1 EA 200800708 A1 EA200800708 A1 EA 200800708A1 EA 200800708 A EA200800708 A EA 200800708A EA 200800708 A EA200800708 A EA 200800708A EA 200800708 A1 EA200800708 A1 EA 200800708A1
Authority
EA
Eurasian Patent Office
Prior art keywords
olefins
catalyst
hydrocarbon
implementation
formula
Prior art date
Application number
EA200800708A
Other languages
English (en)
Other versions
EA012841B1 (ru
Inventor
Вугар О. Алиев
Атих Абу-Раквабах
Мохаммад Захоод
Original Assignee
Сауди Бейсик Индастриз Корпорейшн
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Сауди Бейсик Индастриз Корпорейшн filed Critical Сауди Бейсик Индастриз Корпорейшн
Publication of EA200800708A1 publication Critical patent/EA200800708A1/ru
Publication of EA012841B1 publication Critical patent/EA012841B1/ru

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Настоящее изобретение относится к способу получения линейных низкомолекулярных альфа-олефинов с 4-24 атомами углерода, включающему олигомеризацию этилена в инертном растворителе в присутствии каталитической системы, содержащей: (i) карбоксилат циркония формулы (RCOO)ZrCl, где Rявляется насыщенным или ненасыщенным алифатическим C-Cуглеводородом или ароматическим С-Суглеводородом и m составляет 1≤m≤4; (ii) по меньшей мере одно соединение алюминия, выбранное из алюмоорганических соединений формулы RAlX, где Rявляется C-Салкилом, Х является хлором, бромом или йодом и n составляет 1≤n≤2, и/или алюмоксанов и (iii) по меньшей мере две различные добавки, выбранные из группы, состоящей из водорода, сложных эфиров, кетонов, эфиров, аминов, ангидридов, фосфинов и соединений, содержащих серу, а также к катализатору, применяемому для его осуществления.
EA200800708A 2005-08-31 2006-08-10 Способ получения линейных альфа-олефинов и катализатор для его осуществления EA012841B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP05018878A EP1759766B1 (en) 2005-08-31 2005-08-31 Process for the preparation of linear alpha-olefins and catalyst used therein
PCT/IB2006/002185 WO2007026200A1 (en) 2005-08-31 2006-08-10 Process for the preparation of linear alpha-olefins and catalyst used therein

Publications (2)

Publication Number Publication Date
EA200800708A1 true EA200800708A1 (ru) 2008-06-30
EA012841B1 EA012841B1 (ru) 2009-12-30

Family

ID=35044672

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200800708A EA012841B1 (ru) 2005-08-31 2006-08-10 Способ получения линейных альфа-олефинов и катализатор для его осуществления

Country Status (8)

Country Link
US (1) US8653316B2 (ru)
EP (1) EP1759766B1 (ru)
JP (1) JP5229898B2 (ru)
CN (1) CN101252990B (ru)
DE (1) DE602005024134D1 (ru)
EA (1) EA012841B1 (ru)
ES (1) ES2352741T3 (ru)
WO (1) WO2007026200A1 (ru)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2662219C1 (ru) * 2014-07-18 2018-07-25 Сабик Глобал Текнолоджис Б.В. Каталитическая композиция и способ получения линейных альфа-олефинов

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2070593B1 (en) 2007-12-06 2010-08-04 Saudi Basic Industries Corporation Catalyst composition and process for preparing linear alpha-olefins
MY152801A (en) * 2007-12-12 2014-11-28 Saudi Basic Ind Corp Catalyst composition for oligomerization of ethylene, oligomerization process and method for its preparation
FR2959751B1 (fr) * 2010-05-06 2012-06-08 Inst Francais Du Petrole Procede de production de base pour carburants a partir d'une charge ethylenique mettant en oeuvre au moins une etape d'oligomerisation en presence d'un systeme catalytique homogene.
CN103724146B (zh) * 2013-12-20 2016-06-15 浙江大学 一种减少乙烯齐聚反应中聚乙烯蜡含量的方法
CN109206447B (zh) * 2017-07-06 2021-07-09 中国石油化工股份有限公司 乙烯齐聚催化剂及其制备方法和应用
IN201921051272A (ru) 2019-12-11 2022-01-06
US11667590B2 (en) * 2021-05-26 2023-06-06 Chevron Phillips Chemical Company, Lp Ethylene oligomerization processes
JP2023076813A (ja) 2021-11-23 2023-06-02 インディアン オイル コーポレイション リミテッド エチレンのオリゴマー化における直鎖状α－オレフィンを高収率で製造するためのプロセス及び触媒組成物

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US4442309A (en) 1960-09-14 1984-04-10 Exxon Reserch And Engineering Co. Preparation of linear olefin products
US4486615A (en) * 1960-09-14 1984-12-04 Exxon Research & Engineering Co. Preparation of linear olefin products
US3862257A (en) * 1972-04-17 1975-01-21 Exxon Research Engineering Co Modified ziegler catalyst for alpha olefin wax synthesis
SU1042701A1 (ru) 1978-07-19 1983-09-23 Отделение ордена Ленина института химической физики АН СССР Катализатор дл олигомеризации этилена в высшие альфа-олефины
US4361714A (en) 1981-12-14 1982-11-30 Exxon Research And Engineering Co. Preparation of linear olefin products
US4409409A (en) 1982-06-10 1983-10-11 Exxon Research And Engineering Co. Two stage olefin wax process
EP0241596B1 (en) 1986-04-17 1990-10-31 Idemitsu Petrochemical Co. Ltd. A process for preparing linear alpha-olefins
US4855525A (en) 1987-06-19 1989-08-08 Exxon Chemical Patents Inc. Process for preparing linear alpha-olefins using zirconium adducts as catalysts
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FR2669921B1 (fr) * 1990-12-04 1995-07-21 Inst Francais Du Petrole Procede de conversion de l'ethylene en olefines alpha legeres.
CA2095270C (en) * 1992-05-08 2004-02-17 Kotohiro Nomura Dimerization of lower .alpha.-olefins
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JPH07330634A (ja) 1994-06-02 1995-12-19 Tosoh Corp 鎖状α−オレフィンの製法
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2662219C1 (ru) * 2014-07-18 2018-07-25 Сабик Глобал Текнолоджис Б.В. Каталитическая композиция и способ получения линейных альфа-олефинов

Also Published As

Publication number Publication date
US20090306449A1 (en) 2009-12-10
DE602005024134D1 (de) 2010-11-25
US8653316B2 (en) 2014-02-18
CN101252990B (zh) 2012-11-07
CN101252990A (zh) 2008-08-27
ES2352741T3 (es) 2011-02-22
EP1759766B1 (en) 2010-10-13
EA012841B1 (ru) 2009-12-30
JP5229898B2 (ja) 2013-07-03
EP1759766A1 (en) 2007-03-07
JP2009506103A (ja) 2009-02-12
WO2007026200A1 (en) 2007-03-08
WO2007026200B1 (en) 2007-07-12

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