DE69618032T2 - Estersynthese - Google Patents

Estersynthese

Info

Publication number
DE69618032T2
DE69618032T2 DE69618032T DE69618032T DE69618032T2 DE 69618032 T2 DE69618032 T2 DE 69618032T2 DE 69618032 T DE69618032 T DE 69618032T DE 69618032 T DE69618032 T DE 69618032T DE 69618032 T2 DE69618032 T2 DE 69618032T2
Authority
DE
Germany
Prior art keywords
estersynthese
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69618032T
Other languages
English (en)
Other versions
DE69618032D1 (de
Inventor
Martin Philip Atkins
Bhushan Sharma
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GBGB9515813.5A external-priority patent/GB9515813D0/en
Priority claimed from GBGB9603770.0A external-priority patent/GB9603770D0/en
Priority claimed from GBGB9613227.9A external-priority patent/GB9613227D0/en
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Publication of DE69618032D1 publication Critical patent/DE69618032D1/de
Application granted granted Critical
Publication of DE69618032T2 publication Critical patent/DE69618032T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
DE69618032T 1995-08-02 1996-07-22 Estersynthese Expired - Lifetime DE69618032T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB9515813.5A GB9515813D0 (en) 1995-08-02 1995-08-02 Ester synthesis
GBGB9603770.0A GB9603770D0 (en) 1996-02-22 1996-02-22 Ester synthesis
GBGB9613227.9A GB9613227D0 (en) 1996-06-25 1996-06-25 Ester synthesis

Publications (2)

Publication Number Publication Date
DE69618032D1 DE69618032D1 (de) 2002-01-24
DE69618032T2 true DE69618032T2 (de) 2002-06-27

Family

ID=27267836

Family Applications (2)

Application Number Title Priority Date Filing Date
DE69607536T Expired - Lifetime DE69607536T2 (de) 1995-08-02 1996-07-22 Estersynthese
DE69618032T Expired - Lifetime DE69618032T2 (de) 1995-08-02 1996-07-22 Estersynthese

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE69607536T Expired - Lifetime DE69607536T2 (de) 1995-08-02 1996-07-22 Estersynthese

Country Status (11)

Country Link
US (2) US5861530A (de)
EP (2) EP0959064B1 (de)
JP (2) JP3911048B2 (de)
KR (1) KR100293337B1 (de)
CN (1) CN1085197C (de)
CA (1) CA2182558C (de)
DE (2) DE69607536T2 (de)
MY (1) MY116546A (de)
SA (1) SA96170381B1 (de)
SG (1) SG49973A1 (de)
TW (1) TW338764B (de)

