DK3155074T3 - Fremgangsmåde til hydrogenbehandling af dieselfraktioner under anvendelse af en katalysator baseret på amorft, mesoporøst aluminiumoxid med høj konnektivitet - Google Patents

Fremgangsmåde til hydrogenbehandling af dieselfraktioner under anvendelse af en katalysator baseret på amorft, mesoporøst aluminiumoxid med høj konnektivitet Download PDF

Info

Publication number
DK3155074T3
DK3155074T3 DK15730989.9T DK15730989T DK3155074T3 DK 3155074 T3 DK3155074 T3 DK 3155074T3 DK 15730989 T DK15730989 T DK 15730989T DK 3155074 T3 DK3155074 T3 DK 3155074T3
Authority
DK
Denmark
Prior art keywords
catalyst
volume
alumina
acid
pores
Prior art date
Application number
DK15730989.9T
Other languages
English (en)
Inventor
Malika Boualleg
Elodie Devers
Bertrand Guichard
Original Assignee
Ifp Energies Now
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ifp Energies Now filed Critical Ifp Energies Now
Application granted granted Critical
Publication of DK3155074T3 publication Critical patent/DK3155074T3/da

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
    • C01F7/14—Aluminium oxide or hydroxide from alkali metal aluminates
    • C01F7/141—Aluminium oxide or hydroxide from alkali metal aluminates from aqueous aluminate solutions by neutralisation with an acidic agent
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/653—500-1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/657—Pore diameter larger than 1000 nm
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1059—Gasoil having a boiling range of about 330 - 427 °C

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Nanotechnology (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Claims (14)

