DE68918356D1 - Linse, ein Kunstharz mit hohem Brechungsindex enthaltend und Verfahren zur Herstellung der Linse. - Google Patents

Linse, ein Kunstharz mit hohem Brechungsindex enthaltend und Verfahren zur Herstellung der Linse.

Info

Publication number
DE68918356D1
DE68918356D1 DE68918356T DE68918356T DE68918356D1 DE 68918356 D1 DE68918356 D1 DE 68918356D1 DE 68918356 T DE68918356 T DE 68918356T DE 68918356 T DE68918356 T DE 68918356T DE 68918356 D1 DE68918356 D1 DE 68918356D1
Authority
DE
Germany
Prior art keywords
lens
making
refractive index
high refractive
index resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE68918356T
Other languages
English (en)
Other versions
DE68918356T2 (de
Inventor
Teruyuki Nagata
Koju Okazaki
Tohru Miura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemicals Inc
Original Assignee
Mitsui Toatsu Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Toatsu Chemicals Inc filed Critical Mitsui Toatsu Chemicals Inc
Application granted granted Critical
Publication of DE68918356D1 publication Critical patent/DE68918356D1/de
Publication of DE68918356T2 publication Critical patent/DE68918356T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00—Moulds or cores; Details thereof or accessories therefor
    • B29C33/56—Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
    • B29C33/60—Releasing, lubricating or separating agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3221—Polyhydroxy compounds hydroxylated esters of carboxylic acids other than higher fatty acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3802—Low-molecular-weight compounds having heteroatoms other than oxygen having halogens
    • C08G18/3804—Polyhydroxy compounds
    • C08G18/3806—Polyhydroxy compounds having chlorine and/or bromine atoms
    • C08G18/381—Polyhydroxy compounds having chlorine and/or bromine atoms having bromine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3855—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
    • C08G18/3863—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3855—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
    • C08G18/3874—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing heterocyclic rings having at least one sulfur atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3855—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
    • C08G18/3876—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing mercapto groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/775—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/7875—Nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring
    • C08G18/7893—Nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring having three nitrogen atoms in the ring
DE68918356T 1988-07-14 1989-06-19 Linse, ein Kunstharz mit hohem Brechungsindex enthaltend und Verfahren zur Herstellung der Linse. Expired - Lifetime DE68918356T2 (de)

Applications Claiming Priority (10)

Application Number Priority Date Filing Date Title
JP17606488 1988-07-14
JP18036288 1988-07-21
JP18036188 1988-07-21
JP18757188 1988-07-27
JP18756988 1988-07-27
JP18757088 1988-07-27
JP19268188 1988-08-03
JP21375188 1988-08-30
JP21375288 1988-08-30
JP22135588 1988-09-06

Publications (2)

Publication Number Publication Date
DE68918356D1 true DE68918356D1 (de) 1994-10-27
DE68918356T2 DE68918356T2 (de) 1995-05-11

Family

ID=27580366

Family Applications (1)

Application Number Title Priority Date Filing Date
DE68918356T Expired - Lifetime DE68918356T2 (de) 1988-07-14 1989-06-19 Linse, ein Kunstharz mit hohem Brechungsindex enthaltend und Verfahren zur Herstellung der Linse.

Country Status (8)

Country Link
US (1) US5084545A (de)
EP (1) EP0351073B1 (de)
JP (4) JP3088428B2 (de)
KR (1) KR920010139B1 (de)
CN (3) CN1092211C (de)
AU (1) AU605428B2 (de)
BR (1) BR8903481A (de)
DE (1) DE68918356T2 (de)

Families Citing this family (46)

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FR2649711B1 (fr) * 1989-07-13 1993-01-22 Essilor Int Compositions de polymeres a base de polythiourethanes pour la fabrication de verres organiques
AU637662B2 (en) * 1989-12-28 1993-06-03 Hoya Corporation Polythiol compound, and optical material and product produced therefrom
FR2670486B1 (fr) * 1990-12-14 1993-05-28 Rhone Poulenc Chimie Nouveaux composes soufres et nouveaux polymeres obtenus a partir de ces composes soufres.
US5194559A (en) * 1991-03-25 1993-03-16 Mitsui Toatsu Chemicals, Inc. Optical urethane resins and plastic lenses comprising the same
JP3115371B2 (ja) * 1991-09-03 2000-12-04 ホーヤ株式会社 光学材料用重合体及びその製造方法
US5389708A (en) * 1992-01-31 1995-02-14 Mitsui Toatsu Chemicals, Inc. Sulfur-containing acid phosphoric ester internal release agent
US5446173A (en) * 1992-03-24 1995-08-29 Daiso Co., Ltd. Cyclic sulfide compound, polymerizable compositions for optical products and optical products formed thereof
US5420186A (en) * 1993-01-26 1995-05-30 Air Products And Chemicals, Inc. Internal mold release agents comprising metallic soaps compatibilized with liquid quaternary ammonium salts
JP2695599B2 (ja) * 1993-09-29 1997-12-24 ホーヤ株式会社 ポリウレタンレンズの製造方法
US6008296A (en) * 1995-04-19 1999-12-28 Optima, Inc. Optical terpolymer of polyisocyanate, polythiol and polyene monomers
US6274694B1 (en) 1995-11-20 2001-08-14 Hoya Corporation Process for the production of polyurethane lens
US5908876A (en) * 1996-04-19 1999-06-01 Mitsui Chemicals, Inc. Optical resin composition comprising a thiourethane prepolymer and use thereof
JP3791973B2 (ja) * 1996-07-30 2006-06-28 三井化学株式会社 イソシアナート誘導体およびその用途
JP3995427B2 (ja) * 2000-03-27 2007-10-24 三井化学株式会社 新規なポリチオールを含有する重合性組成物、及びそれを重合させてなる樹脂、並びにレンズ
KR100746067B1 (ko) 2002-11-13 2007-08-03 닛뽕소다 가부시키가이샤 금속-산소 결합을 갖는 분산질, 금속산화물막 및 단분자막
JP4231702B2 (ja) * 2003-01-17 2009-03-04 日東電工株式会社 マイクロレンズアレイ
GB0310270D0 (en) * 2003-05-03 2003-06-11 Univ Edinburgh Biomolecular devices
CN1325943C (zh) * 2003-05-14 2007-07-11 上海康耐特光学有限公司 高折射率光学树脂材料的制备方法
JP4716249B2 (ja) * 2005-03-24 2011-07-06 三菱瓦斯化学株式会社 重合性組成物
US20070037897A1 (en) * 2005-08-12 2007-02-15 Guigui Wang Method for making contact lenses
JP3947751B2 (ja) * 2005-10-07 2007-07-25 セイコーエプソン株式会社 プラスチックレンズ及びプラスチックレンズの製造方法
WO2007092569A1 (en) 2006-02-07 2007-08-16 Battelle Memorial Institute Esters of 5 -hydroxymethylfurfural and methods for their preparation
JP2007246690A (ja) * 2006-03-16 2007-09-27 Seiko Epson Corp 光学基材の製造方法
KR100939451B1 (ko) * 2007-12-24 2010-01-29 주식회사 케이오씨솔루션 멀티코팅 후 내열성과 내충격성이 우수한 광학수지 조성물, 이를 이용한 플라스틱 안경 렌즈 및 그 제조 방법
EP2382294B1 (de) 2008-12-31 2019-02-13 Battelle Memorial Institute Verwendung von fettsäuren als einsatzstoff bei polyolverfahren
EP2382293B1 (de) 2008-12-31 2019-01-16 Battelle Memorial Institute Lösungsmittelfreie herstellung von polyolen durch ozonolyse
EP2382292B1 (de) 2008-12-31 2018-02-21 Battelle Memorial Institute Vorveresterung von primären polyolen zur verbesserung der löslichkeit in bei polyolverfahren verwendeten lösungsmitteln
CN102333755B (zh) 2008-12-31 2016-02-24 巴特尔纪念研究院 通过初始的脂肪酸氧化分解后的酯化反应制备酯和多元醇
BRPI1009394B1 (pt) 2009-03-13 2021-08-17 Battelle Memorial Institute Método para produzir um lubrificante, e, composição lubrificante
EP2445947B1 (de) 2009-06-23 2018-05-23 Carl Zeiss Vision Australia Holdings Limited Thiourethan-basierte linsenelemente und verfahren zu ihrer herstellung
WO2011041476A2 (en) * 2009-09-30 2011-04-07 Battelle Memorial Institute Biobased polyol cross-linkers for use in preparing polyesters and reversible polyurethanes
JP4988067B2 (ja) * 2009-11-06 2012-08-01 三井化学株式会社 ポリチオウレタン系光学材料用内部離型剤の製造方法、ポリチオウレタン系光学材料用内部離型剤およびそれを含む重合性組成物
WO2012064699A1 (en) 2010-11-10 2012-05-18 Novartis Ag Method for making contact lenses
JP6005285B2 (ja) * 2013-07-08 2016-10-12 旭化成株式会社 改質された樹脂及び樹脂組成物
EP3936905A1 (de) 2013-09-30 2022-01-12 Hoya Lens Thailand Ltd. Transparentes kunststoffsubstrat und kunststofflinse
BR112018001382A2 (pt) * 2015-08-06 2018-09-11 Mitsui Chemicals, Inc. processo para produzir composição polimerizável para material óptico e composição polimerizável para material óptico
US10047043B2 (en) 2016-03-24 2018-08-14 Mitsubishi Gas Chemical Company, Inc. Thiol compound composition for optical material
CN107189509A (zh) * 2016-05-19 2017-09-22 湖北航天化学技术研究所 一种涂层组合物、光学膜及其制备方法
JP6788729B2 (ja) * 2017-03-08 2020-11-25 三井化学株式会社 重合性組成物および成形体
CN108215410B (zh) * 2017-12-21 2019-10-11 东莞市雄林新材料科技股份有限公司 一种可用于证件防伪保护的tpu薄膜及其制备方法
CN108219109A (zh) * 2017-12-28 2018-06-29 山东益丰生化环保股份有限公司 一种超高韧性的树脂镜片及其制备方法
CN108084385B (zh) * 2017-12-28 2020-11-03 山东益丰生化环保股份有限公司 一种超高韧性防蓝光的树脂镜片及其制备方法
KR101894921B1 (ko) * 2018-01-19 2018-09-04 에스케이씨 주식회사 플라스틱 광학 렌즈용 폴리티올 조성물
CN108864392A (zh) * 2018-07-27 2018-11-23 望江县天长光学科技有限公司 一种光学树脂产品及其制备方法
CN112521607B (zh) * 2020-12-03 2021-10-15 浙江大学 一种聚硫羰氨酯化合物及其制备方法和应用
CN116162050A (zh) * 2023-01-15 2023-05-26 湖北安卡新材料科技有限公司 一种多元硫醇及其高折光率光学树脂的制备方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3226354A (en) * 1953-08-07 1965-12-28 Monsanto Co Adhesive products of polyisocyanates and polyisothiocyanates
JPS60199016A (ja) * 1984-03-23 1985-10-08 Mitsui Toatsu Chem Inc チオカルバミン酸ｓ―アルキルエステル系レンズ用樹脂の製造方法
JPS60217229A (ja) * 1984-04-11 1985-10-30 Mitsui Toatsu Chem Inc 硫黄原子含有ポリウレタン系レンズ用樹脂の製造方法
US4608042A (en) * 1985-09-25 1986-08-26 Warner-Lambert Company Apparatus for sequential infusion of medical solutions
CA1328527C (en) * 1986-03-01 1994-04-12 Katsuyoshi Sasagawa High-refractivity plastic lens resin
JPS62236818A (ja) * 1986-04-07 1987-10-16 Mitsui Toatsu Chem Inc 含硫ウレタン樹脂の注型重合法
JPS62267316A (ja) * 1986-05-16 1987-11-20 Mitsui Toatsu Chem Inc 高屈折率プラスチツクレンズ用樹脂
JPH0777733B2 (ja) * 1986-12-15 1995-08-23 三井東圧化学株式会社 含硫ウレタン樹脂製レンズの注型重合方法
US4829099A (en) * 1987-07-17 1989-05-09 Bioresearch, Inc. Metabolically acceptable polyisocyanate adhesives

Also Published As

Publication number Publication date
CN1039429A (zh) 1990-02-07
CN1092211C (zh) 2002-10-09
KR900001752A (ko) 1990-02-27
EP0351073A3 (de) 1991-02-13
JP3088428B2 (ja) 2000-09-18
JPH11231104A (ja) 1999-08-27
CN1069331C (zh) 2001-08-08
JP3093191B2 (ja) 2000-10-03
KR920010139B1 (ko) 1992-11-16
CN1149066A (zh) 1997-05-07
JPH11237501A (ja) 1999-08-31
US5084545A (en) 1992-01-28
CN1036463C (zh) 1997-11-19
EP0351073B1 (de) 1994-09-21
DE68918356T2 (de) 1995-05-11
BR8903481A (pt) 1990-03-13
CN1098723A (zh) 1995-02-15
AU3713689A (en) 1990-04-26
JPH02167330A (ja) 1990-06-27
JP3093190B2 (ja) 2000-10-03
AU605428B2 (en) 1991-01-10
EP0351073A2 (de) 1990-01-17
JPH11231103A (ja) 1999-08-27

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