DE60327452D1 - Emulgatorfreies wässriges emulsionspolymerisationsverfahren zur herstellung fluorierter olefine und olefinischer kohlenwasserstoffcopolymere - Google Patents

Emulgatorfreies wässriges emulsionspolymerisationsverfahren zur herstellung fluorierter olefine und olefinischer kohlenwasserstoffcopolymere

Info

Publication number
DE60327452D1
DE60327452D1 DE60327452T DE60327452T DE60327452D1 DE 60327452 D1 DE60327452 D1 DE 60327452D1 DE 60327452 T DE60327452 T DE 60327452T DE 60327452 T DE60327452 T DE 60327452T DE 60327452 D1 DE60327452 D1 DE 60327452D1
Authority
DE
Germany
Prior art keywords
olefin
emulsion polymerization
aqueous emulsion
fluorized
emulsify
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE60327452T
Other languages
German (de)
English (en)
Inventor
Harald Kaspar
Peter J Scott
Klaus Hintzer
Gernot Lohr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Application granted granted Critical
Publication of DE60327452D1 publication Critical patent/DE60327452D1/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18Monomers containing fluorine

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
DE60327452T 2002-10-31 2003-10-21 Emulgatorfreies wässriges emulsionspolymerisationsverfahren zur herstellung fluorierter olefine und olefinischer kohlenwasserstoffcopolymere Expired - Fee Related DE60327452D1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US42277002P 2002-10-31 2002-10-31
PCT/US2003/033233 WO2004041878A1 (en) 2002-10-31 2003-10-21 Emulsifier free aqueous emulsion polymerization to produce copolymers of a fluorinated olefin and hydrocarbon olefin

Publications (1)

Publication Number Publication Date
DE60327452D1 true DE60327452D1 (de) 2009-06-10

Family

ID=32312556

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60327452T Expired - Fee Related DE60327452D1 (de) 2002-10-31 2003-10-21 Emulgatorfreies wässriges emulsionspolymerisationsverfahren zur herstellung fluorierter olefine und olefinischer kohlenwasserstoffcopolymere

Country Status (10)

