DE69717440D1 - Aggregatträger und darauf angebrachte olefinpolymerisationskatalysatoren - Google Patents
Aggregatträger und darauf angebrachte olefinpolymerisationskatalysatorenInfo
- Publication number
- DE69717440D1 DE69717440D1 DE69717440T DE69717440T DE69717440D1 DE 69717440 D1 DE69717440 D1 DE 69717440D1 DE 69717440 T DE69717440 T DE 69717440T DE 69717440 T DE69717440 T DE 69717440T DE 69717440 D1 DE69717440 D1 DE 69717440D1
- Authority
- DE
- Germany
- Prior art keywords
- olefinpolymerization
- aggregatträger
- catalysts
- attached
- olefinpolymerization catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/122—Metal aryl or alkyl compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0045—Drying a slurry, e.g. spray drying
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/12—Making granules characterised by structure or composition
- B29B2009/125—Micropellets, microgranules, microparticles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Catalysts (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US66755396A | 1996-06-21 | 1996-06-21 | |
PCT/US1997/011951 WO1997048742A1 (en) | 1996-06-21 | 1997-06-19 | Aggregate supports and olefin polymerization catalysts supported thereon |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69717440D1 true DE69717440D1 (de) | 2003-01-09 |
DE69717440T2 DE69717440T2 (de) | 2003-10-02 |
Family
ID=24678680
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69717441T Expired - Lifetime DE69717441T2 (de) | 1996-06-21 | 1997-06-19 | Zerbrechlicher sprühgetrockneter agglomeratträger, verfahren zur herstellung solcher träger und darauf angebrachte olefinpolymerisationskatalysatoren |
DE69717440T Expired - Lifetime DE69717440T2 (de) | 1996-06-21 | 1997-06-19 | Aggregatträger und darauf angebrachte olefinpolymerisationskatalysatoren |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69717441T Expired - Lifetime DE69717441T2 (de) | 1996-06-21 | 1997-06-19 | Zerbrechlicher sprühgetrockneter agglomeratträger, verfahren zur herstellung solcher träger und darauf angebrachte olefinpolymerisationskatalysatoren |
Country Status (7)
Country | Link |
---|---|
US (1) | US6329315B1 (de) |
EP (2) | EP0906349B1 (de) |
JP (2) | JP4553986B2 (de) |
KR (1) | KR20000016801A (de) |
AU (2) | AU3655297A (de) |
DE (2) | DE69717441T2 (de) |
WO (2) | WO1997048742A1 (de) |
Families Citing this family (95)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6822062B2 (en) | 1997-03-10 | 2004-11-23 | Eastman Chemical Company | Supported group 8-10 transition metal olefin polymerization catalysts |
US6660677B1 (en) | 1997-03-10 | 2003-12-09 | Eastman Chemical Company | Supported group 8-10 transition metal olefin polymerization catalysts |
US6103658A (en) | 1997-03-10 | 2000-08-15 | Eastman Chemical Company | Olefin polymerization catalysts containing group 8-10 transition metals, processes employing such catalysts and polymers obtained therefrom |
US6200925B1 (en) | 1997-03-13 | 2001-03-13 | Eastman Chemical Company | Catalyst compositions for the polymerization of olefins |
US6245871B1 (en) | 1997-04-18 | 2001-06-12 | Eastman Chemical Company | Group 8-10 transition metal olefin polymerization catalysts |
US6228792B1 (en) | 1998-02-27 | 2001-05-08 | W. R. Grace & Co.-Conn. | Donor-modified olefin polymerization catalysts |
