DK2780108T3 - Fremgangsmåde til fremstilling af en neutral, stabil og transparent fotokatalytisk titandioxid-sol - Google Patents
Fremgangsmåde til fremstilling af en neutral, stabil og transparent fotokatalytisk titandioxid-sol Download PDFInfo
- Publication number
- DK2780108T3 DK2780108T3 DK12849280.8T DK12849280T DK2780108T3 DK 2780108 T3 DK2780108 T3 DK 2780108T3 DK 12849280 T DK12849280 T DK 12849280T DK 2780108 T3 DK2780108 T3 DK 2780108T3
- Authority
- DK
- Denmark
- Prior art keywords
- neutral
- preparing
- procedure
- stable
- titanium dioxide
- Prior art date
Links
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title 2
- 230000007935 neutral effect Effects 0.000 title 1
- 230000001699 photocatalysis Effects 0.000 title 1
- 239000004408 titanium dioxide Substances 0.000 title 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0237—Amines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0239—Quaternary ammonium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/393—Metal or metal oxide crystallite size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Dispersion Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Toxicology (AREA)
- Crystallography & Structural Chemistry (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161560669P | 2011-11-16 | 2011-11-16 | |
| PCT/US2012/065616 WO2013074984A1 (en) | 2011-11-16 | 2012-11-16 | Neutral, stable and transparent photocatalytic titanium dioxide sols |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2780108T3 true DK2780108T3 (da) | 2021-02-15 |
Family
ID=48280861
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK12849280.8T DK2780108T3 (da) | 2011-11-16 | 2012-11-16 | Fremgangsmåde til fremstilling af en neutral, stabil og transparent fotokatalytisk titandioxid-sol |
Country Status (21)
| Country | Link |
|---|---|
| US (2) | US9352299B2 (da) |
| EP (1) | EP2780108B1 (da) |
| JP (1) | JP6146822B2 (da) |
| KR (1) | KR101968367B1 (da) |
| CN (1) | CN104010724B (da) |
| AU (1) | AU2012340198B2 (da) |
| BR (1) | BR112014011860B1 (da) |
| CA (1) | CA2856095C (da) |
| DK (1) | DK2780108T3 (da) |
| ES (1) | ES2860931T3 (da) |
| MX (1) | MX2014005975A (da) |
| MY (1) | MY167566A (da) |
| PH (1) | PH12014501105A1 (da) |
| PL (1) | PL2780108T3 (da) |
| PT (1) | PT2780108T (da) |
| SG (1) | SG11201402330WA (da) |
| SI (1) | SI2780108T1 (da) |
| TW (1) | TWI604889B (da) |
| UA (1) | UA114187C2 (da) |
| WO (1) | WO2013074984A1 (da) |
| ZA (1) | ZA201404097B (da) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103635626A (zh) | 2011-04-15 | 2014-03-12 | 联合生物科学服务股份有限公司 | 形成自净化表面的组合物与方法 |
| US9528009B2 (en) * | 2011-04-15 | 2016-12-27 | Craig Grossman | Composition and method to form a self decontaminating surface |
| US11166458B2 (en) | 2011-04-15 | 2021-11-09 | Allied Bioscience, Inc. | Wet wipes comprising antimicrobial coating compositions |
