DE69932362D1 - Entschwefelungsmittel und verfahren zur entschwefelung von kohlenwasserstoffen - Google Patents

Entschwefelungsmittel und verfahren zur entschwefelung von kohlenwasserstoffen

Info

Publication number
DE69932362D1
DE69932362D1 DE69932362T DE69932362T DE69932362D1 DE 69932362 D1 DE69932362 D1 DE 69932362D1 DE 69932362 T DE69932362 T DE 69932362T DE 69932362 T DE69932362 T DE 69932362T DE 69932362 D1 DE69932362 D1 DE 69932362D1
Authority
DE
Germany
Prior art keywords
desolution
degreasing agent
carbon hydrogen
hydrogen
carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69932362T
Other languages
English (en)
Other versions
DE69932362T2 (de
Inventor
Masataka Masuda
Shin-Ichi Nagase
Susumu Takami
Osamu Okada
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Osaka Gas Co Ltd
Original Assignee
Osaka Gas Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Osaka Gas Co Ltd filed Critical Osaka Gas Co Ltd
Publication of DE69932362D1 publication Critical patent/DE69932362D1/de
Application granted granted Critical
Publication of DE69932362T2 publication Critical patent/DE69932362T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H19/00—Compounds containing a hetero ring sharing one ring hetero atom with a saccharide radical; Nucleosides; Mononucleotides; Anhydro-derivatives thereof
    • C07H19/02—Compounds containing a hetero ring sharing one ring hetero atom with a saccharide radical; Nucleosides; Mononucleotides; Anhydro-derivatives thereof sharing nitrogen
    • C07H19/04—Heterocyclic radicals containing only nitrogen atoms as ring hetero atom
    • C07H19/06—Pyrimidine radicals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
    • B01J20/0229—Compounds of Fe
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0233—Compounds of Cu, Ag, Au
    • B01J20/0237—Compounds of Cu
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/024—Compounds of Zn, Cd, Hg
    • B01J20/0244—Compounds of Zn
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3007—Moulding, shaping or extruding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
DE69932362T 1997-08-21 1999-02-18 Entschwefelungsmittel und verfahren zur entschwefelung von kohlenwasserstoffen Expired - Lifetime DE69932362T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP22486397A JP4096128B2 (ja) 1997-08-21 1997-08-21 脱硫剤の製造方法および炭化水素の脱硫方法
PCT/JP1999/000697 WO2000048733A1 (fr) 1997-08-21 1999-02-18 Agent de desulfuration et procede de desulfuration d'hydrocarbure

Publications (2)

Publication Number Publication Date
DE69932362D1 true DE69932362D1 (de) 2006-08-24
DE69932362T2 DE69932362T2 (de) 2007-07-26

Family

ID=26440091

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69932362T Expired - Lifetime DE69932362T2 (de) 1997-08-21 1999-02-18 Entschwefelungsmittel und verfahren zur entschwefelung von kohlenwasserstoffen

Country Status (7)

