DK3155074T3 - Fremgangsmåde til hydrogenbehandling af dieselfraktioner under anvendelse af en katalysator baseret på amorft, mesoporøst aluminiumoxid med høj konnektivitet - Google Patents
Fremgangsmåde til hydrogenbehandling af dieselfraktioner under anvendelse af en katalysator baseret på amorft, mesoporøst aluminiumoxid med høj konnektivitet Download PDFInfo
- Publication number
- DK3155074T3 DK3155074T3 DK15730989.9T DK15730989T DK3155074T3 DK 3155074 T3 DK3155074 T3 DK 3155074T3 DK 15730989 T DK15730989 T DK 15730989T DK 3155074 T3 DK3155074 T3 DK 3155074T3
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- Denmark
- Prior art keywords
- catalyst
- volume
- alumina
- acid
- pores
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- 239000003054 catalyst Substances 0.000 title claims abstract description 150
- 238000000034 method Methods 0.000 title claims abstract description 96
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 11
- 239000001257 hydrogen Substances 0.000 title claims abstract description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 10
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 title 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 190
- 229910052751 metal Inorganic materials 0.000 claims abstract description 39
- 239000002184 metal Substances 0.000 claims abstract description 39
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 16
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 16
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 16
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 8
- 230000000737 periodic effect Effects 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 4
- 238000001556 precipitation Methods 0.000 claims description 97
- 239000002243 precursor Substances 0.000 claims description 79
- 239000002253 acid Substances 0.000 claims description 64
- 230000008569 process Effects 0.000 claims description 60
- 239000000725 suspension Substances 0.000 claims description 49
- 239000011148 porous material Substances 0.000 claims description 43
- 229910052782 aluminium Inorganic materials 0.000 claims description 40
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 40
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 27
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 23
- 229910052753 mercury Inorganic materials 0.000 claims description 23
- 238000009826 distribution Methods 0.000 claims description 17
- 238000001035 drying Methods 0.000 claims description 16
- 238000002459 porosimetry Methods 0.000 claims description 16
- 239000000843 powder Substances 0.000 claims description 16
- 238000001914 filtration Methods 0.000 claims description 15
- 239000012429 reaction media Substances 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 12
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 10
- 229910052698 phosphorus Inorganic materials 0.000 claims description 10
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 9
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 9
- 229910052750 molybdenum Inorganic materials 0.000 claims description 9
- 229910017604 nitric acid Inorganic materials 0.000 claims description 9
- 239000011574 phosphorus Substances 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 8
- 239000011733 molybdenum Substances 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 7
- 239000012431 aqueous reaction media Substances 0.000 claims description 7
- 229910052796 boron Inorganic materials 0.000 claims description 7
- 229910017052 cobalt Inorganic materials 0.000 claims description 7
- 239000010941 cobalt Substances 0.000 claims description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 7
- 229910021529 ammonia Inorganic materials 0.000 claims description 6
- 238000004821 distillation Methods 0.000 claims description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 229910052721 tungsten Inorganic materials 0.000 claims description 5
- 239000010937 tungsten Substances 0.000 claims description 5
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 4
- 229910052731 fluorine Inorganic materials 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 3
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 3
- 239000002019 doping agent Substances 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000004523 catalytic cracking Methods 0.000 claims description 2
- 238000004939 coking Methods 0.000 claims description 2
- 239000010970 precious metal Substances 0.000 claims 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims 1
- WPUINVXKIPAAHK-UHFFFAOYSA-N aluminum;potassium;oxygen(2-) Chemical compound [O-2].[O-2].[Al+3].[K+] WPUINVXKIPAAHK-UHFFFAOYSA-N 0.000 claims 1
- 229910021472 group 8 element Inorganic materials 0.000 claims 1
- 239000000499 gel Substances 0.000 description 60
- 239000004411 aluminium Substances 0.000 description 37
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 36
- 239000003921 oil Substances 0.000 description 36
- 239000007789 gas Substances 0.000 description 35
- 238000002360 preparation method Methods 0.000 description 31
- 238000012545 processing Methods 0.000 description 30
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 26
- 239000001164 aluminium sulphate Substances 0.000 description 26
- 235000011128 aluminium sulphate Nutrition 0.000 description 26
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 26
- 239000000243 solution Substances 0.000 description 22
- 230000000694 effects Effects 0.000 description 21
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 19
- 239000005864 Sulphur Substances 0.000 description 19
