DE69328954T2 - Verfahren zur Kontrolle des Schmelzpunktes und Molekulargewichtes von syndiotaktischen Olefinpolymeren unter Anwendung eines Metallocen-Kalatysatorsystems - Google Patents
Verfahren zur Kontrolle des Schmelzpunktes und Molekulargewichtes von syndiotaktischen Olefinpolymeren unter Anwendung eines Metallocen-KalatysatorsystemsInfo
- Publication number
- DE69328954T2 DE69328954T2 DE69328954T DE69328954T DE69328954T2 DE 69328954 T2 DE69328954 T2 DE 69328954T2 DE 69328954 T DE69328954 T DE 69328954T DE 69328954 T DE69328954 T DE 69328954T DE 69328954 T2 DE69328954 T2 DE 69328954T2
- Authority
- DE
- Germany
- Prior art keywords
- controlling
- molecular weight
- melting point
- catalyst system
- metallocene catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/903,058 US5710222A (en) | 1992-06-22 | 1992-06-22 | Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69328954D1 DE69328954D1 (de) | 2000-08-10 |
DE69328954T2 true DE69328954T2 (de) | 2000-12-28 |
Family
ID=25416877
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69331752T Expired - Fee Related DE69331752T2 (de) | 1992-06-22 | 1993-06-22 | Verfahren zur Kontrolle des Schmelzpunktes und Molekulargewichtes von syndiotaktischen Olefinpolymeren unter Anwendung eines Metallocen-Katalysatorsystems |
DE69328954T Expired - Fee Related DE69328954T2 (de) | 1992-06-22 | 1993-06-22 | Verfahren zur Kontrolle des Schmelzpunktes und Molekulargewichtes von syndiotaktischen Olefinpolymeren unter Anwendung eines Metallocen-Kalatysatorsystems |
DE69331287T Expired - Fee Related DE69331287T2 (de) | 1992-06-22 | 1993-06-22 | Verfahren zur Kontrolle des Schmelzpunktes und Molekulargewichtes von syndiotaktischen Olefinpolymeren unter Anwendung eines Metallocen-Katalysatorsystems |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69331752T Expired - Fee Related DE69331752T2 (de) | 1992-06-22 | 1993-06-22 | Verfahren zur Kontrolle des Schmelzpunktes und Molekulargewichtes von syndiotaktischen Olefinpolymeren unter Anwendung eines Metallocen-Katalysatorsystems |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69331287T Expired - Fee Related DE69331287T2 (de) | 1992-06-22 | 1993-06-22 | Verfahren zur Kontrolle des Schmelzpunktes und Molekulargewichtes von syndiotaktischen Olefinpolymeren unter Anwendung eines Metallocen-Katalysatorsystems |
Country Status (5)
Country | Link |
---|---|
US (2) | US5710222A (de) |
EP (3) | EP0773238B1 (de) |
JP (2) | JP3399027B2 (de) |
DE (3) | DE69331752T2 (de) |
ES (3) | ES2167623T3 (de) |
Families Citing this family (93)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5401817A (en) * | 1991-05-09 | 1995-03-28 | Phillips Petroleum Company | Olefin polymerization using silyl-bridged metallocenes |
US5571880A (en) * | 1991-05-09 | 1996-11-05 | Phillips Petroleum Company | Organometallic fluorenyl compounds and use thereof in an alpha-olefin polymerization process |
US5668230A (en) * | 1991-07-23 | 1997-09-16 | Phillips Petroleum Company | Olefin polymerization |
BE1006880A3 (fr) * | 1993-03-01 | 1995-01-17 | Solvay | Precurseur solide d'un systeme catalytique pour la polymerisation d'olefines, procede pour sa preparation, systeme catalytique comprenant ce precurseur solide et procede de polymerisation d'olefines en presence de ce systeme catalytique. |
DE4406963A1 (de) * | 1994-03-03 | 1995-09-07 | Basf Ag | Metallocenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem |
EP0709393A3 (de) * | 1994-10-25 | 2003-04-16 | Tosoh Corporation | Olefinpolymerisationkatalysator und Verfahren zur Herstellung eines Olefinpolymers |
KR100417970B1 (ko) | 1994-11-22 | 2004-06-26 | 아토피나 리서치 | 올레핀중합촉매시스템에유용한가교메탈로센 |
US5705578A (en) * | 1995-05-04 | 1998-01-06 | Phillips Petroleum Company | Method for making and using a supported metallocene catalyst system |
US5631203A (en) * | 1995-05-04 | 1997-05-20 | Phillips Petroleum Company | Metallocene compounds and preparation thereof containing terminal alkynes |
US5830958A (en) * | 1995-05-12 | 1998-11-03 | Phillips Petroleum Company | Polynuclear metallocene preparation and use |
