DE69621584T3 - Chelatbildner enthaltender sprühgetrockneter Waschmittelbestandteil - Google Patents
Chelatbildner enthaltender sprühgetrockneter Waschmittelbestandteil Download PDFInfo
- Publication number
- DE69621584T3 DE69621584T3 DE69621584T DE69621584T DE69621584T3 DE 69621584 T3 DE69621584 T3 DE 69621584T3 DE 69621584 T DE69621584 T DE 69621584T DE 69621584 T DE69621584 T DE 69621584T DE 69621584 T3 DE69621584 T3 DE 69621584T3
- Authority
- DE
- Germany
- Prior art keywords
- spray
- dried
- weight
- alkaline earth
- complexing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002738 chelating agent Substances 0.000 title claims description 4
- 239000003599 detergent Substances 0.000 title description 7
- 239000004615 ingredient Substances 0.000 title 1
- 239000008139 complexing agent Substances 0.000 claims description 14
- 150000003839 salts Chemical class 0.000 claims description 9
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 8
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 claims description 8
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 7
- -1 alkaline earth metal sulfate Chemical class 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphonic acid group Chemical group P(O)(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- VKZRWSNIWNFCIQ-UHFFFAOYSA-N 2-[2-(1,2-dicarboxyethylamino)ethylamino]butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NCCNC(C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 3
- 230000000536 complexating effect Effects 0.000 claims description 3
- 239000001384 succinic acid Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical class [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000008187 granular material Substances 0.000 description 3
- 235000019341 magnesium sulphate Nutrition 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- BCXBKOQDEOJNRH-UHFFFAOYSA-N NOP(O)=O Chemical class NOP(O)=O BCXBKOQDEOJNRH-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- VKZRWSNIWNFCIQ-WDSKDSINSA-N (2s)-2-[2-[[(1s)-1,2-dicarboxyethyl]amino]ethylamino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)NCCN[C@H](C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-WDSKDSINSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 230000010736 Chelating Activity Effects 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- PTMHPRAIXMAOOB-UHFFFAOYSA-N phosphoramidic acid Chemical class NP(O)(O)=O PTMHPRAIXMAOOB-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/02—Preparation in the form of powder by spray drying
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/364—Organic compounds containing phosphorus containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3245—Aminoacids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/36—Organic compounds containing phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP96200801A EP0796911B2 (en) | 1996-03-23 | 1996-03-23 | Spray-dried detergent component comprising chelant |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE69621584D1 DE69621584D1 (de) | 2002-07-11 |
| DE69621584T2 DE69621584T2 (de) | 2003-01-16 |
| DE69621584T3 true DE69621584T3 (de) | 2006-06-01 |
Family
ID=8223811
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69621584T Expired - Lifetime DE69621584T3 (de) | 1996-03-23 | 1996-03-23 | Chelatbildner enthaltender sprühgetrockneter Waschmittelbestandteil |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP0796911B2 (ja) |
| JP (1) | JP3093283B2 (ja) |
| CN (1) | CN1119403C (ja) |
| AR (1) | AR006349A1 (ja) |
| AT (1) | ATE218611T1 (ja) |
| BR (1) | BR9708333A (ja) |
| CA (1) | CA2249268C (ja) |
| DE (1) | DE69621584T3 (ja) |
| DK (1) | DK0796911T3 (ja) |
| ES (1) | ES2177718T5 (ja) |
| PT (1) | PT796911E (ja) |
| WO (1) | WO1997035953A1 (ja) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2329188A (en) * | 1997-09-11 | 1999-03-17 | Procter & Gamble | Detergent composition containing a stabilised percarboxylic bleaching system |
| BR9914297B1 (pt) * | 1998-08-27 | 2010-10-19 | processo para produzir uma composição quelante sólida estável de livre escoamento, e quelante de aminocarboxilato estável sólido de livre escoamento. | |
