DE69119736T2 - Zinnhaltige Elastomere und Produkte mit reduzierten Hysteresiseigenschaften - Google Patents

Zinnhaltige Elastomere und Produkte mit reduzierten Hysteresiseigenschaften

Info

Publication number
DE69119736T2
DE69119736T2 DE69119736T DE69119736T DE69119736T2 DE 69119736 T2 DE69119736 T2 DE 69119736T2 DE 69119736 T DE69119736 T DE 69119736T DE 69119736 T DE69119736 T DE 69119736T DE 69119736 T2 DE69119736 T2 DE 69119736T2
Authority
DE
Germany
Prior art keywords
tin
products
hysteresis properties
reduced hysteresis
containing elastomers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69119736T
Other languages
English (en)
Other versions
DE69119736D1 (de
Inventor
William L Hergenrother
Tristram W Bethea
John M Doshak
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bridgestone Firestone Inc
Original Assignee
Bridgestone Firestone Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bridgestone Firestone Inc filed Critical Bridgestone Firestone Inc
Publication of DE69119736D1 publication Critical patent/DE69119736D1/de
Application granted granted Critical
Publication of DE69119736T2 publication Critical patent/DE69119736T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/22—Tin compounds
    • C07F7/2288—Compounds with one or more Sn-metal linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
    • C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
    • C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C08F4/48—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
    • Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction 

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Tires In General (AREA)
  • Polymerisation Methods In General (AREA)
DE69119736T 1991-01-02 1991-12-30 Zinnhaltige Elastomere und Produkte mit reduzierten Hysteresiseigenschaften Expired - Lifetime DE69119736T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/636,961 US5268439A (en) 1991-01-02 1991-01-02 Tin containing elastomers and products having reduced hysteresis properties

Publications (2)

Publication Number Publication Date
DE69119736D1 DE69119736D1 (de) 1996-06-27
DE69119736T2 true DE69119736T2 (de) 1996-10-02

Family

ID=24554020

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69119736T Expired - Lifetime DE69119736T2 (de) 1991-01-02 1991-12-30 Zinnhaltige Elastomere und Produkte mit reduzierten Hysteresiseigenschaften

Country Status (6)

Country Link
US (1) US5268439A (de)
EP (1) EP0493839B1 (de)
JP (2) JPH082927B2 (de)
CA (1) CA2058562C (de)
DE (1) DE69119736T2 (de)
ES (1) ES2087228T3 (de)

