DE69318780D1 - Katalysator zur Polymerisation von Vinylverbindungen - Google Patents
Katalysator zur Polymerisation von VinylverbindungenInfo
- Publication number
- DE69318780D1 DE69318780D1 DE69318780T DE69318780T DE69318780D1 DE 69318780 D1 DE69318780 D1 DE 69318780D1 DE 69318780 T DE69318780 T DE 69318780T DE 69318780 T DE69318780 T DE 69318780T DE 69318780 D1 DE69318780 D1 DE 69318780D1
- Authority
- DE
- Germany
- Prior art keywords
- polymerization
- catalyst
- vinyl compounds
- vinyl
- compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
- C08F4/6428—Component covered by group C08F4/64 with an organo-aluminium compound with an aluminoxane, i.e. a compound containing an Al-O-Al- group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP26552792A JP3301123B2 (ja) | 1992-09-09 | 1992-09-09 | 芳香族ビニル化合物重合用触媒 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69318780D1 true DE69318780D1 (de) | 1998-07-02 |
DE69318780T2 DE69318780T2 (de) | 1998-09-24 |
Family
ID=17418377
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69318780T Expired - Fee Related DE69318780T2 (de) | 1992-09-09 | 1993-09-08 | Katalysator zur Polymerisation von Vinylverbindungen |
Country Status (6)
Country | Link |
---|---|
US (2) | US5347025A (de) |
EP (1) | EP0587143B1 (de) |
JP (1) | JP3301123B2 (de) |
KR (1) | KR100289508B1 (de) |
CA (1) | CA2105690A1 (de) |
DE (1) | DE69318780T2 (de) |
Families Citing this family (43)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE411343T1 (de) | 1994-06-13 | 2008-10-15 | Basell Polyolefine Gmbh | Uebergangsmetallverbindung |
US5527752A (en) * | 1995-03-29 | 1996-06-18 | Union Carbide Chemicals & Plastics Technology Corporation | Catalysts for the production of polyolefins |
ES2124054T3 (es) * | 1995-06-12 | 1999-01-16 | Targor Gmbh | Compuesto de metal de transicion. |
US6417130B1 (en) | 1996-03-25 | 2002-07-09 | Exxonmobil Oil Corporation | One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization |
AU3505497A (en) | 1996-07-15 | 1998-02-09 | Mobil Oil Corporation | Comonomer pretreated bimetallic catalyst for blow molding and film applications |
CA2273794A1 (en) | 1996-12-17 | 1998-06-25 | Narayanaswami Raja Dharmarajan | Themoplastic olefin compositions |
US6153551A (en) | 1997-07-14 | 2000-11-28 | Mobil Oil Corporation | Preparation of supported catalyst using trialkylaluminum-metallocene contact products |
US6051525A (en) | 1997-07-14 | 2000-04-18 | Mobil Corporation | Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution |
US6245868B1 (en) | 1998-05-29 | 2001-06-12 | Univation Technologies | Catalyst delivery method, a catalyst feeder and their use in a polymerization process |
US6100212A (en) | 1998-06-30 | 2000-08-08 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for the polymerization of olefins |
US6875719B2 (en) | 2000-04-27 | 2005-04-05 | Industrial Technology Research Institute | Catalyst composition for preparing olefin polymers |
EP1495038B1 (de) * | 2002-04-12 | 2008-07-23 | Dow Global Technologies Inc. | Azaborolylkomplexe mit metallen der gruppe 4, katalysatoren und verfahren zur olefinepolymerisation |
EP1611169B1 (de) | 2003-03-21 | 2010-06-02 | Dow Global Technologies Inc. | Verfahren zur herstellung von polyolefinen mit kontrollierter morphologie |
EP2218751A1 (de) | 2004-12-17 | 2010-08-18 | Dow Global Technologies Inc. | Rheologiemodifizierte Polyethylenzusammensetzungen |
DE112006001733T5 (de) | 2005-07-01 | 2008-07-31 | Albemarle Corporation | Aluminoxanatsalzzusammensetzungen mit verbesserter Stabilität in aromatischen und aliphatischen Lösungsmitteln |
EP1803747A1 (de) | 2005-12-30 | 2007-07-04 | Borealis Technology Oy | Oberflächemodifizierte Polymerisationskatalysatoren zur Herstellung von Polyolefinfilmen mit niedrigem Gelgehalt |
EP2016128B1 (de) | 2006-05-02 | 2010-07-21 | Dow Global Technologies Inc. | Sehr dichte polyethylenzusammensetzungen, verfahren zu deren herstellung, draht- und kabelhüllen, die daraus hergestellt wurden und verfahren zur herstellung derartiger draht- und kabelhüllen |
US7456244B2 (en) * | 2006-05-23 | 2008-11-25 | Dow Global Technologies | High-density polyethylene compositions and method of making the same |
KR20100014214A (ko) * | 2007-05-02 | 2010-02-10 | 다우 글로벌 테크놀로지스 인크. | 고-밀도 폴리에틸렌 조성물, 그의 제조 방법, 그로부터 만들어진 사출 성형 물품, 및 이러한 물품의 제조 방법 |