Families Citing this family (119)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69607536T2 (de) 1995-08-02 2001-02-08 Bp Chem Int Ltd Estersynthese
US6018076A (en) * 1997-09-30 2000-01-25 Arco Chemical Technology, L.P. Ester preparation
DE69804751T2 (de) 1997-12-23 2002-11-21 Bp Chem Int Ltd Estersynthese
US6060419A (en) * 1998-01-05 2000-05-09 Sunoco, Inc. (R&M) Wells-Dawson type heteropolyacids, their preparation and use as oxidation catalysts
EG21992A (en) * 1998-01-22 2002-05-31 Bp Chem Int Ltd Ester synthesis
GB9815135D0 (en) * 1998-07-14 1998-09-09 Bp Chem Int Ltd Ester synthesis
GB9815117D0 (en) * 1998-07-14 1998-09-09 Bp Chem Int Ltd Ester synthesis
GB9902676D0 (en) * 1999-02-06 1999-03-31 Bp Chem Int Ltd Silica supported catalysts
EP1038578A3 (de) * 1999-03-26 2002-01-30 President of Shizuoka University, a government agency of Japan Verfahren zur direkten Herstellung von Formaldehyd aus Methan
EP1200190B1 (de) * 1999-06-03 2007-08-15 Showa Denko K.K. Verfahren für die herstellung von fettsäureestern
US6818790B1 (en) * 1999-10-05 2004-11-16 Showa Denko K.K. Process for producing mixed gas of lower olefin and lower aliphatic carboxylic acid, and process for producing lower aliphatic ester using the mixed gas
US6849759B1 (en) 1999-10-25 2005-02-01 Showa Denko K.K. Process for producing esters
BR0014991A (pt) * 1999-10-25 2002-06-18 Showa Denko Kk Processo para a produção de ésteres
GB0015568D0 (en) * 2000-06-27 2000-08-16 Bp Chem Int Ltd Ester synthesis
JP2002316048A (ja) * 2001-02-13 2002-10-29 Showa Denko Kk 低級脂肪族カルボン酸エステル製造用触媒に用いる担体、それを用いた低級脂肪族カルボン酸エステル製造用触媒、その触媒の製造方法およびその触媒を用いた低級脂肪族カルボン酸エステルの製造方法
US20040242918A1 (en) * 2000-06-27 2004-12-02 Showa Denko K.K Support and catalyst for use in producing lower aliphatic carboxylic acid ester, process for producing the catalyst and process for producing lower aliphatic carboxylic acid ester using the catalyst
DE60109449D1 (de) * 2000-06-27 2005-04-21 Showa Denko Kk Katalysator brauchbar für die herstellung von niedrigem aliphatischem carbonsäureester,verfahren für die herstellung des katalysators und verfahren für die herstellung der niedrigen aliphatischen carbonsäureesster unter verwendung des katalysators
EP1353749A2 (de) * 2000-09-07 2003-10-22 Showa Denko K.K. Katalysator zur herstellung von niederen aliphatischen carbonsäureestern
JP2002079088A (ja) * 2000-09-07 2002-03-19 Showa Denko Kk 低級脂肪族カルボン酸エステル製造用触媒、該触媒の製造方法、及び該触媒を用いた低級脂肪族カルボン酸エステルの製造方法
BR0113738A (pt) * 2000-09-07 2003-07-22 Showa Denko Kk Catalizador heteropoliácido para produção de éster de ácido carboxìlico alifático inferior
JP4620236B2 (ja) * 2000-09-26 2011-01-26 昭和電工株式会社 低級脂肪族カルボン酸エステルの製造方法
US6696598B2 (en) 2000-09-26 2004-02-24 Showa Denko K.K. Process for producing lower aliphatic carboxylic acid ester
US7145051B2 (en) * 2002-03-22 2006-12-05 Exxonmobil Chemical Patents Inc. Combined oxydehydrogenation and cracking catalyst for production of olefins
TWI272123B (en) 2002-12-20 2007-02-01 Showa Denko Kk Heteropolyacid and/or its salt supported catalyst, production process of the catalyst and production process of compound using the catalyst
US7122494B2 (en) * 2003-02-05 2006-10-17 Exxonmobil Chemical Patents Inc. Combined cracking and selective hydrogen combustion for catalytic cracking
US7125817B2 (en) * 2003-02-20 2006-10-24 Exxonmobil Chemical Patents Inc. Combined cracking and selective hydrogen combustion for catalytic cracking
US7122492B2 (en) * 2003-02-05 2006-10-17 Exxonmobil Chemical Patents Inc. Combined cracking and selective hydrogen combustion for catalytic cracking
JP2006513843A (ja) * 2003-02-05 2006-04-27 エクソンモービル・ケミカル・パテンツ・インク 接触分解のための混合した分解及び選択的水素燃焼
US7122493B2 (en) * 2003-02-05 2006-10-17 Exxonmobil Chemical Patents Inc. Combined cracking and selective hydrogen combustion for catalytic cracking
JP4633339B2 (ja) * 2003-05-26 2011-02-16 三洋化成工業株式会社 カルボン酸エステルの製造方法
GB0320692D0 (en) * 2003-09-03 2003-10-01 Bp Chem Int Ltd Ester synthesis
GB0410603D0 (en) * 2004-05-12 2004-06-16 Bp Chem Int Ltd Ester synthesis
US7413805B2 (en) * 2005-02-25 2008-08-19 Fry's Metals, Inc. Preparation of metallic particles for electrokinetic or electrostatic deposition
JP5083909B2 (ja) * 2006-02-14 2012-11-28 独立行政法人産業技術総合研究所 カルボン酸エステルおよびエーテル化合物の製造方法
EP2089156B1 (de) * 2006-11-22 2022-01-05 Technip E&C Limited Verfahren zur herstellung von alkenen aus oxygenaten durch verwendung geträgerter heteropolysäure-katalysatoren