Country Link
US (1) US7820037B2 (de)
EP (1) EP1192981B1 (de)
JP (1) JP4096128B2 (de)
CA (1) CA2362777C (de)
DE (1) DE69932362T2 (de)
DK (1) DK1192981T3 (de)
WO (1) WO2000048733A1 (de)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4096128B2 (ja) * 1997-08-21 2008-06-04 大阪瓦斯株式会社 脱硫剤の製造方法および炭化水素の脱硫方法
US6254766B1 (en) * 1999-08-25 2001-07-03 Phillips Petroleum Company Desulfurization and novel sorbents for same
US6338794B1 (en) * 1999-11-01 2002-01-15 Phillips Petroleum Company Desulfurization with zinc titanate sorbents
US6271173B1 (en) * 1999-11-01 2001-08-07 Phillips Petroleum Company Process for producing a desulfurization sorbent
US6274533B1 (en) * 1999-12-14 2001-08-14 Phillips Petroleum Company Desulfurization process and novel bimetallic sorbent systems for same
US6429170B1 (en) * 2000-05-30 2002-08-06 Phillips Petroleum Company Sorbents for desulfurizing gasolines and diesel fuel
JP2004518521A (ja) * 2000-09-29 2004-06-24 エンゲルハード・コーポレーシヨン 硫化水素を除去する装置および方法
JP4292362B2 (ja) * 2001-03-28 2009-07-08 大阪瓦斯株式会社 固体高分子型燃料電池発電システム及び固体高分子型燃料電池発電方法
JP4931865B2 (ja) * 2001-03-28 2012-05-16 大阪瓦斯株式会社 固体高分子型燃料電池発電システム及び固体高分子型燃料電池発電方法
DE102005004429A1 (de) * 2005-01-31 2006-08-10 Süd-Chemie AG Verfahren zur Herstellung eines Katalysators für die Entschwefelung von Kohlenwasserstoffströmen
JP4754844B2 (ja) * 2005-02-21 2011-08-24 三菱重工業株式会社 炭化水素系燃料用の脱硫剤の製造方法、炭化水素系燃料用の脱硫剤
US8142646B2 (en) * 2007-11-30 2012-03-27 Saudi Arabian Oil Company Process to produce low sulfur catalytically cracked gasoline without saturation of olefinic compounds
GB0804570D0 (en) * 2008-03-12 2008-04-16 Johnson Matthey Plc Desulphurisation materials
GB0804572D0 (en) * 2008-03-12 2008-04-16 Johnson Matthey Plc Preparation of desulphurisation materials
US8975208B2 (en) 2008-12-31 2015-03-10 China Petroleum Chemical Corporation Desulfurizing adsorbent, preparing process and use thereof
GB0916161D0 (en) * 2009-09-15 2009-10-28 Johnson Matthey Plc Desulphurisation process
CN102380311B (zh) * 2010-09-01 2013-12-25 中国石油化工股份有限公司 汽油吸附脱硫再生烟气处理方法及其尾气加氢催化剂制法
KR20130099100A (ko) * 2010-09-13 2013-09-05 필립스 66 컴퍼니 합성 가스 컨디셔닝을 수반하는 저온 내황성 타르 및 황 제거
JP5755999B2 (ja) * 2011-10-31 2015-07-29 大阪瓦斯株式会社 脱硫剤の製造方法、脱硫剤、および、炭化水素の脱硫方法
JP5782400B2 (ja) * 2012-03-28 2015-09-24 Ｊｘ日鉱日石エネルギー株式会社 脱硫システム、水素製造システム、燃料電池システム、燃料の脱硫方法及び水素の製造方法
US10865709B2 (en) 2012-05-23 2020-12-15 Herng Shinn Hwang Flex-fuel hydrogen reformer for IC engines and gas turbines
WO2015181521A1 (en) * 2014-05-30 2015-12-03 Johnson Matthey Public Limited Company Method for preparing a sorbent
JP5911551B2 (ja) * 2014-10-27 2016-04-27 大阪瓦斯株式会社 脱硫剤の製造方法および炭化水素の脱硫方法
JP6607387B2 (ja) * 2015-02-02 2019-11-20 パナソニックＩｐマネジメント株式会社 脱硫方法及び脱硫器
CN105112093B (zh) * 2015-02-13 2017-01-18 濮阳市联众兴业化工有限公司 一种裂解碳五脱硫方法
SG10201604013RA (en) * 2015-05-28 2016-12-29 Evonik Degussa Gmbh Hydrogen-assisted adsorption of sulphur compounds from olefin mixtures
US10626790B2 (en) 2016-11-16 2020-04-21 Herng Shinn Hwang Catalytic biogas combined heat and power generator
WO2018216555A1 (ja) 2017-05-25 2018-11-29 大阪瓦斯株式会社 ガスの脱硫剤および脱硫方法
JP7027270B2 (ja) * 2017-07-11 2022-03-01 日揮触媒化成株式会社 脱硫剤の製造方法および脱硫剤前駆体の製造方法、並びに脱硫剤前駆体
JP7134019B2 (ja) * 2017-08-22 2022-09-09 大阪瓦斯株式会社 脱硫装置、水素製造装置、脱硫方法及び水素製造方法
WO2020153225A1 (ja) 2019-01-23 2020-07-30 大阪瓦斯株式会社 ガスの脱硫剤および脱硫方法
CN115770545B (zh) * 2021-09-08 2024-03-15 上海迅凯新材料科技有限公司 脱硫吸附剂和制备方法以及在苯深度脱硫方面的应用