US7981517B2 (en) * | 2007-08-28 | 2011-07-19 | Dow Global Technologies Inc. | Bituminous compositions and methods of making and using same |
BRPI0922454A2 (pt) | 2008-12-18 | 2018-05-22 | Univation Tech Llc | método para tratamento de leito de semente para uma reação de polimerização |
CN102361925B (zh) | 2009-01-30 | 2013-08-14 | 陶氏环球技术有限责任公司 | 高密度聚乙烯组合物、其制备方法、由其制备的封闭器件、和制备所述封闭器件的方法 |
ES2540117T3 (es) | 2010-11-22 | 2015-07-08 | Albemarle Corporation | Composiciones de activador, su preparación, y su uso en catálisis |
CN104854150B (zh) | 2012-04-27 | 2017-05-24 | 阿尔比马尔公司 | 活化剂组合物、其制备及其在催化剂中的用途 |
ES2823768T3 (es) | 2012-12-28 | 2021-05-10 | Univation Tech Llc | Métodos para integrar la producción de aluminoxano en la producción de catalizador |
CN105121015A (zh) | 2013-01-14 | 2015-12-02 | 尤尼威蒂恩技术有限责任公司 | 制备高产率催化剂系统的方法 |
CN107660216B (zh) | 2015-05-08 | 2021-05-14 | 埃克森美孚化学专利公司 | 聚合方法 |
WO2018063765A1 (en) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Polymerization process |
WO2018063767A1 (en) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Polymerization process |
WO2018063764A1 (en) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Polymerization process |
WO2018118155A1 (en) | 2016-12-20 | 2018-06-28 | Exxonmobil Chemical Patents Inc. | Polymerization process |
WO2019118073A1 (en) | 2017-12-13 | 2019-06-20 | Exxonmobil Chemical Patents Inc. | Deactivation methods for active components from gas phase polyolefin polymerization process |
WO2019173030A1 (en) | 2018-03-08 | 2019-09-12 | Exxonmobil Chemical Patents Inc. | Methods of preparing and monitoring a seed bed for polymerization reactor startup |
CN112055720B (zh) | 2018-05-02 | 2022-11-22 | 埃克森美孚化学专利公司 | 从中试装置放大到较大生产设施的方法 |
EP3788081A1 (de) | 2018-05-02 | 2021-03-10 | ExxonMobil Chemical Patents Inc. | Verfahren zur aufskalierung von einer pilotanlage zu einer grösseren produktionsanlage |
WO2020014138A1 (en) | 2018-07-09 | 2020-01-16 | Exxonmobil Chemical Patents Inc. | Polyethylene cast films and methods for making the same |
CN112469556B (zh) | 2018-07-26 | 2023-05-02 | 埃克森美孚化学专利公司 | 多层泡沫膜及其制造方法 |
CN113195603B (zh) | 2018-11-13 | 2023-05-26 | 埃克森美孚化学专利公司 | 聚乙烯膜 |
US11649331B2 (en) | 2018-11-13 | 2023-05-16 | Exxonmobil Chemical Patents Inc. | Polyethylene blends and films |
WO2020163079A1 (en) | 2019-02-06 | 2020-08-13 | Exxonmobil Chemical Patents Inc. | Films and backsheets for hygiene articles |
US20230018505A1 (en) | 2019-12-17 | 2023-01-19 | Exxonmobil Chemical Patents Inc. | Films Made of Polyethylene Blends for Improved Sealing Performance and Mechanical Properties |
US20230097375A1 (en) | 2020-03-12 | 2023-03-30 | Exxonmobil Chemical Patents Inc. | Films made of polyethylene blends for improved bending stiffness and high md tear resistance |
WO2022232760A1 (en) | 2021-04-30 | 2022-11-03 | Exxonmobil Chemical Patents Inc. | Processes for transitioning between different polymerization catalysts in a polymerization reactor |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL296403A (de) * | 1962-08-08 | |||
US4607112A (en) * | 1984-03-28 | 1986-08-19 | California Institute Of Technology | Cp2 TiCH2 -containing catalyst for polymerization of difunctional ring compounds |
JP2929465B2 (ja) * | 1991-03-01 | 1999-08-03 | 東ソー株式会社 | 芳香族ビニル化合物重合用触媒および芳香族ビニル化合物重合体の製造方法 |
-
1992
- 1992-09-09 JP JP26552792A patent/JP3301123B2/ja not_active Expired - Fee Related
-
1993
- 1993-09-02 KR KR1019930017462A patent/KR100289508B1/ko not_active IP Right Cessation
- 1993-09-07 US US08/117,290 patent/US5347025A/en not_active Expired - Fee Related
- 1993-09-08 CA CA002105690A patent/CA2105690A1/en not_active Abandoned
- 1993-09-08 DE DE69318780T patent/DE69318780T2/de not_active Expired - Fee Related
- 1993-09-08 EP EP93114423A patent/EP0587143B1/de not_active Expired - Lifetime
-
1994
- 1994-03-10 US US08/208,220 patent/US5348926A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
KR940007044A (ko) | 1994-04-26 |
EP0587143B1 (de) | 1998-05-27 |
US5347025A (en) | 1994-09-13 |
JPH0693009A (ja) | 1994-04-05 |
US5348926A (en) | 1994-09-20 |
DE69318780T2 (de) | 1998-09-24 |
JP3301123B2 (ja) | 2002-07-15 |
CA2105690A1 (en) | 1994-03-10 |
EP0587143A1 (de) | 1994-03-16 |
KR100289508B1 (ko) | 2001-09-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |