DK2961276T3 - Glyphosat og dicamba-tankblandinger med forbedret flygtighed - Google Patents

Glyphosat og dicamba-tankblandinger med forbedret flygtighed Download PDF

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Publication number
DK2961276T3
DK2961276T3 DK14756379.5T DK14756379T DK2961276T3 DK 2961276 T3 DK2961276 T3 DK 2961276T3 DK 14756379 T DK14756379 T DK 14756379T DK 2961276 T3 DK2961276 T3 DK 2961276T3
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glyphosate
carbon atoms
salt
dicamba
hydrocarbyl
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DK14756379.5T
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English (en)
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John Hemminghaus
Alison Macinnes
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Monsanto Technology Llc
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Toxicology (AREA)

Claims (18)

1. Fremgangsmåde til fremstilling afen vandig tankblandingssammensætning omfattende en glyphosat-bestanddel og en dicamba-bestanddel, hvilken fremgangsmåde omfatter: at kombinere en vandig glyphosatkoncentratsammensætning, en dicamba-sammensætning omfattende et eller flere salte af dicamba og fortyndingsvand til dannelse af tankblandingssammensætningen, hvor glyphosatkoncen-tratsammensætningen omfatter et glyphosatsalt, der er valgt fra gruppen bestående af monoethanolaminsalt, kaliumsalt og blandinger deraf ved en glyphosatmængde på mindst 240 gram syreækvivalent pr. liter (g a.e./l.) og et eller flere overfladeaktive stoffer, og hvor pH-værdien på en 5 vægt-%-syre-ækvivalentfortynding af glyphosatkoncentratsammensætningen er fra 5 til 6,5, og hvor molforholdet af glyphosatneutraliseringsbase til glyphosat, der anvendes til fremstilling af glyphosatkoncentratsammensætningen, er fra 1,25:1 til 1,5:1, og hvor det overfladeaktive stof er valgt fra gruppen bestående af: (1) et kvaternært ammoniumsalt med formlen (I):
hvor R1 er hydrocarbyl eller substitueret hydrocarbyl med 1 til 30 carbonato-mer; R2 i hver af grupperne (R2O)x og (R2O)y uafhængigt er C2-C4-alkylen; R3 er hydrogen eller en lineær eller forgrenet alkylgruppe med fra 1 til 4 carbona-tomer; R4 er hydrocarbyl eller substitueret hydrocarbyl med fra 1 til 30 carbo-natomer; x og y uafhængigt er et gennemsnitligt tal fra 1 til 40; og X" er en landbrugsmæssigt acceptabel anion; (2) en alkoxyleret tertiær etheramin med formlen (II):
hvor R5 er et hydrocarbyl eller substitueret hydrocarbyl med fra 4 til 22 carbo-natomer; R6 og R7 hver især uafhængigt er et hydrocarbylen med 2, 3 eller 4 carbonatomer; hvert R8 uafhængigt er hydrogen eller Ci-6-alkyl, m er et gennemsnitligt tal fra 1 til 10; og summen af x og y er en gennemsnitlig værdi i området fra 2 til 60;
(3) et alkylpolysaccharid med formlen (III):
(III) hvor R9 er en lige eller forgrenet kæde substitueret eller usubstitueret hydrocarbyl, der er valgt blandt alkyl, alkenyl, alkylphenyl, alkenylphenyl med fra 4 til 22 carbonatomer; sug-enheden er en saccharidrest; og u er et gennemsnitligt tal fra 1 til 10; (4) en amidoalkylamin med formlen (IV):
hvor Rlu er et hydrocarbyl eller substitueret hydrocarbyl med fra 1 til 22 carbonatomer, R11 og R12 hver især uafhængigt er hydrocarbyl eller substitueret hydrocarbyl med fra 1 til 6 carbonatomer, og R13 er hydrocarbylen eller substitu-teret hydrocarbylen med fra 1 til 6 carbonatomer og kombinationer deraf.
