DE60226342T2 - Fluoriertes terpolymer - Google Patents
Fluoriertes terpolymer Download PDFInfo
- Publication number
- DE60226342T2 DE60226342T2 DE60226342T DE60226342T DE60226342T2 DE 60226342 T2 DE60226342 T2 DE 60226342T2 DE 60226342 T DE60226342 T DE 60226342T DE 60226342 T DE60226342 T DE 60226342T DE 60226342 T2 DE60226342 T2 DE 60226342T2
- Authority
- DE
- Germany
- Prior art keywords
- perfluoro
- vinyl ether
- feve
- fluorine
- fpve
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920001897 terpolymer Polymers 0.000 title claims description 48
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 claims description 53
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 35
- 229910052731 fluorine Inorganic materials 0.000 claims description 35
- 239000011737 fluorine Substances 0.000 claims description 35
- -1 perfluoro Chemical group 0.000 claims description 35
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 35
- KHXKESCWFMPTFT-UHFFFAOYSA-N 1,1,1,2,2,3,3-heptafluoro-3-(1,2,2-trifluoroethenoxy)propane Chemical compound FC(F)=C(F)OC(F)(F)C(F)(F)C(F)(F)F KHXKESCWFMPTFT-UHFFFAOYSA-N 0.000 claims description 19
- 238000000465 moulding Methods 0.000 claims description 10
- 230000009477 glass transition Effects 0.000 claims description 7
- 238000010557 suspension polymerization reaction Methods 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 description 40
- 230000000052 comparative effect Effects 0.000 description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 238000007334 copolymerization reaction Methods 0.000 description 12
- 238000006116 polymerization reaction Methods 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000000243 solution Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 238000001035 drying Methods 0.000 description 6
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 230000008033 biological extinction Effects 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 3
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 230000009878 intermolecular interaction Effects 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- LGUZHRODIJCVOC-UHFFFAOYSA-N perfluoroheptane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F LGUZHRODIJCVOC-UHFFFAOYSA-N 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- RPBWMJBZQXCSFW-UHFFFAOYSA-N 2-methylpropanoyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(=O)C(C)C RPBWMJBZQXCSFW-UHFFFAOYSA-N 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
- ZQBFAOFFOQMSGJ-UHFFFAOYSA-N hexafluorobenzene Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1F ZQBFAOFFOQMSGJ-UHFFFAOYSA-N 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- OVGRCEFMXPHEBL-UHFFFAOYSA-N 1-ethenoxypropane Chemical compound CCCOC=C OVGRCEFMXPHEBL-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000004299 exfoliation Methods 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- SNGREZUHAYWORS-UHFFFAOYSA-N perfluorooctanoic acid Chemical compound OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F SNGREZUHAYWORS-UHFFFAOYSA-N 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000009718 spray deposition Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 238000000870 ultraviolet spectroscopy Methods 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/26—Tetrafluoroethene
- C08F214/262—Tetrafluoroethene with fluorinated vinyl ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001383974 | 2001-12-18 | ||
| JP2001383974 | 2001-12-18 | ||
| JP2002163741A JP3888232B2 (ja) | 2001-12-18 | 2002-06-05 | 含フッ素三元共重合体 |
| JP2002163741 | 2002-06-05 | ||
| PCT/JP2002/013233 WO2003051944A1 (en) | 2001-12-18 | 2002-12-18 | Fluorinated terpolymer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60226342D1 DE60226342D1 (de) | 2008-06-12 |
| DE60226342T2 true DE60226342T2 (de) | 2009-06-10 |
Family
ID=26625105
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60226342T Expired - Lifetime DE60226342T2 (de) | 2001-12-18 | 2002-12-18 | Fluoriertes terpolymer |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7009017B2 (enExample) |
| EP (1) | EP1457505B1 (enExample) |
| JP (1) | JP3888232B2 (enExample) |
| AU (1) | AU2002357600A1 (enExample) |
| DE (1) | DE60226342T2 (enExample) |
