DK2021434T3 - Fremgangsmåde til omdannelse af biomasse til flydende brændstoffer og specialkemikalier - Google Patents

Fremgangsmåde til omdannelse af biomasse til flydende brændstoffer og specialkemikalier Download PDF

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Publication number
DK2021434T3
DK2021434T3 DK07728831.4T DK07728831T DK2021434T3 DK 2021434 T3 DK2021434 T3 DK 2021434T3 DK 07728831 T DK07728831 T DK 07728831T DK 2021434 T3 DK2021434 T3 DK 2021434T3
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DK
Denmark
Prior art keywords
biomass
converted
conversion
bio
oil
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DK07728831.4T
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English (en)
Inventor
Paul O'connor
Dennis Stamires
Sjoerd Daamen
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Kior Inc
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/02—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/04—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/006—Combinations of processes provided in groups C10G1/02 - C10G1/08
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (21)

1. Fremgangsmåde til omdannelse af biomasse til brændstoffer og/eller kemikalier, omfattende trinnene: a) at aktivere biomassen for at gøre den mere modtagelig for omdannelse, hvor det at aktivere omfatter at udsætte biomassen for et pH-udsving på mindst 4 pH-enheder; b) eventuelt at tilsætte et opløsningsmiddel; c) delvist at omdanne den aktiverede biomasse til dannelse af en blanding af en bioolie og en ikke-omdannet biomasse, hvor den ikke-omdannede biomasse refererer til biomasse, der ikke er blevet omdannet til et flydende produkt; d) at separere den ikke-omdannede biomasse fra bioolien; og e) at udsætte den fraseparerede ikke-omdannede biomasse fra trin d) for en omdannelsesproces omfattende pyrolyse eller flashpyrolyse, hvor bioolien er en blanding af derivatforbindelser fra flydende biomasse, og den fraseparerede ikke-konverterede biomasse fra trin c) indeholder genstridig cellulose.
2. Fremgangsmåde ifølge krav 1, hvor trin a) omfatter tilsætning af et uorganisk materiale i partikelform.
3. Fremgangsmåde ifølge krav 2 , hvor det uorganiske materiale er udvalgt fra gruppen bestående af kationisk ler, anionisk ler, naturligt ler, hydrotalkil-lig-nende materialer, lagdelte materialer, malm, mineraler, metaloxider, hydroxider af metaller af alkali- og jordalkaligrupperne og blandinger deraf, hvor de hydrotalkil-lignende materialer omfatter anionisk ler med brucit-lignende hovedlag, der er opbygget af oktaedriske skiftende mellemlag, hvori vandmolekyler og anioner er fordelt.
4. Fremgangsmåde ifølge krav 1, hvor biomassen omfatter cellulose og/eller lignin.
5. Fremgangsmåde ifølge krav 1, hvor separeringen involverer en filtreringsindretning, såsom en filterpresse, en centrifuge, et membranfilter eller et na-nofilter.
6. Fremgangsmåde ifølge krav 5, hvor der tilsættes et opløsningsmiddel og eventuelt varme og/eller damp under separeringstrinnet.
7. Fremgangsmåde ifølge krav 1, hvor den ikke-omdannede biomasse i trin e) er i partikelform, og partiklerne af ikke-konverteret biomasse indeholder partikler af et uorganisk eller organisk materiale.
8. Fremgangsmåde ifølge krav 1, hvor, før trin c), den aktiverede biomasse behandles i en mekanisk indretning for at få en homogen og inderlig blanding af komponenterne.
9. Fremgangsmåde ifølge krav 8, hvor den aktiverede biomasse behandles i en ælteindretning, en formalingsindretning, en fluid bed og/eller en spouted bed, eventuelt ved forhøjet temperatur.
10. Fremgangsmåde ifølge krav 8, hvor den aktiverede biomasse behandles gennem en ekstruder.
11. Fremgangsmåde ifølge krav 10, hvor der under ekstrudering strinnet tilsættes varme og/eller damp.
12. Fremgangsmåde ifølge krav 10, hvor ekstrudater fra ekstruderingstrinnet tørres, dampes og/eller kalcineres før trin e).
13. Fremgangsmåde ifølge krav 1, hvor omdannelsesfremgangsmåden i trin e) indebærer mere end et fremgangsmådetrin.
14. Fremgangsmåde ifølge krav 1, hvor omdanelsesfremgangsmåden i trin e) frembringer en bioolie.
15. Fremgangsmåde ifølge krav 14, omfattende det yderligere trin atomdanne bioolien til et flydende brændstof, som er egnet til anvendelse i en forbrændingsmotor.
16. Fremgangsmåde ifølge krav 1, omfattende det yderligere trin at omdanne bioolien opnået i trin c) til et flydende brændstof, som er egnet til anvendelse i en forbrændingsmotor.
17. Fremgangsmåde ifølge krav 15 eller 16, hvor det yderligere trin omfatter omdannelse i en enhed udvalgt blandt en FCC-enhed, en hydrokrakning-en-hed, en hydrobehandlingsenhed, en termisk krakning-enhed og kombinationer deraf.
18. Fremgangsmåde ifølge krav 1, hvor bioolien fremstillet i trin c) og/eller trin e) blandes med fossile brændstoffer før behandling i et raffinaderi.
19. Fremgangsmåde ifølge krav 1, hvor bioolien opnået i trin c) efterfølgende omdannes til et transportbrændstof ved vandig fase-reformering.
20. Fremgangsmåde ifølge krav 1, hvor, før trin e), den ikke-omdannede biomasse fra trin c) udsættes for elektromagnetisk og/eller ultralyds-energi, eventuelt i nærvær af et polært opløsningsmiddel.
21. Fremgangsmåde ifølge krav 1, hvor, før trin e), den ikke-omdannede biomasse fra trin c) udsættes for inderlig blanding med et tilsætningsstof, eventuelt i nærvær af et opløsningsmiddel.
DK07728831.4T 2006-05-05 2007-05-04 Fremgangsmåde til omdannelse af biomasse til flydende brændstoffer og specialkemikalier DK2021434T3 (da)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP06113564A EP1852493A1 (en) 2006-05-05 2006-05-05 Hydrothermal treatment of carbon-based energy carrier material
US83791506P 2006-08-16 2006-08-16
US85025606P 2006-10-10 2006-10-10
PCT/EP2007/054378 WO2007128800A1 (en) 2006-05-05 2007-05-04 Process for the conversion of biomass to liquid fuels and specialty chemicals

Publications (1)

Publication Number Publication Date
DK2021434T3 true DK2021434T3 (da) 2019-04-23

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Country Link
US (2) US8022260B2 (da)
EP (2) EP1852493A1 (da)
JP (1) JP2009536237A (da)
KR (1) KR20090013817A (da)
CN (1) CN101460594B (da)
BR (1) BRPI0711563A2 (da)
CA (1) CA2651475C (da)
DK (1) DK2021434T3 (da)
MX (1) MX2008014178A (da)
RU (1) RU2427607C2 (da)
WO (1) WO2007128800A1 (da)

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