- 229910052757 nitrogen Inorganic materials 0.000 description 18
- 230000003197 catalytic effect Effects 0.000 description 14
- 238000005470 impregnation Methods 0.000 description 13
- 239000002585 base Substances 0.000 description 11
- JLDSOYXADOWAKB-UHFFFAOYSA-N aluminium nitrate Chemical compound [Al+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O JLDSOYXADOWAKB-UHFFFAOYSA-N 0.000 description 10
- 238000002156 mixing Methods 0.000 description 10
- 238000007493 shaping process Methods 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 9
- IFTRQJLVEBNKJK-UHFFFAOYSA-N Ethylcyclopentane Chemical compound CCC1CCCC1 IFTRQJLVEBNKJK-UHFFFAOYSA-N 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 8
- 238000000889 atomisation Methods 0.000 description 8
- 230000008901 benefit Effects 0.000 description 8
- 238000005984 hydrogenation reaction Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 7
- 229910001593 boehmite Inorganic materials 0.000 description 6
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 6
- 238000006386 neutralization reaction Methods 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
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- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 description 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 5
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- 238000001354 calcination Methods 0.000 description 5
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- KVOIJEARBNBHHP-UHFFFAOYSA-N potassium;oxido(oxo)alumane Chemical compound [K+].[O-][Al]=O KVOIJEARBNBHHP-UHFFFAOYSA-N 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
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- 239000000126 substance Substances 0.000 description 4
- 238000004876 x-ray fluorescence Methods 0.000 description 4
- 239000012687 aluminium precursor Substances 0.000 description 3
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- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 3
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- DHRLEVQXOMLTIM-UHFFFAOYSA-N phosphoric acid;trioxomolybdenum Chemical compound O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.OP(O)(O)=O DHRLEVQXOMLTIM-UHFFFAOYSA-N 0.000 description 1
- IYDGMDWEHDFVQI-UHFFFAOYSA-N phosphoric acid;trioxotungsten Chemical compound O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.OP(O)(O)=O IYDGMDWEHDFVQI-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- CGFYHILWFSGVJS-UHFFFAOYSA-N silicic acid;trioxotungsten Chemical compound O[Si](O)(O)O.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 CGFYHILWFSGVJS-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 150000003568 thioethers Chemical group 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
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- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Claims (14)
1. Fremgangsmåde til hydrogenbehandling af mindst en dieselfraktion fra mindst en dieselfraktion med en vægtet middeltemperatur på mellem 240 °C og 350 °C, foregående ved en temperatur på mellem 250 °C og 400 °C, ved et totalt tryk på mellem 2 MPa og 10 MPa, med et volumenforhold hydrogen pr. volumen carbonhydridføde på mellem 100 og 800 liter pr. liter og ved en rumhastighed, defineret som forholdet mellem volumenstrømmen af flydende carbonhydridføde og volumenet af katalysator påfyldt i reaktoren, på mellem 1 og 10 h_1, hvilken fremgangsmåde anvender mindst en katalysator, som omfatter mindst et metal fra gruppe VIB og/eller mindst et metal fra gruppe VIII i det periodiske system og en bærer, der omfatter et amorft, mesoporøst aluminiumoxid, hvilken fremgangsmåde omfatter mindst følgende trin til fremstilling af aluminiumoxidet: a) mindst et første trin a) til udfældning af aluminiumoxidet i et vandigt reaktionsmedie ud fra mindst en basisk precursor valgt blandt natriumaluminat, kaliumaluminat, ammoniak, natriumhydroxid og kaliumhydroxid, og mindst en sur precursor valgt blandt aluminiumsulfat, aluminiumchlorid, aluminiumnitrat, svovlsyre, saltsyre og salpetersyre, hvor mindst en af de basiske eller sure precursorer omfatter aluminium, idet den relative strømningshastighed af de sure og basiske precursorer er således valgt, at der opnås et pH af reaktionsmediet på mellem 8,5 og 10,5, og idet strømningshastigheden af den eller de sure og basiske precursorer indeholdende aluminium er således indstillet, at der opnås en reaktionsgrad i det første trin på mellem 40 og 100%, hvor reaktionsgraden er defineret som forholdet mellem dannet aluminiumoxid som Al2C>3-ækvivalenter i udfældningstrinnet a) og den totale mængde aluminiumoxid, der er dannet i udgangen af udfældningstrinnet eller udfældningstrinnene, hvor trinnet a) foregår ved en temperatur på mellem 10 og 50 °C og i et tidsrum på mellem 2 minutter og 30 minutter, b) et trin til varmebehandling af suspensionen, der er opnået i udgangen af trin a) , ved en temperatur på mellem 50 og 200 °C i et tidsrum på mellem 30 minutter og 5 timer, hvorved der opnås en aluminiumoxidgel, c) et trin til filtrering af suspensionen, der er opnået i udgangen af varmebehandlingstrinnet b) , efterfulgt af mindst et trin til vask af den opnåede gel, d) et trin til tørring af aluminiumoxidgelen, der er opnået i udgangen af trin c), for at opnå et pulver, e) et trin til formgivning af pulveret, der er opnået i udgangen af trin d), for at opnå et råmateriale, f) et trin til varmebehandling af råmaterialet, der er opnået i udgangen af trin e) , ved en temperatur på mellem 500 og 1000 °C i nærvær eller ej af en luftstrøm indeholdende op til 60 volumen-% vand.