2. Fremgangsmåde ifølge krav 1, hvor pH-værdien af en 5 vægt-%-syreækvi-valentfortynding af glyphosatkoncentratsammensætningen er fra 5,2 til 5,8.
3. Fremgangsmåde ifølge krav 1 eller 2, hvor syreækvivalent-vægtforholdet af glyphosatsalt til dicambasalt i tankblandingssammensætningen er fra 1:1 til 5:1.
4. Fremgangsmåde ifølge et af kravene 1 til 3, hvor dicambasaltet er valgt fra gruppen bestående af monoethanolaminsalt, diglycolaminsalt, kaliumsalt og blandinger deraf.
5. Fremgangsmåde ifølge et af kravene 1 til 4, hvor glyphosatmængden i glyphosatkoncentratsammensætningen er fra 360 g/l til 550 g/l på en syre-ækvivalentbasis. 6 * *
6. Fremgangsmåde ifølge et af kravene 1 til 5, hvor molforholdet af glyphosat- neutraliseringsbase til glyphosat, der anvendes til fremstilling af glyphosatkon- centratsammensætningen er fra 1,25:1 til 1,35:1.
7. Fremgangsmåde ifølge et af kravene 1 til 6, hvor neutraliseringsbasen er en monosyrebase.
8. Fremgangsmåde ifølge et af kravene 1 til 7, hvor glyphosatkoncentratsam-mensætningen har et molforhold af monobasisk glyphosatsalt til dibasisk glyphosatsalt på 1:1 til 3:1.
9. Fremgangsmåde ifølge et af kravene 1 til 8, hvor glyphosatsaltet er kaliumsaltet.
10. Fremgangsmåde ifølge et af kravene 1 til 9, hvor dicambasaltet er diglyco-laminsaltet.
11. Fremgangsmåde ifølge et af kravene 1 til 10, hvor det overfladeaktive stof omfatter det kvaternære ammoniumsalt med formlen (I), hvor R1- og R4-hydro-carbylgrupperne uafhængigt er valgt blandt lineær eller forgrenet alkyl-, lineær eller forgrenet alkenyl-, lineær eller forgrenet alkynyl-, aryl- eller aralkyl-grup-permedfra 1 til 25 carbonatomer; eller lineær eller forgrenet alkyl-grupper med fra 1 til 22 carbonatomer, og R2 i hver af (R2O)x- og (R2O)y-gruppen uafhængigt er C2-C4-alkylen eller ethylen eller propylen; R3 er hydrogen, methyl eller ethyl; og summen af x og y er et gennemsnitligt tal fra 2 til 30 eller fra 2 til 20.
12. Fremgangsmåde ifølge et af kravene 1 til 11, hvor det overfladeaktive stof omfatter den alkoxylerede tertiære etheramin med formlen (II), hvor R5 er en alkyl med en gennemsnitlig værdi i området fra 4 til 22 carbonatomer, fra 8 til 22 carbonatomer eller fra 10 til 20 carbonatomer; R6 og R7 uafhængigt er ethylen, propylen, isopropylen; R8 er hydrogen; m er en gennemsnitlig værdi i området fra 1 til 5; og summen af x og y er en gennemsnitlig værdi i området fra 2 til 25. 13
13. Fremgangsmåde ifølge et af kravene 1 til 12, hvor det overfladeaktive stof omfatter den alkoxylerede tertiære etheramin med formlen (II), hvor R5 er C12-14; R6 er isopropyl; R7 er ethylen; R8 er hydrogen; m er 2; og summen af x og y er 5.
14. Fremgangsmåde ifølge et af kravene 1 til 13, hvor det overfladeaktive stof omfatter alkylpolysaccharid-overfladeaktivt stof med formlen (III), hvor R9 er en forgrenet eller ligekædet alkylgruppe med fra 4 til 22 carbonatomer, fra 8 til 18 carbonatomer eller en blanding af alkylgrupper med en gennemsnitlig vær-dii inden for det givne område; sug er en glucoserest; og u er fra 1 til 5 eller fra 1 til 3.
