DE60319717T2 - Spandexfaser mit ethylendiamin/1,2-diaminopropan als kettenverlängerer und verfahren zu dessen herstellung - Google Patents
Spandexfaser mit ethylendiamin/1,2-diaminopropan als kettenverlängerer und verfahren zu dessen herstellung Download PDFInfo
- Publication number
- DE60319717T2 DE60319717T2 DE60319717T DE60319717T DE60319717T2 DE 60319717 T2 DE60319717 T2 DE 60319717T2 DE 60319717 T DE60319717 T DE 60319717T DE 60319717 T DE60319717 T DE 60319717T DE 60319717 T2 DE60319717 T2 DE 60319717T2
- Authority
- DE
- Germany
- Prior art keywords
- glycol
- spandex
- propanediamine
- poly
- mole percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 title claims description 23
- 239000004970 Chain extender Substances 0.000 title claims description 20
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 title claims description 17
- 238000000034 method Methods 0.000 title claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 93
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 47
- 229920003226 polyurethane urea Polymers 0.000 claims description 40
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 33
- 229920002334 Spandex Polymers 0.000 claims description 28
- 239000004759 spandex Substances 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 21
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 14
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 7
- 125000005442 diisocyanate group Chemical group 0.000 claims description 6
- 239000007795 chemical reaction product Substances 0.000 claims description 5
- 150000002009 diols Chemical class 0.000 claims description 4
- 238000009987 spinning Methods 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 3
- 239000012948 isocyanate Substances 0.000 claims description 3
- 150000002513 isocyanates Chemical class 0.000 claims description 3
- 150000003141 primary amines Chemical class 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 1
- 239000004202 carbamide Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 239000004753 textile Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 description 41
- 239000000835 fiber Substances 0.000 description 22
- 125000001261 isocyanato group Chemical group *N=C=O 0.000 description 13
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 4
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 4
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 3
- SCKHCCSZFPSHGR-UHFFFAOYSA-N cyanophos Chemical compound COP(=S)(OC)OC1=CC=C(C#N)C=C1 SCKHCCSZFPSHGR-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 2
- XTUVJUMINZSXGF-UHFFFAOYSA-N N-methylcyclohexylamine Chemical compound CNC1CCCCC1 XTUVJUMINZSXGF-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 2
- 150000004056 anthraquinones Chemical class 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 125000004427 diamine group Chemical group 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- -1 glycol diols Chemical class 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 235000019359 magnesium stearate Nutrition 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- DPBLXKKOBLCELK-UHFFFAOYSA-N pentan-1-amine Chemical compound CCCCCN DPBLXKKOBLCELK-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000909 polytetrahydrofuran Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- XHJGXOOOMKCJPP-UHFFFAOYSA-N 2-[tert-butyl(2-hydroxyethyl)amino]ethanol Chemical compound OCCN(C(C)(C)C)CCO XHJGXOOOMKCJPP-UHFFFAOYSA-N 0.000 description 1
- FEUISMYEFPANSS-UHFFFAOYSA-N 2-methylcyclohexan-1-amine Chemical compound CC1CCCCC1N FEUISMYEFPANSS-UHFFFAOYSA-N 0.000 description 1
- ZGMQLPDXPUINCQ-UHFFFAOYSA-N 3,3,5-trimethylcyclohexan-1-amine Chemical compound CC1CC(N)CC(C)(C)C1 ZGMQLPDXPUINCQ-UHFFFAOYSA-N 0.000 description 1
- JYDYHSHPBDZRPU-UHFFFAOYSA-N 3-methylcyclohexan-1-amine Chemical compound CC1CCCC(N)C1 JYDYHSHPBDZRPU-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- WJYIASZWHGOTOU-UHFFFAOYSA-N Heptylamine Chemical compound CCCCCCCN WJYIASZWHGOTOU-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- DKNWSYNQZKUICI-UHFFFAOYSA-N amantadine Chemical compound C1C(C2)CC3CC2CC1(N)C3 DKNWSYNQZKUICI-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- JEPPYVOSGKWVSJ-UHFFFAOYSA-N bicyclo[2.2.1]heptan-3-amine Chemical compound C1CC2C(N)CC1C2 JEPPYVOSGKWVSJ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- CXUJOBCFZQGUGO-UHFFFAOYSA-F calcium trimagnesium tetracarbonate Chemical compound [Mg++].[Mg++].[Mg++].[Ca++].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O CXUJOBCFZQGUGO-UHFFFAOYSA-F 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- 229910000515 huntite Inorganic materials 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/70—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3228—Polyamines acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3271—Hydroxyamines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S528/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S528/906—Fiber or elastomer prepared from an isocyanate reactant
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Polyurethanes Or Polyureas (AREA)
- Woven Fabrics (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/264,742 US6984708B2 (en) | 2002-10-04 | 2002-10-04 | Spandex of a particular composition and process for making same |
| US264742 | 2002-10-04 | ||
| PCT/US2003/031555 WO2004033514A2 (en) | 2002-10-04 | 2003-10-03 | Spandex fiber using ethylene diamene/1,2-diaminopropane as chain extender and process for making same. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60319717D1 DE60319717D1 (de) | 2008-04-24 |
| DE60319717T2 true DE60319717T2 (de) | 2009-03-12 |
Family
ID=32042315
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60319717T Expired - Lifetime DE60319717T2 (de) | 2002-10-04 | 2003-10-03 | Spandexfaser mit ethylendiamin/1,2-diaminopropan als kettenverlängerer und verfahren zu dessen herstellung |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US6984708B2 (enExample) |
| EP (1) | EP1546226B1 (enExample) |
| JP (1) | JP4425793B2 (enExample) |
| KR (1) | KR101036077B1 (enExample) |
| CN (1) | CN1280327C (enExample) |
| AU (1) | AU2003284003A1 (enExample) |
| DE (1) | DE60319717T2 (enExample) |
| TW (1) | TWI300071B (enExample) |
| WO (1) | WO2004033514A2 (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7838617B2 (en) * | 2003-05-05 | 2010-11-23 | Invista North America S.àr.l. | Dyeable spandex |
| BRPI0509904A (pt) * | 2004-04-15 | 2007-09-18 | Textronics Inc | estrutura elastomérica eletricamente condutiva, fibra, tecido ou pelìcula, e, método para produzir estruturas e fibras elastoméricas eletricamente condutivas |
| US20080004395A1 (en) * | 2005-02-11 | 2008-01-03 | Invista North America S.A.R.L. | Aqueous polyurethaneurea compositions including dispersions and films |
| JP2008540765A (ja) * | 2005-05-09 | 2008-11-20 | インヴィスタ テクノロジー エスアエルエル | 高エチレンエーテル含有率を有するポリ（テトラメチレン−コ−エチレンエーテル）グリコールからのスパンデックス |
| KR101322054B1 (ko) * | 2005-05-09 | 2013-10-25 | 인비스타 테크놀러지스 에스.에이.알.엘. | 고속 방사용 스판덱스 조성물 |
| US20070174972A1 (en) * | 2005-11-14 | 2007-08-02 | Invista North America S.A R.I. | Spandex having enhanced whiteness, and fabrics and garments comprising the same |
| US20070117949A1 (en) * | 2005-11-22 | 2007-05-24 | Palmer Charles F Jr | Spandex from poly(tetramethylene-co-ethyleneether) glycols having low ethyleneether content |
| ES2403419T3 (es) * | 2005-11-22 | 2013-05-17 | Invista Technologies S.À.R.L. | Elastano obtenido a partir de poli(tetrametilén-co-etilén éter)glicoles mezclados con glicoles poliméricos |
| US9441314B2 (en) * | 2005-11-22 | 2016-09-13 | Invista North America S.A.R.L. | Spandex from high molecular weight poly (tetramethylene-co-ethyleneether) glycols |
| KR100711644B1 (ko) * | 2006-07-31 | 2007-04-25 | 주식회사 효성 | 열세트성이 향상된 폴리우레탄 탄성사 |
| EP2190642A1 (en) * | 2007-08-30 | 2010-06-02 | Invista Technologies S.A R.L. | Preparation of thin-walled articles of polyurethaneurea |
| US9499929B2 (en) * | 2007-11-29 | 2016-11-22 | Invista North America S.A.R.L. | High-loft nonwoven including stabilizer or binder |
| US8167490B2 (en) | 2009-04-22 | 2012-05-01 | Reynolds Consumer Products Inc. | Multilayer stretchy drawstring |
| BR112012017395B8 (pt) * | 2010-01-14 | 2020-08-04 | Invista Tech Sarl | artigo e processo para a preparação do spandex |
| WO2012124691A1 (ja) | 2011-03-14 | 2012-09-20 | 旭化成せんい株式会社 | ポリウレタン弾性繊維 |
| KR101396107B1 (ko) | 2012-10-26 | 2014-05-15 | 주식회사 효성 | 열세트성이 향상된 폴리우레탄우레아 탄성사 및 그 제조 방법 |
| WO2015088059A1 (ko) * | 2013-12-10 | 2015-06-18 | 주식회사 효성 | 열세트성이 향상된 폴리우레탄우레아 탄성사 및 그 제조 방법 |
| KR20200073966A (ko) | 2018-12-14 | 2020-06-24 | 삼성전자주식회사 | 진공 청소기와 도킹 스테이션을 포함하는 청소 장치 |
| TW202319427A (zh) * | 2021-10-08 | 2023-05-16 | 英商萊卡英國有限公司 | 可再加工斯潘德克斯及其纖維與物件 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58194915A (ja) | 1982-05-10 | 1983-11-14 | Fuji Boseki Kk | ポリウレタン弾性体の製造方法 |
| WO1985005315A1 (fr) * | 1984-05-22 | 1985-12-05 | Toyo Boseki Kabushiki Kaisha | Procede de production d'un film de polyamide |
| US5000899A (en) | 1988-05-26 | 1991-03-19 | E. I. Du Pont De Nemours And Company | Spandex fiber with copolymer soft segment |
| US4973647A (en) | 1989-05-31 | 1990-11-27 | E. I. Du Pont De Nemours And Company | Fiber from polyether-based spandex |
| JP3023483B2 (ja) | 1990-03-27 | 2000-03-21 | 東洋紡績株式会社 | ポリウレタン弾性繊維の製造方法 |
| US5362432A (en) | 1993-04-02 | 1994-11-08 | E. I. Du Pont De Nemours And Company | Process for dry spinning spandex |
| JPH08113824A (ja) | 1994-10-19 | 1996-05-07 | Toyobo Co Ltd | 熱セット性の改善されたポリウレタン弾性糸 |
| KR0182018B1 (ko) * | 1995-07-24 | 1999-05-01 | 김광호 | 액정 표시 장치의 공통 전극 기판 및 그 제조 방법 |
| US5961686A (en) * | 1997-08-25 | 1999-10-05 | Guardian Fiberglass, Inc. | Side-discharge melter for use in the manufacture of fiberglass |
| US5981686A (en) | 1998-03-26 | 1999-11-09 | E. I. Du Pont De Nemours And Company | Spandex made with 1,3-diaminopentane |
| US6402316B1 (en) * | 1998-12-28 | 2002-06-11 | Canon Kabushiki Kaisha | Recording medium, production process of the recording medium, and image forming process using the recording medium |
| TW507028B (en) | 1999-02-12 | 2002-10-21 | Asahi Chemical Ind | A moisture-absorbable synthetic fiber with an improved moisture-release property |
| WO2001040345A1 (en) * | 1999-12-03 | 2001-06-07 | Du Pont-Toray Company, Ltd. | Spandex having low set at low temperatures |
-
2002
- 2002-10-04 US US10/264,742 patent/US6984708B2/en not_active Expired - Lifetime
-
2003
- 2003-10-03 JP JP2004543365A patent/JP4425793B2/ja not_active Expired - Fee Related
- 2003-10-03 CN CNB038014645A patent/CN1280327C/zh not_active Expired - Fee Related
- 2003-10-03 WO PCT/US2003/031555 patent/WO2004033514A2/en not_active Ceased
- 2003-10-03 AU AU2003284003A patent/AU2003284003A1/en not_active Abandoned
- 2003-10-03 DE DE60319717T patent/DE60319717T2/de not_active Expired - Lifetime
- 2003-10-03 TW TW092127432A patent/TWI300071B/zh not_active IP Right Cessation
- 2003-10-03 KR KR1020057005686A patent/KR101036077B1/ko not_active Expired - Fee Related
- 2003-10-03 EP EP03776230A patent/EP1546226B1/en not_active Expired - Lifetime
-
2005
- 2005-08-31 US US11/216,733 patent/US20050288477A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| JP4425793B2 (ja) | 2010-03-03 |
| TWI300071B (en) | 2008-08-21 |
| JP2006502320A (ja) | 2006-01-19 |
| EP1546226B1 (en) | 2008-03-12 |
| KR101036077B1 (ko) | 2011-05-19 |
| WO2004033514A3 (en) | 2004-11-04 |
| EP1546226A2 (en) | 2005-06-29 |
| AU2003284003A8 (en) | 2004-05-04 |
| US20050288477A1 (en) | 2005-12-29 |
| DE60319717D1 (de) | 2008-04-24 |
| CN1592763A (zh) | 2005-03-09 |
| TW200422313A (en) | 2004-11-01 |
| KR20050055740A (ko) | 2005-06-13 |
| WO2004033514A2 (en) | 2004-04-22 |
| AU2003284003A1 (en) | 2004-05-04 |
| CN1280327C (zh) | 2006-10-18 |
| US6984708B2 (en) | 2006-01-10 |
| US20040068080A1 (en) | 2004-04-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE60319717T2 (de) | Spandexfaser mit ethylendiamin/1,2-diaminopropan als kettenverlängerer und verfahren zu dessen herstellung | |
| DE68917212T2 (de) | Elasthanfaser mit copolymeren Weichsegmenten. | |
| DE602004011661T2 (de) | Schmelzgesponnene tpu-fasern und verfahren | |
| DE69626850T2 (de) | Elastische polyurethanfasern und verfahren zu ihrer herstellung | |
| DE69401749T2 (de) | Schnellgesponnene spandex auf polyetherbasis | |
| DE60224376T2 (de) | Elastomerfasern aus polyurethan und verfahren zu ihrer herstellung | |
| WO2007122124A1 (de) | SEGMENTIERTE POLYURETHANELASTOMERE MIT HOHER REIßDEHNUNG | |
| US20020193550A1 (en) | Spandex having low set at low temperatures | |
| DE60001356T2 (de) | Verfahren zum schmelzspinnen von spandex fasern | |
| JP4112336B2 (ja) | 高度に均一なスパンデックスおよびスパンデックスの製造方法 | |
| EP4190954A1 (en) | Polyurethane urea elastic yarn dyeable with reactive dye and manufacturing method therefor | |
| DE112020004306T5 (de) | Elastische Polyurethanfasern, diese enthaltendes Produkt und Oberflächenbehandlungsmittel für elastische Polyurethanfasern | |
| DE69705058T2 (de) | Verbesserte spandex elastomere | |
| DE3932948A1 (de) | Verfahren zur herstellung von segmentierten polyurethanharnstoff-elastomerloesungen, sowie faeden und folien daraus | |
| DE60112271T2 (de) | Spandex mit hoher effizienz bei der thermofixierung | |
| EP1088015B1 (de) | Polyurethanharnstoffe, polyurethanharnstofffasern und verfahren zu ihrer herstellung | |
| EP1200518B1 (de) | Polyurethanharnstofffasern mit erhöhter festigkeit | |
| DE2115419C3 (de) | Verfahren zur Herstellung einer stabilisierten Polyurethanlösung | |
| EP1431429A1 (de) | Verfahren zur Herstellung von Polyurethanharnstofffasern durch Einspinnen einer Kombination aus Polydimethylsiloxan, alkoxyliertem Polydimethylsiloxan und Fettsäuresalz | |
| DE1669411C3 (de) | Verfahren zur Herstellung gummielastischer Fäden | |
| DE69202863T2 (de) | Stabilisierte polyurethanharnstoff-lösungen und spandex-fasern. | |
| DE60024150T2 (de) | Spandex mit niedriger bleibender verformung bei niedrigen temperaturen | |
| DE69914494T2 (de) | Polyvinylidenfluorid enthaltende polyurethanfaser | |
| US6376071B1 (en) | Polyurethane fiber containing poly(vinylidene fluoride) | |
| DE69915892T2 (de) | Spandexfaser polyurethanharnstoff polymere hergestellt durch verwendung von 1,3-diaminopentan als kettenverlängerer |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition |