DE69225334D1 - Umwandlung von kohlenwasserstoffen - Google Patents

Umwandlung von kohlenwasserstoffen

Info

Publication number
DE69225334D1
DE69225334D1 DE69225334T DE69225334T DE69225334D1 DE 69225334 D1 DE69225334 D1 DE 69225334D1 DE 69225334 T DE69225334 T DE 69225334T DE 69225334 T DE69225334 T DE 69225334T DE 69225334 D1 DE69225334 D1 DE 69225334D1
Authority
DE
Germany
Prior art keywords
methane
effluent
cracking
coupling
cracking process
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69225334T
Other languages
English (en)
Other versions
DE69225334T2 (de
Inventor
Mark Kaminsky
Mark Kleefisch
George Huff
Don Waschecheck
Mark Barr
Victor Shum
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Corp North America Inc
Original Assignee
BP Corp North America Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Corp North America Inc filed Critical BP Corp North America Inc
Application granted granted Critical
Publication of DE69225334D1 publication Critical patent/DE69225334D1/de
Publication of DE69225334T2 publication Critical patent/DE69225334T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G57/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one cracking process or refining process and at least one other conversion process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2475—Membrane reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B01J8/009—Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
    • C07C2/84—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling catalytic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/04—Thermal processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00054—Controlling or regulating the heat exchange system
    • B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2219/00058—Temperature measurement
    • B01J2219/00063—Temperature measurement of the reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00117—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with two or more reactions in heat exchange with each other, such as an endothermic reaction in heat exchange with an exothermic reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00121—Controlling the temperature by direct heating or cooling
    • B01J2219/00123—Controlling the temperature by direct heating or cooling adding a temperature modifying medium to the reactants
    • B01J2219/00126—Cryogenic coolants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/0015—Controlling the temperature by thermal insulation means
    • B01J2219/00155—Controlling the temperature by thermal insulation means using insulating materials or refractories
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/909—Heat considerations
    • Y10S585/91—Exploiting or conserving heat of quenching, reaction, or regeneration
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/909—Heat considerations
    • Y10S585/911—Heat considerations introducing, maintaining, or removing heat by atypical procedure
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/929—Special chemical considerations
    • Y10S585/943—Synthesis from methane or inorganic carbon source, e.g. coal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Control Of Motors That Do Not Use Commutators (AREA)
  • Catalysts (AREA)
DE69225334T 1991-12-31 1992-12-16 Umwandlung von kohlenwasserstoffen Expired - Fee Related DE69225334T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/815,244 US5254781A (en) 1991-12-31 1991-12-31 Olefins process which combines hydrocarbon cracking with coupling methane
PCT/US1992/010777 WO1993013037A1 (en) 1991-12-31 1992-12-16 Hydrocarbon conversion

Publications (2)

Publication Number Publication Date
DE69225334D1 true DE69225334D1 (de) 1998-06-04
DE69225334T2 DE69225334T2 (de) 1998-12-17

Family

ID=25217277

Family Applications (2)

Application Number Title Priority Date Filing Date
DE69225334T Expired - Fee Related DE69225334T2 (de) 1991-12-31 1992-12-16 Umwandlung von kohlenwasserstoffen
DE69215080T Expired - Fee Related DE69215080T2 (de) 1991-12-31 1992-12-21 Verfahren zur Herstellung von Olefinen

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE69215080T Expired - Fee Related DE69215080T2 (de) 1991-12-31 1992-12-21 Verfahren zur Herstellung von Olefinen

Country Status (7)

Country Link
US (1) US5254781A (de)
EP (2) EP0623101B1 (de)
JP (2) JPH07502733A (de)
AT (2) ATE165593T1 (de)
DE (2) DE69225334T2 (de)
ES (1) ES2093402T3 (de)
WO (2) WO1993013037A1 (de)

