BRPI0709454B8 - complexo de haleto de magnésio, processo para preparar o complexo de olefínica, catalisador para a polimerização de uma olefina e processo para polimerizar olefinas - Google Patents

complexo de haleto de magnésio, processo para preparar o complexo de olefínica, catalisador para a polimerização de uma olefina e processo para polimerizar olefinas

Info

Publication number
BRPI0709454B8
BRPI0709454B8 BRPI0709454A BRPI0709454A BRPI0709454B8 BR PI0709454 B8 BRPI0709454 B8 BR PI0709454B8 BR PI0709454 A BRPI0709454 A BR PI0709454A BR PI0709454 A BRPI0709454 A BR PI0709454A BR PI0709454 B8 BRPI0709454 B8 BR PI0709454B8
Authority
BR
Brazil
Prior art keywords
catalyst
magnesium halide
olefin
complex
polymerization
Prior art date
Application number
BRPI0709454A
Other languages
English (en)
Inventor
Ma Jing
Yin Maoping
Gao Mingzhi
Gao Ping
Peng Renqi
Qiao Suzhen
Zhang Tianyi
Wang Xinsheng
Xia Xianzhi
Chen Ying
Liu Yuexiang
Original Assignee
Beijing Res Inst Chemical Ind China Petroleum & Chemical Corp
China Petroleum & Chem Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CNB2006100671779A external-priority patent/CN100491410C/zh
Priority claimed from CN200610113864XA external-priority patent/CN101165074B/zh
Application filed by Beijing Res Inst Chemical Ind China Petroleum & Chemical Corp, China Petroleum & Chem Corp filed Critical Beijing Res Inst Chemical Ind China Petroleum & Chemical Corp
Publication of BRPI0709454A2 publication Critical patent/BRPI0709454A2/pt
Publication of BRPI0709454B1 publication Critical patent/BRPI0709454B1/pt
Publication of BRPI0709454A8 publication Critical patent/BRPI0709454A8/pt
Publication of BRPI0709454B8 publication Critical patent/BRPI0709454B8/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic System
    • C07F3/02—Magnesium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B01J31/30—Halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J25/00—Catalysts of the Raney type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

complexo de haleto de magnésio, processo para preparar o complexo de haleto de magnésio, componente catalisador útil em polimerizaçao olefinica, catalisador para apolimerizaçao de uma olefina e processo para polimerizar olefinas. a invenção provê um complexo de haleto de magnésio, lendo uma composição representada pela fórmula (1) mgx~ 2~.mrohneph~ 2~o (1) na qual x é cloreto, brometo, ou um alcoxi ou ariloxi de c~ 1~-c~ 14~; r é alquila de c~ 1~-c~ 12~, cicloalquila de c~ 3~-c~ 10~ ou arila de c~ 6~-c~ 10~; e é hidrocarboneto com di-hidrocarbiloxigeminado representado pela fórmula (ii) na qual r~ 1~ e r~ 2~, que são idênticos ou diferentes, são hidrogênio ou alquila linear ou ramificado de c~ 1~-c~ 10~,cicloalquila de c~ 3~-c~ 10~, arila de c~ 6~-c~ 10~, alquilarila ou arilalquila de c~ 7~-c~ 10~, os ditos arila, alquilarila e arilalquila sendo opcionalmente substituidos por um ou mais átomos de halogênio no anel aromático; opcionalmente r~ 1~ e r~ 2~ ligam-se um ao outro para formar um anel ou sistema de anel fundido; r~ 3~ e r~ 4~ têm os mesmos significados definidos para r~ 1~ e r~ 2~ outros que não hidrogênio; m está na faixa de 1 a 5; n está na faixa de 0,005 a 1,0; e p está na faixa de o a 0,8. a invenção refere-se ainda a um componente catalisador esférico e a um catalisador preparado com o complexo de haleto de magnésio esférico, e ao uso do catalisador na polimerização de cx-olefinas ch~ 2~=chr ou uma mistura das mesmas, na qual r é h, ou alquila ou arila tendo de 1 a 12 átomos de carbono.
BRPI0709454A 2006-04-06 2007-04-06 complexo de haleto de magnésio, processo para preparar o complexo de olefínica, catalisador para a polimerização de uma olefina e processo para polimerizar olefinas BRPI0709454B8 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CN200610067177.9 2006-04-06
CNB2006100671779A CN100491410C (zh) 2006-04-06 2006-04-06 一种卤化镁加合物及其制备方法和应用
CN200610113864XA CN101165074B (zh) 2006-10-20 2006-10-20 用于烯烃聚合的催化剂组分及其催化剂
CN200610113864.X 2006-10-20
PCT/CN2007/001123 WO2007112700A1 (en) 2006-04-06 2007-04-06 Magnesium halide adduct, olefins polymerization catalyst component and catalyst made therefrom