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL175835B (nl) * 1973-04-17 1984-08-01 Shell Int Research Werkwijze ter bereiding van een waterstofrijk gas uit een koolmonoxyde-bevattend gas met behulp van een nikkel en/of kobalt en molybdeen bevattende katalysator.
US4891462A (en) * 1986-10-31 1990-01-02 Amoco Corporation Cyclization-dehydrogentation of 1-ethyl-naphthalene over copper aluminum borate
US4876402A (en) * 1986-11-03 1989-10-24 Union Carbide Chemicals And Plastics Company Inc. Improved aldehyde hydrogenation process
US4762817A (en) * 1986-11-03 1988-08-09 Union Carbide Corporation Aldehyde hydrogenation catalyst
US5685890A (en) * 1987-12-17 1997-11-11 Osaka Gas Company Limited Process for steam reforming of hydrocarbons
US5302470A (en) * 1989-05-16 1994-04-12 Osaka Gas Co., Ltd. Fuel cell power generation system
US5347021A (en) * 1990-04-16 1994-09-13 Isp Investments Inc. Process of vapor phase catalytic hydrogenation of maleic anhydride to gamma-butyrolactone in high conversion and high selectivity using an activated catalyst
US5157201A (en) * 1990-06-22 1992-10-20 Exxon Chemical Patents Inc. Process for adsorbing sulfur species from propylene/propane using regenerable adsorbent
US5800798A (en) * 1992-04-06 1998-09-01 Nippon Oil Co., Ltd Process for producing fuel gas for fuel cell
JP3242514B2 (ja) * 1992-11-27 2001-12-25 大阪瓦斯株式会社 都市ガスの脱硫方法
CN1037778C (zh) * 1992-11-28 1998-03-18 大阪瓦斯株式会社 烃的脱硫方法
JP3261192B2 (ja) * 1993-02-01 2002-02-25 出光興産株式会社 燃料電池用炭化水素原料の脱硫方法
US5401391A (en) * 1993-03-08 1995-03-28 Mobil Oil Corporation Desulfurization of hydrocarbon streams
US5482617A (en) * 1993-03-08 1996-01-09 Mobil Oil Corporation Desulfurization of hydrocarbon streams
US5637735A (en) * 1994-08-10 1997-06-10 China Petrochemical Corporation Process for the preparation of gamma-butyrolactone
US5935421A (en) * 1995-05-02 1999-08-10 Exxon Research And Engineering Company Continuous in-situ combination process for upgrading heavy oil
US5626742A (en) * 1995-05-02 1997-05-06 Exxon Reseach & Engineering Company Continuous in-situ process for upgrading heavy oil using aqueous base
US5695632A (en) * 1995-05-02 1997-12-09 Exxon Research And Engineering Company Continuous in-situ combination process for upgrading heavy oil
US5635056A (en) * 1995-05-02 1997-06-03 Exxon Research And Engineering Company Continuous in-situ process for upgrading heavy oil using aqueous base
JP4096128B2 (ja) * 1997-08-21 2008-06-04 大阪瓦斯株式会社 脱硫剤の製造方法および炭化水素の脱硫方法

Also Published As

Publication number Publication date
JPH1161154A (ja) 1999-03-05
CA2362777A1 (en) 2000-08-24
EP1192981B1 (de) 2006-07-12
US20090071876A1 (en) 2009-03-19
WO2000048733A1 (fr) 2000-08-24
DK1192981T3 (da) 2006-10-30
CA2362777C (en) 2005-04-19
JP4096128B2 (ja) 2008-06-04
EP1192981A4 (de) 2005-04-13
EP1192981A1 (de) 2002-04-03
US7820037B2 (en) 2010-10-26
DE69932362T2 (de) 2007-07-26

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