US6117959A (en) * | 1998-09-02 | 2000-09-12 | Eastman Chemical Company | Polyolefin catalysts |
US6413901B1 (en) | 1998-10-16 | 2002-07-02 | Saudi Basic Industries Corporation | Highly active, supported ziegler-natta catalyst systems for olefin polymerization, methods of making and using the same |
WO2000023481A1 (en) * | 1998-10-16 | 2000-04-27 | Saudi Basic Industries Corporation | Process for polymerizing olefins with supported ziegler-natta catalyst systems |
JP2004506745A (ja) | 1999-02-22 | 2004-03-04 | イーストマン ケミカル カンパニー | N−ピロリル置換窒素供与体を含む触媒 |
US6545108B1 (en) | 1999-02-22 | 2003-04-08 | Eastman Chemical Company | Catalysts containing N-pyrrolyl substituted nitrogen donors |
US6620896B1 (en) | 1999-02-23 | 2003-09-16 | Eastman Chemical Company | Mixed olefin polymerization catalysts, processes employing such catalysts, and polymers obtained therefrom |
US6281303B1 (en) | 1999-07-27 | 2001-08-28 | Eastman Chemical Company | Olefin oligomerization and polymerization catalysts |
US6908879B1 (en) * | 1999-09-06 | 2005-06-21 | Nippon Shokubai Co., Ltd. | Ceramic article, carrier for catalyst, methods for production thereof, catalyst for producing ethylene oxide using the carrier, and method for producing ethylene oxide |
US6399535B1 (en) | 1999-11-01 | 2002-06-04 | W. R. Grace & Co.-Conn. | Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation |
US6559090B1 (en) * | 1999-11-01 | 2003-05-06 | W. R. Grace & Co.-Conn. | Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation |
DE10002653A1 (de) | 2000-01-21 | 2001-07-26 | Targor Gmbh | Neuartige Katalysatorsysteme vom Typ der Ziegler-Natta-Katalysatoren |
US7056996B2 (en) | 2000-02-18 | 2006-06-06 | E. I. Du Pont De Nemours And Company | Productivity catalysts and microstructure control |
US6605677B2 (en) | 2000-02-18 | 2003-08-12 | Eastman Chemical Company | Olefin polymerization processes using supported catalysts |
US6579823B2 (en) | 2000-02-18 | 2003-06-17 | Eastman Chemical Company | Catalysts containing per-ortho aryl substituted aryl or heteroaryl substituted nitrogen donors |
WO2002002652A2 (de) | 2000-07-05 | 2002-01-10 | Basell Polyolefine Gmbh | Geträgerter, titanisierter chrom-katalysator und seine verwendung zur herstellung von ethylenhomopolymerisaten und -copolymerisaten |
US6458738B1 (en) * | 2000-09-22 | 2002-10-01 | Union Carbide Chemicals & Plastics Technology Corporation | Spray-drying compositions and methods of spray-drying |
EP1240943A1 (de) * | 2000-10-21 | 2002-09-18 | Degussa AG | Katalysatorträger |
US6706891B2 (en) | 2000-11-06 | 2004-03-16 | Eastman Chemical Company | Process for the preparation of ligands for olefin polymerization catalysts |
US6897273B2 (en) * | 2000-12-04 | 2005-05-24 | Univation Technologies, Llc | Catalyst composition, method of polymerization and polymer therefrom |
DK1401890T3 (da) * | 2001-04-30 | 2011-03-14 | Grace W R & Co | Chrombærer-agglomerat-overgangsmetalpolymerisationskatalysatorer og fremgangsmåder til anvendelse heraf |
EP1453868A2 (de) | 2001-04-30 | 2004-09-08 | W. R. Grace & Co.-Conn | Koordinationskatalysatorsysteme unter verwendung von chromträgeragglomerat und verfahren zu ihrer herstellung |
ATE337343T1 (de) | 2001-04-30 | 2006-09-15 | Grace W R & Co | Geträgerte dualübergangsmetallkatalysatorsysteme |
US6943224B2 (en) | 2001-04-30 | 2005-09-13 | W. R. Grace & Co.-Conn. | Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby |
WO2002088196A1 (en) * | 2001-04-30 | 2002-11-07 | W.R. Grace & Co.-Conn. | Heterogeneous chromium catalysts and processes of polymerization of olefins using same |
EP1401889B1 (de) * | 2001-04-30 | 2010-06-09 | W.R. Grace & Co.-Conn. | Verfahren zur herstellung von geträgerten übergangsmetallpolymerisationskatalysatoren und daraus gebildete zusammensetzungen |
ATE356102T1 (de) * | 2001-07-02 | 2007-03-15 | Exxonmobil Chem Patents Inc | Inhibierung der katalysatorverkokung bei der herstellung eines olefins |
DE10163154A1 (de) * | 2001-12-20 | 2003-07-03 | Basell Polyolefine Gmbh | Pyrogene Kieselsäuren enthaltender Katalysatorfeststoff zur Olefinpolymerisation |
US7271123B2 (en) * | 2002-03-20 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Molecular sieve catalyst composition, its making and use in conversion process |
US6872680B2 (en) * | 2002-03-20 | 2005-03-29 | Exxonmobil Chemical Patents Inc. | Molecular sieve catalyst composition, its making and use in conversion processes |
EP1509552A1 (de) * | 2002-06-03 | 2005-03-02 | Univation Technologies LLC | Feste, feinteilige, sprühgetrocknete, heterogene katalysatorzusammensetzung |
US7153915B2 (en) | 2003-01-15 | 2006-12-26 | Rohm And Haas Company | Precision fragmentation assemblages and olefin polymerization catalysts made therefrom |
WO2004074329A1 (fr) * | 2003-02-24 | 2004-09-02 | China Petroleum & Chemical Corporation | Support complexe pour catalyseur de polymerisation du propylene, composant de catalyseur et catalyseur contenant ce composant |
WO2004092232A1 (en) * | 2003-04-15 | 2004-10-28 | Basell Poliolefine Italia, s.r.l. | Ziegler-natta catalyst systems and process for their preparation |
US7341977B2 (en) * | 2003-06-20 | 2008-03-11 | Nanoscale Corporation | Method of sorbing sulfur compounds using nanocrystalline mesoporous metal oxides |
US6962889B2 (en) * | 2004-01-28 | 2005-11-08 | Engelhard Corporation | Spherical catalyst for olefin polymerization |
DE102004006113A1 (de) * | 2004-02-06 | 2005-08-25 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von Trägern für Katalysatoren |
DE102004006104A1 (de) * | 2004-02-06 | 2005-08-25 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von geträgerten Katalysatoren für die Polymerisation |
KR101227198B1 (ko) * | 2004-06-15 | 2013-01-28 | 더블유.알. 그레이스 앤드 캄파니-콘. | 실리카의 화학-보조 분쇄 |
DE102004028765A1 (de) | 2004-06-16 | 2006-01-05 | Basell Polyolefine Gmbh | Chrom und Zirkon enthaltender Katalysator für die Polymerisation und/oder Copolymerisation von Olefinen |
JP2008502759A (ja) * | 2004-06-16 | 2008-01-31 | バーゼル・ポリオレフィン・ゲーエムベーハー | オレフィンの重合及び/又は共重合用クロム系触媒の製造法 |
US8173569B2 (en) * | 2004-08-09 | 2012-05-08 | Union Carbide Chemicals & Plastics Technology Llc | Robust spray-dried ziegler-natta procatalyst and polymerization process employing same |
US20060266707A1 (en) * | 2005-05-26 | 2006-11-30 | Fisher Jon R | Drying method for macroporous polymers, and method of preparation and use of macroporous polymers made using the method |
US8318627B2 (en) * | 2005-08-10 | 2012-11-27 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Process for preparation of a catalyst carrier |