1. Fremgangsmåde til hydrogenbehandling af mindst en dieselfraktion fra mindst en dieselfraktion med en vægtet middeltemperatur på mellem 240 °C og 350 °C, foregående ved en temperatur på mellem 250 °C og 400 °C, ved et totalt tryk på mellem 2 MPa og 10 MPa, med et volumenforhold hydrogen pr. volumen carbonhydridføde på mellem 100 og 800 liter pr. liter og ved en rumhastighed, defineret som forholdet mellem volumenstrømmen af flydende carbonhydridføde og volumenet af katalysator påfyldt i reaktoren, på mellem 1 og 10 h_1, hvilken fremgangsmåde anvender mindst en katalysator, som omfatter mindst et metal fra gruppe VIB og/eller mindst et metal fra gruppe VIII i det periodiske system og en bærer, der omfatter et amorft, mesoporøst aluminiumoxid, hvilken fremgangsmåde omfatter mindst følgende trin til fremstilling af aluminiumoxidet: a) mindst et første trin a) til udfældning af aluminiumoxidet i et vandigt reaktionsmedie ud fra mindst en basisk precursor valgt blandt natriumaluminat, kaliumaluminat, ammoniak, natriumhydroxid og kaliumhydroxid, og mindst en sur precursor valgt blandt aluminiumsulfat, aluminiumchlorid, aluminiumnitrat, svovlsyre, saltsyre og salpetersyre, hvor mindst en af de basiske eller sure precursorer omfatter aluminium, idet den relative strømningshastighed af de sure og basiske precursorer er således valgt, at der opnås et pH af reaktionsmediet på mellem 8,5 og 10,5, og idet strømningshastigheden af den eller de sure og basiske precursorer indeholdende aluminium er således indstillet, at der opnås en reaktionsgrad i det første trin på mellem 40 og 100%, hvor reaktionsgraden er defineret som forholdet mellem dannet aluminiumoxid som Al2C>3-ækvivalenter i udfældningstrinnet a) og den totale mængde aluminiumoxid, der er dannet i udgangen af udfældningstrinnet eller udfældningstrinnene, hvor trinnet a) foregår ved en temperatur på mellem 10 og 50 °C og i et tidsrum på mellem 2 minutter og 30 minutter, b) et trin til varmebehandling af suspensionen, der er opnået i udgangen af trin a) , ved en temperatur på mellem 50 og 200 °C i et tidsrum på mellem 30 minutter og 5 timer, hvorved der opnås en aluminiumoxidgel, c) et trin til filtrering af suspensionen, der er opnået i udgangen af varmebehandlingstrinnet b) , efterfulgt af mindst et trin til vask af den opnåede gel, d) et trin til tørring af aluminiumoxidgelen, der er opnået i udgangen af trin c), for at opnå et pulver, e) et trin til formgivning af pulveret, der er opnået i udgangen af trin d), for at opnå et råmateriale, f) et trin til varmebehandling af råmaterialet, der er opnået i udgangen af trin e) , ved en temperatur på mellem 500 og 1000 °C i nærvær eller ej af en luftstrøm indeholdende op til 60 volumen-% vand.
2. Fremgangsmåde ifølge krav 1, hvor den anvendte dieselfraktion er valgt blandt dieselfraktionerne, der stammer fra direkte destillation alene eller i blanding med mindst en fraktion, der stammer fra en forkoksningsenhed, eller mindst en fraktion, der stammer fra katalytisk krakning, eller mindst en dieselfraktion, der hidrører fra andre omdannelsesfremgangsmåder, såsom mild hydrokrakning eller hydrogenbehandling af restprodukter.
3. Fremgangsmåde ifølge et af kravene 1 eller 2, hvor grundstofferne fra gruppe VIII er valgt blandt cobalt og nikkel taget alene eller i blanding.
4. Fremgangsmåde ifølge et af kravene 1 til 3, hvor grundstofferne fra gruppe VIB er valgt blandt wolfram og molybden taget alene eller i blanding.
5. Fremgangsmåde ifølge et af kravene 1 til 4, hvor koncentrationen af metal fra gruppe VIB ligger på mellem 10 og 35 vægt-% oxid i forhold til den totale masse af katalysatoren, og koncentrationen af ikke-ædelmetal fra gruppe VIII ligger på mellem 1 og 10 vægt-% oxid i forhold til den totale masse af katalysatoren, i det tilfælde hvor katalysatoren omfatter mindst et metal fra gruppe VIB i kombination med mindst et ikke-ædelmetal fra gruppe VIII.
6. Fremgangsmåde ifølge et af kravene 1 til 5, hvor katalysatoren indeholder mindst et doteringsgrundstof valgt blandt phosphor, bor, fluor og silicium, alene eller i blanding.
7. Fremgangsmåde ifølge krav 6, hvor koncentrationen af phosphor i katalysatoren ligger på mellem 0,5 og 15 vægt-% P2O5 ·
8. Fremgangsmåde ifølge et af kravene 1 til 7, hvor katalysatorens bærer omfatter et amorft, mesoporøst aluminiumoxid, som har en konnektivitet (Z) på mellem 3 og 7.
9. Fremgangsmåde ifølge et af kravene 1 til 8, hvor katalysatoren udviser en konnektivitet (Z) på mellem 3 og 7.
10. Fremgangsmåde ifølge et af kravene 1 til 9, hvor katalysatorens bærer udviser følgende porefordeling, målt ved kviksølvporosimetri: - procentdelen af volumenet, der er indeholdt i porer med en størrelse på mellem 2 og 6 nm, i forhold til det samlede porevolumen, ligger på mellem 1 og 25 %, - procentdelen af volumenet, der er indeholdt i porer med en størrelse på over 6 nm og under 15 nm, svarer til mellem 60 og 95 % af det samlede porevolumen, - procentdelen af volumenet, der er indeholdt i porer med en størrelse på mellem 15 og 50 nm, repræsenterer 0 til 8 % af det samlede porevolumen, og - procentdelen af volumenet, der er indeholdt i porer med en størrelse på mellem 50 og 7000 nm, svarende til det makroporøse volumen, repræsenterer 0 til 5 %.
11. Fremgangsmåde ifølge et af kravene 1 til 10, hvor bæreren udviser en middeldiameter af mesoporerne, målt ved kviksølvporosimetri og bestemt på volumenbasis, på mellem 7 og 12,5 nm.
12. Fremgangsmåde ifølge et af kravene 1 til 11, hvor bæreren udviser et volumen af mesoporerne, målt ved kviksølvporosimetri, på mellem 0,5 og 0,8 ml/g.
13. Fremgangsmåde ifølge et af kravene 1 til 12, hvor katalysatorens udviser følgende porefordeling, bestemt ved kviksølvporosimetri: - procentdelen af volumenet, der er indeholdt i porer med en størrelse på mellem 2 og 6 nm, i forhold til det samlede porevolumen, ligger på mellem 1 og 25 %, - procentdelen af volumenet, der er indeholdt i porer med en størrelse på over 6 nm og under 15 nm, svarer til mellem 60 og 95 % af det samlede porevolumen, - procentdelen af volumenet, der er indeholdt i porer med en størrelse på mellem 15 og 50 nm, repræsenterer 0 til 15 % af det samlede porevolumen, og - procentdelen af volumenet, der er indeholdt i porer med en størrelse på mellem 50 og 7000 nm, svarende til det makroporøse volumen, repræsenterer 0 til 5 % af det samlede porevolumen.
14. Fremgangsmåde ifølge et af kravene 1 til 13, hvor katalysatoren udviser et samlet porevolumen, målt ved kviksølvporosimetri, der er større end eller lig med 0,35 ml/g.
DK15730989.9T 2014-06-13 2015-06-09 Fremgangsmåde til hydrogenbehandling af dieselfraktioner under anvendelse af en katalysator baseret på amorft, mesoporøst aluminiumoxid med høj konnektivitet DK3155074T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1455424A FR3022254B1 (fr) 2014-06-13 2014-06-13 Procede d'hydrotraitement de coupes gazoles utilisant un catalyseur a base d'une alumine mesoporeuse amorphe ayant une connectivite elevee
PCT/EP2015/062827 WO2015189201A1 (fr) 2014-06-13 2015-06-09 Procede d'hydrotraitement de coupes gazoles utilisant un catalyseur a base d'une alumine mesoporeuse amorphe ayant une connectivite elevee

