DE69615105T2 - Enzymatische Behandlung von Kakao - Google Patents
Enzymatische Behandlung von KakaoInfo
- Publication number
- DE69615105T2 DE69615105T2 DE69615105T DE69615105T DE69615105T2 DE 69615105 T2 DE69615105 T2 DE 69615105T2 DE 69615105 T DE69615105 T DE 69615105T DE 69615105 T DE69615105 T DE 69615105T DE 69615105 T2 DE69615105 T2 DE 69615105T2
- Authority
- DE
- Germany
- Prior art keywords
- cocoa
- mixture
- beans
- fermented
- mass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 235000009470 Theobroma cacao Nutrition 0.000 title claims description 114
- 230000002255 enzymatic effect Effects 0.000 title description 5
- 244000240602 cacao Species 0.000 title 1
- 244000299461 Theobroma cacao Species 0.000 claims description 117
- 244000046052 Phaseolus vulgaris Species 0.000 claims description 114
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims description 114
- 239000000203 mixture Substances 0.000 claims description 99
- 238000006460 hydrolysis reaction Methods 0.000 claims description 58
- 230000007062 hydrolysis Effects 0.000 claims description 55
- 238000000034 method Methods 0.000 claims description 31
- 102000004169 proteins and genes Human genes 0.000 claims description 30
- 108090000623 proteins and genes Proteins 0.000 claims description 30
- 108091005804 Peptidases Proteins 0.000 claims description 28
- 239000004365 Protease Substances 0.000 claims description 28
- 150000001413 amino acids Chemical class 0.000 claims description 28
- 238000000855 fermentation Methods 0.000 claims description 23
- 230000004151 fermentation Effects 0.000 claims description 23
- 102000004190 Enzymes Human genes 0.000 claims description 19
- 108090000790 Enzymes Proteins 0.000 claims description 19
- 108010051210 beta-Fructofuranosidase Proteins 0.000 claims description 19
- 235000011073 invertase Nutrition 0.000 claims description 19
- 102000004196 processed proteins & peptides Human genes 0.000 claims description 13
- 108090000765 processed proteins & peptides Proteins 0.000 claims description 13
- 230000002209 hydrophobic effect Effects 0.000 claims description 9
- 239000012736 aqueous medium Substances 0.000 claims description 8
- IAIWVQXQOWNYOU-BAQGIRSFSA-N [(z)-(5-nitrofuran-2-yl)methylideneamino]urea Chemical compound NC(=O)N\N=C/C1=CC=C([N+]([O-])=O)O1 IAIWVQXQOWNYOU-BAQGIRSFSA-N 0.000 claims description 6
- 235000000346 sugar Nutrition 0.000 claims description 5
- 108010084185 Cellulases Proteins 0.000 claims description 2
- 102000005575 Cellulases Human genes 0.000 claims description 2
- 108010031186 Glycoside Hydrolases Proteins 0.000 claims description 2
- 102000005744 Glycoside Hydrolases Human genes 0.000 claims description 2
- 108090000854 Oxidoreductases Proteins 0.000 claims description 2
- 102000004316 Oxidoreductases Human genes 0.000 claims description 2
- 108010059820 Polygalacturonase Proteins 0.000 claims description 2
- 108010093305 exopolygalacturonase Proteins 0.000 claims description 2
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims 4
- 239000000047 product Substances 0.000 description 44
- 235000018102 proteins Nutrition 0.000 description 28
- 235000001014 amino acid Nutrition 0.000 description 27
- 102000035195 Peptidases Human genes 0.000 description 24
- 239000001573 invertase Substances 0.000 description 16
- 239000002243 precursor Substances 0.000 description 16
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 15
- 239000000872 buffer Substances 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 13
- 150000008442 polyphenolic compounds Chemical class 0.000 description 12
- 235000013824 polyphenols Nutrition 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 11
- 101710118538 Protease Proteins 0.000 description 11
- 239000008103 glucose Substances 0.000 description 11
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 10
- 238000004458 analytical method Methods 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 9
- 229930091371 Fructose Natural products 0.000 description 8