DE102005040286A1 (de) * | 2005-08-25 | 2007-03-01 | Basf Ag | Mechanisch stabiler Katalysator auf Basis von alpha-Aluminiumoxid |
US20070049711A1 (en) * | 2005-09-01 | 2007-03-01 | Chi-I Kuo | Catalyst compositions comprising support materials having an improved particle-size distribution |
JP4794246B2 (ja) * | 2005-09-13 | 2011-10-19 | 日本ポリプロ株式会社 | オレフィン重合用触媒担体の製造方法、それを用いたオレフィン重合用触媒成分 |
DE102005061965A1 (de) * | 2005-12-23 | 2007-07-05 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Oxidische Agglomeratpartikel, Verfahren zur Herstellung von Nanokompositen sowie deren Verwendung |
EP1803743B1 (de) * | 2005-12-30 | 2016-08-10 | Borealis Technology Oy | Katalysatorpartikel |
DE102006004705A1 (de) | 2006-01-31 | 2007-08-02 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von Ethylenpolymerisaten für Blasfolien |
DE102006058800A1 (de) * | 2006-12-13 | 2008-06-19 | Wacker Chemie Ag | Verfahren zur Herstellung von Katalysatoren und deren Verwendung für die Gasphasenoxidation von Olefinen |
AU2008343844A1 (en) * | 2007-12-20 | 2009-07-09 | W.R. Grace & Co. - Conn. | Process for preparing high attrition resistant inorganic compositions and compositions prepared therefrom |
JP5847586B2 (ja) | 2008-12-31 | 2016-01-27 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | 置換された1,2−フェニレン芳香族ジエステルの内部供与体を有するプロ触媒組成物及び方法 |
US9365664B2 (en) | 2009-01-29 | 2016-06-14 | W. R. Grace & Co. -Conn. | Catalyst on silica clad alumina support |
US8673806B2 (en) | 2009-01-29 | 2014-03-18 | W.R. Grace & Co.-Conn. | Catalyst on silica clad alumina support |
DE102010019148A1 (de) | 2010-05-03 | 2011-11-03 | Merck Patent Gmbh | Katalysatorträger |
JP5358556B2 (ja) * | 2010-12-24 | 2013-12-04 | 日本ポリエチレン株式会社 | エチレン重合用触媒及びそれを用いたエチレン系重合体の製造方法 |
WO2012138582A1 (en) * | 2011-04-02 | 2012-10-11 | Pulstar International Corporation | Pulse dry cooking and hydration process |
CN103788235B (zh) * | 2012-10-26 | 2016-06-29 | 中国石油化工股份有限公司 | 一种负载型茂金属催化剂用载体及茂金属催化剂 |
BR112015002630A2 (pt) * | 2013-10-17 | 2018-05-22 | Petroleo Brasileiro S A / Petrobras | método de preparo de catalisadores ziegler-natta bissuportados |
US10294316B2 (en) | 2015-06-05 | 2019-05-21 | Exxonmobil Chemical Patents Inc. | Silica supports with high aluminoxane loading capability |
US9725537B2 (en) | 2015-06-05 | 2017-08-08 | Exxonmobil Chemical Patents Inc. | High activity catalyst supportation |
US10329360B2 (en) | 2015-06-05 | 2019-06-25 | Exxonmobil Chemical Patents Inc. | Catalyst system comprising supported alumoxane and unsupported alumoxane particles |
US9725569B2 (en) | 2015-06-05 | 2017-08-08 | Exxonmobil Chemical Patents Inc. | Porous propylene polymers |
EP3303422B1 (de) | 2015-06-05 | 2021-03-17 | ExxonMobil Chemical Patents Inc. | Herstellung von heterophasischen polymeren in gas- oder schlämmephase |
US10280235B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers |
US10077325B2 (en) | 2015-06-05 | 2018-09-18 | Exxonmobil Chemical Patents Inc. | Silica supports with high aluminoxane loading capability |
US9738779B2 (en) | 2015-06-05 | 2017-08-22 | Exxonmobil Chemical Patents Inc. | Heterophasic copolymers and sequential polymerization |
WO2016196331A1 (en) | 2015-06-05 | 2016-12-08 | Exxonmobil Chemical Patents Inc. | Supported metallocene catalyst systems for polymerization |
