DE69310044D1 - Hemmung der Polymerisation von vinylaromatischen Monomeren - Google Patents
Hemmung der Polymerisation von vinylaromatischen MonomerenInfo
- Publication number
- DE69310044D1 DE69310044D1 DE69310044T DE69310044T DE69310044D1 DE 69310044 D1 DE69310044 D1 DE 69310044D1 DE 69310044 T DE69310044 T DE 69310044T DE 69310044 T DE69310044 T DE 69310044T DE 69310044 D1 DE69310044 D1 DE 69310044D1
- Authority
- DE
- Germany
- Prior art keywords
- inhibition
- polymerization
- vinyl aromatic
- aromatic monomers
- monomers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/50—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/20—Use of additives, e.g. for stabilisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogenated Pyridines (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/921,824 US5254760A (en) | 1992-07-29 | 1992-07-29 | Inhibiting polymerization of vinyl aromatic monomers |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69310044D1 true DE69310044D1 (de) | 1997-05-28 |
DE69310044T2 DE69310044T2 (de) | 1997-11-20 |
Family
ID=25446025
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69310044T Revoked DE69310044T2 (de) | 1992-07-29 | 1993-07-20 | Hemmung der Polymerisation von vinylaromatischen Monomeren |
Country Status (14)
Country | Link |
---|---|
US (1) | US5254760A (de) |
EP (1) | EP0581737B1 (de) |
JP (1) | JP2855399B2 (de) |
KR (1) | KR0177045B1 (de) |
CN (1) | CN1041513C (de) |
AU (1) | AU666024B2 (de) |
BR (1) | BR9303023A (de) |
CA (1) | CA2101359C (de) |
DE (1) | DE69310044T2 (de) |
ES (1) | ES2101995T3 (de) |
MX (1) | MX9304506A (de) |
RU (1) | RU2116285C1 (de) |
SA (1) | SA93140161B1 (de) |
TW (1) | TW226023B (de) |
Families Citing this family (85)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW294658B (de) † | 1994-06-02 | 1997-01-01 | Nippon Catalytic Chem Ind | |
US5728872A (en) * | 1994-06-27 | 1998-03-17 | Lutz Riemenschneider | Stabilized acrylic acid compositions |
US5888356A (en) * | 1994-08-19 | 1999-03-30 | Huels Aktiengesellschaft | Inhibition of polymerization of vinylaromatic or vinylaliphatic |
EP0697386B1 (de) * | 1994-08-19 | 1998-11-25 | Hüls Aktiengesellschaft | Inhibierung der Polymerisation von Styrol |
US5545786C1 (en) * | 1994-11-28 | 2001-10-16 | Ciba Geigy Corp | Method for inhibiting premature polymerization of vinyl aromatic monomers |
DE19510184A1 (de) * | 1995-03-21 | 1996-09-26 | Basf Ag | 4-Acylaminopiperidin-N-oxyle |
US5616774A (en) * | 1995-04-14 | 1997-04-01 | Ciba-Geigy Corporation | Inhibition of unsaturated monomers with 7-aryl quinone methides |
DE19531649A1 (de) * | 1995-08-29 | 1997-03-06 | Basf Ag | Dübelmasse für die chemische Befestigungstechnik |
US5654434A (en) * | 1995-11-09 | 1997-08-05 | Ciba-Geigy Corporation | Hydrogen peroxide oxidation of 4-hydroxy-2, 2, 6, 6-tetramethylpiperidine |
US5629426A (en) * | 1995-11-09 | 1997-05-13 | Ciba-Geigy Corporation | Carbonate-mediated hydrogen peroxide oxidations of 4-hydroxy-2,2,6,6-tetramethylpiperidine |
DE19609312A1 (de) * | 1996-03-09 | 1997-09-11 | Basf Ag | Stabilisierte Monomerenzusammensetzung |