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JP3330991B2 (ja) * 1992-12-28 2002-10-07 株式会社ブリヂストン 重合体の製造方法
US5506319A (en) * 1993-03-02 1996-04-09 Bridgestone Corporation Vinyl-substituted benzylorganotin compound and a polymer thereof
JP3378605B2 (ja) * 1993-03-25 2003-02-17 株式会社ブリヂストン 重合体の製造方法
US5508336A (en) * 1993-12-29 1996-04-16 Bridgestone Corporation Rubber composition
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US5502129A (en) * 1994-05-13 1996-03-26 Bridgestone Corporation Triorganotin lithium, process to prepare same and anionic polymerization initiated therewith
US5610227A (en) * 1995-06-07 1997-03-11 Bridgestone/Firestone, Inc. Lithium amino magnesiate polymerization initiators and elastomers having reduced hysteresis
ES2116199B1 (es) * 1995-07-17 1999-04-01 Repsol Quimica Sa Procedimiento de preparacion de copolimeros de 1,3 butadieno y estireno utiles para la fabricacion de neumaticos con baja resistencia a la rodadura y copolimeros de 1,3-butadieno y estireno asi obtenidos,
CN1048989C (zh) * 1995-10-17 2000-02-02 中国石油化工总公司 多官能团有机碱金属引发剂及其合成方法
DE19623678A1 (de) * 1996-06-14 1997-12-18 Metallgesellschaft Ag Verfahren zur Herstellung Triorganostannyllithiumverbindungen sowie deren Verwendung
US5700888A (en) * 1996-11-07 1997-12-23 Bridgestone Corporation Synthesis of macrocyclic polymers having low hysteresis compounded properties
US5877336A (en) * 1996-12-31 1999-03-02 Bridgestone Corporation Synthesis of tributyltin lithium
US5981639A (en) * 1997-01-31 1999-11-09 The Goodyear Tire & Rubber Company Stabilization of tin-coupled polymers
US6043321A (en) * 1998-01-19 2000-03-28 The Goodyear Tire & Rubber Company Asymmetrical tin-coupled rubbery polymers
US6252007B1 (en) * 1997-07-11 2001-06-26 Bridgestone Corporation Elastomers having a reduced hysteresis via interaction of polymer with silica surfaces
US6136914A (en) 1998-03-13 2000-10-24 Bridgestone Corporation Anionic polymerization initiators for preparing macro-branched diene rubbers
US6071847A (en) * 1998-03-13 2000-06-06 Bridgestone Corporation Gas phase anionic polymerization of diene elastomers
US6433105B1 (en) * 2000-06-09 2002-08-13 Bridgestone Corporation Process for desolventizing low molecular weight diene polymers
US6313210B1 (en) 2000-07-31 2001-11-06 Bridgestone Coporation Silica-reinforced rubber compounds containing moisture stabilized polymers
US6420484B1 (en) 2000-09-29 2002-07-16 The Goodyear Tire & Rubber Company Asymmetrical tin-coupled rubbery polymers
US20030111770A1 (en) * 2001-12-13 2003-06-19 Bridgestone Corp. Method of improving carbon black dispersion in rubber compositions
CN1181101C (zh) 2001-12-31 2004-12-22 中国石油化工股份有限公司 含锡有机锂化合物及其制备方法
US7250476B1 (en) * 2002-08-01 2007-07-31 Bridgestone Corporation Multi-functional polymers
DE60316445T2 (de) * 2002-08-30 2008-06-26 Bridgestone Corp. Funktionalisiertes polymer und verbesserte vulkanisate daraus
US7671139B1 (en) 2004-06-18 2010-03-02 Bridgestone Corporation Functionalized polymers and tires made therefrom
WO2006076629A1 (en) 2005-01-14 2006-07-20 Bridgestone Corporation Functionalized polymers and improved tires therefrom
US20060223917A1 (en) * 2005-04-05 2006-10-05 Bridgestone Corporation Method of optimizing a tire tread compound, and a tire tread compound made by said method
US7335712B2 (en) * 2005-04-21 2008-02-26 Bridgestone Corporation Process of producing a siloxy-functionalized polymer
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CN101563398B (zh) * 2006-10-06 2012-10-24 株式会社普利司通 支化聚合物及其合成和使用方法
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CN101255223B (zh) * 2007-02-28 2010-12-01 中国石油化工股份有限公司 一种具有低滚动阻力和高抗湿滑性能的三元共聚橡胶、其制备方法及其应用
US10023723B2 (en) 2007-06-05 2018-07-17 Momentive Performance Materials Inc. Process for preparing rubber compositions and articles made therefrom
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US8314189B2 (en) 2007-10-12 2012-11-20 Bridgestone Corporation Polymers functionalized with heterocyclic nitrile compounds
US7816435B2 (en) * 2007-10-31 2010-10-19 Momentive Performance Materials Inc. Halo-functional silane, process for its preparation, rubber composition containing same and articles manufactured therefrom
RU2485146C2 (ru) 2007-12-31 2013-06-20 Бриджстоун Корпорейшн Способ получения полимерной композиции и полимерная композиция
US8058357B2 (en) * 2007-12-31 2011-11-15 Bridgestone Corporation Vulcanizable compositions and tire treads prepared therewith
US9732178B1 (en) 2008-07-24 2017-08-15 Bridgestone Corporation Block copolymers including high vinyl segments
BRPI0903440A2 (pt) 2008-08-05 2010-06-01 Bridgestone Corp método para aperfeiçoar a resistência ao escoamento a frio de polìmeros
US8143336B2 (en) * 2008-08-07 2012-03-27 Momentive Performance Materials Inc. Activated halo-containing aralkylsilane composition, process of preparing same and rubber compositions made therefrom
JP5257046B2 (ja) * 2008-12-16 2013-08-07 日本ゼオン株式会社 脂環式炭化水素ランダム共重合体、その製造方法、樹脂組成物、及び成形物
FR2940294B1 (fr) * 2008-12-23 2011-02-18 Michelin Soc Tech Nouveau systeme d'amorcage pour polymerisation anionique de dienes conjugues, procede de preparation d'elastomeres dieniques.
US8338544B2 (en) 2009-12-21 2012-12-25 Bridgestone Corporation Polymers functionalized with polyoxime compounds and methods for their manufacture
WO2011087841A1 (en) 2009-12-22 2011-07-21 Bridgestone Corporation Improved vinyl modifier composition and processes for utilizing such composition
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ES2626141T3 (es) 2010-01-22 2017-07-24 Bridgestone Corporation Polímeros funcionalizados con compuestos de nitrilo que contienen un grupo amino protegido
US8748531B2 (en) 2010-12-10 2014-06-10 Bridgestone Corporation Polymers functionalized with oxime compounds containing an acyl group
US8962745B2 (en) 2010-12-27 2015-02-24 Bridgestone Corporation Functionalized polymers and vulcanizates with reduced hysteretic loss
RU2599633C2 (ru) 2011-03-29 2016-10-10 Бриджстоун Корпорейшн Полимеры, функционализированные сложным эфиром карбоновой или тиокарбоновой кислоты, содержащим силилированную аминогруппу
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FR2980206B1 (fr) * 2011-09-19 2013-09-27 Michelin Soc Tech Bande de roulement de pneumatique hors la route
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JP2017501289A (ja) 2013-12-12 2017-01-12 ファイアストン ポリマーズ エルエルシー 官能化ポリマーを含むポリマー組成物の製造方法
US10030083B2 (en) 2014-05-15 2018-07-24 Bridgestone Corporation Polymers functionalized with protected oxime compounds containing a cyano group
CN107567464B (zh) 2014-10-07 2020-04-14 株式会社普利司通 用于生产冷流性降低的聚二烯和聚二烯共聚物的方法
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US10519266B2 (en) 2015-09-23 2019-12-31 Bridgestone Corporation Polydienes and diene copolymers using 1,1-bis(hydrocarbylthio)hydrocarbyl-1-ene compounds
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Also Published As

Publication number Publication date
CA2058562A1 (en) 1992-07-03
EP0493839B1 (de) 1996-05-22
DE69119736D1 (de) 1996-06-27
JPH082927B2 (ja) 1996-01-17
ES2087228T3 (es) 1996-07-16
CA2058562C (en) 2003-05-27
EP0493839A1 (de) 1992-07-08
JPH07309914A (ja) 1995-11-28
JPH04314705A (ja) 1992-11-05
US5268439A (en) 1993-12-07
JP2539188B2 (ja) 1996-10-02

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