DE69801797T2 - Verfahren zur Herstellung von Acrylsäure - Google Patents
Verfahren zur Herstellung von AcrylsäureInfo
- Publication number
- DE69801797T2 DE69801797T2 DE69801797T DE69801797T DE69801797T2 DE 69801797 T2 DE69801797 T2 DE 69801797T2 DE 69801797 T DE69801797 T DE 69801797T DE 69801797 T DE69801797 T DE 69801797T DE 69801797 T2 DE69801797 T2 DE 69801797T2
- Authority
- DE
- Germany
- Prior art keywords
- production
- acrylic acid
- acrylic
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
- C07C57/04—Acrylic acid; Methacrylic acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/067—Heating or cooling the reactor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00212—Plates; Jackets; Cylinders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00513—Controlling the temperature using inert heat absorbing solids in the bed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
- B01J2208/023—Details
- B01J2208/024—Particulate material
- B01J2208/025—Two or more types of catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
- B01J23/8885—Tungsten containing also molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP29375697A JP3948798B2 (ja) | 1997-10-27 | 1997-10-27 | アクリル酸の製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69801797D1 DE69801797D1 (de) | 2001-10-31 |
DE69801797T2 true DE69801797T2 (de) | 2002-05-23 |
Family
ID=17798828
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69801797T Expired - Lifetime DE69801797T2 (de) | 1997-10-27 | 1998-10-27 | Verfahren zur Herstellung von Acrylsäure |
Country Status (11)
Country | Link |
---|---|
US (1) | US6069271A (de) |
EP (1) | EP0911313B1 (de) |
JP (1) | JP3948798B2 (de) |
KR (1) | KR100407030B1 (de) |
CN (1) | CN1093117C (de) |
BR (1) | BR9804243B1 (de) |
DE (1) | DE69801797T2 (de) |
ID (1) | ID21140A (de) |
MY (1) | MY120056A (de) |
SG (1) | SG70657A1 (de) |
TW (1) | TW460455B (de) |
Families Citing this family (78)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6384274B1 (en) | 1998-09-27 | 2002-05-07 | Rohm And Haas Company | Single reactor process for preparing acrylic acid from propylene having improved capacity |
DE60000708T2 (de) | 1999-06-28 | 2003-07-24 | Rohm & Haas | Verfahren zur Herstellung von (Meth)acrylsäure |
JP3895527B2 (ja) * | 1999-08-31 | 2007-03-22 | 株式会社日本触媒 | 接触気相酸化方法 |
DE19952964A1 (de) * | 1999-11-03 | 2001-05-10 | Basf Ag | Verfahren zur katalytischen Gasphasenoxidation zu (Meth)Acrolein und/oder (Meth)Acrylsäure |
JP3646027B2 (ja) | 1999-11-05 | 2005-05-11 | 株式会社日本触媒 | 接触気相酸化用反応器およびそれを使用した(メタ)アクリル酸の製造方法 |
US6620968B1 (en) | 1999-11-23 | 2003-09-16 | Rohm And Haas Company | High hydrocarbon space velocity process for preparing unsaturated aldehydes and acids |
JP3744750B2 (ja) * | 1999-12-08 | 2006-02-15 | 株式会社日本触媒 | 複合酸化物触媒およびアクリル酸の製造方法 |
JP2001213839A (ja) | 2000-02-03 | 2001-08-07 | Nippon Shokubai Co Ltd | (メタ)アクリル酸の製造方法 |
