DK2281013T3 - Fremgangsmåder til at styre molekylvægtfordeling af polymerer og sammensætninger deraf - Google Patents

Fremgangsmåder til at styre molekylvægtfordeling af polymerer og sammensætninger deraf Download PDF

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Publication number
DK2281013T3
DK2281013T3 DK09759050.9T DK09759050T DK2281013T3 DK 2281013 T3 DK2281013 T3 DK 2281013T3 DK 09759050 T DK09759050 T DK 09759050T DK 2281013 T3 DK2281013 T3 DK 2281013T3
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Prior art keywords
reaction
catalyst
molecular weight
polymerization
time
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DK09759050.9T
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English (en)
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Scott D Allen
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Saudi Aramco Tech Co
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20General preparatory processes
    • C08G64/32General preparatory processes using carbon dioxide
    • C08G64/34General preparatory processes using carbon dioxide and cyclic ethers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)

Claims (5)

1. Fremgangsmåde til at styre en molekylvægtfordeling af et produkt fra en additionspolymerisationsreaktion omfattende de følgende trin: a) at indlede additionspolymerisationsreaktionen på et indledningstidspunkt; og b) at tilsætte mindst en reaktionskomponent til reaktionen i løbet af den mindst ene reaktionstid efter indledningstidspunktet; hvor reaktionskomponenten er udvalgt fra gruppen bestående af: a) mindst en katalysator; a) mindst en co-katalysator; c) mindst et reversibelt kædeoverførselsmiddel; og d) en hvilken som helst kombination af a), b) og c); hvor produktet fra additionspolymerisationsreaktionen er et polycarbonat, hvor additionspolymerisationen er en co-polymerisation af carbondioxid og et epoxid, og hvor reaktionskomponenten tilsættes kontinuerligt til reaktionen med en kontinuerlig additionshastighed og efter indledningen af reaktionen.
2. Fremgangsmåde ifølge krav 1, hvor katalysatoren omfatter mindst en metalbaseret katalysator udvalgt fra gruppen bestående af: a) en aluminumbaseret katalysator; b) en manganbaseret katalysator; c) en chrombaseret katalysator; d) en koboltbaseret katalysator; e) en yttriumbaseret katalysator; f) en zinkbaseret katalysator; g) en cadmiumbaseret katalysator; h) en nikkelbaseret katalysator; og i) en hvilken som helst kombination af a) til h).
3. Fremgangsmåde ifølge krav 1 eller krav 2, hvor additionspolymerisationen er en co-polymerisation af carbondioxid og propylenoxid.
4. Fremgangsmåde ifølge et af kravene 1 til 3, yderligere omfattende at tilsætte et kædeafbrydelsesmiddel før et afslutningstidspunkt, når reaktionen er stoppet.
5. Fremgangsmåde ifølge krav 1, hvor den kontinuerlige additionshastighed varieres over tid.
DK09759050.9T 2008-05-29 2009-05-27 Fremgangsmåder til at styre molekylvægtfordeling af polymerer og sammensætninger deraf DK2281013T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/129,106 US7858729B2 (en) 2008-05-29 2008-05-29 Methods of controlling molecular weight distribution of polymers and compositions thereof
PCT/US2009/045216 WO2009148889A2 (en) 2008-05-29 2009-05-27 Methods of controlling molecular weight distribution of polymers and compositions thereof

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DK2281013T3 true DK2281013T3 (da) 2018-03-05

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US (2) US7858729B2 (da)
EP (1) EP2281013B1 (da)
JP (1) JP5552116B2 (da)
KR (2) KR101979576B1 (da)
CN (2) CN102046695B (da)
DK (1) DK2281013T3 (da)
ES (1) ES2663704T3 (da)
HU (1) HUE038560T2 (da)
NO (1) NO2281013T3 (da)
PL (1) PL2281013T3 (da)
PT (1) PT2281013T (da)
TR (1) TR201802600T4 (da)
WO (1) WO2009148889A2 (da)

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KR20240033183A (ko) 2011-06-23 2024-03-12 아블린쓰 엔.브이. 면역글로불린 단일 가변 도메인을 수반하는 어세이에서 비특이적 단백질 간섭을 예측하고 검출하고 감소시키는 기법
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Also Published As

Publication number Publication date
EP2281013A2 (en) 2011-02-09
HUE038560T2 (hu) 2018-10-29
EP2281013A4 (en) 2015-04-29
JP2011522091A (ja) 2011-07-28
TR201802600T4 (tr) 2018-03-21
PL2281013T3 (pl) 2018-06-29
KR101979576B1 (ko) 2019-05-17
KR101825340B1 (ko) 2018-02-05
US7858729B2 (en) 2010-12-28
CN102046695B (zh) 2013-08-21
US20110065894A1 (en) 2011-03-17
WO2009148889A3 (en) 2010-02-25
NO2281013T3 (da) 2018-05-26
US8324337B2 (en) 2012-12-04
CN102046695A (zh) 2011-05-04
KR20110013493A (ko) 2011-02-09
US20090299032A1 (en) 2009-12-03
CN103626983A (zh) 2014-03-12
PT2281013T (pt) 2018-03-28
ES2663704T3 (es) 2018-04-16
EP2281013B1 (en) 2017-12-27
KR20180014844A (ko) 2018-02-09
WO2009148889A2 (en) 2009-12-10
CN103626983B (zh) 2016-12-28
JP5552116B2 (ja) 2014-07-16

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