- 239000005715 Fructose Substances 0.000 description 8
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 8
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 8
- 230000014759 maintenance of location Effects 0.000 description 8
- 230000002829 reductive effect Effects 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 238000004587 chromatography analysis Methods 0.000 description 7
- 230000001953 sensory effect Effects 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 102000005367 Carboxypeptidases Human genes 0.000 description 6
- 108010006303 Carboxypeptidases Proteins 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000010828 elution Methods 0.000 description 6
- 238000002415 sodium dodecyl sulfate polyacrylamide gel electrophoresis Methods 0.000 description 6
- 102000000496 Carboxypeptidases A Human genes 0.000 description 5
- 108010080937 Carboxypeptidases A Proteins 0.000 description 5
- 244000013123 dwarf bean Species 0.000 description 5
- 235000021331 green beans Nutrition 0.000 description 5
- 235000019640 taste Nutrition 0.000 description 5
- 235000019568 aromas Nutrition 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 229920002401 polyacrylamide Polymers 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 101000985493 Mus musculus Hermansky-Pudlak syndrome 3 protein homolog Proteins 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 235000019606 astringent taste Nutrition 0.000 description 3
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 3
- 230000007071 enzymatic hydrolysis Effects 0.000 description 3
- 238000006047 enzymatic hydrolysis reaction Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000000796 flavoring agent Substances 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 235000011846 forastero Nutrition 0.000 description 3
- 244000237494 forastero Species 0.000 description 3
- 238000004128 high performance liquid chromatography Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 150000008163 sugars Chemical class 0.000 description 3
- 239000006228 supernatant Substances 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- MEYZIGGCNFHINA-UHFFFAOYSA-N (6-aminoquinolin-2-yl) n-(2,5-dioxopyrrolidin-1-yl)-n-hydroxycarbamate Chemical compound C1=CC2=CC(N)=CC=C2N=C1OC(=O)N(O)N1C(=O)CCC1=O MEYZIGGCNFHINA-UHFFFAOYSA-N 0.000 description 2
- 102000004400 Aminopeptidases Human genes 0.000 description 2
- 108090000915 Aminopeptidases Proteins 0.000 description 2
- 208000035404 Autolysis Diseases 0.000 description 2
- 206010057248 Cell death Diseases 0.000 description 2
- 102000006395 Globulins Human genes 0.000 description 2
- 108010044091 Globulins Proteins 0.000 description 2
- LOUPRKONTZGTKE-WZBLMQSHSA-N Quinine Chemical compound C([C@H]([C@H](C1)C=C)C2)C[N@@]1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OC)C=C21 LOUPRKONTZGTKE-WZBLMQSHSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000011942 biocatalyst Substances 0.000 description 2
- 235000019219 chocolate Nutrition 0.000 description 2
- 238000004925 denaturation Methods 0.000 description 2
- 230000036425 denaturation Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000000338 in vitro Methods 0.000 description 2
- 238000011534 incubation Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- -1 re Species 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 230000028043 self proteolysis Effects 0.000 description 2
- 230000035807 sensation Effects 0.000 description 2
- 235000019615 sensations Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- 235000001258 Cinchona calisaya Nutrition 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 206010017076 Fracture Diseases 0.000 description 1
- 241001632576 Hyacinthus Species 0.000 description 1
- 235000010254 Jasminum officinale Nutrition 0.000 description 1
- 240000005385 Jasminum sambac Species 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- ROHFNLRQFUQHCH-YFKPBYRVSA-N L-leucine Chemical compound CC(C)C[C@H](N)C(O)=O ROHFNLRQFUQHCH-YFKPBYRVSA-N 0.000 description 1