Country Link
US (1) US7064170B2 (enExample)
EP (1) EP1556426B1 (enExample)
JP (1) JP2006504844A (enExample)
CN (1) CN100354324C (enExample)
AT (1) ATE430169T1 (enExample)
AU (1) AU2003291646A1 (enExample)
DE (1) DE60327452D1 (enExample)
RU (1) RU2342403C2 (enExample)
WO (1) WO2004041878A1 (enExample)
ZA (1) ZA200504411B (enExample)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7125941B2 (en) * 2001-03-26 2006-10-24 3M Innovative Properties Company Aqueous emulsion polymerization process for producing fluoropolymers
JP4624646B2 (ja) * 2001-05-02 2011-02-02 スリーエム イノベイティブ プロパティズ カンパニー フルオロポリマーを製造するための連鎖移動剤としてのエーテルの存在下での水性乳化重合
US7279522B2 (en) 2001-09-05 2007-10-09 3M Innovative Properties Company Fluoropolymer dispersions containing no or little low molecular weight fluorinated surfactant
JP2006504844A (ja) * 2002-10-31 2006-02-09 スリーエム イノベイティブ プロパティズ カンパニー フッ化オレフィンと炭化水素オレフィンとのコポリマーを製造するための、乳化剤非含有水性乳化重合
ATE502062T1 (de) 2003-10-24 2011-04-15 3M Innovative Properties Co Wässrige dispersionen von polytetrafluorethylenteilchen
EP1533325B1 (en) 2003-11-17 2011-10-19 3M Innovative Properties Company Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant
PL1570917T3 (pl) * 2004-03-01 2009-10-30 3M Innovative Properties Co Sposób powlekania substratu dyspersją fluoropolimeru
US7691932B2 (en) 2004-09-27 2010-04-06 3M Innovative Properties Company Method of making a composition and nanocomposites therefrom
US20060270780A1 (en) * 2005-05-25 2006-11-30 Ping Xu High purity perfluoroelastomer composites and a processes to produce the same
US7488781B2 (en) * 2005-05-25 2009-02-10 Gore Enterprise Holdings, Inc. High purity transparent perfluoroelastomer parts and a process to produce the same
GB2427170A (en) * 2005-06-17 2006-12-20 3M Innovative Properties Co Fluoropolymer film having glass microspheres
GB0525978D0 (en) * 2005-12-21 2006-02-01 3M Innovative Properties Co Fluorinated Surfactants For Making Fluoropolymers
US20070015937A1 (en) * 2005-07-15 2007-01-18 3M Innovative Properties Company Process for recovery of fluorinated carboxylic acid surfactants from exhaust gas
GB0514387D0 (en) * 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant
GB0523853D0 (en) 2005-11-24 2006-01-04 3M Innovative Properties Co Fluorinated surfactants for use in making a fluoropolymer
GB0514398D0 (en) * 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant
US20080015304A1 (en) 2006-07-13 2008-01-17 Klaus Hintzer Aqueous emulsion polymerization process for producing fluoropolymers
GB2430437A (en) * 2005-09-27 2007-03-28 3M Innovative Properties Co Method of making a fluoropolymer
US7728087B2 (en) 2005-12-23 2010-06-01 3M Innovative Properties Company Fluoropolymer dispersion and method for making the same
EP2017292B1 (en) 2006-05-10 2011-09-07 Daikin Industries, Ltd. Process for production of fluorine-containing polymers
US7754795B2 (en) * 2006-05-25 2010-07-13 3M Innovative Properties Company Coating composition
US20070276103A1 (en) * 2006-05-25 2007-11-29 3M Innovative Properties Company Fluorinated Surfactants
US8119750B2 (en) * 2006-07-13 2012-02-21 3M Innovative Properties Company Explosion taming surfactants for the production of perfluoropolymers
BRPI0807109A2 (pt) * 2007-02-16 2014-05-06 3M Innovative Properties Co Sistema e processo para a remoção de fluoroquiímicos da água
US20080264864A1 (en) 2007-04-27 2008-10-30 3M Innovative Properties Company PROCESS FOR REMOVING FLUORINATED EMULSIFIER FROM FLUOROPOLMER DISPERSIONS USING AN ANION-EXCHANGE RESIN AND A pH-DEPENDENT SURFACTANT AND FLUOROPOLYMER DISPERSIONS CONTAINING A pH-DEPENDENT SURFACTANT
KR20100017848A (ko) * 2007-05-23 2010-02-16 쓰리엠 이노베이티브 프로퍼티즈 컴파니 플루오르화 계면활성제의 수성 조성물 및 그의 사용 방법
CN101679569A (zh) * 2007-06-06 2010-03-24 3M创新有限公司 氟化醚组合物以及使用该组合物的方法
JP5532532B2 (ja) * 2007-06-25 2014-06-25 ダイキン工業株式会社 低分子量ポリテトラフルオロエチレン水性分散液及びその製造方法
GB0712191D0 (en) * 2007-06-25 2007-08-01 3M Innovative Properties Co Process for removing fluorinated compounds for an aqueous phase originating from the preparation of fluoropolymers
US9650479B2 (en) 2007-10-04 2017-05-16 W. L. Gore & Associates, Inc. Dense articles formed from tetrafluoroethylene core shell copolymers and methods of making the same
US9040646B2 (en) 2007-10-04 2015-05-26 W. L. Gore & Associates, Inc. Expandable TFE copolymers, methods of making, and porous, expanded articles thereof
US8637144B2 (en) * 2007-10-04 2014-01-28 W. L. Gore & Associates, Inc. Expandable TFE copolymers, method of making, and porous, expended articles thereof
WO2010009191A2 (en) * 2008-07-18 2010-01-21 3M Innovative Properties Company Fluorinated ether compounds and methods of using the same
US20110232530A1 (en) * 2008-11-25 2011-09-29 Dams Rudolf J Fluorinated ether urethanes and methods of using the same
US8629089B2 (en) 2008-12-18 2014-01-14 3M Innovative Properties Company Method of contacting hydrocarbon-bearing formations with fluorinated ether compositions
JP5407643B2 (ja) * 2009-07-31 2014-02-05 旭硝子株式会社 含フッ素共重合体の製造方法
WO2012064846A1 (en) 2010-11-09 2012-05-18 E. I. Du Pont De Nemours And Company Nucleation in aqueous polymerization of fluoromonomer
JP6030562B2 (ja) 2010-11-09 2016-11-24 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company 水性分散体フルオロモノマーの重合における炭化水素含有界面活性剤のテロゲン性挙動の低下
CN103201300B (zh) 2010-11-09 2016-11-09 纳幕尔杜邦公司 使用烃表面活性剂的含氟单体的含水聚合
WO2012150253A1 (en) * 2011-05-03 2012-11-08 Solvay Specialty Polymers Italy S.P.A. Method for manufacturing fluoroelastomers
CA2839389C (en) 2011-07-15 2020-09-01 Solvay Specialty Polymers Italy S.P.A. Aqueous vinylidene fluoride polymer latex
WO2014115679A1 (ja) * 2013-01-23 2014-07-31 ダイキン工業株式会社 含フッ素エーテルの回収方法
EP3074430B1 (en) 2013-11-26 2019-02-20 The Chemours Company FC, LLC Employing polyalkylene oxides for nucleation in aqueous polymerization of fluoromonomer
US9644054B2 (en) 2014-12-19 2017-05-09 W. L. Gore & Associates, Inc. Dense articles formed from tetrafluoroethylene core shell copolymers and methods of making the same
CN110494516B (zh) * 2017-04-11 2022-11-04 索尔维特殊聚合物意大利有限公司 用于制造氟聚合物的方法
CN110078855B (zh) * 2019-04-22 2020-07-14 中昊晨光化工研究院有限公司 一种含氟聚合物及其制备方法
CN116178598A (zh) * 2022-06-20 2023-05-30 福建海德福新材料有限公司 一种四氟乙烯基聚合物树脂及其制备方法

