DE69117163D1 - Stickoxidreduktion mittels eines harnstoffhydrolysats - Google Patents
Stickoxidreduktion mittels eines harnstoffhydrolysatsInfo
- Publication number
- DE69117163D1 DE69117163D1 DE69117163T DE69117163T DE69117163D1 DE 69117163 D1 DE69117163 D1 DE 69117163D1 DE 69117163 T DE69117163 T DE 69117163T DE 69117163 T DE69117163 T DE 69117163T DE 69117163 D1 DE69117163 D1 DE 69117163D1
- Authority
- DE
- Germany
- Prior art keywords
- hydrolysate
- urea
- nitrogen reduction
- urea hydrolysate
- nitrogen oxides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000413 hydrolysate Substances 0.000 title abstract 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 title abstract 3
- 239000004202 carbamide Substances 0.000 title abstract 3
- 230000009467 reduction Effects 0.000 title abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 title 2
- BHCBLTRDEYPMFZ-UHFFFAOYSA-N 5-acetamido-1-n,3-n-bis(2,3-dihydroxypropyl)-2,4,6-triiodobenzene-1,3-dicarboxamide Chemical compound CC(=O)NC1=C(I)C(C(=O)NCC(O)CO)=C(I)C(C(=O)NCC(O)CO)=C1I BHCBLTRDEYPMFZ-UHFFFAOYSA-N 0.000 title 1
- 229910052757 nitrogen Inorganic materials 0.000 title 1
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract 6
- 238000000034 method Methods 0.000 abstract 2
- 238000002485 combustion reaction Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/56—Nitrogen oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/08—Preparation of ammonia from nitrogenous organic substances
- C01C1/086—Preparation of ammonia from nitrogenous organic substances from urea
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2240/00—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
- F01N2240/40—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being a hydrolysis catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treating Waste Gases (AREA)
- Polyesters Or Polycarbonates (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Cosmetics (AREA)
- Measuring Or Testing Involving Enzymes Or Micro-Organisms (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/561,154 US5240688A (en) | 1990-08-01 | 1990-08-01 | Process for the in-line hydrolysis of urea |
PCT/US1991/005461 WO1992002450A1 (en) | 1990-08-01 | 1991-08-01 | Nitrogen oxides reduction using a urea hydrolysate |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69117163D1 true DE69117163D1 (de) | 1996-03-28 |
DE69117163T2 DE69117163T2 (de) | 1996-09-05 |
Family
ID=24240855
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69114503T Expired - Fee Related DE69114503T2 (de) | 1990-08-01 | 1991-08-01 | Verfahren zur in-line-hydrolyse von harnstoff. |
DE69117163T Expired - Fee Related DE69117163T2 (de) | 1990-08-01 | 1991-08-01 | Stickoxidreduktion mittels eines harnstoffhydrolysats |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69114503T Expired - Fee Related DE69114503T2 (de) | 1990-08-01 | 1991-08-01 | Verfahren zur in-line-hydrolyse von harnstoff. |
Country Status (8)
Country | Link |
---|---|
US (2) | US5240688A (de) |
EP (2) | EP0542792B1 (de) |
AT (2) | ATE129925T1 (de) |
AU (1) | AU8297991A (de) |
CA (2) | CA2063811C (de) |
DE (2) | DE69114503T2 (de) |
FI (1) | FI930377A (de) |
WO (2) | WO1992002291A1 (de) |
Families Citing this family (77)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5441713A (en) * | 1988-04-29 | 1995-08-15 | Nalco Fuel Tech | Hardness suppression in urea solutions |
US6051040A (en) * | 1988-12-28 | 2000-04-18 | Clean Diesel Technologies, Inc. | Method for reducing emissions of NOx and particulates from a diesel engine |
US5543123A (en) * | 1990-08-01 | 1996-08-06 | Nalco Fuel Tech | Low pressure formation of a urea hydrolysate for nitrogen oxides reduction |