- COLNVLDHVKWLRT-QMMMGPOBSA-N L-phenylalanine Chemical compound OC(=O)[C@@H](N)CC1=CC=CC=C1 COLNVLDHVKWLRT-QMMMGPOBSA-N 0.000 description 1
- ROHFNLRQFUQHCH-UHFFFAOYSA-N Leucine Natural products CC(C)CC(N)C(O)=O ROHFNLRQFUQHCH-UHFFFAOYSA-N 0.000 description 1
- 235000011430 Malus pumila Nutrition 0.000 description 1
- 235000015103 Malus silvestris Nutrition 0.000 description 1
- 240000008790 Musa x paradisiaca Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- 235000014443 Pyrus communis Nutrition 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 244000297179 Syringa vulgaris Species 0.000 description 1
- 235000004338 Syringa vulgaris Nutrition 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000019658 bitter taste Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- LOUPRKONTZGTKE-UHFFFAOYSA-N cinchonine Natural products C1C(C(C2)C=C)CCN2C1C(O)C1=CC=NC2=CC=C(OC)C=C21 LOUPRKONTZGTKE-UHFFFAOYSA-N 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 229940110456 cocoa butter Drugs 0.000 description 1
- 235000019868 cocoa butter Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 230000002068 genetic effect Effects 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 230000000415 inactivating effect Effects 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 210000003254 palate Anatomy 0.000 description 1
- 238000009931 pascalization Methods 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- COLNVLDHVKWLRT-UHFFFAOYSA-N phenylalanine Natural products OC(=O)C(N)CC1=CC=CC=C1 COLNVLDHVKWLRT-UHFFFAOYSA-N 0.000 description 1
- 239000008363 phosphate buffer Substances 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 230000002797 proteolythic effect Effects 0.000 description 1
- 229960000948 quinine Drugs 0.000 description 1
- 238000004007 reversed phase HPLC Methods 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 235000019613 sensory perceptions of taste Nutrition 0.000 description 1
- 235000021309 simple sugar Nutrition 0.000 description 1
- 238000002798 spectrophotometry method Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 230000035923 taste sensation Effects 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000012384 transportation and delivery Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/32—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
- A23G1/42—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds containing microorganisms or enzymes; containing paramedical or dietetical agents, e.g. vitamins
- A23G1/423—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds containing microorganisms or enzymes; containing paramedical or dietetical agents, e.g. vitamins containing microorganisms, enzymes
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/02—Preliminary treatment, e.g. fermentation of cocoa
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Biotechnology (AREA)
- Health & Medical Sciences (AREA)
- Microbiology (AREA)
- Nutrition Science (AREA)
- Inorganic Chemistry (AREA)
- Confectionery (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Seasonings (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Medicines Containing Plant Substances (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP95201668A EP0749694A1 (fr) | 1995-06-20 | 1995-06-20 | Traitement enzymatique du cacao |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69615105D1 DE69615105D1 (de) | 2001-10-18 |
DE69615105T2 true DE69615105T2 (de) | 2002-01-24 |
Family
ID=8220394
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69615105T Expired - Fee Related DE69615105T2 (de) | 1995-06-20 | 1996-06-18 | Enzymatische Behandlung von Kakao |
Country Status (26)
Country | Link |
---|---|
US (1) | US5888562A (ko) |
EP (2) | EP0749694A1 (ko) |
JP (1) | JPH09156A (ko) |
KR (1) | KR970000051A (ko) |
CN (1) | CN1146862A (ko) |
AR (1) | AR002538A1 (ko) |
AT (1) | ATE205365T1 (ko) |
AU (1) | AU697619B2 (ko) |
CA (1) | CA2179533A1 (ko) |
CO (1) | CO4750598A1 (ko) |
CZ (1) | CZ179796A3 (ko) |
DE (1) | DE69615105T2 (ko) |
DK (1) | DK0755632T3 (ko) |
ES (1) | ES2161967T3 (ko) |
HU (1) | HU219572B (ko) |
IL (1) | IL118678A (ko) |
MX (1) | MX9602397A (ko) |
MY (1) | MY114713A (ko) |
NZ (1) | NZ286835A (ko) |
PE (1) | PE20398A1 (ko) |
PL (1) | PL314868A1 (ko) |
PT (1) | PT755632E (ko) |
SG (1) | SG50740A1 (ko) |
TR (1) | TR199600516A2 (ko) |
YU (1) | YU37796A (ko) |
ZA (1) | ZA965206B (ko) |
Families Citing this family (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0888717B1 (fr) * | 1997-07-02 | 2003-09-17 | Societe Des Produits Nestle S.A. | Extrait d'arômes |
OA11667A (en) * | 1998-10-15 | 2004-12-08 | Kraft Food R & D Inc | Low-flavor cocoa, a method of its production and ause thereof. |
US7407678B2 (en) | 1998-11-20 | 2008-08-05 | Chi's Research Corporation | Method for enzymatic treatment of a vegetable composition |
US6576275B1 (en) * | 1999-02-02 | 2003-06-10 | Archer-Daniels-Midland Company | Process for extracting polyphenolic antioxidants from purine-containing plants |
US7597922B2 (en) * | 1999-05-18 | 2009-10-06 | Nestec S.A. | System for dispensing a liquid beverage concentrate |
US7060315B2 (en) * | 2001-03-23 | 2006-06-13 | Nestec S.A. | Aroma-containing components |
FR2810242B1 (fr) * | 2000-06-16 | 2003-01-17 | Nuxe Lab | Composition cosmetique et/ou dermatologique a base d'extraits de cacao |
GB0103618D0 (en) * | 2001-02-14 | 2001-03-28 | Nestle Sa | Enzymatically hydrolysed cocoa in chocolate flavour reactions |
GB2370213A (en) * | 2000-12-20 | 2002-06-26 | Nestle Sa | Chocolate flavour manipulation |
MXPA03008548A (es) * | 2001-03-23 | 2003-12-08 | Nestle Sa | Mejoras en componentes que contienen aroma. |
OA12516A (en) | 2001-07-06 | 2006-05-29 | Nestle Sa | Novel carboxypeptidase of cocoa. |
EP1308094A3 (en) * | 2001-10-30 | 2004-02-25 | Societe Des Produits Nestle S.A. | Chocolate crumb flavour manipulation |
RU2318393C2 (ru) * | 2001-10-30 | 2008-03-10 | Сосьете Де Продюи Нестле С.А. | Манипулирование ароматом шоколада |
JP2005506846A (ja) * | 2001-10-30 | 2005-03-10 | ソシエテ デ プロデユイ ネツスル ソシエテ アノニム | チョコレート風味調節 |
AU2003216213B2 (en) * | 2002-02-07 | 2008-10-02 | The Trustees Of Columbia University In The City Of New York | Zinc salt compositions for the prevention of mucosal irritation from spermicides and microbicides |
US7879365B2 (en) * | 2002-02-07 | 2011-02-01 | The Trustees Of Columbia University In The City Of New York | Zinc salt compositions for the prevention of dermal and mucosal irritation |
ES2284739T3 (es) * | 2002-03-20 | 2007-11-16 | Societe Des Produits Nestle S.A. | Extracto de cacao con bajo contenido en grasa. |
JP2007534620A (ja) * | 2003-07-17 | 2007-11-29 | ザ トラスティース オブ コロンビア ユニバーシティ イン ザ シティ オブ ニューヨーク | 第4級アンモニウム化合物と精油および/またはその構成要素の相乗的組合せを含む抗菌組成物 |
DE10340739A1 (de) * | 2003-09-04 | 2005-04-07 | Satia Gmbh | Verfahren zur enzymatischen Herstellung von Mono- und Diacylglycerid-haltigen Emulgatoren |
WO2006037655A2 (en) * | 2004-10-07 | 2006-04-13 | Nestec S.A. | Bioactive compositions, natural methods of producing them and computational methods for designing natural production processes |
US20070286935A1 (en) * | 2004-10-07 | 2007-12-13 | Nestec S.A. | Bioactive Compositions, Natural Methods of Producing Them and Computational Methods for Designing Natural Production Processes |
KR20070007556A (ko) * | 2005-07-11 | 2007-01-16 | 엘지전자 주식회사 | 식기 세척기 및 그 제어방법 |
JP4758169B2 (ja) * | 2005-08-09 | 2011-08-24 | 長谷川香料株式会社 | カカオ酵素処理物およびその製造方法 |
KR100738648B1 (ko) * | 2005-12-30 | 2007-07-11 | 씨제이 주식회사 | 단백질 분해 효소를 첨가한 된장의 제조방법 및 된장 |
US7759327B2 (en) * | 2006-01-06 | 2010-07-20 | The Trustees Of Columbia University In The City Of New York | Compositions containing zinc salts for coating medical articles |
CN101073366B (zh) * | 2007-06-19 | 2010-12-29 | 无锡华东可可食品有限公司 | 一种从可可豆中分离可可果仁的生产方法 |
MX2010005431A (es) * | 2007-11-19 | 2010-06-02 | Hershey Co | Proceso para preparar ingredientes de cacao rojo, chocolate rojo y productos alimenticios. |
GB0801119D0 (en) * | 2008-01-22 | 2008-02-27 | Barry Callebaut Ag | Composition |