US5777126A (en) * | 1996-05-01 | 1998-07-07 | Ciba Specialty Chemicals Corporation | Carbonate-mediated hydrogen peroxide oxidation of 4-acylamino-2,2,6,6-tetramethylpiperidine |
CN1082499C (zh) * | 1996-06-05 | 2002-04-10 | Basf公司 | 含单体和稳定剂的混合物 |
US5711767A (en) * | 1996-07-11 | 1998-01-27 | Ciba Specialty Chemicals Corporation | Stabilizers for the prevention of gum formation in gasoline |
US6409887B1 (en) | 1996-07-15 | 2002-06-25 | Aah Marks And Company Limited | Polymerization inhibitor |
GB9614854D0 (en) * | 1996-07-15 | 1996-09-04 | Marks A H & Co Ltd | Free radical scavengers |
DE19638868A1 (de) * | 1996-09-23 | 1998-03-26 | Basf Ag | Stabilisierte Monomerenzusammensetzung |
EP0845448B1 (de) * | 1996-12-02 | 2002-01-30 | Ondeo Nalco Energy Services, L.P. | Hemmung der Polymerisation von vinylaromatischen Monomeren |
DE19651307A1 (de) | 1996-12-10 | 1998-06-18 | Basf Ag | Stoffmischungen, enthaltend vinylgruppenhaltige Verbindungen und Stabilisatoren |
US5847035A (en) * | 1997-03-13 | 1998-12-08 | Uniroyal Chemical Company, Inc. | Substituteed tetrahydropyrimidine derivatives and their use as polymerization inhibitors for vinyl aromatic compounds |
DE19811602A1 (de) * | 1997-03-20 | 1998-11-12 | Ciba Geigy Ag | Polymerisationsinhibitor-Verfahren |
US6281311B1 (en) * | 1997-03-31 | 2001-08-28 | Pmd Holdings Corp. | Controlled free radical polymerization process |
US5932735A (en) * | 1997-06-13 | 1999-08-03 | Ciba Specialty Chemicals Corporation | Derivatives of 1-oxyl-4-hydroxy-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers |
DE19725519A1 (de) * | 1997-06-17 | 1998-12-24 | Basf Ag | Stoffmischung, enthaltend vinylgruppenhaltige Verbindungen und Stabilisatoren |
US5969369A (en) * | 1997-08-29 | 1999-10-19 | Fogarty; Charles M. | Infrared emissive module |
US5869717A (en) * | 1997-09-17 | 1999-02-09 | Uop Llc | Process for inhibiting the polymerization of vinyl aromatics |
US5955643A (en) * | 1997-10-17 | 1999-09-21 | Nalco/Exxon Energy Chemicals, L.P. | Composition and method for inhibiting polymerization during the anaerobic of styrene |
US5880230A (en) * | 1997-12-31 | 1999-03-09 | Nalco/Exxon Energy Chemicals, L.P. | Shortstop agents for vinyl polymerizations |
US6024894A (en) * | 1998-03-25 | 2000-02-15 | Betzdearborn Inc. | Compositions and methods for inhibiting vinyl aromatic monomer polymerization |
US5907071A (en) * | 1998-04-21 | 1999-05-25 | Betzdearborn Inc. | Compositions and methods for inhibiting vinyl aromatic monomer polymerization |
US5910232A (en) * | 1998-06-10 | 1999-06-08 | Nalco/Exxon Energy Chemicals, L.P. | Method for inhibiting polymer formation in styrene processing |
EP1095006B1 (de) | 1998-07-14 | 2008-12-24 | Ciba Holding Inc. | 1-oxyl-4-hydroxy-2,2,6,6-tetramethylpiperidinderivate als polymerisationsinhibitoren für (meth)acrylatmonomere |
KR20010079775A (ko) * | 1998-09-09 | 2001-08-22 | 칼 에이. 로월드 | 치환 디히드록시아렌 및 니트록시드를 이용한 스티렌모노머 중합반응 억제방법 |
WO2000036052A1 (en) * | 1998-12-17 | 2000-06-22 | Nalco/Exxon Energy Chemicals, L.P. | Inhibiting polymerization of vinyl aromatic monomers using synergistic mixtures containing nitroxide stabilizers |
US20040019247A1 (en) * | 1999-02-26 | 2004-01-29 | Basf Aktiengesellschaft | Continuous recovery of styrene from a styrene-containing mixture |
DE19922103A1 (de) * | 1999-05-17 | 2000-11-23 | Basf Ag | Stoffmischungen, enthaltend vinylgruppenhaltige Verbindungen und Stabilisatoren |
DE19926758A1 (de) | 1999-06-11 | 2000-12-14 | Basf Ag | Verfahren zur Verhinderung unerwünschter Polymerisation in einem ethylenisch ungesättigte Verbindungen enthaltenden Stoffgemisch |
US6395943B1 (en) | 1999-08-10 | 2002-05-28 | Uop Llc | Process for inhibiting the polymerization of vinyl aromatic compounds |
US6395942B1 (en) | 1999-08-10 | 2002-05-28 | Uop Llc | Increasing the thermal stability of a vinyl aromatic polymerization inhibitor |
US6300533B1 (en) | 1999-08-16 | 2001-10-09 | Uniroyal Chemical Company, Inc. | Inhibition of polymerization of ethylenically unsaturated monomers |
US6342648B1 (en) * | 1999-09-30 | 2002-01-29 | Baker Hughes Incorporated | Methods and compositions for inhibiting vinyl aromatic monomer polymerization |
AR029410A1 (es) | 1999-12-02 | 2003-06-25 | Crompton Corp | Metodo para inhibir la polimerizacion prematura de monomeros etilenicamente insaturados y composiciones de los mismos |
ATE307789T1 (de) | 1999-12-02 | 2005-11-15 | Crompton Corp | Polymerisationsinhibierung von ungesättigten monomeren |
ES2292487T3 (es) * | 1999-12-03 | 2008-03-16 | Chemtura Corporation | Composicion y metodo para inhibir la polimerizacion y el crecimiento polimerico. |
US6403850B1 (en) | 2000-01-18 | 2002-06-11 | Uniroyal Chemical Company, Inc. | Inhibition of polymerization of unsaturated monomers |
US6344560B1 (en) * | 2000-05-03 | 2002-02-05 | Uniroyal Chemical Company, Inc. | Nitroaromatic solubilizer for nitroxyls in aromatic solvents |
US6339177B1 (en) | 2000-05-24 | 2002-01-15 | Sea Lion Technology, Inc. | Dinitroalkyl aromatics polymerization retarders or inhibitors and methods for making and for using same |
US6447649B1 (en) | 2000-07-24 | 2002-09-10 | Ge Betz, Inc. | Polymerization inhibitor for vinyl-containing materials |
DE60127188T2 (de) * | 2000-08-02 | 2007-11-08 | Uniroyal Chemical Co., Inc., Middlebury | Wiedergewinnung von nitroxyl-enthaltenden strömen bei niedriger temperatur |
US6685823B2 (en) * | 2000-10-16 | 2004-02-03 | Uniroyal Chemical Company, Inc. | C-nitrosoaniline compounds and their blends as polymerization inhibitors |
WO2002033026A1 (en) * | 2000-10-16 | 2002-04-25 | Uniroyal Chemical Company, Inc. | Blends of quinone alkide and nitroxyl compounds as polymerization inhibitors |
US20030009031A1 (en) * | 2001-04-30 | 2003-01-09 | Mikolaj Jawosiuk | Novel hindered spiro-ketal nitroxides |
US6579442B2 (en) | 2001-05-22 | 2003-06-17 | Ge Betz, Inc. | Methods and compositions for inhibiting polymerization of vinyl monomers |
US6639026B2 (en) | 2001-05-22 | 2003-10-28 | Ge Betz, Inc. | Methods and compositions for inhibiting polymerization of vinyl monomers |
JP2003119205A (ja) * | 2001-10-12 | 2003-04-23 | Asahi Denka Kogyo Kk | 重合禁止剤組成物 |
US6563753B1 (en) * | 2001-11-16 | 2003-05-13 | Agilent Technologies, Inc. | Sense amplifier with independent write-back capability for ferroelectric random-access memories |
