ATE430169T1 - Emulgatorfreies wässriges emulsionspolymerisationsverfahren zur herstellung fluorierter olefine und olefinischer kohlenwasserstoffcopolymere - Google Patents

Emulgatorfreies wässriges emulsionspolymerisationsverfahren zur herstellung fluorierter olefine und olefinischer kohlenwasserstoffcopolymere

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Publication number
ATE430169T1
ATE430169T1 AT03768534T AT03768534T ATE430169T1 AT E430169 T1 ATE430169 T1 AT E430169T1 AT 03768534 T AT03768534 T AT 03768534T AT 03768534 T AT03768534 T AT 03768534T AT E430169 T1 ATE430169 T1 AT E430169T1
Authority
AT
Austria
Prior art keywords
emulsion polymerization
aqueous emulsion
emulgator
free aqueous
polymerization process
Prior art date
Application number
AT03768534T
Other languages
English (en)
Inventor
Harald Kaspar
Peter Scott
Klaus Hintzer
Gernot Lohr
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Application granted granted Critical
Publication of ATE430169T1 publication Critical patent/ATE430169T1/de

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
AT03768534T 2002-10-31 2003-10-21 Emulgatorfreies wässriges emulsionspolymerisationsverfahren zur herstellung fluorierter olefine und olefinischer kohlenwasserstoffcopolymere ATE430169T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US42277002P 2002-10-31 2002-10-31
PCT/US2003/033233 WO2004041878A1 (en) 2002-10-31 2003-10-21 Emulsifier free aqueous emulsion polymerization to produce copolymers of a fluorinated olefin and hydrocarbon olefin

Publications (1)

Publication Number Publication Date
ATE430169T1 true ATE430169T1 (de) 2009-05-15

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
AT03768534T ATE430169T1 (de) 2002-10-31 2003-10-21 Emulgatorfreies wässriges emulsionspolymerisationsverfahren zur herstellung fluorierter olefine und olefinischer kohlenwasserstoffcopolymere

Country Status (10)