JP4648515B2 (ja) * | 2000-05-02 | 2011-03-09 | 株式会社日本触媒 | 反応器のスタートアップ方法 |
US7321058B2 (en) | 2000-06-14 | 2008-01-22 | Basf Aktiengesellschaft | Method for producing acrolein and/or acrylic acid |
US6441227B1 (en) | 2000-06-23 | 2002-08-27 | Saudi Basic Industries Corporation | Two stage process for the production of unsaturated carboxylic acids by oxidation of lower unsaturated hydrocarbons |
ZA200200048B (en) | 2001-01-25 | 2002-07-16 | Nippon Catalytic Chem Ind | Process for extracting sold material from shell-and-tube reactor. |
DE10127374A1 (de) * | 2001-06-06 | 2002-12-12 | Basf Ag | Reaktor zum Testen von Katalysatorsystemen |
DE10137534A1 (de) | 2001-08-01 | 2003-02-13 | Basf Ag | Verfahren zur Herstellung von Maleinsäureanhydrid |
DE10148566A1 (de) * | 2001-10-01 | 2003-04-10 | Basf Ag | Verfahren zur Herstellung von Acrylsäure durch heterogen katalysierte Gasphasenoxidation |
AU2002343701A1 (en) | 2001-11-16 | 2003-06-10 | Chevron Phillips Chemical Company Lp | A process to produce a dilute ethylene stream and a dilute propylene stream |
JP4028392B2 (ja) * | 2002-01-11 | 2007-12-26 | 三菱化学株式会社 | 気相接触酸化方法 |
ES2547074T3 (es) | 2002-01-11 | 2015-10-01 | Mitsubishi Chemical Corporation | Método de oxidación catalítica en fase de vapor que usa un reactor de tipo intercambiador de calor multitubular |
WO2003076373A1 (fr) * | 2002-03-11 | 2003-09-18 | Mitsubishi Chemical Corporation | Procede d'oxydation catalytique en phase vapeur |
KR100450234B1 (ko) * | 2002-07-10 | 2004-09-24 | 주식회사 엘지화학 | 개선된 열교환 시스템을 갖는 촉매 산화 반응기 |
US7115776B2 (en) | 2002-07-18 | 2006-10-03 | Basf Aktiengesellschaft | Heterogeneously catalyzed gas-phase partial oxidation of at least one organic compound |
EP1569744A1 (de) * | 2002-12-12 | 2005-09-07 | MAN DWE GmbH | Mantelrohrreaktor mit einem bypass für den wärmeträger |
US20060292046A1 (en) * | 2003-07-31 | 2006-12-28 | Dow Global Technologies Inc. | Oxidation process and reactor with modified feed system |
JP4604607B2 (ja) * | 2003-08-22 | 2011-01-05 | 三菱化学株式会社 | 触媒再生方法 |
KR100553825B1 (ko) | 2003-09-01 | 2006-02-21 | 주식회사 엘지화학 | 고정층 촉매 부분 산화 반응기에서 개선된 제열 시스템을통한 불포화알데히드 및 불포화산의 제조 방법 |
EP1697278B1 (de) * | 2003-12-24 | 2016-06-01 | LG Chem, Ltd. | Verfahren zur herstellung ungesättigter säure in einem festbettreaktor zur katalytischen partiellen oxidation mit verbessertem wärmeregelungssystem |
TWI292755B (en) * | 2003-12-26 | 2008-01-21 | Lg Chemical Ltd | Method of producing unsaturated aldehyde and/or unsaturated fatty acid |
DE102004005863A1 (de) * | 2004-02-05 | 2005-09-08 | Stockhausen Gmbh | Reaktor mit einem einen Einsatz aufweisenden Wärmetauscherbereich |
US20060090398A1 (en) * | 2004-11-02 | 2006-05-04 | Katikaneni Sai P | Pre-processing assembly for pre-processing fuel feedstocks for use in a fuel cell system |
KR100850857B1 (ko) * | 2005-02-01 | 2008-08-06 | 주식회사 엘지화학 | 불포화 지방산의 제조방법 |
KR100714606B1 (ko) * | 2005-02-25 | 2007-05-07 | 주식회사 엘지화학 | 불포화 알데히드 및/또는 불포화 산의 제조방법 |