US5342599A (en) * | 1990-09-14 | 1994-08-30 | Cummins Power Generation, Inc. | Surface stabilized sources of isocyanic acid |
US5281403B1 (en) * | 1991-09-27 | 1996-06-11 | Noell Inc | Method for converting urea to ammonia |
FR2682110B1 (fr) * | 1991-10-02 | 1995-05-24 | Atta | Ligands amphiphiles perfluoroalkyles leurs complexes metalliques et leurs utilisations dans des preparations a usage therapeutique. |
EP0555746B1 (de) * | 1992-02-10 | 1997-09-10 | MAN Nutzfahrzeuge Aktiengesellschaft | Vorrichtung zur katalytischen NOX-Reduktion |
TW229225B (de) * | 1992-05-06 | 1994-09-01 | Malco Fuel Tech | |
US5489419A (en) * | 1992-10-13 | 1996-02-06 | Nalco Fuel Tech | Process for pollution control |
US5536482A (en) * | 1992-10-13 | 1996-07-16 | Nalco Fuel Tech | Process for pollution control |
US5404841A (en) * | 1993-08-30 | 1995-04-11 | Valentine; James M. | Reduction of nitrogen oxides emissions from diesel engines |
EP0722421A4 (de) * | 1993-10-06 | 1997-05-28 | Nalco Fuel Tech | Niederdruckherstellung eines harnstoffhydrolysats für die reduktion von stickstoffoxiden |
US5489420A (en) * | 1994-03-10 | 1996-02-06 | Nalco Fuel Tech | Nitrogen oxides reducing agent and a phosphate |
US5658547A (en) * | 1994-06-30 | 1997-08-19 | Nalco Fuel Tech | Simplified efficient process for reducing NOx, SOx, and particulates |
DE4425420A1 (de) * | 1994-07-19 | 1995-07-27 | Daimler Benz Ag | Verfahren zur Verminderung des Gehaltes an Stickstoffoxiden in den Abgasen von Verbrennungskraftmaschinen |
AU3495195A (en) * | 1994-08-26 | 1996-03-22 | Us Sulfamate, Inc. | Molten urea dehydrate derived compositions |
GB9513989D0 (en) * | 1995-07-08 | 1995-09-06 | Brunner Mond & Co Ltd | Treatment of flue gases |
FR2740356B1 (fr) * | 1995-10-31 | 1997-11-28 | Rhone Poulenc Chimie | Procede de traitement de fumees avec du carbonate et/ou du bicarbonate de sodium humidifies |
US5992141A (en) * | 1996-04-02 | 1999-11-30 | Kleen Air Systems, Inc. | Ammonia injection in NOx control |
US5681536A (en) * | 1996-05-07 | 1997-10-28 | Nebraska Public Power District | Injection lance for uniformly injecting anhydrous ammonia and air into a boiler cavity |
US20050019363A1 (en) * | 1996-09-30 | 2005-01-27 | Blount David H. | Hydrolyzed urea condensate fertilizer, fungicide and insecticide |
US6077491A (en) | 1997-03-21 | 2000-06-20 | Ec&C Technologies | Methods for the production of ammonia from urea and/or biuret, and uses for NOx and/or particulate matter removal |
US6361754B1 (en) * | 1997-03-27 | 2002-03-26 | Clean Diesel Technologies, Inc. | Reducing no emissions from an engine by on-demand generation of ammonia for selective catalytic reduction |
US5809775A (en) * | 1997-04-02 | 1998-09-22 | Clean Diesel Technologies, Inc. | Reducing NOx emissions from an engine by selective catalytic reduction utilizing solid reagents |
US5976475A (en) * | 1997-04-02 | 1999-11-02 | Clean Diesel Technologies, Inc. | Reducing NOx emissions from an engine by temperature-controlled urea injection for selective catalytic reduction |
JPH11171535A (ja) * | 1997-12-05 | 1999-06-29 | Mitsubishi Heavy Ind Ltd | アンモニア発生方法及び排ガス処理方法 |
EP0969915A1 (de) * | 1997-12-12 | 2000-01-12 | FEV Motorentechnik GmbH | Verfahren zur reduktion von stickoxiden in sauerstoffhaltigen abgasen, insbesondere abgasen von verbrennungsmotoren |
WO1999056858A2 (de) * | 1998-04-30 | 1999-11-11 | Siemens Aktiengesellschaft | Verfahren und vorrichtung zur katalytischen stickoxidminderung |
ITMI981155A1 (it) * | 1998-05-25 | 1999-11-25 | Siirtec Nigi S P A | Processo per la produzione di ammoniaca mediante idrolisi dell'urea |
