DE69215080T2 - Verfahren zur Herstellung von Olefinen - Google Patents
Verfahren zur Herstellung von OlefinenInfo
- Publication number
- DE69215080T2 DE69215080T2 DE69215080T DE69215080T DE69215080T2 DE 69215080 T2 DE69215080 T2 DE 69215080T2 DE 69215080 T DE69215080 T DE 69215080T DE 69215080 T DE69215080 T DE 69215080T DE 69215080 T2 DE69215080 T2 DE 69215080T2
- Authority
- DE
- Germany
- Prior art keywords
- methane
- effluent
- cracking
- coupling
- olefins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G57/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one cracking process or refining process and at least one other conversion process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2475—Membrane reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of germanium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
- B01J8/009—Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
- C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
- C07C2/84—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling catalytic
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
- C07C4/04—Thermal processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00054—Controlling or regulating the heat exchange system
- B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
- B01J2219/00058—Temperature measurement
- B01J2219/00063—Temperature measurement of the reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00117—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with two or more reactions in heat exchange with each other, such as an endothermic reaction in heat exchange with an exothermic reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00121—Controlling the temperature by direct heating or cooling
- B01J2219/00123—Controlling the temperature by direct heating or cooling adding a temperature modifying medium to the reactants
- B01J2219/00126—Cryogenic coolants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/0015—Controlling the temperature by thermal insulation means
- B01J2219/00155—Controlling the temperature by thermal insulation means using insulating materials or refractories
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/909—Heat considerations
- Y10S585/91—Exploiting or conserving heat of quenching, reaction, or regeneration
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/909—Heat considerations
- Y10S585/911—Heat considerations introducing, maintaining, or removing heat by atypical procedure
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/929—Special chemical considerations
- Y10S585/943—Synthesis from methane or inorganic carbon source, e.g. coal
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Control Of Motors That Do Not Use Commutators (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/815,244 US5254781A (en) | 1991-12-31 | 1991-12-31 | Olefins process which combines hydrocarbon cracking with coupling methane |
PCT/US1992/011038 WO1993013039A1 (en) | 1991-12-31 | 1992-12-21 | An olefins process which combines hydrocarbon cracking with methane coupling |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69215080D1 DE69215080D1 (de) | 1996-12-12 |
DE69215080T2 true DE69215080T2 (de) | 1997-03-06 |
Family
ID=25217277
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69225334T Expired - Fee Related DE69225334T2 (de) | 1991-12-31 | 1992-12-16 | Umwandlung von kohlenwasserstoffen |
DE69215080T Expired - Fee Related DE69215080T2 (de) | 1991-12-31 | 1992-12-21 | Verfahren zur Herstellung von Olefinen |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69225334T Expired - Fee Related DE69225334T2 (de) | 1991-12-31 | 1992-12-16 | Umwandlung von kohlenwasserstoffen |
Country Status (7)
Country | Link |
---|---|
US (1) | US5254781A (de) |
EP (2) | EP0623101B1 (de) |
JP (2) | JPH07502733A (de) |
AT (2) | ATE165593T1 (de) |
DE (2) | DE69225334T2 (de) |
ES (1) | ES2093402T3 (de) |
WO (2) | WO1993013037A1 (de) |
Families Citing this family (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5599510A (en) * | 1991-12-31 | 1997-02-04 | Amoco Corporation | Catalytic wall reactors and use of catalytic wall reactors for methane coupling and hydrocarbon cracking reactions |