KR100677051B1 (ko) * | 2005-03-18 | 2007-02-01 | 주식회사 엘지화학 | 올레핀으로부터 불포화산을 제조하는 방법 |
DE102005030414A1 (de) * | 2005-06-30 | 2007-01-18 | Stockhausen Gmbh | Reaktor und Verfahren zur katalytischen Gasphasenreaktion sowie Verfahren zur Applikation eines Katalysators in einem Reaktor |
US7851397B2 (en) * | 2005-07-25 | 2010-12-14 | Saudi Basic Industries Corporation | Catalyst for methacrolein oxidation and method for making and using same |
US7649111B2 (en) * | 2005-07-25 | 2010-01-19 | Saudi Basic Industries Corporation | Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same |
US7649112B2 (en) | 2005-07-25 | 2010-01-19 | Saudi Basic Industries Corporation | Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon |
US7732367B2 (en) * | 2005-07-25 | 2010-06-08 | Saudi Basic Industries Corporation | Catalyst for methacrolein oxidation and method for making and using same |
WO2007088118A1 (de) * | 2006-02-01 | 2007-08-09 | Basf Aktiengesellschaft | Verfahren zur herstellung von vicinalen dioxoverbindungen |
EP2029520B1 (de) * | 2006-02-14 | 2013-07-31 | Basf Se | Verfahren zur herstellung von ethylenaminen und ethanolaminen aus monoethylenglykol (meg) |
EP1986990B1 (de) * | 2006-02-14 | 2013-08-14 | Basf Se | Verfahren zur herstellung von ethylenaminen und ethanolaminen durch hydrierende aminierung von monoethylenglykol und ammoniak in gegenwart eines katalysators |
KR100873271B1 (ko) | 2006-03-13 | 2008-12-11 | 주식회사 엘지화학 | 고정층 촉매 부분산화 반응기에서 고효율의 불포화알데히드 및/또는 불포화 지방산의 제조방법 |
JP5171031B2 (ja) * | 2006-07-19 | 2013-03-27 | 株式会社日本触媒 | 接触気相酸化用反応器およびそれを用いたアクリル酸の製造方法 |
US7897813B2 (en) | 2006-07-19 | 2011-03-01 | Nippon Shokubai Co., Ltd. | Reactor for gas phase catalytic oxidation and a process for producing acrylic acid using it |
JP5311751B2 (ja) * | 2007-03-09 | 2013-10-09 | 株式会社日本触媒 | 固定床反応装置およびその使用方法 |
US7884235B2 (en) | 2006-07-20 | 2011-02-08 | Nippon Shokubai Co., Ltd. | Method for gas-phase catalytic oxidation using a fixed bed reactor |
JP2008024644A (ja) * | 2006-07-20 | 2008-02-07 | Nippon Shokubai Co Ltd | 固定床反応装置およびその使用方法 |
US7799946B2 (en) * | 2007-02-14 | 2010-09-21 | Saudi Basic Industries Corporation | Process for separating methacrolein from methacrylic acid in a gas phase product from the partial oxidation of isobutene |
US8013185B2 (en) | 2007-04-03 | 2011-09-06 | Lg Chem, Ltd. | Method for preparing unsaturated aldehyde and/or unsaturated fatty acid using fixed-bed catalytic partial oxidation reactor |
DE102007025869A1 (de) | 2007-06-01 | 2008-07-03 | Basf Se | Verfahren der Wiederbeschickung der Reaktionsrohre eines Rohrbündelreaktors mit einem neuen Katalysatorfestbett |
DE102007028333A1 (de) | 2007-06-15 | 2008-12-18 | Basf Se | Verfahren zum Einbringen einer wenigstens einer Produktionscharge von ringförmigen Schalenkatalysatoren K entnommenen Teilmenge in ein Reaktionsrohr eines Rohrbündelreaktors |