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US5599510A (en) * 1991-12-31 1997-02-04 Amoco Corporation Catalytic wall reactors and use of catalytic wall reactors for methane coupling and hydrocarbon cracking reactions
EP0639548A1 (de) * 1993-08-17 1995-02-22 Amoco Corporation Reaktoren mit katalytischen Wänden und Anwendung von diesen Reaktoren bei der Methankopplung kombiniert mit Kohlenwasserstoffcrackung
CN1044787C (zh) * 1993-12-29 1999-08-25 厦门大学 异丁烷氧化脱氢制异丁烯催化剂及其制造方法
JP2925963B2 (ja) * 1994-12-05 1999-07-28 石油公団 メタンの酸化カップリング方法とその装置
US5512255A (en) * 1994-12-06 1996-04-30 Wright Malta Corporation Apparatus for producing methanol
US6441263B1 (en) * 2000-07-07 2002-08-27 Chevrontexaco Corporation Ethylene manufacture by use of molecular redistribution on feedstock C3-5 components
US6518476B1 (en) 2000-09-18 2003-02-11 Union Carbide Chemicals & Plastics Technology Corporation Methods for manufacturing olefins from lower alkans by oxidative dehydrogenation
GB0311774D0 (en) * 2003-05-22 2003-06-25 Bp Chem Int Ltd Production of olefins
US7208647B2 (en) * 2003-09-23 2007-04-24 Synfuels International, Inc. Process for the conversion of natural gas to reactive gaseous products comprising ethylene
US7183451B2 (en) * 2003-09-23 2007-02-27 Synfuels International, Inc. Process for the conversion of natural gas to hydrocarbon liquids
US8127527B2 (en) * 2004-11-22 2012-03-06 General Electric Company Methods and systems for operating oxidizer systems
US8013197B2 (en) * 2005-02-18 2011-09-06 Synfuels International, Inc. Absorption and conversion of acetylenic compounds
US7875755B2 (en) * 2007-11-30 2011-01-25 Uop Llc Cracking C5+ paraffins to increase light olefin production
WO2010073841A1 (ja) 2008-12-26 2010-07-01 新日本石油株式会社 ジシクロペンタジエンの精製方法
JP5441025B2 (ja) * 2008-12-26 2014-03-12 Ｊｘ日鉱日石エネルギー株式会社 ジシクロペンタジエンの精製方法
US8710286B2 (en) * 2009-03-31 2014-04-29 Fina Technology, Inc. Oxidative coupling of hydrocarbons as heat source
CN102260519B (zh) 2010-05-31 2017-03-01 通用电气公司 烃类裂解方法和反应装置
CN102557855B (zh) 2010-12-22 2015-11-25 通用电气公司 烃类裂解方法和反应装置以及烃类裂解反应装置的涂布方法
US9062525B2 (en) * 2011-07-07 2015-06-23 Single Buoy Moorings, Inc. Offshore heavy oil production
WO2013106771A2 (en) 2012-01-13 2013-07-18 Siluria Technologies, Inc. Process for separating hydrocarbon compounds
US9969660B2 (en) 2012-07-09 2018-05-15 Siluria Technologies, Inc. Natural gas processing and systems
DE102012018602A1 (de) * 2012-09-20 2014-03-20 Linde Aktiengesellschaft Anlage und Verfahren zur Herstellung von Ethylen
CA2893948C (en) 2012-12-07 2022-12-06 Siluria Technologies, Inc. Integrated processes and systems for conversion of methane to ethylene and conversion of ethylene to higher hydrocarbon products
RU2534991C1 (ru) * 2013-04-22 2014-12-10 Юрий Николаевич Филимонов Устройство для получения непредельных углеводородов, преимущественно этилена
DE102013106837A1 (de) 2013-06-28 2014-12-31 Jenoptik Katasorb Gmbh Verfahren und Vorrichtung zur thermischen Umsetzung eines Stoffgemisches in einem Reaktorraum zu Partikeln
WO2015057753A1 (en) * 2013-10-16 2015-04-23 Saudi Basic Industries Corporation Method for converting methane to ethylene
EP3074119B1 (de) 2013-11-27 2019-01-09 Siluria Technologies, Inc. Reaktoren und systeme zur oxidativen kupplung von methan
CN106068323B (zh) 2014-01-08 2019-09-06 希路瑞亚技术公司 乙烯成液体的系统和方法
US10377682B2 (en) 2014-01-09 2019-08-13 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
AU2015204709B2 (en) 2014-01-09 2019-08-15 Lummus Technology Llc Oxidative coupling of methane implementations for olefin production
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EP3056480A1 (de) * 2015-02-16 2016-08-17 Linde Aktiengesellschaft Verfahren und Anlage zur Erzeugung von Kohlenwasserstoffen
US10793490B2 (en) 2015-03-17 2020-10-06 Lummus Technology Llc Oxidative coupling of methane methods and systems
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WO2017065947A1 (en) 2015-10-16 2017-04-20 Siluria Technologies, Inc. Separation methods and systems for oxidative coupling of methane
EP4071131A1 (de) 2016-04-13 2022-10-12 Lummus Technology LLC Vorrichtung und verfahren zum wärmetausch
EP3248670A1 (de) * 2016-05-24 2017-11-29 Linde Aktiengesellschaft Prozess und anlagenverbund zur herstellung stickstoffhaltiger syntheseprodukte
EP3554672A4 (de) 2016-12-19 2020-08-12 Siluria Technologies, Inc. Verfahren und systeme für chemische abscheidungen
EP3630707B1 (de) 2017-05-23 2023-09-06 Lummus Technology LLC Integration einer oxidativen kopplung von methanprozessen
RU2020102298A (ru) 2017-07-07 2021-08-10 Люммус Текнолоджи Ллс Системы и способы окислительного сочетания метана
EP3434662A1 (de) * 2017-07-26 2019-01-30 Linde Aktiengesellschaft Verfahren und anlage zur gewinnung von olefinen
US10662130B2 (en) * 2017-08-15 2020-05-26 Exxonmobil Research And Engineering Company Process for generation of olefins
CN110041156A (zh) * 2019-05-30 2019-07-23 中国科学院山西煤炭化学研究所 一种甲烷直接转化制乙烯的集成工艺
CN113816822A (zh) * 2020-06-18 2021-12-21 中国石油化工股份有限公司 一种丙烷催化脱氢反应与甲烷氧化偶联反应耦合的方法及系统

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US2549844A (en) * 1948-08-23 1951-04-24 Standard Oil Dev Co Dehydrogenation catalyst
US3223746A (en) * 1962-12-28 1965-12-14 Socony Mobil Oil Co Inc High temperature heat exchange
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US5012028A (en) * 1986-07-11 1991-04-30 The Standard Oil Company Process for upgrading light hydrocarbons using oxidative coupling and pyrolysis
FR2629451B1 (fr) * 1988-04-05 1991-07-12 Inst Francais Du Petrole Procede de production d'olefines a partir du gaz naturel
US5024984A (en) * 1988-08-17 1991-06-18 Amoco Corporation Catalysts for the oxidative conversion of methane to higher hydrocarbons
IT1238086B (it) * 1990-02-07 1993-07-05 Snam Progetti Sistema catalittico e procedimento per la conversione del metano in idrocarburi superiori

Also Published As

Publication number Publication date
EP0623101B1 (de) 1998-04-29
JPH07502733A (ja) 1995-03-23
DE69215080D1 (de) 1996-12-12
DE69225334T2 (de) 1998-12-17
ATE144970T1 (de) 1996-11-15
US5254781A (en) 1993-10-19
DE69215080T2 (de) 1997-03-06
ATE165593T1 (de) 1998-05-15
WO1993013037A1 (en) 1993-07-08
EP0623101A1 (de) 1994-11-09
WO1993013039A1 (en) 1993-07-08
ES2093402T3 (es) 1996-12-16
JPH06506482A (ja) 1994-07-21
EP0575579A1 (de) 1993-12-29
EP0575579B1 (de) 1996-11-06

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