Publications (1)

Publication Number Publication Date
DK3155074T3 true DK3155074T3 (da) 2018-07-30

Family

ID=51610245

Family Applications (1)

Application Number Title Priority Date Filing Date
DK15730989.9T DK3155074T3 (da) 2014-06-13 2015-06-09 Fremgangsmåde til hydrogenbehandling af dieselfraktioner under anvendelse af en katalysator baseret på amorft, mesoporøst aluminiumoxid med høj konnektivitet

Country Status (11)

Country Link
US (1) US10626337B2 (da)
EP (1) EP3155074B1 (da)
JP (1) JP6703956B2 (da)
CN (1) CN107155314A (da)
BR (1) BR112016028971A2 (da)
DK (1) DK3155074T3 (da)
ES (1) ES2677523T3 (da)
FR (1) FR3022254B1 (da)
RU (1) RU2689116C2 (da)
SA (1) SA516380456B1 (da)
WO (1) WO2015189201A1 (da)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106092812B (zh) * 2016-07-25 2018-11-09 西南石油大学 一种高精度电子多活度等温吸附实验装置
FR3068984B1 (fr) 2017-07-13 2020-01-17 IFP Energies Nouvelles Procede d'hydrogenation des aromatiques mettant en œuvre un catalyseur obtenu par impregnation comprenant un support specifique.
CN109529899A (zh) * 2018-12-04 2019-03-29 宁波中科远东催化工程技术有限公司 重油加氢复合催化剂及其制备方法和使用方法
WO2020135714A1 (zh) 2018-12-28 2020-07-02 中国石油化工股份有限公司 一种拟薄水铝石、其制造方法及其应用
RU2741303C1 (ru) * 2019-12-27 2021-01-25 федеральное государственное бюджетное образовательное учреждение высшего образования "Самарский государственный технический университет" Катализатор глубокой гидроочистки нефтяных фракций и способ его приготовления
FR3143592A1 (fr) * 2022-12-20 2024-06-21 IFP Energies Nouvelles Procede de preparation d’alumine mesoporeuse par coagulation chimique

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2914461A (en) * 1954-11-09 1959-11-24 Socony Mobil Oil Co Inc Hydrocracking of a high boiling hydrocarbon oil with a platinum catalyst containing alumina and an aluminum halide
CN1048651C (zh) * 1994-06-29 2000-01-26 中国石油化工总公司抚顺石油化工研究院 一种加氢催化剂载体的制备方法
CN1147360C (zh) * 1999-01-15 2004-04-28 阿克佐诺贝尔公司 新型混合金属催化剂、利用共沉淀的其制备及其用途
US6589908B1 (en) * 2000-11-28 2003-07-08 Shell Oil Company Method of making alumina having bimodal pore structure, and catalysts made therefrom
EP1663490A1 (en) * 2003-09-17 2006-06-07 Shell Internationale Researchmaatschappij B.V. Process and catalyst for the hydroconversion of a heavy hydrocarbon feedstock
US7294882B2 (en) 2004-09-28 2007-11-13 Sandisk Corporation Non-volatile memory with asymmetrical doping profile
CN101433842B (zh) * 2008-09-27 2011-04-20 中国石油天然气股份有限公司 一种加氢催化剂及制备方法
US9187702B2 (en) * 2009-07-01 2015-11-17 Chevron U.S.A. Inc. Hydroprocessing catalyst and method of making the same
JP5797766B2 (ja) * 2010-11-11 2015-10-21 シェブロン ユー．エス．エー． インコーポレイテッド 水素化変換多金属触媒及びその作製方法
FR2972648B1 (fr) * 2011-03-18 2013-04-26 Ifp Energies Now Catalyseur utilisable en hydrotraitement comprenant des metaux des groupes viii et vib et preparation avec de l'acide citrique et du succinate de dialkyle c1-c4
WO2013095856A1 (en) * 2011-12-22 2013-06-27 Advanced Refining Technologies Llc Silica containing alumina supports, catalysts made therefrom and processes using the same

Also Published As

Publication number Publication date
WO2015189201A1 (fr) 2015-12-17
ES2677523T3 (es) 2018-08-03
BR112016028971A2 (pt) 2017-08-22
FR3022254B1 (fr) 2016-07-29
EP3155074B1 (fr) 2018-04-18
EP3155074A1 (fr) 2017-04-19
US10626337B2 (en) 2020-04-21
CN107155314A (zh) 2017-09-12
US20170137724A1 (en) 2017-05-18
RU2017100965A3 (da) 2018-12-11
JP2017524758A (ja) 2017-08-31
SA516380456B1 (ar) 2021-04-26
RU2017100965A (ru) 2018-07-17
RU2689116C2 (ru) 2019-05-24
FR3022254A1 (fr) 2015-12-18
JP6703956B2 (ja) 2020-06-03

Similar Documents

Publication Publication Date Title
DK3155074T3 (da) Fremgangsmåde til hydrogenbehandling af dieselfraktioner under anvendelse af en katalysator baseret på amorft, mesoporøst aluminiumoxid med høj konnektivitet
US10130942B2 (en) Mesoporous catalyst for hydroconversion of residues and method for preparing the latter
CN106660017B (zh) 用于加氢转化渣油的中孔和大孔催化剂及制备方法
CN106660019B (zh) 通过共研获得的具有活性相的介孔与大孔催化剂、其制备方法及其用于渣油的加氢处理的用途
CN106922134B (zh) 具有双峰孔隙度的催化剂，通过共拌和活性相来制备它的方法及其用于烃残余物的加氢的用途
JP5022903B2 (ja) アルミノシリケートドープ触媒および炭化水素供給材料処理の改良法
JP4055088B2 (ja) ホウ素およびケイ素を含む触媒および炭化水素仕込原料の水素化処理におけるその使用
JP5560269B2 (ja) 制御されたメソ多孔度を有するアルミナの調製方法
US10392570B2 (en) Method for the hydrotreatment of distillate cuts using a catalyst made from an amorphous mesoporous alumina having high connectivity
JP2011508667A (ja) 少なくとも１種の特定のゼオライトと少なくとも１つのシリカ−アルミナとを含む触媒、および前記触媒を用いた炭化水素供給原料の水素化分解方法
US10723960B2 (en) Method for hydrocracking hydrocarbon feedstocks using a catalyst comprising a zeolite and an amorphous mesoporous alumina
JP5331280B2 (ja) 調整された酸度を有する触媒を用いる炭化水素転換方法
JP2013209595A (ja) 潤滑油用基油の製造方法