Country Link
US (1) US7064170B2 (de)
EP (1) EP1556426B1 (de)
JP (1) JP2006504844A (de)
CN (1) CN100354324C (de)
AT (1) ATE430169T1 (de)
AU (1) AU2003291646A1 (de)
DE (1) DE60327452D1 (de)
RU (1) RU2342403C2 (de)
WO (1) WO2004041878A1 (de)
ZA (1) ZA200504411B (de)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7125941B2 (en) * 2001-03-26 2006-10-24 3M Innovative Properties Company Aqueous emulsion polymerization process for producing fluoropolymers
WO2002088203A2 (en) * 2001-05-02 2002-11-07 3M Innovative Properties Company Aqueous emulsion polymerization in the presence of ethers as chain transfer agents to produce fluoropolymers
US7279522B2 (en) 2001-09-05 2007-10-09 3M Innovative Properties Company Fluoropolymer dispersions containing no or little low molecular weight fluorinated surfactant
US7064170B2 (en) * 2002-10-31 2006-06-20 3M Innovative Properties Company Emulsifier free aqueous emulsion polymerization to produce copolymers of a fluorinated olefin and hydrocarbon olefin
EP1529785B1 (de) 2003-10-24 2011-03-16 3M Innovative Properties Company Wässrige Dispersionen von Polytetrafluorethylenteilchen
ATE529451T1 (de) 2003-11-17 2011-11-15 3M Innovative Properties Co Wässrige ptfe-dispersionen mit einem niedrigen gehalt an fluorierten emulgatoren
DE602004021467D1 (de) * 2004-03-01 2009-07-23 3M Innovative Properties Co Verfahren zum Beschichten eines Gegenstands mit einer fluorhaltigen Kunststoffsdispersion
US7691932B2 (en) 2004-09-27 2010-04-06 3M Innovative Properties Company Method of making a composition and nanocomposites therefrom
US20060270780A1 (en) * 2005-05-25 2006-11-30 Ping Xu High purity perfluoroelastomer composites and a processes to produce the same
US7488781B2 (en) * 2005-05-25 2009-02-10 Gore Enterprise Holdings, Inc. High purity transparent perfluoroelastomer parts and a process to produce the same
GB2427170A (en) * 2005-06-17 2006-12-20 3M Innovative Properties Co Fluoropolymer film having glass microspheres
US20070015937A1 (en) * 2005-07-15 2007-01-18 3M Innovative Properties Company Process for recovery of fluorinated carboxylic acid surfactants from exhaust gas
GB0523853D0 (en) 2005-11-24 2006-01-04 3M Innovative Properties Co Fluorinated surfactants for use in making a fluoropolymer
GB0514398D0 (en) * 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant
GB0514387D0 (en) * 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant
US20080015304A1 (en) 2006-07-13 2008-01-17 Klaus Hintzer Aqueous emulsion polymerization process for producing fluoropolymers
GB0525978D0 (en) * 2005-12-21 2006-02-01 3M Innovative Properties Co Fluorinated Surfactants For Making Fluoropolymers
GB2430437A (en) * 2005-09-27 2007-03-28 3M Innovative Properties Co Method of making a fluoropolymer
US7728087B2 (en) 2005-12-23 2010-06-01 3M Innovative Properties Company Fluoropolymer dispersion and method for making the same
CN101443366B (zh) 2006-05-10 2012-07-18 大金工业株式会社 含氟聚合物的制造方法
US7754795B2 (en) * 2006-05-25 2010-07-13 3M Innovative Properties Company Coating composition
US20070276103A1 (en) * 2006-05-25 2007-11-29 3M Innovative Properties Company Fluorinated Surfactants