WO2003054083A1 (de) | 2001-12-20 | 2003-07-03 | Ami - Agrolinz Melamine International Gmbh | Additiv zur inhibierung von photolytischen abbaureaktionen in aminoplasten |
US7125475B2 (en) * | 2002-02-15 | 2006-10-24 | Crompton Corporation | Nitrosophenols and C-nitrosoanilines as polymerization inhibitors |
US6960279B2 (en) * | 2002-05-06 | 2005-11-01 | Fina Technology, Inc. | Method for stabilizing vinyl aromatic monomers using selected polymerization inhibitors and polymers prepared therewith |
US20060069219A1 (en) * | 2004-09-28 | 2006-03-30 | Vilan Kosover | Sulfonated phenols with nitrophenols as polymerization inhibitors |
US7691952B2 (en) * | 2004-09-28 | 2010-04-06 | Chemtura Corporation | Sulfonated nitrophenols as polymerization inhibitors |
US7696290B2 (en) | 2004-12-03 | 2010-04-13 | Crompton Corporation | Aromatic sulfonic acids, amines, and nitrophenols in combination with nitroxyl radical-containing compounds or C-nitrosanilines as polymerization inhibitors |
JP2006176417A (ja) * | 2004-12-21 | 2006-07-06 | Hakuto Co Ltd | 芳香族ビニル化合物の重合抑制方法 |
JP4679144B2 (ja) * | 2004-12-28 | 2011-04-27 | 伯東株式会社 | ジビニルベンゼンと、スチレン又はスチレン誘導体を含む共重合体の重合抑制方法 |
EP1843995B1 (de) * | 2005-02-04 | 2013-06-05 | Chemtura Corporation | Mittel zur steuerung der exothermen reaktion von styrolmonomeren mit sulfonsäuren |
US7553896B2 (en) * | 2005-06-17 | 2009-06-30 | Chemtura Corporation | Ortho-nitrosophenols as polymerization inhibitors |
JP5068765B2 (ja) * | 2005-12-14 | 2012-11-07 | ノバルティス アーゲー | シリコーンヒドロゲルの製造方法 |
US8246858B2 (en) | 2006-03-24 | 2012-08-21 | Hakuto Co., Ltd. | Process for inhibiting polymerization of an aromatic vinyl compound |
CN101466804B (zh) | 2006-04-13 | 2012-02-22 | 西巴控股有限公司 | 硫鎓盐引发剂 |
EP2197840B1 (de) | 2007-10-10 | 2013-11-06 | Basf Se | Sulfoniumsalzinitiatoren |
GB0903005D0 (en) | 2009-02-23 | 2009-04-08 | Nufarm Ltd | Composition for controlling polymerisation |
GB201011594D0 (en) | 2010-07-09 | 2010-08-25 | Nufarm Uk Ltd | Retarder composition |
US9206268B2 (en) | 2011-09-16 | 2015-12-08 | General Electric Company | Methods and compositions for inhibiting polystyrene formation during styrene production |
CN102516005A (zh) * | 2011-11-21 | 2012-06-27 | 上海泰顿化工有限公司 | 一种硝酰基化合物组合及用途 |
CA2857384C (en) * | 2011-11-29 | 2016-08-16 | Dorf Ketal Chemicals (India) Private Limited | Amine based additive composition for control and inhibition of polymerization of styrene, and method of use thereof |
US9725649B2 (en) | 2011-12-02 | 2017-08-08 | Dorf Ketal Chemicals (India) Private Limited | Amine and nitroxide based additive composition for control and inhibition of polymerization of styrene, and method of use thereof |
PL2788303T3 (pl) | 2011-12-09 | 2015-12-31 | Dorf Ketal Chemicals India Private Ltd | Ulepszona kompozycja dodatków do kontroli i hamowania polimeryzacji aromatycznych monomerów winylowych oraz sposób jej stosowania |
US8901362B2 (en) | 2012-02-02 | 2014-12-02 | General Electric Company | Methods and compositions for styrene inhibition via in situ generation of quinone methides |