Family Cites Families (58)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2567011A (en) 1949-01-10 1951-09-04 Minnesota Mining & Mfg Fluorocarbon acids and derivatives
US2732398A (en) 1953-01-29 1956-01-24 cafiicfzsojk
US2809990A (en) 1955-12-29 1957-10-15 Minnesota Mining & Mfg Fluorocarbon acids and derivatives
US3345317A (en) * 1963-04-04 1967-10-03 Thiokol Chemical Corp Emulsion polymerization of tetrafluoroethylene using trifluorotrichloroethane as emulsion stabilizer
JPS4928026B1 (enExample) * 1965-01-12 1974-07-23
GB1291936A (en) 1970-11-19 1972-10-04 Asahi Glass Co Ltd Process for producing a copolymer of tetrafluoroethylene and propylene
US3876654A (en) 1970-12-23 1975-04-08 Du Pont Fluoroelastomer composition
JPS497058B1 (enExample) 1970-12-30 1974-02-18
US4025481A (en) * 1971-01-28 1977-05-24 Produits Chimiques Ugine Kuhlmann Method for the preparation of aqueous dispersions of polytetrafluoroethylene with halogenated hydrocarbon as stabilizing agent
US4000356A (en) 1972-06-19 1976-12-28 Dynamit Nobel Aktiengesellschaft Process for the preparation of thermoplastically workable fluoro-olefin polymers
US4277586A (en) * 1974-11-20 1981-07-07 Asahi Glass Company, Ltd. Process for preparing a propylene-tetrafluoroethylene copolymer
US4035565A (en) 1975-03-27 1977-07-12 E. I. Du Pont De Nemours And Company Fluoropolymer containing a small amount of bromine-containing olefin units
US4029868A (en) 1976-03-10 1977-06-14 E. I. Du Pont De Nemours And Company Tetrafluoroethylene terpolymers
JPS539848A (en) 1976-07-16 1978-01-28 Asahi Glass Co Ltd Heat treatment of fluorine-containing elastomers
JPS53125491A (en) 1977-04-08 1978-11-01 Daikin Ind Ltd Fluorine-containing polymer easily curable and its curable composition
JPS54132691A (en) * 1978-04-06 1979-10-15 Asahi Glass Co Ltd Preparation of ethylene-tetrafluoroethylene copolymer
JPS5529519A (en) * 1978-08-22 1980-03-01 Asahi Glass Co Ltd Preparation of fluorocopolymer
DE2903981A1 (de) 1979-02-02 1980-08-07 Hoechst Ag Rueckgewinnung fluorierter emulgatorsaeuren aus basischen anionenaustauschern
US4233421A (en) 1979-02-26 1980-11-11 Minnesota Mining And Manufacturing Company Fluoroelastomer composition containing sulfonium curing agents
US4463144A (en) 1980-09-10 1984-07-31 Asahi Glass Company Ltd. Process for producing propylene-tetrafluoroethylene copolymer
DE3135598A1 (de) 1981-09-09 1983-03-17 Hoechst Ag, 6000 Frankfurt "kontinuierliches verfahren zur agglomerierung von ptee-pulvern im fluessigen medium und damit gewonnenes modifiziertes ptee-pulver"
JPS5920310A (ja) 1982-07-27 1984-02-02 Daikin Ind Ltd 含フッ素ポリマー硬化用組成物
US5086123A (en) 1984-02-27 1992-02-04 Minnesota Mining And Manufacturing Company Fluoroelastomer compositions containing fluoroaliphatic sulfonamides as curing agents
JPS60248710A (ja) * 1984-05-22 1985-12-09 Daikin Ind Ltd 新規エチレン/テトラフルオロエチレン系共重合体
DE3662142D1 (en) * 1985-03-28 1989-03-30 Daikin Ind Ltd Novel fluorovinyl ether and copolymer comprising the same
IT1187684B (it) 1985-07-08 1987-12-23 Montefluos Spa Procedimento per la preparazione di fluoroelastomeri vulcanizzabili e prodotti cosi' ottenuti
JPS62260807A (ja) 1986-05-07 1987-11-13 Nippon Mektron Ltd 含フッ素重合体の製造方法
IT1204903B (it) 1986-06-26 1989-03-10 Ausimont Spa Processo di polimerizzazione in dispersione acquosa di monomeri florati
GB8728884D0 (en) * 1987-12-10 1988-01-27 Ici Plc Aqueous-based fluoropolymer compositions