US8119750B2 (en) * 2006-07-13 2012-02-21 3M Innovative Properties Company Explosion taming surfactants for the production of perfluoropolymers
EP2132143B1 (de) * 2007-02-16 2012-12-26 3M Innovative Properties Company System und verfahren zur entfernung von fluorchemikalien aus wasser
US20080264864A1 (en) * 2007-04-27 2008-10-30 3M Innovative Properties Company PROCESS FOR REMOVING FLUORINATED EMULSIFIER FROM FLUOROPOLMER DISPERSIONS USING AN ANION-EXCHANGE RESIN AND A pH-DEPENDENT SURFACTANT AND FLUOROPOLYMER DISPERSIONS CONTAINING A pH-DEPENDENT SURFACTANT
EP2155830A1 (de) * 2007-05-23 2010-02-24 3M Innovative Properties Company Wässrige zusammensetzungen von fluortensiden und ihre verwendung
US8476385B2 (en) * 2007-06-06 2013-07-02 3M Innovative Properties Company Fluorinated ether compositions and methods of using the same
JP5532532B2 (ja) * 2007-06-25 2014-06-25 ダイキン工業株式会社 低分子量ポリテトラフルオロエチレン水性分散液及びその製造方法
GB0712191D0 (en) * 2007-06-25 2007-08-01 3M Innovative Properties Co Process for removing fluorinated compounds for an aqueous phase originating from the preparation of fluoropolymers
US8637144B2 (en) * 2007-10-04 2014-01-28 W. L. Gore & Associates, Inc. Expandable TFE copolymers, method of making, and porous, expended articles thereof
US9650479B2 (en) 2007-10-04 2017-05-16 W. L. Gore & Associates, Inc. Dense articles formed from tetrafluoroethylene core shell copolymers and methods of making the same
US9040646B2 (en) 2007-10-04 2015-05-26 W. L. Gore & Associates, Inc. Expandable TFE copolymers, methods of making, and porous, expanded articles thereof
JP2011528659A (ja) * 2008-07-18 2011-11-24 スリーエム イノベイティブ プロパティズ カンパニー フッ素化エーテル化合物及びその使用方法
US20110232530A1 (en) * 2008-11-25 2011-09-29 Dams Rudolf J Fluorinated ether urethanes and methods of using the same
WO2010080473A1 (en) 2008-12-18 2010-07-15 3M Innovative Properties Company Method of contacting hydrocarbon-bearing formations with fluorinated ether compositions
JP5407643B2 (ja) * 2009-07-31 2014-02-05 旭硝子株式会社 含フッ素共重合体の製造方法
CN103201301B (zh) 2010-11-09 2017-02-08 纳幕尔杜邦公司 含氟单体的含水聚合反应中的成核作用
CN103201300B (zh) 2010-11-09 2016-11-09 纳幕尔杜邦公司 使用烃表面活性剂的含氟单体的含水聚合
CN103210003B (zh) 2010-11-09 2016-09-07 纳幕尔杜邦公司 减弱含烃表面活性剂在含氟单体含水分散体聚合反应中的调聚性能
WO2012150256A1 (en) * 2011-05-03 2012-11-08 Solvay Specialty Polymers Italy S.P.A. Method for manufacturing fluoroelastomers
EP2731990B1 (de) 2011-07-15 2016-12-28 Solvay Specialty Polymers Italy S.p.A. Wässriger vinylidenfluoridpolymerlatex
EP2927246B1 (de) * 2013-01-23 2017-10-25 Daikin Industries, Ltd. Verfahren zur rückgewinnung von fluorhaltigem ether
US9676929B2 (en) 2013-11-26 2017-06-13 The Chemours Company Fc, Llc Employing polyalkylene oxides for nucleation in aqueous polymerization of fluoromonomer
US9644054B2 (en) 2014-12-19 2017-05-09 W. L. Gore & Associates, Inc. Dense articles formed from tetrafluoroethylene core shell copolymers and methods of making the same
JP7403317B2 (ja) * 2017-04-11 2023-12-22 ソルベイ スペシャルティ ポリマーズ イタリー エス．ピー．エー． 溶融加工性フルオロポリマー
CN110078855B (zh) * 2019-04-22 2020-07-14 中昊晨光化工研究院有限公司 一种含氟聚合物及其制备方法
CN116178598A (zh) * 2022-06-20 2023-05-30 福建海德福新材料有限公司 一种四氟乙烯基聚合物树脂及其制备方法