2. Fremgangsmåde ifølge krav 1, hvor den anvendte dieselfraktion er valgt blandt dieselfraktionerne, der stammer fra direkte destillation alene eller i blanding med mindst en fraktion, der stammer fra en forkoksningsenhed, eller mindst en fraktion, der stammer fra katalytisk krakning, eller mindst en dieselfraktion, der hidrører fra andre omdannelsesfremgangsmåder, såsom mild hydrokrakning eller hydrogenbehandling af restprodukter.
3. Fremgangsmåde ifølge et af kravene 1 eller 2, hvor grundstofferne fra gruppe VIII er valgt blandt cobalt og nikkel taget alene eller i blanding.
4. Fremgangsmåde ifølge et af kravene 1 til 3, hvor grundstofferne fra gruppe VIB er valgt blandt wolfram og molybden taget alene eller i blanding.
5. Fremgangsmåde ifølge et af kravene 1 til 4, hvor koncentrationen af metal fra gruppe VIB ligger på mellem 10 og 35 vægt-% oxid i forhold til den totale masse af katalysatoren, og koncentrationen af ikke-ædelmetal fra gruppe VIII ligger på mellem 1 og 10 vægt-% oxid i forhold til den totale masse af katalysatoren, i det tilfælde hvor katalysatoren omfatter mindst et metal fra gruppe VIB i kombination med mindst et ikke-ædelmetal fra gruppe VIII.
6. Fremgangsmåde ifølge et af kravene 1 til 5, hvor katalysatoren indeholder mindst et doteringsgrundstof valgt blandt phosphor, bor, fluor og silicium, alene eller i blanding.
7. Fremgangsmåde ifølge krav 6, hvor koncentrationen af phosphor i katalysatoren ligger på mellem 0,5 og 15 vægt-% P2O5 ·
8. Fremgangsmåde ifølge et af kravene 1 til 7, hvor katalysatorens bærer omfatter et amorft, mesoporøst aluminiumoxid, som har en konnektivitet (Z) på mellem 3 og 7.
9. Fremgangsmåde ifølge et af kravene 1 til 8, hvor katalysatoren udviser en konnektivitet (Z) på mellem 3 og 7.
10. Fremgangsmåde ifølge et af kravene 1 til 9, hvor katalysatorens bærer udviser følgende porefordeling, målt ved kviksølvporosimetri: - procentdelen af volumenet, der er indeholdt i porer med en størrelse på mellem 2 og 6 nm, i forhold til det samlede porevolumen, ligger på mellem 1 og 25 %, - procentdelen af volumenet, der er indeholdt i porer med en størrelse på over 6 nm og under 15 nm, svarer til mellem 60 og 95 % af det samlede porevolumen, - procentdelen af volumenet, der er indeholdt i porer med en størrelse på mellem 15 og 50 nm, repræsenterer 0 til 8 % af det samlede porevolumen, og - procentdelen af volumenet, der er indeholdt i porer med en størrelse på mellem 50 og 7000 nm, svarende til det makroporøse volumen, repræsenterer 0 til 5 %.
11. Fremgangsmåde ifølge et af kravene 1 til 10, hvor bæreren udviser en middeldiameter af mesoporerne, målt ved kviksølvporosimetri og bestemt på volumenbasis, på mellem 7 og 12,5 nm.
12. Fremgangsmåde ifølge et af kravene 1 til 11, hvor bæreren udviser et volumen af mesoporerne, målt ved kviksølvporosimetri, på mellem 0,5 og 0,8 ml/g.
13. Fremgangsmåde ifølge et af kravene 1 til 12, hvor katalysatorens udviser følgende porefordeling, bestemt ved kviksølvporosimetri: - procentdelen af volumenet, der er indeholdt i porer med en størrelse på mellem 2 og 6 nm, i forhold til det samlede porevolumen, ligger på mellem 1 og 25 %, - procentdelen af volumenet, der er indeholdt i porer med en størrelse på over 6 nm og under 15 nm, svarer til mellem 60 og 95 % af det samlede porevolumen, - procentdelen af volumenet, der er indeholdt i porer med en størrelse på mellem 15 og 50 nm, repræsenterer 0 til 15 % af det samlede porevolumen, og - procentdelen af volumenet, der er indeholdt i porer med en størrelse på mellem 50 og 7000 nm, svarende til det makroporøse volumen, repræsenterer 0 til 5 % af det samlede porevolumen.