Publications (4)

Publication Number Publication Date
BRPI0709454A2 BRPI0709454A2 (pt) 2011-07-12
BRPI0709454B1 BRPI0709454B1 (pt) 2017-11-07
BRPI0709454A8 BRPI0709454A8 (pt) 2018-01-30
BRPI0709454B8 true BRPI0709454B8 (pt) 2018-02-27

Family

ID=38563120

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0709454A BRPI0709454B8 (pt) 2006-04-06 2007-04-06 complexo de haleto de magnésio, processo para preparar o complexo de olefínica, catalisador para a polimerização de uma olefina e processo para polimerizar olefinas

Country Status (7)

Country Link
US (1) US20100099833A1 (pt)
EP (1) EP2036928B1 (pt)
KR (1) KR101173267B1 (pt)
BR (1) BRPI0709454B8 (pt)
MY (1) MY151043A (pt)
SG (1) SG189559A1 (pt)
WO (1) WO2007112700A1 (pt)

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ES2478017T3 (es) 2009-07-15 2014-07-18 China Petroleum&Chemical Corporation Aducto de haluro de magnesio esférico, componente de catalizador y catalizador para la polimerización de olefinas preparado a partir del mismo
CN102796127B (zh) * 2011-05-27 2015-02-11 中国石油化工股份有限公司 一种球形卤化镁加合物及其制备方法和应用
CN103788249B (zh) * 2012-10-29 2016-01-13 中国石油化工股份有限公司 一种烯烃聚合催化剂载体及其应用
CN103788246B (zh) * 2012-10-29 2015-10-21 中国石油化工股份有限公司 一种烯烃聚合催化剂载体及其制备方法和应用
CN103788244B (zh) * 2012-10-29 2016-03-30 中国石油化工股份有限公司 一种烯烃聚合催化剂载体及其应用
WO2021050272A1 (en) 2019-09-11 2021-03-18 Brink's Network Inc. Self-service modular drop safes
EP4190822A1 (en) * 2021-12-06 2023-06-07 Clariant International Ltd Process for the preparation of a spherical support for ziegler-natta catalyst
KR20230138188A (ko) 2022-03-23 2023-10-05 숭실대학교산학협력단 차량통과 높이판별 장치 및 그 제어방법

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Also Published As

Publication number Publication date
KR101173267B1 (ko) 2012-08-10
SG189559A1 (en) 2013-05-31
EP2036928B1 (en) 2015-12-23
BRPI0709454A2 (pt) 2011-07-12
WO2007112700A1 (en) 2007-10-11
US20100099833A1 (en) 2010-04-22
BRPI0709454A8 (pt) 2018-01-30
MY151043A (en) 2014-03-31
BRPI0709454B1 (pt) 2017-11-07
EP2036928A4 (en) 2014-10-08
EP2036928A1 (en) 2009-03-18
KR20080112360A (ko) 2008-12-24

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B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 07/11/2017, OBSERVADAS AS CONDICOES LEGAIS.

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