Family Cites Families (58)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2567011A (en) * 1949-01-10 1951-09-04 Minnesota Mining & Mfg Fluorocarbon acids and derivatives
US2732398A (en) * 1953-01-29 1956-01-24 cafiicfzsojk
US2809990A (en) * 1955-12-29 1957-10-15 Minnesota Mining & Mfg Fluorocarbon acids and derivatives
US3345317A (en) * 1963-04-04 1967-10-03 Thiokol Chemical Corp Emulsion polymerization of tetrafluoroethylene using trifluorotrichloroethane as emulsion stabilizer
JPS4928026B1 (de) * 1965-01-12 1974-07-23
GB1291936A (en) 1970-11-19 1972-10-04 Asahi Glass Co Ltd Process for producing a copolymer of tetrafluoroethylene and propylene
US3876654A (en) * 1970-12-23 1975-04-08 Du Pont Fluoroelastomer composition
JPS497058B1 (de) * 1970-12-30 1974-02-18
US4025481A (en) * 1971-01-28 1977-05-24 Produits Chimiques Ugine Kuhlmann Method for the preparation of aqueous dispersions of polytetrafluoroethylene with halogenated hydrocarbon as stabilizing agent
US4000356A (en) * 1972-06-19 1976-12-28 Dynamit Nobel Aktiengesellschaft Process for the preparation of thermoplastically workable fluoro-olefin polymers
US4277586A (en) * 1974-11-20 1981-07-07 Asahi Glass Company, Ltd. Process for preparing a propylene-tetrafluoroethylene copolymer
US4035565A (en) * 1975-03-27 1977-07-12 E. I. Du Pont De Nemours And Company Fluoropolymer containing a small amount of bromine-containing olefin units
US4029868A (en) * 1976-03-10 1977-06-14 E. I. Du Pont De Nemours And Company Tetrafluoroethylene terpolymers
JPS539848A (en) * 1976-07-16 1978-01-28 Asahi Glass Co Ltd Heat treatment of fluorine-containing elastomers
JPS53125491A (en) * 1977-04-08 1978-11-01 Daikin Ind Ltd Fluorine-containing polymer easily curable and its curable composition
JPS54132691A (en) * 1978-04-06 1979-10-15 Asahi Glass Co Ltd Preparation of ethylene-tetrafluoroethylene copolymer
JPS5529519A (en) * 1978-08-22 1980-03-01 Asahi Glass Co Ltd Preparation of fluorocopolymer
DE2903981A1 (de) * 1979-02-02 1980-08-07 Hoechst Ag Rueckgewinnung fluorierter emulgatorsaeuren aus basischen anionenaustauschern
US4233421A (en) * 1979-02-26 1980-11-11 Minnesota Mining And Manufacturing Company Fluoroelastomer composition containing sulfonium curing agents
US4463144A (en) * 1980-09-10 1984-07-31 Asahi Glass Company Ltd. Process for producing propylene-tetrafluoroethylene copolymer
DE3135598A1 (de) * 1981-09-09 1983-03-17 Hoechst Ag, 6000 Frankfurt "kontinuierliches verfahren zur agglomerierung von ptee-pulvern im fluessigen medium und damit gewonnenes modifiziertes ptee-pulver"
JPS5920310A (ja) 1982-07-27 1984-02-02 Daikin Ind Ltd 含フッ素ポリマー硬化用組成物
US5086123A (en) * 1984-02-27 1992-02-04 Minnesota Mining And Manufacturing Company Fluoroelastomer compositions containing fluoroaliphatic sulfonamides as curing agents
JPS60248710A (ja) * 1984-05-22 1985-12-09 Daikin Ind Ltd 新規エチレン／テトラフルオロエチレン系共重合体
EP0199138B1 (de) * 1985-03-28 1989-02-22 Daikin Industries, Limited Fluorvinylether und diese enthaltende Copolymere
IT1187684B (it) * 1985-07-08 1987-12-23 Montefluos Spa Procedimento per la preparazione di fluoroelastomeri vulcanizzabili e prodotti cosi' ottenuti
JPS62260807A (ja) * 1986-05-07 1987-11-13 Nippon Mektron Ltd 含フッ素重合体の製造方法
IT1204903B (it) * 1986-06-26 1989-03-10 Ausimont Spa Processo di polimerizzazione in dispersione acquosa di monomeri florati
GB8728884D0 (en) * 1987-12-10 1988-01-27 Ici Plc Aqueous-based fluoropolymer compositions
US4912171A (en) * 1988-04-01 1990-03-27 Minnesota Mining And Manufacturing Company Fluoroelastomer curing process with phosphonium compound
IT1235545B (it) 1989-07-10 1992-09-09 Ausimont Srl Fluoroelastomeri dotati di migliore processabilita' e procedimento di preparazione
US5037921A (en) * 1990-03-01 1991-08-06 E. I. Du Pont De Nemours And Company Base resistant fluoroelastomers with improved processibility and curability