US9920176B2 (en) * | 2015-06-05 | 2018-03-20 | Exxonmobil Chemical Patents Inc. | Single site catalyst supportation |
US10280233B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst systems and methods of making and using the same |
US9809664B2 (en) * | 2015-06-05 | 2017-11-07 | Exxonmobil Chemical Patents Inc. | Bimodal propylene polymers and sequential polymerization |
WO2016196334A1 (en) | 2015-06-05 | 2016-12-08 | Exxonmobil Chemical Patents Inc. | Single reactor production of polymers in gas or slurry phase |
CN107922527A (zh) | 2015-08-31 | 2018-04-17 | 埃克森美孚化学专利公司 | 用于聚烯烃反应的具有悬垂烯烃的铝烷基 |
US10618988B2 (en) | 2015-08-31 | 2020-04-14 | Exxonmobil Chemical Patents Inc. | Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof |
CN107921424A (zh) | 2015-08-31 | 2018-04-17 | 埃克森美孚化学专利公司 | 粘土上的具有悬垂烯烃的烷基铝 |
US9982067B2 (en) | 2015-09-24 | 2018-05-29 | Exxonmobil Chemical Patents Inc. | Polymerization process using pyridyldiamido compounds supported on organoaluminum treated layered silicate supports |
US9975973B2 (en) | 2015-10-02 | 2018-05-22 | Exxonmobil Chemical Patents Inc. | Asymmetric fluorenyl-substituted salan catalysts |
US9994657B2 (en) | 2015-10-02 | 2018-06-12 | Exxonmobil Chemical Patents Inc. | Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports |
US9982076B2 (en) | 2015-10-02 | 2018-05-29 | Exxonmobil Chemical Patents Inc. | Supported bis phenolate transition metals complexes, production and use thereof |
US10414887B2 (en) | 2015-10-02 | 2019-09-17 | Exxonmobil Chemical Patents Inc. | Supported catalyst systems and methods of using same |
US10000593B2 (en) | 2015-10-02 | 2018-06-19 | Exxonmobil Chemical Patents Inc. | Supported Salan catalysts |
US9994658B2 (en) | 2015-10-02 | 2018-06-12 | Exxonmobil Chemical Patents Inc. | Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports |
US11059918B2 (en) | 2016-05-27 | 2021-07-13 | Exxonmobil Chemical Patents Inc. | Metallocene catalyst compositions and polymerization process therewith |
US10562987B2 (en) | 2016-06-30 | 2020-02-18 | Exxonmobil Chemical Patents Inc. | Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents |
WO2018067367A1 (en) | 2016-10-06 | 2018-04-12 | W.R. Grace & Co.-Conn. | Procatalyst composition made with a combination of internal electron donors |
US10626200B2 (en) | 2017-02-28 | 2020-04-21 | Exxonmobil Chemical Patents Inc. | Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof |
WO2018160278A1 (en) | 2017-03-01 | 2018-09-07 | Exxonmobil Chemical Patents Inc. | Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof |
MX2022013280A (es) | 2020-04-30 | 2022-11-30 | Dow Global Technologies Llc | Sistemas (pro)catalizadores ziegler-natta elaborados con compuesto azaheterocilico. |
CN113637100A (zh) * | 2021-09-14 | 2021-11-12 | 无锡玖汇科技有限公司 | 一种高氯化镁含量的硅胶复合载体 |
Family Cites Families (43)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2288873A (en) * | 1939-12-30 | 1942-07-07 | Standard Oil Co | Polymerization of olefins |
US2470410A (en) * | 1946-04-09 | 1949-05-17 | Standard Oil Dev Co | Preparation of silica magnesia catalysts |
US2529283A (en) * | 1946-06-20 | 1950-11-07 | Standard Oil Dev Co | Preparation of a silica-aluminamagnesia catalyst |
US2532525A (en) * | 1947-07-25 | 1950-12-05 | Universal Oil Prod Co | Preparation of a hydrocarbon conversion catalyst |