EP0639548A1 (de) * | 1993-08-17 | 1995-02-22 | Amoco Corporation | Reaktoren mit katalytischen Wänden und Anwendung von diesen Reaktoren bei der Methankopplung kombiniert mit Kohlenwasserstoffcrackung |
CN1044787C (zh) * | 1993-12-29 | 1999-08-25 | 厦门大学 | 异丁烷氧化脱氢制异丁烯催化剂及其制造方法 |
JP2925963B2 (ja) * | 1994-12-05 | 1999-07-28 | 石油公団 | メタンの酸化カップリング方法とその装置 |
US5512255A (en) * | 1994-12-06 | 1996-04-30 | Wright Malta Corporation | Apparatus for producing methanol |
US6441263B1 (en) * | 2000-07-07 | 2002-08-27 | Chevrontexaco Corporation | Ethylene manufacture by use of molecular redistribution on feedstock C3-5 components |
US6518476B1 (en) | 2000-09-18 | 2003-02-11 | Union Carbide Chemicals & Plastics Technology Corporation | Methods for manufacturing olefins from lower alkans by oxidative dehydrogenation |
GB0311774D0 (en) * | 2003-05-22 | 2003-06-25 | Bp Chem Int Ltd | Production of olefins |
US7183451B2 (en) * | 2003-09-23 | 2007-02-27 | Synfuels International, Inc. | Process for the conversion of natural gas to hydrocarbon liquids |
US7208647B2 (en) * | 2003-09-23 | 2007-04-24 | Synfuels International, Inc. | Process for the conversion of natural gas to reactive gaseous products comprising ethylene |
US8127527B2 (en) * | 2004-11-22 | 2012-03-06 | General Electric Company | Methods and systems for operating oxidizer systems |
US8013197B2 (en) * | 2005-02-18 | 2011-09-06 | Synfuels International, Inc. | Absorption and conversion of acetylenic compounds |
US7875755B2 (en) * | 2007-11-30 | 2011-01-25 | Uop Llc | Cracking C5+ paraffins to increase light olefin production |
JP5441025B2 (ja) * | 2008-12-26 | 2014-03-12 | Jx日鉱日石エネルギー株式会社 | ジシクロペンタジエンの精製方法 |
CA2748247C (en) | 2008-12-26 | 2019-04-02 | Jx Nippon Oil & Energy Corporation | Method for refining dicyclopentadiene |
US8710286B2 (en) * | 2009-03-31 | 2014-04-29 | Fina Technology, Inc. | Oxidative coupling of hydrocarbons as heat source |
CN102260519B (zh) | 2010-05-31 | 2017-03-01 | 通用电气公司 | 烃类裂解方法和反应装置 |
CN102557855B (zh) | 2010-12-22 | 2015-11-25 | 通用电气公司 | 烃类裂解方法和反应装置以及烃类裂解反应装置的涂布方法 |
US9062525B2 (en) * | 2011-07-07 | 2015-06-23 | Single Buoy Moorings, Inc. | Offshore heavy oil production |
US9133079B2 (en) | 2012-01-13 | 2015-09-15 | Siluria Technologies, Inc. | Process for separating hydrocarbon compounds |
US9969660B2 (en) * | 2012-07-09 | 2018-05-15 | Siluria Technologies, Inc. | Natural gas processing and systems |
DE102012018602A1 (de) * | 2012-09-20 | 2014-03-20 | Linde Aktiengesellschaft | Anlage und Verfahren zur Herstellung von Ethylen |
WO2014089479A1 (en) | 2012-12-07 | 2014-06-12 | Siluria Technologies, Inc. | Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products |
RU2534991C1 (ru) * | 2013-04-22 | 2014-12-10 | Юрий Николаевич Филимонов | Устройство для получения непредельных углеводородов, преимущественно этилена |
DE102013106837A1 (de) * | 2013-06-28 | 2014-12-31 | Jenoptik Katasorb Gmbh | Verfahren und Vorrichtung zur thermischen Umsetzung eines Stoffgemisches in einem Reaktorraum zu Partikeln |
WO2015057753A1 (en) * | 2013-10-16 | 2015-04-23 | Saudi Basic Industries Corporation | Method for converting methane to ethylene |
WO2015081122A2 (en) | 2013-11-27 | 2015-06-04 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
CN106068323B (zh) | 2014-01-08 | 2019-09-06 | 希路瑞亚技术公司 | 乙烯成液体的系统和方法 |
US10377682B2 (en) | 2014-01-09 | 2019-08-13 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
WO2015106023A1 (en) | 2014-01-09 | 2015-07-16 | Siluria Technologies, Inc. | Oxidative coupling of methane implementations for olefin production |
EP3056481A1 (de) * | 2015-02-16 | 2016-08-17 | Linde Aktiengesellschaft | Verfahren und Anlage zur Herstellung von Kohlenwasserstoffen |
EP3056480A1 (de) * | 2015-02-16 | 2016-08-17 | Linde Aktiengesellschaft | Verfahren und Anlage zur Erzeugung von Kohlenwasserstoffen |
US10793490B2 (en) | 2015-03-17 | 2020-10-06 | Lummus Technology Llc | Oxidative coupling of methane methods and systems |
US9334204B1 (en) | 2015-03-17 | 2016-05-10 | Siluria Technologies, Inc. | Efficient oxidative coupling of methane processes and systems |