US4912171A (en) 1988-04-01 1990-03-27 Minnesota Mining And Manufacturing Company Fluoroelastomer curing process with phosphonium compound
IT1235545B (it) 1989-07-10 1992-09-09 Ausimont Srl Fluoroelastomeri dotati di migliore processabilita' e procedimento di preparazione
US5037921A (en) 1990-03-01 1991-08-06 E. I. Du Pont De Nemours And Company Base resistant fluoroelastomers with improved processibility and curability
US5453477A (en) * 1992-05-01 1995-09-26 Alliedsignal Inc. Process of polymerizing chloroetrifluoroethylene with alkyl hydroperoxide and metal metabisulfite
US5262490A (en) 1992-08-24 1993-11-16 Minnesota Mining And Manufacturing Company Fluoroelastomer composition with organo-onium compounds
US5285002A (en) 1993-03-23 1994-02-08 Minnesota Mining And Manufacturing Company Fluorine-containing polymers and preparation and use thereof
IT1266647B1 (it) * 1993-10-29 1997-01-09 Ausimont Spa Processo di (co)polimerizzazione di monomeri olefinici fluorurati in emulsione acquosa
IT1265461B1 (it) 1993-12-29 1996-11-22 Ausimont Spa Fluoroelastomeri comprendenti unita' monomeriche derivanti da una bis-olefina
WO1996024622A1 (en) 1995-02-10 1996-08-15 Alliedsignal Inc. Production of fluoropolymers, fluoropolymer suspension and polymer formed therefrom
JP3223776B2 (ja) 1995-03-31 2001-10-29 日本メクトロン株式会社 含フッ素エラストマー組成物
JP3082626B2 (ja) 1995-07-19 2000-08-28 日本メクトロン株式会社 含フッ素エラストマー組成物
JPH0977829A (ja) * 1995-09-08 1997-03-25 Toagosei Co Ltd パーハロオレフィン共重合体及び該共重合体からなる架橋成形体の製造方法
IT1276979B1 (it) 1995-10-20 1997-11-03 Ausimont Spa Composizioni fluoroelastomeriche
US5955556A (en) * 1995-11-06 1999-09-21 Alliedsignal Inc. Method of manufacturing fluoropolymers
US5591804A (en) 1995-12-21 1997-01-07 Minnesota Mining And Manufacturing Company Fluorinated onium salts, curable compositions containing same, and method of curing using same
US5936060A (en) 1996-11-25 1999-08-10 E. I. Du Pont De Nemours And Company Perfluoroelastomer composition having improved processability
US5677389A (en) 1996-11-25 1997-10-14 E. I. Du Pont De Nemours Perfluoroelastomer composition having enhanced curing performance
US5728773A (en) 1997-02-21 1998-03-17 Minnesota Mining And Manufacturing Company Fluoroelastomer composition with organo-onium and blocked-carbonate compounds
US6281296B1 (en) 1998-08-10 2001-08-28 Dupont Dow Elastomers L.L.C. Curable perfluoroelastomer composition
CN1215085C (zh) 1998-10-13 2005-08-17 大金工业株式会社 含氟聚合物的制造方法
WO2000032655A1 (en) 1998-11-30 2000-06-08 E.I. Du Pont De Nemours And Company Fluoromonomer polymerization
DE19857111A1 (de) 1998-12-11 2000-06-15 Dyneon Gmbh Wäßrige Dispersionen von Fluorpolymeren
WO2000047641A1 (en) * 1999-02-15 2000-08-17 Daikin Industries, Ltd. Process for producing fluoropolymer
US6429258B1 (en) * 1999-05-20 2002-08-06 E. I. Du Pont De Nemours & Company Polymerization of fluoromonomers
JP4352546B2 (ja) 1999-12-22 2009-10-28 ユニマテック株式会社 フルオロエラストマー、その製造方法、架橋性組成物およびその硬化物
CA2445998A1 (en) * 2001-05-02 2002-11-07 3M Innovative Properties Company Emulsifier free aqueous emulsion polymerization process for making fluoropolymers
EP1427788B1 (en) * 2001-09-05 2014-05-21 3M Innovative Properties Company Fluoropolymer dispersion containing no or little low molecular weight fluorinated surfactant
EP1364972B1 (en) 2002-05-22 2006-08-30 3M Innovative Properties Company Process for reducing the amount of fluorinated surfactant in aqueous fluoropolymer dispersions
JP2006504844A (ja) * 2002-10-31 2006-02-09 スリーエム イノベイティブ プロパティズ カンパニー フッ化オレフィンと炭化水素オレフィンとのコポリマーを製造するための、乳化剤非含有水性乳化重合