US2958648A (en) * | 1956-11-27 | 1960-11-01 | Nalco Chemical Co | Conversion of hydrocarbons with a synthetic silica-alumina-magnesia catalyst composite |
US2988521A (en) * | 1957-11-19 | 1961-06-13 | American Cyanamid Co | Process for preparing a silicamagnesia catalyst |
NL231551A (de) * | 1958-09-22 | |||
US3607777A (en) | 1968-06-18 | 1971-09-21 | Grace W R & Co | Process for preparing microspheroidal desiccant silica gel |
US3887494A (en) | 1970-11-12 | 1975-06-03 | Phillips Petroleum Co | Olefin polymerization catalyst |
US3965042A (en) | 1973-12-07 | 1976-06-22 | W. R. Grace & Co. | Formation of alumina-containing particles with aluminum hydroxide binder |
JPS524490A (en) * | 1975-06-27 | 1977-01-13 | Kuraray Co Ltd | Catalyst carrier |
US4022714A (en) | 1975-07-17 | 1977-05-10 | W. R. Grace & Co. | Silica hydrosol bound cracking catalysts |
FR2332234A1 (fr) | 1975-11-20 | 1977-06-17 | Rhone Poulenc Ind | Corps siliceux agglomeres |
US4070286A (en) | 1976-06-15 | 1978-01-24 | E. I. Du Pont De Nemours And Company | Macroporous microspheroids and a process for their manufacture |
NL7707961A (nl) | 1977-07-18 | 1979-01-22 | Stamicarbon | Werkwijze ter bereiding van poreus, zuiver siliciumdioxyde. |
US4131542A (en) | 1977-07-19 | 1978-12-26 | E. I. Dupont De Nemours And Company | Spray dried silica for chromatography |
US4257874A (en) | 1977-08-31 | 1981-03-24 | E. I. Du Pont De Nemours And Company | Petroleum refinery processes using catalyst of aluminosilicate sols and powders |
DE3174832D1 (en) | 1980-03-24 | 1986-07-24 | Ici Plc | Preparation of a dried transition metal product |
US4548912A (en) | 1980-04-14 | 1985-10-22 | Ashland Oil, Inc. | Microspherical catalysts |
JPS6011718A (ja) | 1983-06-29 | 1985-01-22 | Isuzu Motors Ltd | 自動クラツチの制御装置 |
US4657880A (en) | 1985-03-18 | 1987-04-14 | Corning Glass Works | Preparation of high surface area agglomerates for catalyst support and preparation of monolithic support structures containing them |
FR2584698B1 (fr) | 1985-07-15 | 1990-05-18 | Rhone Poulenc Spec Chim | Procede de preparation de particules de silice spheroidales |
US4677084A (en) | 1985-11-27 | 1987-06-30 | E. I. Du Pont De Nemours And Company | Attrition resistant catalysts, catalyst precursors and catalyst supports and process for preparing same |
JPH0725817B2 (ja) | 1986-04-23 | 1995-03-22 | 日本石油株式会社 | オレフイン重合用触媒 |
US4902666A (en) | 1986-07-02 | 1990-02-20 | Chevron Research Company | Process for the manufacture of spheroidal bodies by selective agglomeration |
JPH0699135B2 (ja) * | 1989-02-20 | 1994-12-07 | 富士デヴィソン株式会社 | 球状シリカゲルの製造法 |
US5352645A (en) | 1989-04-14 | 1994-10-04 | E. I. Du Pont De Nemours And Company | Silica microspheres, method of improving attrition resistance and use |
US5128114A (en) | 1989-04-14 | 1992-07-07 | E. I. Du Pont De Nemours And Company | Silica microspheres, method of improving attrition resistance |
US5108975A (en) | 1991-01-28 | 1992-04-28 | Phillips Petroleum Company | Composition and method of making high porosity, high strength compositions |
DE4132230A1 (de) | 1991-09-27 | 1993-04-01 | Grace Gmbh | Verwendung von kugelfoermigem siliciumdioxid |