EP1982761A1 (de) * 2006-11-22 2008-10-22 BP Chemicals Limited Unterstützte Heteropolysäurekatalysatoren
US8680317B2 (en) * 2008-07-31 2014-03-25 Celanese International Corporation Processes for making ethyl acetate from acetic acid
US8338650B2 (en) 2008-07-31 2012-12-25 Celanese International Corporation Palladium catalysts for making ethanol from acetic acid
US8546622B2 (en) 2008-07-31 2013-10-01 Celanese International Corporation Process for making ethanol from acetic acid using acidic catalysts
US8309773B2 (en) 2010-02-02 2012-11-13 Calanese International Corporation Process for recovering ethanol
US8309772B2 (en) 2008-07-31 2012-11-13 Celanese International Corporation Tunable catalyst gas phase hydrogenation of carboxylic acids
US20100197486A1 (en) * 2008-07-31 2010-08-05 Celanese International Corporation Catalysts for making ethyl acetate from acetic acid
US8637714B2 (en) 2008-07-31 2014-01-28 Celanese International Corporation Process for producing ethanol over catalysts containing platinum and palladium
US8501652B2 (en) 2008-07-31 2013-08-06 Celanese International Corporation Catalysts for making ethanol from acetic acid
US8304586B2 (en) 2010-02-02 2012-11-06 Celanese International Corporation Process for purifying ethanol
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US7820852B2 (en) * 2008-07-31 2010-10-26 Celanese International Corporation Direct and selective production of ethyl acetate from acetic acid utilizing a bimetal supported catalyst
US8450535B2 (en) 2009-07-20 2013-05-28 Celanese International Corporation Ethanol production from acetic acid utilizing a cobalt catalyst
US8710277B2 (en) * 2009-10-26 2014-04-29 Celanese International Corporation Process for making diethyl ether from acetic acid
US8680321B2 (en) * 2009-10-26 2014-03-25 Celanese International Corporation Processes for making ethanol from acetic acid using bimetallic catalysts
US8211821B2 (en) 2010-02-01 2012-07-03 Celanese International Corporation Processes for making tin-containing catalysts
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US8575403B2 (en) 2010-05-07 2013-11-05 Celanese International Corporation Hydrolysis of ethyl acetate in ethanol separation process
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US8747492B2 (en) 2010-02-02 2014-06-10 Celanese International Corporation Ethanol/fuel blends for use as motor fuels
US8394985B2 (en) * 2010-02-02 2013-03-12 Celanese International Corporation Process for producing an ester feed stream for esters production and co-production of ethanol
US8394984B2 (en) 2010-02-02 2013-03-12 Celanese International Corporation Process for producing an ethyl acetate solvent and co-production of ethanol
US8460405B2 (en) * 2010-02-02 2013-06-11 Celanese International Corporation Ethanol compositions
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US8569551B2 (en) 2010-05-07 2013-10-29 Celanese International Corporation Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process
US8754267B2 (en) 2010-05-07 2014-06-17 Celanese International Corporation Process for separating acetaldehyde from ethanol-containing mixtures
US8664454B2 (en) 2010-07-09 2014-03-04 Celanese International Corporation Process for production of ethanol using a mixed feed using copper containing catalyst
US8901358B2 (en) 2010-07-09 2014-12-02 Celanese International Corporation Esterification of vapor crude product in the production of alcohols
US9150474B2 (en) 2010-07-09 2015-10-06 Celanese International Corporation Reduction of acid within column through esterification during the production of alcohols
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US8846988B2 (en) 2010-07-09 2014-09-30 Celanese International Corporation Liquid esterification for the production of alcohols
US8710279B2 (en) 2010-07-09 2014-04-29 Celanese International Corporation Hydrogenolysis of ethyl acetate in alcohol separation processes
US9272970B2 (en) 2010-07-09 2016-03-01 Celanese International Corporation Hydrogenolysis of ethyl acetate in alcohol separation processes
US8350098B2 (en) 2011-04-04 2013-01-08 Celanese International Corporation Ethanol production from acetic acid utilizing a molybdenum carbide catalyst