US20100130777A1 (en) * | 2007-07-27 | 2010-05-27 | Michio Tanimoto | Process for producing acrylic acid by two-stage catalytic vapor-phase oxidation |
EP2327681B1 (de) | 2008-09-22 | 2016-05-04 | Nippon Shokubai Co., Ltd. | Festbettreaktor und verfahren zur herstellung von acrylsäure bei anwendung des reaktors |
JP5232584B2 (ja) * | 2008-09-26 | 2013-07-10 | 東亞合成株式会社 | アクリル酸の製造方法 |
JP5314983B2 (ja) * | 2008-09-26 | 2013-10-16 | 日本化薬株式会社 | メタクリル酸の製造方法 |
JP5548132B2 (ja) * | 2008-09-30 | 2014-07-16 | 株式会社日本触媒 | アクリル酸製造用の触媒および該触媒を用いたアクリル酸の製造方法 |
CN102076411B (zh) * | 2008-09-30 | 2013-02-13 | 株式会社日本触媒 | 用于制备丙烯醛和/或丙烯酸的催化剂以及使用了该催化剂的丙烯醛和/或丙烯酸的制备方法 |
US20100185001A1 (en) | 2009-01-19 | 2010-07-22 | Van Maaren Wouter | Process and apparatus for the production of ethylene oxide |
KR101257411B1 (ko) | 2009-10-09 | 2013-04-23 | 주식회사 엘지화학 | (메트)아크릴산의 제조방법 |
JP2010070579A (ja) * | 2010-01-07 | 2010-04-02 | Nippon Shokubai Co Ltd | アクリル酸の製造方法 |
DE102011011895A1 (de) * | 2011-02-21 | 2012-08-23 | Lurgi Gmbh | Rohrreaktor |
US8921257B2 (en) | 2011-12-02 | 2014-12-30 | Saudi Basic Industries Corporation | Dual function partial oxidation catalyst for propane to acrylic acid conversion |
US8722940B2 (en) | 2012-03-01 | 2014-05-13 | Saudi Basic Industries Corporation | High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins |
US9440903B2 (en) | 2012-09-24 | 2016-09-13 | Arkema Inc. | Shell and tube oxidation reactor with improved resistance to fouling |
DE102013217386A1 (de) * | 2013-09-02 | 2015-03-05 | Evonik Industries Ag | Verfahren zur Herstellung von Acrylsäure |
CN105473539A (zh) | 2014-04-30 | 2016-04-06 | 三菱丽阳株式会社 | (甲基)丙烯酸的制造方法 |
US10035747B2 (en) | 2014-08-01 | 2018-07-31 | Nippon Shokubai Co., Ltd. | Method for recovering inert material and method for producing acrylic acid using inert material recovered by said method |
US10377846B2 (en) | 2014-11-03 | 2019-08-13 | Arkema Inc. | Processes for increasing density of polymer flakes and powders |
EP3341350B1 (de) * | 2015-08-24 | 2019-09-25 | Rohm and Haas Company | Verfahren zur bestimmung der trägheit von materialien zur verwendung in der monomerherstellung |
EP3341351B1 (de) * | 2015-08-24 | 2019-10-02 | Rohm and Haas Company | Verfahren zur bestimmung der trägheit von materialien zur verwendung in der monomerherstellung |
CA2904477A1 (en) * | 2015-09-14 | 2017-03-14 | Nova Chemicals Corporation | Heat dissipating diluent in fixed bed reactors |
CN109153627B (zh) * | 2016-04-21 | 2022-08-02 | 罗门哈斯公司 | 在单体生产中使用大孔惰性材料的方法 |
WO2018145160A1 (en) * | 2017-02-08 | 2018-08-16 | Commonwealth Scientific And Industrial Research Organisation | Isothermal reactor |
KR102625804B1 (ko) | 2019-01-25 | 2024-01-16 | 가부시기가이샤 닛뽕쇼꾸바이 | 노즐, 고형물의 발출 장치, 고형물의 발출 시스템, 및 고형물의 발출 방법 |
KR20220005580A (ko) | 2019-07-09 | 2022-01-13 | 가부시기가이샤 닛뽕쇼꾸바이 | 거리 측정 장치 및 거리 측정 방법 |
EP3770145A1 (de) | 2019-07-24 | 2021-01-27 | Basf Se | Verfahren zur kontinuierlichen herstellung von acrolein oder acrylsäure als zielprodukt aus propen |