BE1005718A3 (fr) * | 1992-03-10 | 1993-12-28 | Solvay | Procede pour la fabrication d'une poudre microspheroidale a faible dispersite, poudre microspheroidale a faible dispersite ainsi obtenue, catalyseurs pour la polymerisation d'alpha-olefines et procede de polymerisation d'alpha-olefines. |
GB9210265D0 (en) * | 1992-05-13 | 1992-07-01 | Unilever Plc | Catalysts and catalyst supports |
US5552361A (en) | 1993-11-04 | 1996-09-03 | W. R. Grace & Co.-Conn. | Aluminum phosphate composition with high pore volume and large pore diameter, process for its production and use thereof |
US5403809A (en) | 1992-12-21 | 1995-04-04 | W. R. Grace & Co.-Conn. | Composite inorganic supports containing carbon for bioremediation |
US5403799A (en) | 1992-12-21 | 1995-04-04 | W. R. Grace & Co.-Conn. | Process upset-resistant inorganic supports for bioremediation |
US5302566A (en) | 1993-01-25 | 1994-04-12 | E. I. Du Pont De Nemours And Company | Process for preparing attrition resistant catalysts |
US5604170A (en) | 1993-02-23 | 1997-02-18 | Nippon Oil Company, Limited | Solid catalyst components for olefin polemerization and use thereof |
JP3454554B2 (ja) * | 1993-12-28 | 2003-10-06 | 水澤化学工業株式会社 | 非晶質シリカ粒状体及びその製法 |
US5661097A (en) | 1994-08-12 | 1997-08-26 | The Dow Chemical Company | Supported olefin polymerization catalyst |
GB9417059D0 (en) * | 1994-08-24 | 1994-10-12 | Bp Chem Int Ltd | Oxide catalysts |
US5714424A (en) | 1995-01-09 | 1998-02-03 | W. R. Grace & Co.-Conn. | Multi-component polyolefin catalysts |
DE19516253A1 (de) | 1995-04-26 | 1996-10-31 | Grace Gmbh | Mattierungsmittel auf Basis von aggregiertem Siliciumdioxid mit verbesserter Effizienz |
ES2114335T3 (es) | 1995-08-09 | 1998-05-16 | Basf Ag | Sistemas catalizadores del tipo de los catalizadores de ziegler-natta. |
-
1997
- 1997-06-19 EP EP97932564A patent/EP0906349B1/de not_active Expired - Lifetime
- 1997-06-19 US US08/878,476 patent/US6329315B1/en not_active Expired - Lifetime
- 1997-06-19 AU AU36552/97A patent/AU3655297A/en not_active Abandoned
- 1997-06-19 EP EP97933346A patent/EP0906350B1/de not_active Expired - Lifetime
- 1997-06-19 WO PCT/US1997/011951 patent/WO1997048742A1/en not_active Application Discontinuation
- 1997-06-19 AU AU35992/97A patent/AU3599297A/en not_active Abandoned
- 1997-06-19 JP JP50362598A patent/JP4553986B2/ja not_active Expired - Lifetime
- 1997-06-19 JP JP10503624A patent/JP2000513402A/ja not_active Ceased
- 1997-06-19 DE DE69717441T patent/DE69717441T2/de not_active Expired - Lifetime
- 1997-06-19 WO PCT/US1997/011953 patent/WO1997048743A1/en active IP Right Grant
- 1997-06-19 KR KR1019980710413A patent/KR20000016801A/ko not_active Application Discontinuation
- 1997-06-19 DE DE69717440T patent/DE69717440T2/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
AU3599297A (en) | 1998-01-07 |
JP2000513402A (ja) | 2000-10-10 |
US6329315B1 (en) | 2001-12-11 |
KR20000016801A (ko) | 2000-03-25 |
DE69717441D1 (de) | 2003-01-09 |
JP4553986B2 (ja) | 2010-09-29 |
EP0906349A1 (de) | 1999-04-07 |
EP0906350A1 (de) | 1999-04-07 |
EP0906350B1 (de) | 2002-11-27 |
EP0906349B1 (de) | 2002-11-27 |
DE69717441T2 (de) | 2003-10-02 |
DE69717440T2 (de) | 2003-10-02 |
JP2000513403A (ja) | 2000-10-10 |
WO1997048743A1 (en) | 1997-12-24 |
WO1997048742A1 (en) | 1997-12-24 |
AU3655297A (en) | 1998-01-07 |
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