| UA114187C2 (uk) | 2011-11-16 | 2017-05-10 | Крістал Юесей Інк. | Нейтральні, стабільні й прозорі золі фотокаталітичного діоксиду титану |
| WO2013138298A1 (en) * | 2012-03-16 | 2013-09-19 | Intecrete, Llc | Multi-layered cement compositions containing photocatalyst particles and method for creating multi-layered cement compositions containing photocatalyst particles |
| WO2014118372A1 (en) * | 2013-02-02 | 2014-08-07 | Joma International A/S | An aqueous dispersion comprising tio2 particles |
| EP2950924A1 (en) | 2013-02-03 | 2015-12-09 | Joma International AS | A catalytic substrate surface containing particles |
| GB2521405B (en) | 2013-12-18 | 2015-12-02 | Dublin Inst Of Technology | A surface coating |
| CN104626680B (zh) * | 2015-03-03 | 2016-09-07 | 中国科学院上海硅酸盐研究所 | 一种复合黑色二氧化钛薄膜及其制备方法 |
| SI3365394T1 (sl) | 2015-10-21 | 2020-10-30 | Tronox Llc | Oplaščenja, ki znižujejo NOx in postopki za zniževanje NOx s pomočjo njih |
| US20180326401A1 (en) * | 2015-11-20 | 2018-11-15 | Cristal Usa Inc. | Titanium dioxide compositions and their use as depolluting agents |
| US10995012B2 (en) * | 2015-12-10 | 2021-05-04 | Tronox Llc | Concentrated photoactive, neutral titanium dioxide sol |
| WO2017156372A1 (en) * | 2016-03-10 | 2017-09-14 | Cristal Usa Inc. | Photocatalytic coating compositions |
| KR101856971B1 (ko) | 2016-12-20 | 2018-05-15 | (주) 클레어 | TiO2 졸과 유기산 발효액이 함유된 새집증후군 제거제의 제조방법 |
| CN107352579A (zh) * | 2017-07-17 | 2017-11-17 | 上海友兰科技有限公司 | 一种超亲水自清洁二氧化钛溶胶的制备方法 |
| CN107917351A (zh) * | 2017-10-27 | 2018-04-17 | 中山市汉庭照明科技有限公司 | 一种具有除甲醛效果的 led 灯泡及制备方法 |
| IT201800003836A1 (it) * | 2018-03-21 | 2019-09-21 | Andrea Gaglianone | Composizione e metodo di sanificazione per la sanificazione-purificazione di superfici e ambienti |
| US11951221B2 (en) | 2018-06-19 | 2024-04-09 | Northwestern University | Silver and titanium dioxide based optically transparent antimicrobial coatings and related methods |
| CN108967442B (zh) * | 2018-07-24 | 2020-06-05 | 广东省生态环境技术研究所 | 一种抑制水稻镉砷积累的亚铁改性硒溶胶及其制备方法与应用 |
| TWI779203B (zh) * | 2018-12-10 | 2022-10-01 | 愛爾蘭商卡斯特斯科技公司 | 摻磷表面塗層及其製備方法 |
| EP3894484A1 (en) * | 2018-12-10 | 2021-10-20 | Kastus Technologies DAC | P-doped surface coatings and process of preparation thereof |
| PL428604A1 (pl) * | 2019-01-16 | 2020-07-27 | Bolix Spółka Akcyjna | Sposób zabezpieczenia nowo wykonanej elewacji przed wystąpieniem skażenia mikrobiologicznego oraz sposób renowacji elewacji budynku dotkniętej skażeniem mikrobiologicznym |
| CN110090571A (zh) * | 2019-04-01 | 2019-08-06 | 江苏奥净嘉环保科技有限公司 | 一种纳米二氧化钛分散液的制备方法 |
| DE102020110567A1 (de) * | 2020-04-17 | 2021-10-21 | Mursall Aktive Coating GmbH | Verfahren zum Aufbringen einer Beschichtung auf eine Glasoberfläche |
| CN112246262A (zh) * | 2020-10-27 | 2021-01-22 | 长春工业大学 | 过渡金属Zn、Ag修饰的催化剂的制备 |