CN114746388B (zh) * | 2020-02-05 | 2024-04-12 | 三菱化学株式会社 | (甲基)丙烯醛的制造方法和(甲基)丙烯酸的制造方法 |
EP3892367A1 (de) * | 2020-04-09 | 2021-10-13 | Röhm GmbH | Rohrbündelreaktor und verfahren für die herstellung von methacrylsäure durch die teiloxidierung von methacrolein |
CN116782992A (zh) | 2020-11-19 | 2023-09-19 | 巴斯夫欧洲公司 | α,β-烯键式不饱和羧酸的两阶段制备方法及用于该目的的设备 |
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---|---|---|---|---|
US3147084A (en) * | 1962-03-08 | 1964-09-01 | Shell Oil Co | Tubular catalytic reactor with cooler |
DE2513405C2 (de) * | 1975-03-26 | 1982-10-21 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Acrylsäure durch Oxidation von Propylen mit Sauerstoff enthaltenden Gasen in zwei getrennten Katalysatorstufen, die in einem Röhrenreaktor hintereinander angeordnet sind |
AU529228B2 (en) * | 1977-07-13 | 1983-06-02 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Catalytic vapour phase oxidation |
JPS5673041A (en) * | 1979-11-19 | 1981-06-17 | Mitsubishi Petrochem Co Ltd | Preparation of acrylic acid |
JPH0813778B2 (ja) * | 1988-07-11 | 1996-02-14 | 住友化学工業株式会社 | メタクリル酸の製造方法 |
EP0383224B1 (de) * | 1989-02-17 | 1992-09-16 | Jgc Corporation | Rohrbündelapparat mit einer Zwischenrohrplatte |
DE4023239A1 (de) * | 1990-07-21 | 1992-01-23 | Basf Ag | Verfahren zur katalytischen gasphasenoxidation von propen oder iso-buten zu acrolein oder methacrolein |
-
1997
- 1997-10-27 JP JP29375697A patent/JP3948798B2/ja not_active Expired - Lifetime
-
1998
- 1998-10-23 KR KR10-1998-0044543A patent/KR100407030B1/ko not_active IP Right Cessation
- 1998-10-26 BR BRPI9804243-2A patent/BR9804243B1/pt not_active IP Right Cessation
- 1998-10-27 DE DE69801797T patent/DE69801797T2/de not_active Expired - Lifetime
- 1998-10-27 MY MYPI98004870A patent/MY120056A/en unknown
- 1998-10-27 SG SG1998004291A patent/SG70657A1/en unknown
- 1998-10-27 CN CN98123609A patent/CN1093117C/zh not_active Expired - Lifetime
- 1998-10-27 ID IDP981410A patent/ID21140A/id unknown
- 1998-10-27 EP EP98308754A patent/EP0911313B1/de not_active Expired - Lifetime
- 1998-10-27 TW TW087117799A patent/TW460455B/zh not_active IP Right Cessation
- 1998-10-27 US US09/178,737 patent/US6069271A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
BR9804243B1 (pt) | 2008-11-18 |
KR19990037343A (ko) | 1999-05-25 |
JP3948798B2 (ja) | 2007-07-25 |
CN1215718A (zh) | 1999-05-05 |
MX9808885A (de) | 2000-04-30 |
JPH11130722A (ja) | 1999-05-18 |
SG70657A1 (en) | 2000-02-22 |
MX207634B (de) | 2002-04-29 |
BR9804243A (pt) | 2000-04-11 |
ID21140A (id) | 1999-04-29 |
US6069271A (en) | 2000-05-30 |
DE69801797D1 (de) | 2001-10-31 |
TW460455B (en) | 2001-10-21 |
CN1093117C (zh) | 2002-10-23 |
EP0911313A1 (de) | 1999-04-28 |
MY120056A (en) | 2005-08-30 |
KR100407030B1 (ko) | 2004-03-22 |
EP0911313B1 (de) | 2001-09-26 |
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