US10131817B2 (en) | 2012-10-02 | 2018-11-20 | Elkem Silicones France Sas | Cationically cross-linkable/polymerizable composition comprising an iodonium borate and releasing an acceptable odor |
EP2993164B1 (de) | 2014-09-08 | 2017-02-15 | Evonik Degussa GmbH | Phenolische (Thio)Acetale als Inhibitoren der Polymerisation von olefinisch ungesättigten Monomeren |
TWI669317B (zh) | 2014-09-22 | 2019-08-21 | 德商贏創德固賽有限責任公司 | 反應性單體的改良製造方法 |
ES2870125T3 (es) * | 2017-03-09 | 2021-10-26 | Ecolab Usa Inc | Composiciones de inhibidores de polimerización |
JP7228877B2 (ja) * | 2018-12-05 | 2023-02-27 | 精工化学株式会社 | 重合性ビニル化合物の製造方法 |
CN113825723A (zh) | 2019-04-02 | 2021-12-21 | 埃科莱布美国股份有限公司 | 具有减少的酸用量的纯二氧化氯生成系统 |
JP7445960B2 (ja) * | 2020-01-21 | 2024-03-08 | 精工化学株式会社 | 重合禁止剤及び重合性不飽和結合を有する化合物の製造方法 |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US465441A (en) * | 1891-12-15 | weisser | ||
GB1218456A (en) * | 1968-09-06 | 1971-01-06 | Bp Chem Int Ltd | Process for the stabilisation of butadiene |
GB1346774A (en) * | 1970-10-05 | 1974-02-13 | Bp Chem Int Ltd | Stabilisation of acrylonitrile |
US3733326A (en) * | 1971-03-10 | 1973-05-15 | Sankyo Co | Inhibition of the polymerization of vinyl monomers |
US3988212A (en) * | 1975-03-21 | 1976-10-26 | Cosden Technology, Inc. | Polymerization inhibitor for vinyl aromatic compounds |
US4086147A (en) * | 1976-12-10 | 1978-04-25 | Cosden Technology, Inc. | Polymerization inhibitor for vinyl aromatic compounds |
US4105506A (en) * | 1977-02-24 | 1978-08-08 | Cosden Technology, Inc. | Polymerization inhibitor for vinyl aromatic compounds |
US4132602A (en) * | 1977-11-23 | 1979-01-02 | Cosden Technology, Inc. | Polymerization inhibitor for vinyl aromatic compounds |
US4132603A (en) * | 1977-11-23 | 1979-01-02 | Cosden Technology, Inc. | Polymerization inhibitor for vinyl aromatic compounds |
US4252615A (en) * | 1978-07-18 | 1981-02-24 | Cosden Technology, Inc. | Polymerization inhibitor for vinyl aromatic compounds |
JPS5846496B2 (ja) * | 1979-09-07 | 1983-10-17 | 大阪有機化学工業株式会社 | α,β−不飽和カルボン酸エステルのポツプコ−ン重合防止法 |
US4341600A (en) * | 1981-04-06 | 1982-07-27 | Cosden Technology, Inc. | Polymerization inhibitor for vinyltoluene |
SU1027150A1 (ru) * | 1981-10-21 | 1983-07-07 | Научно-Исследовательский Институт Механики И Физики При Саратовском Ордена Трудового Красного Знамени Государственном Университете Им.Н.Г.Чернышевского | Способ стабилизации стирола или метилметакрилата |
US4376678A (en) * | 1982-07-29 | 1983-03-15 | American Hoechst Corporation | Method of inhibiting polymerization of vinyl aromatic compounds |
US4466904A (en) * | 1983-01-10 | 1984-08-21 | Cosden Technology, Inc. | Polymerization co-inhibitors for vinyl aromatic compounds |
US4468343A (en) * | 1983-04-11 | 1984-08-28 | Cosden Technology, Inc. | Polymerization co-inhibitors for vinyl aromatic compounds |
SU1139722A1 (ru) * | 1983-04-12 | 1985-02-15 | Ереванское Отделение Охтинского Ордена Ленина И Ордена Трудового Красного Знамени Научно-Производственного Объединения "Пластполимер" | Способ ингибировани полимеризации стирола |
JPS6036501A (ja) * | 1983-08-10 | 1985-02-25 | Adeka Argus Chem Co Ltd | ビニル重合禁止剤 |
US4654451A (en) * | 1985-12-27 | 1987-03-31 | Atlantic Richfield Company | Inhibiting polymerization of vinyl aromatic monomers |
US4664845A (en) * | 1986-01-09 | 1987-05-12 | Uniroyal Chemical Company, Inc. | Phenylenediamine solubilizer for dinitrophenol in aromatic solvent |
US4670131A (en) * | 1986-01-13 | 1987-06-02 | Exxon Chemical Patents Inc. | Method for controlling fouling of hydrocarbon compositions containing olefinic compounds |
EP0240297A1 (de) * | 1986-04-01 | 1987-10-07 | Betz Europe, Inc. | Verfahren zur Inhibierung der Polymerisierung von vinylaromatischen Verbindungen |
JPS63316745A (ja) * | 1987-06-19 | 1988-12-26 | Mitsubishi Petrochem Co Ltd | 芳香族ビニル化合物の重合防止方法 |
SU1558888A1 (ru) * | 1987-12-11 | 1990-04-23 | Всесоюзный Научно-Исследовательский Институт Химических Реактивов И Особочистых Химических Веществ | Способ ингибировани полимеризации стирола |
US4967027A (en) * | 1987-12-22 | 1990-10-30 | Mitsubishi Petrochemical Co., Ltd. | Method of inhibiting polymerization of styrenes |
JPH01165534A (ja) * | 1987-12-22 | 1989-06-29 | Mitsubishi Petrochem Co Ltd | スチレン類の重合防止剤 |
MX170841B (es) * | 1988-09-26 | 1993-09-20 | Goodyear Tire & Rubber | Proceso mejorado para la sintesis catalizada de metacrilaminadas y acrilimidas n-substituidas |
JPH02270837A (ja) * | 1989-04-11 | 1990-11-05 | Mitsui Petrochem Ind Ltd | イソプロペニルアセトフェノン組成物 |
-
1992
- 1992-07-29 US US07/921,824 patent/US5254760A/en not_active Expired - Lifetime
-
1993
- 1993-07-09 TW TW082105491A patent/TW226023B/zh active
- 1993-07-12 RU RU93048468A patent/RU2116285C1/ru not_active IP Right Cessation
- 1993-07-20 EP EP93810519A patent/EP0581737B1/de not_active Revoked
- 1993-07-20 ES ES93810519T patent/ES2101995T3/es not_active Expired - Lifetime
- 1993-07-20 DE DE69310044T patent/DE69310044T2/de not_active Revoked
- 1993-07-27 CA CA002101359A patent/CA2101359C/en not_active Expired - Lifetime
- 1993-07-27 MX MX9304506A patent/MX9304506A/es unknown
- 1993-07-28 KR KR1019930014662A patent/KR0177045B1/ko not_active IP Right Cessation
- 1993-07-28 BR BR9303023A patent/BR9303023A/pt not_active IP Right Cessation
- 1993-07-28 CN CN93108469A patent/CN1041513C/zh not_active Expired - Lifetime
- 1993-07-28 AU AU44250/93A patent/AU666024B2/en not_active Ceased
- 1993-07-29 JP JP5207235A patent/JP2855399B2/ja not_active Expired - Lifetime
- 1993-09-08 SA SA93140161A patent/SA93140161B1/ar unknown
Also Published As
Publication number | Publication date |
---|---|
JP2855399B2 (ja) | 1999-02-10 |
US5254760A (en) | 1993-10-19 |
AU4425093A (en) | 1994-02-03 |
JPH06166636A (ja) | 1994-06-14 |
MX9304506A (es) | 1994-01-31 |
CA2101359C (en) | 2001-03-20 |
ES2101995T3 (es) | 1997-07-16 |
DE69310044T2 (de) | 1997-11-20 |
KR0177045B1 (ko) | 1999-05-15 |
CA2101359A1 (en) | 1994-01-30 |
BR9303023A (pt) | 1994-03-15 |
AU666024B2 (en) | 1996-01-25 |
CN1041513C (zh) | 1999-01-06 |
TW226023B (de) | 1994-07-01 |
EP0581737B1 (de) | 1997-04-23 |
CN1084155A (zh) | 1994-03-23 |
SA93140161B1 (ar) | 2005-06-13 |
EP0581737A2 (de) | 1994-02-02 |
RU2116285C1 (ru) | 1998-07-27 |
KR940005687A (ko) | 1994-03-22 |
EP0581737A3 (de) | 1995-06-21 |
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