| US11253842B1 (en) * | 2021-04-02 | 2022-02-22 | TiCoat, Inc. | Titanium dioxide containing peroxo titanium complex and methods of manufacturing and application of the same |
| CN114604947A (zh) * | 2022-03-21 | 2022-06-10 | 衡阳市建衡实业有限公司 | 一种含钛复合聚硫酸铁絮凝剂及其制备方法与应用 |
| KR102632414B1 (ko) * | 2022-10-21 | 2024-02-05 | (재)한국건설생활환경시험연구원 | 압전소자와 광촉매 개질제를 이용한 스마트 도로 관리 시스템 |
| CN117380172B (zh) * | 2023-10-11 | 2024-04-16 | 齐鲁工业大学(山东省科学院) | 具有双亲性结构的光催化自清洁金属氢氧化物/TiO2水溶胶及其制备方法与应用 |
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| GB8300554D0 (en) * | 1983-01-10 | 1983-02-09 | Atomic Energy Authority Uk | Catalyst preparation |
| EP0261560B1 (en) | 1986-09-22 | 1992-04-01 | Ishihara Sangyo Kaisha, Ltd. | Titania sol and process for producing same |
| JPS63215520A (ja) * | 1987-03-03 | 1988-09-08 | Ishihara Sangyo Kaisha Ltd | 中性チタニアゾル及びその製造方法 |
| US5403513A (en) * | 1987-10-07 | 1995-04-04 | Catalyst & Chemical Industries, Co., Ltd. | Titanium oxide sol and process for preparation thereof |
| WO1996010917A1 (fr) | 1994-10-05 | 1996-04-18 | Toto Ltd. | Solide antibacterien, son procede de preparation et son procede d'utilisation |
| CN1097477C (zh) | 1994-10-31 | 2003-01-01 | 财团法人神奈川科学技术研究院日本曹达株式会社 | 二氧化钛光催化剂构件及其制造方法 |
| US6387844B1 (en) * | 1994-10-31 | 2002-05-14 | Akira Fujishima | Titanium dioxide photocatalyst |
| US5897958A (en) * | 1995-10-26 | 1999-04-27 | Asahi Glass Company Ltd. | Modified titanium oxide sol, photocatalyst composition and photocatalyst composition-forming agent |
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| KR100696225B1 (ko) * | 1998-05-14 | 2007-03-20 | 쇼와 덴코 가부시키가이샤 | 산화티탄졸, 박막 및 그들의 제조법 |
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| JP2002179949A (ja) * | 2000-12-11 | 2002-06-26 | Hitachi Chem Co Ltd | チタニア膜形成用液体、チタニア膜の形成法、チタニア膜及びチタニア膜を用いた部材 |
| US7060643B2 (en) * | 2000-12-28 | 2006-06-13 | Showa Denko Kabushiki Kaisha | Photo-functional powder and applications thereof |
| KR20030043536A (ko) * | 2001-11-28 | 2003-06-02 | 티오켐 주식회사 | 수열합성법을 이용한 고활성 광촉매 산화티탄 졸 제조 방법 |
| FR2838734B1 (fr) | 2002-04-17 | 2005-04-15 | Saint Gobain | Substrat a revetement auto-nettoyant |
| CN1218634C (zh) | 2002-04-30 | 2005-09-14 | 香港中文大学 | 具有高杀菌光活性介孔二氧化钛薄膜的制备方法 |
| US7521039B2 (en) | 2002-11-08 | 2009-04-21 | Millennium Inorganic Chemicals, Inc. | Photocatalytic rutile titanium dioxide |
| KR100541750B1 (ko) * | 2003-04-03 | 2006-01-10 | (주)선한엠엔티 | 중성 이산화티탄 콜로이드 용액, 그것의 제조방법 및그것을 포함하는 코팅제 |
| JP4540971B2 (ja) * | 2003-12-05 | 2010-09-08 | 石原産業株式会社 | 中性酸化チタンゾルおよびその製造方法 |
| JP4522082B2 (ja) * | 2003-12-05 | 2010-08-11 | 石原産業株式会社 | 光触媒液状組成物およびそれを用いて形成した光触媒体 |
| WO2005083013A1 (en) | 2004-01-30 | 2005-09-09 | Millennium Chemicals | Coating composition having surface depolluting properties |
| DE102005036427A1 (de) | 2005-08-03 | 2007-02-08 | Schott Ag | Substrat, umfassend zumindest eine voll- oder teilflächige makrostrukturierte Schicht, Verfahren zu deren Herstellung und deren Verwendung |
| US20070195259A1 (en) | 2006-02-22 | 2007-08-23 | Microban Products Company | Antimicrobial spectacle |
| JP4606385B2 (ja) * | 2006-06-05 | 2011-01-05 | 多木化学株式会社 | アルカリ型酸化チタンゾルの製造方法 |
| JP4880410B2 (ja) * | 2006-09-28 | 2012-02-22 | 多木化学株式会社 | 光触媒コーティング組成物が被覆された部材 |
| ATE535563T1 (de) | 2006-12-19 | 2011-12-15 | Evonik Degussa Gmbh | Sol-gel-prozess zur herstellung von schutzfolien für polymersubstrate |
| US7763565B2 (en) * | 2007-08-31 | 2010-07-27 | Millennium Inorganic Chemicals, Inc. | Transparent, stable titanium dioxide sols |
| US7820724B2 (en) * | 2008-02-14 | 2010-10-26 | Millennium Inorganic Chemicals, Inc. | Colloidal titanium dioxide sols |
| KR100935512B1 (ko) * | 2008-05-15 | 2010-01-06 | 경북대학교 산학협력단 | 이산화티타늄 광촉매의 제조방법 및 이에 의해 제조된이산화티타늄 광촉매 |
| JP2010148999A (ja) * | 2008-12-24 | 2010-07-08 | Taki Chem Co Ltd | 光触媒酸化チタンゾル及びその製造方法 |
| JP2011190152A (ja) * | 2010-03-16 | 2011-09-29 | Tayca Corp | 無定形チタニアゾルおよびその製造方法 |
| UA114187C2 (uk) | 2011-11-16 | 2017-05-10 | Крістал Юесей Інк. | Нейтральні, стабільні й прозорі золі фотокаталітичного діоксиду титану |
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2012
- 2012-11-16 UA UAA201406459A patent/UA114187C2/uk unknown
- 2012-11-16 CN CN201280064925.1A patent/CN104010724B/zh active Active
- 2012-11-16 MY MYPI2014701243A patent/MY167566A/en unknown
- 2012-11-16 DK DK12849280.8T patent/DK2780108T3/da active
- 2012-11-16 SI SI201231883T patent/SI2780108T1/sl unknown
- 2012-11-16 KR KR1020147016257A patent/KR101968367B1/ko active IP Right Grant
- 2012-11-16 PL PL12849280T patent/PL2780108T3/pl unknown
- 2012-11-16 US US13/679,252 patent/US9352299B2/en active Active
- 2012-11-16 BR BR112014011860-4A patent/BR112014011860B1/pt active IP Right Grant
- 2012-11-16 JP JP2014542505A patent/JP6146822B2/ja active Active
- 2012-11-16 AU AU2012340198A patent/AU2012340198B2/en active Active
- 2012-11-16 WO PCT/US2012/065616 patent/WO2013074984A1/en active Application Filing
- 2012-11-16 MX MX2014005975A patent/MX2014005975A/es unknown
- 2012-11-16 SG SG11201402330WA patent/SG11201402330WA/en unknown
- 2012-11-16 TW TW101142963A patent/TWI604889B/zh active
- 2012-11-16 CA CA2856095A patent/CA2856095C/en active Active
- 2012-11-16 EP EP12849280.8A patent/EP2780108B1/en active Active
- 2012-11-16 ES ES12849280T patent/ES2860931T3/es active Active
- 2012-11-16 PT PT128492808T patent/PT2780108T/pt unknown
-
2014
- 2014-05-16 PH PH12014501105A patent/PH12014501105A1/en unknown
- 2014-06-05 ZA ZA2014/04097A patent/ZA201404097B/en unknown
-
2016
- 2016-04-21 US US15/134,854 patent/US20160228850A1/en not_active Abandoned
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