US20160289143A1 (en) | 2015-04-01 | 2016-10-06 | Siluria Technologies, Inc. | Advanced oxidative coupling of methane |
US9328297B1 (en) | 2015-06-16 | 2016-05-03 | Siluria Technologies, Inc. | Ethylene-to-liquids systems and methods |
EP3362425B1 (de) | 2015-10-16 | 2020-10-28 | Lummus Technology LLC | Trennverfahren und systeme zur oxidativen kupplung von methan |
CA3019396A1 (en) | 2016-04-13 | 2017-10-19 | Siluria Technologies, Inc. | Oxidative coupling of methane for olefin production |
EP3248670A1 (de) * | 2016-05-24 | 2017-11-29 | Linde Aktiengesellschaft | Prozess und anlagenverbund zur herstellung stickstoffhaltiger syntheseprodukte |
US20180169561A1 (en) | 2016-12-19 | 2018-06-21 | Siluria Technologies, Inc. | Methods and systems for performing chemical separations |
US11001542B2 (en) | 2017-05-23 | 2021-05-11 | Lummus Technology Llc | Integration of oxidative coupling of methane processes |
WO2019010498A1 (en) | 2017-07-07 | 2019-01-10 | Siluria Technologies, Inc. | SYSTEMS AND METHODS FOR OXIDIZING METHANE COUPLING |
EP3434662A1 (de) * | 2017-07-26 | 2019-01-30 | Linde Aktiengesellschaft | Verfahren und anlage zur gewinnung von olefinen |
US10662130B2 (en) * | 2017-08-15 | 2020-05-26 | Exxonmobil Research And Engineering Company | Process for generation of olefins |
CN110041156A (zh) * | 2019-05-30 | 2019-07-23 | 中国科学院山西煤炭化学研究所 | 一种甲烷直接转化制乙烯的集成工艺 |
CN113800995A (zh) * | 2020-06-17 | 2021-12-17 | 中国石油化工股份有限公司 | 一种丙烷催化脱氢反应与甲烷氧化偶联反应耦合的方法及系统 |
CN113816822A (zh) * | 2020-06-18 | 2021-12-21 | 中国石油化工股份有限公司 | 一种丙烷催化脱氢反应与甲烷氧化偶联反应耦合的方法及系统 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2549844A (en) * | 1948-08-23 | 1951-04-24 | Standard Oil Dev Co | Dehydrogenation catalyst |
US3223746A (en) * | 1962-12-28 | 1965-12-14 | Socony Mobil Oil Co Inc | High temperature heat exchange |
NL128466C (de) * | 1964-03-07 | |||
US4656155A (en) * | 1985-07-25 | 1987-04-07 | Atlantic Richfield Company | Reducible metal oxide compositions containing zirconium oxide, yttrium oxide and an alkali metal component |
US5012028A (en) * | 1986-07-11 | 1991-04-30 | The Standard Oil Company | Process for upgrading light hydrocarbons using oxidative coupling and pyrolysis |
FR2629451B1 (fr) * | 1988-04-05 | 1991-07-12 | Inst Francais Du Petrole | Procede de production d'olefines a partir du gaz naturel |
US5024984A (en) * | 1988-08-17 | 1991-06-18 | Amoco Corporation | Catalysts for the oxidative conversion of methane to higher hydrocarbons |
IT1238086B (it) * | 1990-02-07 | 1993-07-05 | Snam Progetti | Sistema catalittico e procedimento per la conversione del metano in idrocarburi superiori |
-
1991
- 1991-12-31 US US07/815,244 patent/US5254781A/en not_active Expired - Fee Related
-
1992
- 1992-12-16 WO PCT/US1992/010777 patent/WO1993013037A1/en active IP Right Grant
- 1992-12-16 AT AT93901343T patent/ATE165593T1/de not_active IP Right Cessation
- 1992-12-16 DE DE69225334T patent/DE69225334T2/de not_active Expired - Fee Related
- 1992-12-16 JP JP5511715A patent/JPH07502733A/ja active Pending
- 1992-12-16 EP EP93901343A patent/EP0623101B1/de not_active Expired - Lifetime
- 1992-12-21 JP JP5511807A patent/JPH06506482A/ja not_active Withdrawn
- 1992-12-21 ES ES93901141T patent/ES2093402T3/es not_active Expired - Lifetime
- 1992-12-21 EP EP93901141A patent/EP0575579B1/de not_active Expired - Lifetime
- 1992-12-21 WO PCT/US1992/011038 patent/WO1993013039A1/en active IP Right Grant
- 1992-12-21 AT AT93901141T patent/ATE144970T1/de not_active IP Right Cessation
- 1992-12-21 DE DE69215080T patent/DE69215080T2/de not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE69225334T2 (de) | 1998-12-17 |
DE69215080D1 (de) | 1996-12-12 |
WO1993013037A1 (en) | 1993-07-08 |
ES2093402T3 (es) | 1996-12-16 |
US5254781A (en) | 1993-10-19 |
EP0623101A1 (de) | 1994-11-09 |
ATE165593T1 (de) | 1998-05-15 |
DE69225334D1 (de) | 1998-06-04 |
JPH07502733A (ja) | 1995-03-23 |
ATE144970T1 (de) | 1996-11-15 |
EP0623101B1 (de) | 1998-04-29 |
EP0575579A1 (de) | 1993-12-29 |
JPH06506482A (ja) | 1994-07-21 |
WO1993013039A1 (en) | 1993-07-08 |
EP0575579B1 (de) | 1996-11-06 |
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