US5453477A (en) * 1992-05-01 1995-09-26 Alliedsignal Inc. Process of polymerizing chloroetrifluoroethylene with alkyl hydroperoxide and metal metabisulfite
US5262490A (en) * 1992-08-24 1993-11-16 Minnesota Mining And Manufacturing Company Fluoroelastomer composition with organo-onium compounds
US5285002A (en) * 1993-03-23 1994-02-08 Minnesota Mining And Manufacturing Company Fluorine-containing polymers and preparation and use thereof
IT1266647B1 (it) * 1993-10-29 1997-01-09 Ausimont Spa Processo di (co)polimerizzazione di monomeri olefinici fluorurati in emulsione acquosa
IT1265461B1 (it) 1993-12-29 1996-11-22 Ausimont Spa Fluoroelastomeri comprendenti unita' monomeriche derivanti da una bis-olefina
WO1996024622A1 (en) 1995-02-10 1996-08-15 Alliedsignal Inc. Production of fluoropolymers, fluoropolymer suspension and polymer formed therefrom
JP3223776B2 (ja) * 1995-03-31 2001-10-29 日本メクトロン株式会社 含フッ素エラストマー組成物
JP3082626B2 (ja) * 1995-07-19 2000-08-28 日本メクトロン株式会社 含フッ素エラストマー組成物
JPH0977829A (ja) * 1995-09-08 1997-03-25 Toagosei Co Ltd パーハロオレフィン共重合体及び該共重合体からなる架橋成形体の製造方法
IT1276979B1 (it) 1995-10-20 1997-11-03 Ausimont Spa Composizioni fluoroelastomeriche
US5955556A (en) * 1995-11-06 1999-09-21 Alliedsignal Inc. Method of manufacturing fluoropolymers
US5591804A (en) * 1995-12-21 1997-01-07 Minnesota Mining And Manufacturing Company Fluorinated onium salts, curable compositions containing same, and method of curing using same
US5936060A (en) * 1996-11-25 1999-08-10 E. I. Du Pont De Nemours And Company Perfluoroelastomer composition having improved processability
US5677389A (en) * 1996-11-25 1997-10-14 E. I. Du Pont De Nemours Perfluoroelastomer composition having enhanced curing performance
US5728773A (en) * 1997-02-21 1998-03-17 Minnesota Mining And Manufacturing Company Fluoroelastomer composition with organo-onium and blocked-carbonate compounds
US6281296B1 (en) 1998-08-10 2001-08-28 Dupont Dow Elastomers L.L.C. Curable perfluoroelastomer composition
US6642307B1 (en) * 1998-10-13 2003-11-04 Daikin Industries, Ltd. Process for producing fluoropolymer
CN1206249C (zh) 1998-11-30 2005-06-15 纳幕尔杜邦公司 氟单体的聚合反应
DE19857111A1 (de) 1998-12-11 2000-06-15 Dyneon Gmbh Wäßrige Dispersionen von Fluorpolymeren
JP5092184B2 (ja) * 1999-02-15 2012-12-05 ダイキン工業株式会社 フルオロポリマーの製造法
US6429258B1 (en) * 1999-05-20 2002-08-06 E. I. Du Pont De Nemours & Company Polymerization of fluoromonomers
JP4352546B2 (ja) * 1999-12-22 2009-10-28 ユニマテック株式会社 フルオロエラストマー、その製造方法、架橋性組成物およびその硬化物
US7074862B2 (en) * 2001-05-02 2006-07-11 3M Innovative Properties Company Emulsifier free aqueous emulsion polymerization process for making fluoropolymers
RU2294940C2 (ru) * 2001-09-05 2007-03-10 Зм Инновейтив Пропертиз Компани Дисперсия фторполимера, не содержащая либо содержащая малое количество низкомолекулярного фторированного поверхностно-активного вещества
DE60214343T2 (de) * 2002-05-22 2007-03-29 3M Innovative Properties Co., Saint Paul Prozess zur Reduzierung des Gehaltes an fluorierten Emulgatoren in wässrigen Fluorpolymer-Dispersionen
US7064170B2 (en) * 2002-10-31 2006-06-20 3M Innovative Properties Company Emulsifier free aqueous emulsion polymerization to produce copolymers of a fluorinated olefin and hydrocarbon olefin

Also Published As

Publication number Publication date
EP1556426B1 (de) 2009-04-29
US20040087703A1 (en) 2004-05-06
DE60327452D1 (de) 2009-06-10
US7064170B2 (en) 2006-06-20
ZA200504411B (en) 2006-02-22
WO2004041878A1 (en) 2004-05-21
EP1556426A1 (de) 2005-07-27
CN100354324C (zh) 2007-12-12
RU2342403C2 (ru) 2008-12-27
JP2006504844A (ja) 2006-02-09
RU2005111865A (ru) 2005-10-27
AU2003291646A1 (en) 2004-06-07
CN1708519A (zh) 2005-12-14

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