Also Published As

Publication number Publication date
CN1708519A (zh) 2005-12-14
RU2005111865A (ru) 2005-10-27
US7064170B2 (en) 2006-06-20
ATE430169T1 (de) 2009-05-15
CN100354324C (zh) 2007-12-12
AU2003291646A1 (en) 2004-06-07
US20040087703A1 (en) 2004-05-06
JP2006504844A (ja) 2006-02-09
RU2342403C2 (ru) 2008-12-27
WO2004041878A1 (en) 2004-05-21
EP1556426A1 (en) 2005-07-27
EP1556426B1 (en) 2009-04-29
ZA200504411B (en) 2006-02-22

Similar Documents

Publication Publication Date Title
DE60327452D1 (de) Emulgatorfreies wässriges emulsionspolymerisationsverfahren zur herstellung fluorierter olefine und olefinischer kohlenwasserstoffcopolymere
DE60220253D1 (de) Verfahren zur oligomerisierung von olefinen
AR060640A1 (es) Proceso de polimerizacion de solucion de poliolefina y polimero
ATE555847T1 (de) Verfahren zur herstellung von polyethylen- copolymeren
ATE473954T1 (de) Verfahren zur herstellung von linearen alpha- olefinen und ethylen
ATE284418T1 (de) Radikalische polymerisationsmethode für fluorierte copolymere
ATE353343T1 (de) Verfahren zur polymerisation von 1-buten und 1- buten polymeren
DE60030123D1 (de) Herstellung von olefinen
DE502005011278D1 (de) Verfahren zur nachvernetzung wasserabsorbierender polymere
DE60102448D1 (de) Verfahren zur herstellung von polyolefinen
DE60233961D1 (de) Verfahren zur Polymerisation von Buten-1
ATE432951T1 (de) Verfahren zur polymerisation von ethylen, höheren alpha-olefin-comonomeren und dienen, insbesondere vinyl norbornen und nach diesem verfahren hergestellte polymere
DE60122581D1 (de) Verfahren zur herstellung eines katalysators für die homo- oder copolymerisation von ethylen
RU2018107929A (ru) Комбинации и их использование
ATE463472T1 (de) Verfahren zur herstellung von olefinen
DE602004019782D1 (de) Lagerstabile silanmodifizierte wässrig dispergierte polymere
ATE499391T1 (de) Verfahren zur copolymerisation von ethylen mit vinylsilanen
EA200700980A1 (ru) Способ полимеризации в суспензионной фазе
DE602005023844D1 (de) Verfahren zur polymerisation von 1-hexen oder höheren alpha-olefinen
BR0113368A (pt) Misturas de polìmeros de olefina e borrachas de nitrila
MX2007010286A (es) Proceso para preparar propeno de corrientes de alimentacion ricas en 2-buteno-e isobuteno.
DE60205104D1 (de) Verfahren zur olefinpolymerisation
ATE492573T1 (de) Verfahren zur polymerisation von ethylen und mischpolymere davon
RU2003136369A (ru) Регулятор степени полимеризации
DE602004027473D1 (de) Verfahren zur herstellung von polyolefinen mit kontrollierter morphologie

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee