DK2872450T3 - Doterede nikkelatforbindelser. - Google Patents

Doterede nikkelatforbindelser. Download PDF

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Publication number
DK2872450T3
DK2872450T3 DK13739252.8T DK13739252T DK2872450T3 DK 2872450 T3 DK2872450 T3 DK 2872450T3 DK 13739252 T DK13739252 T DK 13739252T DK 2872450 T3 DK2872450 T3 DK 2872450T3
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Denmark
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nanio
xmno
range
cathode
ion cell
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DK13739252.8T
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Jeremy Barker
Richard Heap
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Faradion Ltd
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Nickelates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Nickelates
    • C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Nickelates
    • C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
    • C01G53/44—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese of the type [MnO2]n-, e.g. Li(NixMn1-x)O2, Li(MyNixMn1-x-y)O2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Nickelates
    • C01G53/66—Nickelates containing alkaline earth metals, e.g. SrNiO3, SrNiO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Claims (15)

1. Forbindelse med formlen: Ai-5 M^v M^w X M\ O2 hvor A er et eller flere alkalimetaller omfattende natrium og/eller kalium enten alene eller i blanding med lithium som bibestanddel; er nikkel i oxidationstrin +2 omfatter et metal i oxidationstrin +4, udvalgt blandt et eller flere af mangan, titan og zirconium; omfatter et metal i oxidationstrin +2, udvalgt blandt et eller flere af magnesium, calcium, kobber, zink og kobolt; omfatter et metal i oxidationstrin +4, udvalgt blandt et eller flere af titan, mangan og zirconium; omfatter et metal i oxidationstrin +3, udvalgt blandt et eller flere af aluminium, jern, kobolt, molybdæn, krom, vanadium, scandium og yttrium; hvor 0 < δ < 0,1 V er i området 0 < V <0,5; W er i området 0 < W < 0,5; X er i området 0 < X < 0,5; Y er i området 0 < Y < 0,5; Z er > 0; og hvor desuden V + W + X + Y + Z = l.
2. Forbindelse ifølge krav 1, hvor V er i området 0,1 < V < 0,45; W er i området 0 < W < 0,5; X er i området 0 < X < 0,5; Y er i området 0 < Y < 0,5; Z er > 0; og hvor V + W + X + Y + Z = l.
3. Forbindelse ifølge krav 1, hvor V er i området 0,3 < V < 0,45; W er i området 0,1 < W < 0,5; X er i området 0,05 < X < 0,45; Y er i området 0 < Y < 0,45; Z er > 0; og hvor V + W + X + Y + Z = l.
4. Forbindelse ifølge krav 1, hvor Φ
5. Forbindelse ifølge krav 1 med formlen: NaNio.5-x/2Tio.5-x/2Alx02; NaNio.5-x/2Mno,5- χ/2ΑΙχθ2; NaNio.5-xMno,5-xMgxTlx02; NaNio.5-xMno,5-xMgx/2 ΤΙχ/2ΑΙχθ2; ΝοΝΙο.5-χΜηο.5-χΟθχΤΙχθ2; NaNio.s-xMno.s-xCOxTixOz; NaNio.5-xMno.5-xCUxTix02; ΝοΝΙο.5-χΜηο.5-χΖηχΤΙχθ2; NaNlo.s-xMno.s-xMgxZrx02; NaNio.5-xMno.25-x/2CaxTio.25+x/202; NaNio.5-xMno.5Cax02; NaNio.5-xMno.5-YCaxTlY02; NaNio.5-xTio.5-xMgxMnx02; NaNio.5-xTio.5-xCaxMnx02; NaNio.5-xTio.5-xCUxMnx02; NaNio.5-xTio.5- xCOxMnx02; NaNio.5-xTio.5-xZnxMnx02; NaNio.5-xMno.5Mgx02; NaNio.5-xMno.5Cax02; NaNio.s-xMno.sCUx02, NaNio.5-xMno.5COx02; NaNio.5-xMno.5Znx02; NaNio.5-xMno.5-yMgxTiy02; NaNio.5-xMno.5-yCaxTiy02; NaNio.5-xMno.5-yCUxTiy02; NaNio.5-xMno.5-yCOxTiy02; NaNio.5-xMno.5-yZnxTiy02; NaNio.s- xMno.25-x/2MgxTio. 25-1-X/2O2; NaNio.5-xMno.25-x/2CaxTio.25-1-x/2O2; NaNio.5-xMno.25-x/2CUxTio.25-1-x/2O2; NaNio.5-xMno.25-x/2COxTio.25-1-x/2O2; NaNio.5-xMno.25-x/2ZnxTio.25-1-x/2O2; NaNio.5-xMno.5- χΙ^9χ/2Τίχ/2ΑΙχθ2; NaNio.5-xl^rio.5-xCax/2Tix/2Alx02; NaNio.5-xMno.5-xCUx/2Tix/2Alx02; NaNio.s-xMno.s- χί-Οχ/2Τίχ/2ΑΙχθ2; NaNio.5-xMno.5-xZnx/2Tix/2Alx02 og Nao.9sNio.3i57Tio.3157^90.ΐ583Μηο.2θ83θ2·
6. Elektrode omfattende en virksom forbindelse ifølge krav 1.
7. Elektrode ifølge krav 6 anvendt i forbindelse med en modelektrode og et eller flere elektrolytmaterialer.
8. Elektrode ifølge krav 7, hvor elektrolytmaterialet omfatter et vandigt elektrolytmateriale.
9. Elektrode ifølge krav 7, hvor elektrolytmaterialet omfatter en ikke-vandig elektrolyt.
10. Energilagringsanordning omfattende en elektrode ifølge krav 6.
11. Energilagringsanordning ifølge krav 10 egnet til anvendelse som en eller flere af følgende: en natrium- og/eller kaliumioncelle; en natrium- og/eller kalium-metalcelle; en ikke-vandig elektrolyt-natrium- og/eller -kalium-ioncelle, og en vandig elektrolyt-natrium-og/eller -kalium-ioncelle; i hvert enkelt tilfælde eventuelt indbefattende lithium som bibestanddel.
12. Genopladeligt batteri omfattende en elektrode ifølge krav 6.
13. Elektrokemisk anordning omfattende en elektrode ifølge krav 6.
14. Elektrokrom anordning omfattende en elektrode ifølge krav 6.
15. Fremgangsmåde til fremstilling af forbindelserne ifølge krav 1, hvilken fremgangsmåde omfatter følgende trin: a) at sammenblande udgangsmaterialerne; b) at opvarme de sammenblandede udgangsmaterialer i en smelteovn ved en temperatur på mellem 400 °C og 1500 °C i mellem 2 og 20 timer; og c) at tillade reaktionsprodukterne at afkøles.
DK13739252.8T 2012-07-10 2013-07-10 Doterede nikkelatforbindelser. DK2872450T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB1212261.0A GB2503896A (en) 2012-07-10 2012-07-10 Nickel doped compound for use as an electrode material in energy storage devices
PCT/GB2013/051821 WO2014009722A1 (en) 2012-07-10 2013-07-10 Doped nickelate compounds

Publications (1)

Publication Number Publication Date
DK2872450T3 true DK2872450T3 (da) 2016-07-18

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Country Status (11)

Country Link
US (2) US20150137031A1 (da)
EP (2) EP2872450B1 (da)
JP (3) JP2015531143A (da)
KR (2) KR102073785B1 (da)
CN (2) CN104428256B (da)
DK (1) DK2872450T3 (da)
ES (1) ES2579856T3 (da)
GB (1) GB2503896A (da)
HK (1) HK1206706A1 (da)
PL (1) PL2872450T3 (da)
WO (2) WO2014009723A1 (da)

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