14. Fremgangsmåde ifølge et af kravene 1 til 13, hvor katalysatoren udviser et samlet porevolumen, målt ved kviksølvporosimetri, der er større end eller lig med 0,35 ml/g.
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FR1455424A FR3022254B1 (fr) | 2014-06-13 | 2014-06-13 | Procede d'hydrotraitement de coupes gazoles utilisant un catalyseur a base d'une alumine mesoporeuse amorphe ayant une connectivite elevee |
PCT/EP2015/062827 WO2015189201A1 (fr) | 2014-06-13 | 2015-06-09 | Procede d'hydrotraitement de coupes gazoles utilisant un catalyseur a base d'une alumine mesoporeuse amorphe ayant une connectivite elevee |
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CN106092812B (zh) * | 2016-07-25 | 2018-11-09 | 西南石油大学 | 一种高精度电子多活度等温吸附实验装置 |
FR3068984B1 (fr) * | 2017-07-13 | 2020-01-17 | IFP Energies Nouvelles | Procede d'hydrogenation des aromatiques mettant en œuvre un catalyseur obtenu par impregnation comprenant un support specifique. |
CN109529899A (zh) * | 2018-12-04 | 2019-03-29 | 宁波中科远东催化工程技术有限公司 | 重油加氢复合催化剂及其制备方法和使用方法 |
KR20210106568A (ko) | 2018-12-28 | 2021-08-30 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 슈도-베마이트, 및 이의 제조방법 및 용도 |
RU2741303C1 (ru) * | 2019-12-27 | 2021-01-25 | федеральное государственное бюджетное образовательное учреждение высшего образования "Самарский государственный технический университет" | Катализатор глубокой гидроочистки нефтяных фракций и способ его приготовления |
FR3143592A1 (fr) * | 2022-12-20 | 2024-06-21 | IFP Energies Nouvelles | Procede de preparation d’alumine mesoporeuse par coagulation chimique |
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US2914461A (en) * | 1954-11-09 | 1959-11-24 | Socony Mobil Oil Co Inc | Hydrocracking of a high boiling hydrocarbon oil with a platinum catalyst containing alumina and an aluminum halide |
CN1048651C (zh) * | 1994-06-29 | 2000-01-26 | 中国石油化工总公司抚顺石油化工研究院 | 一种加氢催化剂载体的制备方法 |
PL212430B1 (pl) * | 1999-01-15 | 2012-09-28 | Albemarle Netherlands Bv | Sposób wytwarzania kompozycji katalizatora zawierajacej czastki siarczkowego katalizatora w masie, kompozycja katalizatora i jej zastosowanie |
US6589908B1 (en) * | 2000-11-28 | 2003-07-08 | Shell Oil Company | Method of making alumina having bimodal pore structure, and catalysts made therefrom |
WO2005028106A1 (en) * | 2003-09-17 | 2005-03-31 | Shell Internationale Research Maatschappij B.V. | Process and catalyst for the hydroconversion of a heavy hydrocarbon feedstock |
US7294882B2 (en) | 2004-09-28 | 2007-11-13 | Sandisk Corporation | Non-volatile memory with asymmetrical doping profile |
CN101433842B (zh) * | 2008-09-27 | 2011-04-20 | 中国石油天然气股份有限公司 | 一种加氢催化剂及制备方法 |
US9187702B2 (en) * | 2009-07-01 | 2015-11-17 | Chevron U.S.A. Inc. | Hydroprocessing catalyst and method of making the same |
JP5797766B2 (ja) * | 2010-11-11 | 2015-10-21 | シェブロン ユー.エス.エー. インコーポレイテッド | 水素化変換多金属触媒及びその作製方法 |
FR2972648B1 (fr) * | 2011-03-18 | 2013-04-26 | Ifp Energies Now | Catalyseur utilisable en hydrotraitement comprenant des metaux des groupes viii et vib et preparation avec de l'acide citrique et du succinate de dialkyle c1-c4 |
EP2794088B1 (en) * | 2011-12-22 | 2021-03-31 | Advanced Refining Technologies, LLC | Silica containing alumina supports and methods of preparation thereof |
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FR3022254B1 (fr) | 2016-07-29 |
US10626337B2 (en) | 2020-04-21 |
JP6703956B2 (ja) | 2020-06-03 |
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RU2017100965A (ru) | 2018-07-17 |
JP2017524758A (ja) | 2017-08-31 |
CN107155314A (zh) | 2017-09-12 |
BR112016028971A2 (pt) | 2017-08-22 |
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