US5635437A (en) * | 1995-07-28 | 1997-06-03 | Exxon Chemicals Patents, Inc. | Method for preparing metallocene catalyst systems |
US6066588A (en) * | 1995-11-22 | 2000-05-23 | Fina Research, S.A. | Bridged metallocenes catalyst for polymerization of olefins |
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JP2000513399A (ja) | 1996-06-17 | 2000-10-10 | エクソン・ケミカル・パテンツ・インク | オレフィン重合用の混合遷移金属触媒系 |
ATE276263T1 (de) | 1996-08-08 | 2004-10-15 | Dow Global Technologies Inc | Metallkomplexe enthaltend ein an position 3 substituierte cyclopentadienylgruppe und ein olefinpolymerisationsverfahren |
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US5886202A (en) * | 1997-01-08 | 1999-03-23 | Jung; Michael | Bridged fluorenyl/indenyl metallocenes and the use thereof |
FI970349A (fi) * | 1997-01-28 | 1998-07-29 | Borealis As | Uudet metalloseeniyhdisteiden aktivaattorisysteemit |
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US6160072A (en) * | 1997-05-02 | 2000-12-12 | Ewen; John A. | Process for polymerizing tactioselective polyolefins in condensed phase using titanocenes |
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US8497330B2 (en) | 1997-12-08 | 2013-07-30 | Univation Technologies, Llc | Methods for polymerization using spray dried and slurried catalyst |
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US6015766A (en) * | 1997-12-18 | 2000-01-18 | Mobil Oil Corporation | Catalyst systems for olefin polymerization based on metallocene complexes and oligoalkylaluminates with sterically hindered alkyl groups as cocatalysts |
DE69922548T2 (de) | 1998-10-23 | 2006-01-05 | Exxonmobil Chemical Patents Inc., Baytown | Verbrückte metallocene zur olefincopolymerisation |
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CA2499951C (en) | 2002-10-15 | 2013-05-28 | Peijun Jiang | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
JP2005200452A (ja) * | 2004-01-13 | 2005-07-28 | Mitsui Chemicals Inc | α−オレフィン(共)重合体の製造方法 |
US7683140B2 (en) | 2004-05-20 | 2010-03-23 | Univation Technologies, Llc | Method for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring |
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-
1992
- 1992-06-22 US US07/903,058 patent/US5710222A/en not_active Expired - Lifetime
-
1993
- 1993-06-21 JP JP17383693A patent/JP3399027B2/ja not_active Expired - Lifetime
- 1993-06-22 ES ES97100762T patent/ES2167623T3/es not_active Expired - Lifetime
- 1993-06-22 ES ES97100761T patent/ES2172707T3/es not_active Expired - Lifetime
- 1993-06-22 DE DE69331752T patent/DE69331752T2/de not_active Expired - Fee Related
- 1993-06-22 DE DE69328954T patent/DE69328954T2/de not_active Expired - Fee Related
- 1993-06-22 EP EP97100761A patent/EP0773238B1/de not_active Expired - Lifetime
- 1993-06-22 DE DE69331287T patent/DE69331287T2/de not_active Expired - Fee Related
- 1993-06-22 EP EP97100762A patent/EP0773239B1/de not_active Expired - Lifetime
- 1993-06-22 ES ES93870112T patent/ES2148214T3/es not_active Expired - Lifetime
- 1993-06-22 EP EP93870112A patent/EP0577581B1/de not_active Expired - Lifetime
-
1995
- 1995-06-06 US US08/471,055 patent/US5688735A/en not_active Expired - Lifetime
-
2002
- 2002-07-05 JP JP2002196965A patent/JP2003105014A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
ES2167623T3 (es) | 2002-05-16 |
EP0577581A3 (en) | 1994-08-24 |
DE69331752D1 (de) | 2002-04-25 |
EP0773239A2 (de) | 1997-05-14 |
EP0773238A3 (de) | 1998-02-11 |
EP0773239A3 (de) | 1998-02-11 |
ES2148214T3 (es) | 2000-10-16 |
EP0577581A2 (de) | 1994-01-05 |
DE69331752T2 (de) | 2002-11-07 |
JP3399027B2 (ja) | 2003-04-21 |
EP0577581B1 (de) | 2000-07-05 |
JPH06172443A (ja) | 1994-06-21 |
EP0773238B1 (de) | 2002-03-20 |
EP0773239B1 (de) | 2001-12-05 |
DE69331287D1 (de) | 2002-01-17 |
JP2003105014A (ja) | 2003-04-09 |
ES2172707T3 (es) | 2002-10-01 |
DE69331287T2 (de) | 2002-08-08 |
US5710222A (en) | 1998-01-20 |
EP0773238A2 (de) | 1997-05-14 |
DE69328954D1 (de) | 2000-08-10 |
US5688735A (en) | 1997-11-18 |
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