| AU1311200A (en) * | 1998-10-05 | 2000-04-26 | Procter & Gamble Company, The | Process for delivering chelant agglomerate into detergent composition for improving its storage stability, flowability and scoopability |
| US6451224B1 (en) | 1999-07-21 | 2002-09-17 | The Dow Chemical Company | Stable free-flowing solid chelants |
| US6635612B1 (en) | 1999-10-01 | 2003-10-21 | The Procter & Gamble Company | Process for delivering chelant agglomerate into detergent composition for improving its storage stability, flowability and scoopability |
| EP1281676A1 (en) * | 2001-08-01 | 2003-02-05 | NV Solutia Europe S.A. | Solid free-flowing phosphonate composition and method of use |
| US7423005B2 (en) * | 2003-11-20 | 2008-09-09 | Ecolab Inc. | Binding agent for solidification matrix |
| EP2380962B1 (en) * | 2010-04-23 | 2016-03-30 | The Procter and Gamble Company | Particle |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE374762B (ja) † | 1968-03-04 | 1975-03-17 | Monsanto Co | |
| US3717589A (en) † | 1970-09-17 | 1973-02-20 | Monsanto Co | Sodium nitrilotriacetate and processes for producing same |
| IL47489A (en) * | 1974-11-04 | 1978-07-31 | Witco Chemical Corp | Non-caking linear alkyl aryl sulfonate detergent compositions |
| GB1513550A (en) † | 1975-05-05 | 1978-06-07 | Unilever Ltd | Hard surface cleaning compositions |
| US4105573A (en) † | 1976-10-01 | 1978-08-08 | The Procter & Gamble Company | Dishwasher detergent composition |
| CH642678A5 (de) * | 1979-04-06 | 1984-04-30 | Unilever Nv | Bleich- und reinigungsmittel. |
| GR75249B (ja) * | 1980-05-10 | 1984-07-13 | Procter & Gamble | |
| GB8504489D0 (en) † | 1985-02-21 | 1985-03-27 | Monsanto Europe Sa | Aminomethylenephosphonate compositions |
| GB8529409D0 (en) * | 1985-11-29 | 1986-01-08 | Monsanto Europe Sa | Aminomethylenephosphonate compositions |
| CA2096255C (en) * | 1990-11-14 | 1998-01-20 | Jeffrey D. Painter | Nonphosphated automatic dishwashing compositions with oxygen bleach systems and process for their preparation |
| FR2677370A1 (fr) * | 1991-06-05 | 1992-12-11 | Nln Sa | Agent sequestrant pour compositions detergentes liquides; compositions detergeantes liquides contenant ledit agent sequestrant. |
| EP0678572A1 (en) † | 1994-04-20 | 1995-10-25 | The Procter & Gamble Company | Detergent powder compositions |
-
1996
- 1996-03-23 EP EP96200801A patent/EP0796911B2/en not_active Expired - Lifetime
- 1996-03-23 ES ES96200801T patent/ES2177718T5/es not_active Expired - Lifetime
- 1996-03-23 PT PT96200801T patent/PT796911E/pt unknown
- 1996-03-23 DE DE69621584T patent/DE69621584T3/de not_active Expired - Lifetime
- 1996-03-23 AT AT96200801T patent/ATE218611T1/de not_active IP Right Cessation
- 1996-03-23 DK DK96200801T patent/DK0796911T3/da active
-
1997
- 1997-03-21 CA CA002249268A patent/CA2249268C/en not_active Expired - Fee Related
- 1997-03-21 AR ARP970101151A patent/AR006349A1/es active IP Right Grant
- 1997-03-21 BR BR9708333A patent/BR9708333A/pt not_active IP Right Cessation
- 1997-03-21 JP JP09534515A patent/JP3093283B2/ja not_active Expired - Lifetime
- 1997-03-21 CN CN97194764A patent/CN1119403C/zh not_active Expired - Lifetime
- 1997-03-21 WO PCT/US1997/004651 patent/WO1997035953A1/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| JP3093283B2 (ja) | 2000-10-03 |
| BR9708333A (pt) | 1999-08-03 |
| CA2249268A1 (en) | 1997-10-02 |
| CN1219197A (zh) | 1999-06-09 |
| ATE218611T1 (de) | 2002-06-15 |
| AR006349A1 (es) | 1999-08-25 |
| EP0796911B2 (en) | 2005-07-13 |
| ES2177718T5 (es) | 2005-12-01 |
| DE69621584D1 (de) | 2002-07-11 |
| JPH11507098A (ja) | 1999-06-22 |
| CA2249268C (en) | 2002-02-05 |
| WO1997035953A1 (en) | 1997-10-02 |
| PT796911E (pt) | 2002-10-31 |
| DE69621584T2 (de) | 2003-01-16 |
| CN1119403C (zh) | 2003-08-27 |
| EP0796911A1 (en) | 1997-09-24 |
| ES2177718T3 (es) | 2002-12-16 |
| DK0796911T3 (da) | 2002-09-30 |
| EP0796911B1 (en) | 2002-06-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8363 | Opposition against the patent | ||
| 8366 | Restricted maintained after opposition proceedings |