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US9000232B2 (en) 2011-04-26 2015-04-07 Celanese International Corporation Extractive distillation of crude alcohol product
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US9024085B2 (en) 2011-04-26 2015-05-05 Celanese International Corporation Process to reduce ethanol recycled to hydrogenation reactor
US8592635B2 (en) 2011-04-26 2013-11-26 Celanese International Corporation Integrated ethanol production by extracting halides from acetic acid
US8933278B2 (en) 2011-04-26 2015-01-13 Celanese International Corporation Process for producing ethanol and reducing acetic acid concentration
US9024084B2 (en) 2011-04-26 2015-05-05 Celanese International Corporation Reduced energy alcohol separation process having controlled pressure
US9024082B2 (en) 2011-04-26 2015-05-05 Celanese International Corporation Using a dilute acid stream as an extractive agent
US9000233B2 (en) 2011-04-26 2015-04-07 Celanese International Corporation Process to recover alcohol with secondary reactors for hydrolysis of acetal
US8884081B2 (en) 2011-04-26 2014-11-11 Celanese International Corporation Integrated process for producing acetic acid and alcohol
US8686200B2 (en) 2011-04-26 2014-04-01 Celanese International Corporation Process to recover alcohol from an acidic residue stream
US8927784B2 (en) 2011-04-26 2015-01-06 Celanese International Corporation Process to recover alcohol from an ethyl acetate residue stream
US8927788B2 (en) 2011-04-26 2015-01-06 Celanese International Corporation Process to recover alcohol with reduced water from overhead of acid column
US8686199B2 (en) 2011-04-26 2014-04-01 Celanese International Corporation Process for reducing the concentration of acetic acid in a crude alcohol product
US8754268B2 (en) 2011-04-26 2014-06-17 Celanese International Corporation Process for removing water from alcohol mixtures
US9073816B2 (en) 2011-04-26 2015-07-07 Celanese International Corporation Reducing ethyl acetate concentration in recycle streams for ethanol production processes
US8575405B2 (en) 2011-08-03 2013-11-05 Celanese International Corporation Reducing acetals during ethanol separation process
US8895786B2 (en) 2011-08-03 2014-11-25 Celanese International Corporation Processes for increasing alcohol production
US8748676B2 (en) 2011-08-03 2014-06-10 Celanese International Corporation Process for purifying a crude ethanol product
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US8658843B2 (en) 2011-10-06 2014-02-25 Celanese International Corporation Hydrogenation catalysts prepared from polyoxometalate precursors and process for using same to produce ethanol while minimizing diethyl ether formation
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US8703868B2 (en) 2011-11-28 2014-04-22 Celanese International Corporation Integrated process for producing polyvinyl alcohol or a copolymer thereof and ethanol
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US8729311B2 (en) 2012-02-10 2014-05-20 Celanese International Corporaton Catalysts for converting acetic acid to acetone
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CN103214365B (zh) * 2013-04-18 2015-04-08 湖南长岭石化科技开发有限公司 一种由苯生产乙酸环己酯的方法
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CN104117378B (zh) * 2014-06-29 2016-03-02 陈昆 酯化反应催化剂的制备方法
JP6425530B2 (ja) * 2014-12-11 2018-11-21 昭和電工株式会社 脂肪族カルボン酸エステルの製造方法
JP6986908B2 (ja) 2017-09-05 2021-12-22 昭和電工株式会社 脂肪族カルボン酸エステルの製造方法
JP6910252B2 (ja) 2017-09-05 2021-07-28 昭和電工株式会社 シリカ担体の製造方法
CN110152648B (zh) * 2018-02-12 2022-01-04 中国石油化工股份有限公司 锡催化剂的制备方法、锡催化剂及其应用

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DE69607536T2 (de) 1995-08-02 2001-02-08 Bp Chem Int Ltd Estersynthese

Also Published As

Publication number Publication date
CN1085197C (zh) 2002-05-22
CA2182558A1 (en) 1997-02-03
DE69607536D1 (de) 2000-05-11
US5861530A (en) 1999-01-19
EP0959064A1 (de) 1999-11-24
CA2182558C (en) 2006-10-24
SA96170381B1 (ar) 2007-01-20
JPH09118647A (ja) 1997-05-06
CN1150585A (zh) 1997-05-28
KR100293337B1 (ko) 2001-07-12
TW338764B (en) 1998-08-21
JP2005298527A (ja) 2005-10-27
USRE41341E1 (en) 2010-05-18
SG49973A1 (en) 1998-06-15
MY116546A (en) 2004-02-28
EP0757027B1 (de) 2000-04-05
DE69607536T2 (de) 2001-02-08
DE69618032D1 (de) 2002-01-24
EP0959064B1 (de) 2001-12-12
KR980002006A (ko) 1998-03-30
EP0757027A1 (de) 1997-02-05
JP3911048B2 (ja) 2007-05-09

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