15. Fremgangsmåde ifølge et af kravene 1 til 14, hvor det overfladeaktive stof omfatter en amidoalkylamin med formlen (IV), hvor R10 er alkyl eller substitueret alkyl med en gennemsnitlig værdi af carbonatomer mellem 4 til 20 carbonatomer, R11 og R12 uafhængigt er en alkyl eller substitueret alkyl med fra 1 til 4 carbonatomer, og R13 er en alkylen eller substitueret alkylen med fra 1 til 4 carbonatomer.
16. Fremgangsmåde ifølge et af kravene 1 til 15, hvor glyphosatkoncen-tratsammensætningen har koncentration af overfladeaktivt stof på fra 2,5 vægt-% til 10 vægt-%.
17. Tankblandingssammensætning omfattende: en blanding af monobasiske og dibasiske salte af glyphosat, hvor molforholdet af monobasisk glyphosatsalt til dibasisk glyphosatsalt er fra 1:1 til 3:1; et eller flere salte af dicamba; fortyndingsvand; og et overfladeaktivt stof, hvor tankblandingssammensætningen haren samlet ukrudtsmiddelkoncentration på ikke mere end 10 vægtprocent a.e. og en pH-værdi på fra 5,2 til 5,8, og hvor det overfladeaktive stof er valgt fra gruppen bestående af: (1) et kvaternært ammoniumsalt med formlen (I):
hvor R1 er hydrocarbyl eller substitueret hydrocarbyl med 1 til 30 carbonatomer; R2 i hver af grupperne (R2O)x og (R2O)y uafhængigt er C2-C4-alkylen; R3 er hydrogen eller en lineær eller forgrenet alkylgruppe med fra 1 til 4 carbona-
tomer; R4 er hydrocarbyl eller substitueret hydrocarbyl med fra 1 til 30 carbonatomer; x og y uafhængigt er et gennemsnitligt tal fra 1 til 40; og X" er en landbrugsmæssigt acceptabel anion; (2) en alkoxvleret tertiær etheramin med formlen (II):
hvor R5 er et hydrocarbyl eller substitueret hydrocarbyl med fra 4 til 22 carbonatomer; R6 og R7 hver især uafhængigt er et hydrocarbylen med 2, 3 eller 4 carbonatomer; hvert R8 uafhængigt er hydrogen eller Ci-6-alkyl, m er et gennemsnitligt tal fra 1 til 10; og summen af x og y er en gennemsnitlig værdi i området fra 2 til 60; (3) et alkylpolysaccharid med formlen (III):
(III) hvor R9 er en lige eller forgrenet kæde substitueret eller usubstitueret hydrocarbyl, der er valgt blandt alkyl, alkenyl, alkylphenyl, alkenylphenyl med fra 4 til 22 carbonatomer; sug-enheden er en saccharidrest; og u er et gennemsnitligt tal fra 1 til 10; (4) en amidoalkylamin med formlen (IV):
hvor R10 er et hydrocarbyl eller substitueret hydrocarbyl med fra 1 til 22 carbonatomer, R11 og R12 hver især uafhængigt er hydrocarbyl eller substitueret hydrocarbyl med fra 1 til 6 carbonatomer, og R13 er hydrocarbylen eller substitu-teret hydrocarbylen med fra 1 til 6 carbonatomer og kombinationer deraf.
18. Tankblandingssammensætning ifølge krav 17, hvor glyphosatsaltet omfatter monoethanolaminsaltet, kaliumsaltet eller blandinger deraf.
DK14756379.5T 2013-02-27 2014-02-27 Glyphosat og dicamba-tankblandinger med forbedret flygtighed DK2961276T3 (da)

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US201361769943P 2013-02-27 2013-02-27
PCT/US2014/018829 WO2014134235A1 (en) 2013-02-27 2014-02-27 Glyphosate composition for dicamba tank mixtures with improved volatility

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EP (1) EP2961276B1 (da)
CN (2) CN105072912A (da)
AR (2) AR094909A1 (da)
AU (1) AU2014223496B2 (da)
BR (1) BR112015020639B1 (da)
CA (3) CA3123572A1 (da)
DK (1) DK2961276T3 (da)
ES (1) ES2694509T3 (da)
HK (1) HK1219621A1 (da)
HU (1) HUE040466T2 (da)
MX (1) MX2015011054A (da)
PL (1) PL2961276T3 (da)
TR (1) TR201815726T4 (da)
UY (1) UY35352A (da)
WO (1) WO2014134235A1 (da)

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