BRPI0800944A2 (pt) * | 2008-02-22 | 2009-10-06 | Dario Ahnert | método para obtenção de amêndoas de cacau (treobroma cacao l.) e massa de cacau torrado ("liquors"), para fazer chocolate, com sabor diversificado através da adição de ingredientes aromáticos à polpa do cacau antes ou durante o processo de fermentação de sementes frescas de cacau |
US9833009B2 (en) * | 2008-11-28 | 2017-12-05 | Olam International Limited | Method of washing cocoa beans to improve the quality of the cocoa products obtained from such beans |
CN101445766B (zh) * | 2008-12-17 | 2010-10-13 | 华宝食用香精香料(上海)有限公司 | 可可香料的制备方法、采用该方法所得到的产品及其用途 |
JP2012520077A (ja) * | 2009-03-11 | 2012-09-06 | カーギル・インコーポレイテッド | ココア製品の製法 |
CN102687838A (zh) * | 2011-03-21 | 2012-09-26 | 广州市名花香料有限公司 | 一种制备可可提取物的方法 |
US10334868B2 (en) | 2016-06-16 | 2019-07-02 | Sigma Phase, Corp. | System for providing a single serving of a frozen confection |
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-
1995
- 1995-06-20 EP EP95201668A patent/EP0749694A1/fr not_active Withdrawn
-
1996
- 1996-06-07 US US08/660,901 patent/US5888562A/en not_active Expired - Fee Related
- 1996-06-08 MY MYPI96002322A patent/MY114713A/en unknown
- 1996-06-14 PE PE1996000455A patent/PE20398A1/es not_active Application Discontinuation
- 1996-06-18 EP EP96201692A patent/EP0755632B9/fr not_active Expired - Lifetime
- 1996-06-18 AT AT96201692T patent/ATE205365T1/de not_active IP Right Cessation
- 1996-06-18 DE DE69615105T patent/DE69615105T2/de not_active Expired - Fee Related
- 1996-06-18 PT PT96201692T patent/PT755632E/pt unknown
- 1996-06-18 DK DK96201692T patent/DK0755632T3/da active
- 1996-06-18 ES ES96201692T patent/ES2161967T3/es not_active Expired - Lifetime
- 1996-06-18 NZ NZ286835A patent/NZ286835A/en unknown
- 1996-06-18 IL IL11867896A patent/IL118678A/xx not_active IP Right Cessation
- 1996-06-19 CZ CZ961797A patent/CZ179796A3/cs unknown
- 1996-06-19 KR KR1019960022380A patent/KR970000051A/ko not_active Application Discontinuation
- 1996-06-19 MX MX9602397A patent/MX9602397A/es unknown
- 1996-06-19 TR TR96/00516A patent/TR199600516A2/xx unknown
- 1996-06-19 CN CN96111002A patent/CN1146862A/zh active Pending
- 1996-06-19 PL PL96314868A patent/PL314868A1/xx unknown
- 1996-06-19 JP JP8158229A patent/JPH09156A/ja not_active Withdrawn
- 1996-06-19 ZA ZA9605206A patent/ZA965206B/xx unknown
- 1996-06-19 CO CO96031750A patent/CO4750598A1/es unknown
- 1996-06-19 CA CA002179533A patent/CA2179533A1/en not_active Abandoned
- 1996-06-19 AU AU56059/96A patent/AU697619B2/en not_active Ceased
- 1996-06-20 SG SG1996010116A patent/SG50740A1/en unknown
- 1996-06-20 AR ARP960103237A patent/AR002538A1/es unknown
- 1996-06-20 YU YU37796A patent/YU37796A/sh unknown
- 1996-06-20 HU HU9601700A patent/HU219572B/hu not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CN1146862A (zh) | 1997-04-09 |
DE69615105D1 (de) | 2001-10-18 |
MY114713A (en) | 2002-12-31 |
CZ179796A3 (en) | 1997-10-15 |
CA2179533A1 (en) | 1996-12-21 |
NZ286835A (en) | 1998-07-28 |
IL118678A0 (en) | 1996-10-16 |
AR002538A1 (es) | 1998-03-25 |
EP0755632A2 (fr) | 1997-01-29 |
HU9601700D0 (en) | 1996-08-28 |
EP0755632B1 (fr) | 2001-09-12 |
EP0755632A3 (fr) | 1997-03-19 |
TR199600516A2 (tr) | 1996-08-21 |
EP0755632B9 (fr) | 2002-05-15 |
KR970000051A (ko) | 1997-01-21 |
US5888562A (en) | 1999-03-30 |
MX9602397A (es) | 1997-02-28 |
EP0749694A1 (fr) | 1996-12-27 |
PT755632E (pt) | 2001-12-28 |
YU37796A (sh) | 1998-08-14 |
HUP9601700A2 (en) | 1997-05-28 |
HUP9601700A3 (en) | 1998-03-02 |
HU219572B (hu) | 2001-05-28 |
SG50740A1 (en) | 1998-07-20 |
IL118678A (en) | 2000-01-31 |
AU697619B2 (en) | 1998-10-15 |
JPH09156A (ja) | 1997-01-07 |
ATE205365T1 (de) | 2001-09-15 |
ZA965206B (en) | 1997-12-19 |
PL314868A1 (en) | 1996-12-23 |
PE20398A1 (es) | 1998-04-20 |
CO4750598A1 (es) | 1999-03-31 |
DK0755632T3 (da) | 2001-10-15 |
ES2161967T3 (es) | 2001-12-16 |
AU5605996A (en) | 1997-01-09 |
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