US6093380A (en) * | 1998-10-16 | 2000-07-25 | Siirtec Nigi, S.P.A. | Method and apparatus for pollution control in exhaust gas streams from fossil fuel burning facilities |
US6403046B1 (en) | 1999-07-26 | 2002-06-11 | Hera, Llc | Pollution control systems using urea and ammonia for the control of emissions from the flue gas of fossil fuel burning facilities |
US6146605A (en) * | 1999-07-26 | 2000-11-14 | Hera, Llc | Combined SCR/SNCR process |
US6511644B1 (en) | 2000-08-28 | 2003-01-28 | The Chemithon Corporation | Method for removing contaminants in reactors |
US6436359B1 (en) | 2000-10-25 | 2002-08-20 | Ec&C Technologies, Inc. | Method for controlling the production of ammonia from urea for NOx scrubbing |
US6761868B2 (en) | 2001-05-16 | 2004-07-13 | The Chemithon Corporation | Process for quantitatively converting urea to ammonia on demand |
JP3820163B2 (ja) * | 2002-02-22 | 2006-09-13 | 三井化学株式会社 | 尿素濃度測定方法および装置 |
US20030211024A1 (en) * | 2002-05-10 | 2003-11-13 | Wojichowski David Lee | Methods of converting urea to ammonia for SCR, SNCR and flue gas conditioning |
US6887284B2 (en) * | 2002-07-12 | 2005-05-03 | Dannie B. Hudson | Dual homogenization system and process for fuel oil |
KR100498083B1 (ko) * | 2002-08-27 | 2005-07-01 | 강희수 | 원사 빔 적재대 |
US6887449B2 (en) * | 2002-11-21 | 2005-05-03 | The Chemithon Corporation | Method of quantitatively producing ammonia from urea |
RU2393116C2 (ru) * | 2004-05-05 | 2010-06-27 | Роберт К. ГРАУПНЕР | Композиция на основе гуанидина и система для указанной композиции |
EP1853799A1 (de) * | 2005-02-16 | 2007-11-14 | Imi Vision Limited | Abgasbehandlung |
WO2006087541A1 (en) * | 2005-02-16 | 2006-08-24 | Imi Vision Limited | Exhaust gas treatment |
US7985280B2 (en) * | 2007-02-20 | 2011-07-26 | Hitachi Power Systems America, Ltd. | Separation of aqueous ammonia components for NOx reduction |
US20080267837A1 (en) * | 2007-04-27 | 2008-10-30 | Phelps Calvin E | Conversion of urea to reactants for NOx reduction |
CA2693466A1 (en) * | 2007-07-12 | 2009-01-15 | Powerspan Corp. | Scrubbing of ammonia with urea ammonium nitrate solution |
EP2190781A2 (de) * | 2007-08-24 | 2010-06-02 | Powerspan Corp. | Verfahren und vorrichtung zur herstellung von ammoniumcarbonat aus harnstoff |
US20090148370A1 (en) * | 2007-12-06 | 2009-06-11 | Spencer Iii Herbert W | Process to produce ammonia from urea |
WO2010014583A1 (en) * | 2008-07-29 | 2010-02-04 | Powerspan Corp. | Using raman spectroscopy to control carbonate / bicarbonate concentrations |
US8562929B2 (en) | 2010-04-02 | 2013-10-22 | Ohio University | Selective catalytic reduction via electrolysis of urea |
UA109657C2 (uk) | 2010-04-02 | 2015-09-25 | Огайо Юніверсіті | Селективне каталітичне відновлення шляхом електролізу сечовини |
WO2012104205A1 (en) * | 2011-02-04 | 2012-08-09 | Paul Scherrer Institut | Ammonia generator converting liquid ammonia precursor solutions to gaseous ammonia for denox-applications using selective catalytic reduction of nitrogen oxides |
WO2012123378A1 (en) | 2011-03-11 | 2012-09-20 | Puregeneration (Uk) Ltd | Production and use of cyanoguanidine and cyanamide |
US8518354B2 (en) * | 2011-07-29 | 2013-08-27 | Deere & Company | Diesel exhaust fluid formulation having a high ammonium content and a low freezing point |
CN102553412A (zh) * | 2012-02-10 | 2012-07-11 | 山东大学 | 一种利用高反应活性氨基还原剂进行烟气脱硝的方法 |
DE102014204307A1 (de) | 2013-03-19 | 2014-09-25 | Ford Global Technologies, Llc | Verfahren und Anordnung zur Behandlung von Abgasen eines Verbrennungsmotors |
EP2926886A1 (de) * | 2014-04-01 | 2015-10-07 | Inergy Automotive Systems Research (Société Anonyme) | System mit Zersetzungseinheit zur Verwendung an Bord eines Fahrzeugs |
US9586831B2 (en) | 2014-06-09 | 2017-03-07 | Wahlco, Inc. | Urea to ammonia process |
CN104477939B (zh) * | 2014-10-28 | 2017-01-18 | 河南骏化发展股份有限公司 | 一种低压水解工艺 |
CN106807193A (zh) * | 2015-12-02 | 2017-06-09 | 昆山市三维换热器有限公司 | 一种烟气脱硝工艺系统 |
US10844763B2 (en) | 2017-03-10 | 2020-11-24 | R. F. Macdonald Co. | Process for direct urea injection with selective catalytic reduction (SCR) for NOx reduction in hot gas streams and related systems and assemblies |
CN106986434B (zh) * | 2017-04-20 | 2022-12-02 | 中国科学院生态环境研究中心 | 一种抗生素生产废水的预处理方法 |
US10767529B2 (en) | 2018-11-08 | 2020-09-08 | Faurecia Emissions Control Technologies, Usa, Llc | Automotive exhaust aftertreatment system having onboard ammonia reactor with heated doser |
US10683787B2 (en) | 2018-11-08 | 2020-06-16 | Faurecia Emissions Control Technologies, Usa, Llc | Automotive exhaust aftertreatment system having onboard ammonia reactor with hybrid heating |
US10876454B2 (en) | 2018-11-08 | 2020-12-29 | Faurecia Emissions Control Technologies, Usa, Llc | Automotive exhaust aftertreatment system with multi-reductant injection and doser controls |
US11193413B2 (en) | 2019-12-12 | 2021-12-07 | Faurecia Emissions Control Technologies, Usa, Llc | Exhaust aftertreatment system with virtual temperature determination and control |
CN111135714A (zh) * | 2020-01-15 | 2020-05-12 | 安徽晨晰洁净科技有限公司 | 一种碳酸氢铵作为scr脱硝还原剂的方法 |
US11319853B2 (en) | 2020-03-31 | 2022-05-03 | Faurecia Emissions Control Technologies, Usa, Llc | Automotive exhaust aftertreatment system with doser |
US11022014B1 (en) | 2020-04-28 | 2021-06-01 | Faurecia Emissions Control Technologies, Usa, Llc | Exhaust aftertreatment system with heated flash-boiling doser |
US11511239B2 (en) | 2020-04-29 | 2022-11-29 | Faurecia Emissions Control Technologies, Usa, Llc | Heated flash-boiling doser with integrated helix |
US11092054B1 (en) | 2020-04-29 | 2021-08-17 | Faurecia Emissions Control Technologies, Usa, Llc | Flash-boiling doser with thermal transfer helix |
US11384667B2 (en) | 2020-05-29 | 2022-07-12 | Faurecia Emissions Control Technologies, Usa, Llc | Exhaust aftertreatment system with heated dosing control |
US11225894B1 (en) | 2020-06-30 | 2022-01-18 | Faurecia Emissions Control Technologies, Usa, Llc | Exhaust aftertreatment system with thermally controlled reagent doser |
CN112354487B (zh) * | 2020-11-06 | 2022-10-14 | 李东田 | 一种碳酸铵原料气的制备方法 |
CN112661172A (zh) * | 2020-12-23 | 2021-04-16 | 中国华电科工集团有限公司 | 一种scr脱硝尿素非均相催化水解制氨的系统及方法 |
CN114405450A (zh) * | 2022-02-23 | 2022-04-29 | 西安热工研究院有限公司 | 一种填料式的尿素催化水解装置 |
CN115057454B (zh) * | 2022-06-28 | 2023-06-23 | 江苏国瑞特环保工程技术有限公司 | 一种强碱性环境改良型尿素水解制氨系统 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE200617C (de) * | ||||
US3900554A (en) * | 1973-03-16 | 1975-08-19 | Exxon Research Engineering Co | Method for the reduction of the concentration of no in combustion effluents using ammonia |
US4208386A (en) * | 1976-03-03 | 1980-06-17 | Electric Power Research Institute, Inc. | Urea reduction of NOx in combustion effluents |
JPS5314662A (en) * | 1976-07-28 | 1978-02-09 | Hitachi Ltd | Method for decreasing nitrogen oxides concentration of combustion exhaust gas |
US4087513A (en) * | 1977-08-12 | 1978-05-02 | Olin Corporation | Method of hydrolyzing urea contained in waste water streams |
US4325924A (en) * | 1977-10-25 | 1982-04-20 | Electric Power Research Institute, Inc. | Urea reduction of NOx in fuel rich combustion effluents |
JPS5486020A (en) * | 1977-12-21 | 1979-07-09 | Okubo Yoshinori | Combustion method of hydrocarbon fuel |
US4168299A (en) * | 1978-03-20 | 1979-09-18 | Olin Corporation | Catalytic method for hydrolyzing urea |
NL8102391A (nl) * | 1981-05-15 | 1982-12-01 | Unie Van Kunstmestfab Bv | Werkwijze voor het winnen van waardevolle bestanddelen uit de afvalstromen verkregen bij de ureumbereiding. |
NL8105027A (nl) * | 1981-11-06 | 1983-06-01 | Stamicarbon | Werkwijze voor het omzetten in ammoniak en kooldioxide van gasvormige verbindingen die stikstof- en koolstofatomen bevatten. |
US4626417A (en) * | 1983-09-29 | 1986-12-02 | Union Oil Company Of California | Methods for chemically reducing nitrogen oxides |
US4780289A (en) * | 1987-05-14 | 1988-10-25 | Fuel Tech, Inc. | Process for nitrogen oxides reduction and minimization of the production of other pollutants |
US4777024A (en) * | 1987-03-06 | 1988-10-11 | Fuel Tech, Inc. | Multi-stage process for reducing the concentration of pollutants in an effluent |
JPS6419665A (en) * | 1987-07-14 | 1989-01-23 | Jeol Ltd | Ion beam device |
JPH03503735A (ja) * | 1988-02-02 | 1991-08-22 | ジョーンズ,デイル ゴードン | 窒素酸化物の還元を目的とする2段ボイラー注入方法と装置 |
AT390208B (de) * | 1988-05-09 | 1990-04-10 | Waagner Biro Ag | Verfahren zur entfernung von stickoxiden |
DE3830045C2 (de) * | 1988-09-03 | 1993-09-30 | Bayer Ag | Verfahren zur Reduktion von in Abgasen enthaltenen Stickoxiden mittels eines zeolithhaltigen Katalysators |
JPH02191528A (ja) * | 1989-01-20 | 1990-07-27 | Babcock Hitachi Kk | 固体還元剤を用いた脱硝装置 |
US4987513A (en) * | 1989-04-12 | 1991-01-22 | Shelley Edwin F | Apparatus and method for selectively delaying the connection of an electrical supply voltage to an electrical load |
US4997631A (en) * | 1990-03-07 | 1991-03-05 | Fuel Tech, Inc. | Process for reducing nitrogen oxides without generating nitrous oxide |
-
1990
- 1990-08-01 US US07/561,154 patent/US5240688A/en not_active Expired - Fee Related
-
1991
- 1991-08-01 AT AT91913756T patent/ATE129925T1/de not_active IP Right Cessation
- 1991-08-01 WO PCT/EP1991/001450 patent/WO1992002291A1/en active IP Right Grant
- 1991-08-01 EP EP91913756A patent/EP0542792B1/de not_active Expired - Lifetime
- 1991-08-01 WO PCT/US1991/005461 patent/WO1992002450A1/en active IP Right Grant
- 1991-08-01 AT AT91916169T patent/ATE134155T1/de not_active IP Right Cessation
- 1991-08-01 AU AU82979/91A patent/AU8297991A/en not_active Abandoned
- 1991-08-01 CA CA002063811A patent/CA2063811C/en not_active Expired - Fee Related
- 1991-08-01 EP EP91916169A patent/EP0495089B1/de not_active Expired - Lifetime
- 1991-08-01 DE DE69114503T patent/DE69114503T2/de not_active Expired - Fee Related
- 1991-08-01 CA CA002088576A patent/CA2088576A1/en not_active Abandoned
- 1991-08-01 DE DE69117163T patent/DE69117163T2/de not_active Expired - Fee Related
-
1992
- 1992-02-26 US US07/820,907 patent/US5399325A/en not_active Expired - Fee Related
-
1993
- 1993-01-29 FI FI930377A patent/FI930377A/fi not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
EP0542792A1 (de) | 1993-05-26 |
CA2063811C (en) | 2000-05-09 |
EP0495089A4 (en) | 1993-03-10 |
DE69114503D1 (de) | 1995-12-14 |
DE69117163T2 (de) | 1996-09-05 |
EP0495089A1 (de) | 1992-07-22 |
CA2063811A1 (en) | 1992-02-02 |
CA2088576A1 (en) | 1992-02-02 |
WO1992002291A1 (en) | 1992-02-20 |
DE69114503T2 (de) | 1996-05-02 |
FI930377A0 (fi) | 1993-01-29 |
ATE134155T1 (de) | 1996-02-15 |
WO1992002450A1 (en) | 1992-02-20 |
US5399325A (en) | 1995-03-21 |
FI930377A (fi) | 1993-01-29 |
US5240688A (en) | 1993-08-31 |
EP0495089B1 (de) | 1996-02-14 |
ATE129925T1 (de) | 1995-11-15 |
EP0542792B1 (de) | 1995-11-08 |
AU8297991A (en) | 1992-03-02 |
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