| WO (1) | WO2003051944A1 (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3888232B2 (ja) * | 2001-12-18 | 2007-02-28 | ユニマテック株式会社 | 含フッ素三元共重合体 |
| JPWO2005100421A1 (ja) * | 2004-04-15 | 2008-03-06 | ダイキン工業株式会社 | 含フッ素重合体および処理剤組成物 |
| CN100475867C (zh) * | 2004-04-15 | 2009-04-08 | 大金工业株式会社 | 含氟聚合物和处理剂组合物 |
| JP2005325275A (ja) * | 2004-05-17 | 2005-11-24 | Yunimatekku Kk | 含フッ素重合体成形品およびその積層体 |
| JP4640021B2 (ja) * | 2004-08-25 | 2011-03-02 | 旭硝子株式会社 | 含フッ素共重合体 |
| EP2377610A3 (en) * | 2004-12-22 | 2012-02-08 | E. I. Du Pont De Nemours And Company | Process for increasing the fluorine content by photochemical reactions |
| JP2006316174A (ja) * | 2005-05-13 | 2006-11-24 | Yunimatekku Kk | フッ素化処理含フッ素共重合体の製造法 |
| JP2007112916A (ja) * | 2005-10-21 | 2007-05-10 | Yunimatekku Kk | 非晶質含フッ素共重合体 |
| JP5162818B2 (ja) | 2005-11-17 | 2013-03-13 | ユニマテック株式会社 | 含フッ素共重合体ブレンド物 |
| JP2007197561A (ja) * | 2006-01-26 | 2007-08-09 | Yunimatekku Kk | 含フッ素三元共重合体の製造法 |
| JP2007302708A (ja) * | 2006-05-08 | 2007-11-22 | Yunimatekku Kk | 可視化計測用もしくは光学的計測用成形体 |
| WO2008047906A1 (en) * | 2006-10-20 | 2008-04-24 | Daikin Industries, Ltd. | Fluorinated copolymer, electric wire, and method for production of the electric wire |
| TWI496796B (zh) * | 2009-02-13 | 2015-08-21 | Solvay Solexis Spa | 全氟彈性體 |
| TWI482784B (zh) * | 2009-02-13 | 2015-05-01 | Solvay Solexis Spa | 全氟彈性體 |
| JP6017550B2 (ja) * | 2011-06-09 | 2016-11-02 | ソルベイ スペシャルティ ポリマーズ イタリー エス．ピー．エー． | 超分岐フルオロエラストマー添加剤 |
| JP6150483B2 (ja) * | 2012-09-27 | 2017-06-21 | 三井・デュポンフロロケミカル株式会社 | パーフルオロ（エチルビニルエーテル）を含有する非晶質フッ素重合体溶剤組成物 |
| CN104926979B (zh) * | 2015-06-18 | 2017-05-10 | 巨化集团技术中心 | 一种乙烯/四氟乙烯共聚物粉体及其制备方法 |
| JP2018184618A (ja) * | 2018-08-03 | 2018-11-22 | 三井・ケマーズ フロロプロダクツ株式会社 | テトラフルオロエチレンとパーフルオロ（エチルビニルエーテル）との共重合体の水性分散体または溶液 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4029868A (en) * | 1976-03-10 | 1977-06-14 | E. I. Du Pont De Nemours And Company | Tetrafluoroethylene terpolymers |
| IT1264661B1 (it) * | 1993-07-05 | 1996-10-04 | Ausimont Spa | Copolimeri termoprocessabilin del tetrafluoroetilene |
| JPH07126329A (ja) * | 1993-10-29 | 1995-05-16 | Nippon Mektron Ltd | テトラフルオロエチレン−パーフルオロビニルエ−テル共重合体 |
| DE69601335T2 (de) | 1995-08-17 | 1999-08-12 | E.I. Du Pont De Nemours And Co., Wilmington, Del. | Tetrafluorethylen-Terpolymer |
| US5760151A (en) * | 1995-08-17 | 1998-06-02 | E. I. Du Pont De Nemours And Company | Tetrafluoroethylene copolymer |
| US5919878A (en) * | 1996-09-13 | 1999-07-06 | E. I. Du Pont De Nemours And Company | Amorphous fluoropolymer containing perfluoro(ethyl vinyl ether) |
| US6197904B1 (en) * | 1998-02-26 | 2001-03-06 | E. I. Du Pont De Nemours And Company | Low-melting tetrafluoroethylene copolymer |
| JP4392706B2 (ja) * | 2000-02-02 | 2010-01-06 | 三井・デュポンフロロケミカル株式会社 | 熱溶融性フッ素樹脂組成物 |
| JP2002295450A (ja) | 2001-04-02 | 2002-10-09 | Nippon Mektron Ltd | 定着ローラ被覆チューブ用材料 |
| JP3888232B2 (ja) * | 2001-12-18 | 2007-02-28 | ユニマテック株式会社 | 含フッ素三元共重合体 |
-
2002
- 2002-06-05 JP JP2002163741A patent/JP3888232B2/ja not_active Expired - Fee Related
- 2002-12-12 US US10/472,851 patent/US7009017B2/en not_active Expired - Fee Related
- 2002-12-18 WO PCT/JP2002/013233 patent/WO2003051944A1/ja not_active Ceased
- 2002-12-18 EP EP02805025A patent/EP1457505B1/en not_active Expired - Lifetime
- 2002-12-18 AU AU2002357600A patent/AU2002357600A1/en not_active Abandoned
- 2002-12-18 DE DE60226342T patent/DE60226342T2/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US20040214972A1 (en) | 2004-10-28 |
| EP1457505A4 (en) | 2006-12-06 |
| EP1457505A1 (en) | 2004-09-15 |
| DE60226342D1 (de) | 2008-06-12 |
| US7009017B2 (en) | 2006-03-07 |
| JP2003246823A (ja) | 2003-09-05 |
| WO2003051944A1 (en) | 2003-06-26 |
| EP1457505B1 (en) | 2008-04-30 |
| AU2002357600A1 (en) | 2003-06-30 |
| JP3888232B2 (ja) | 2007-02-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE60226342T2 (de) | Fluoriertes terpolymer | |
| DE69819458T2 (de) | Fluorierte thermoplastische Elastomere | |
| DE60314125T2 (de) | Vinylether modifiziertes sinterbares polytetrafluorethylen | |
| DE60320285T2 (de) | Peroxidhärtbare fluorelastomere | |
| DE69602607T2 (de) | Copolymer aus tetrafluorethylen | |
| DE68927130T2 (de) | Verfahren zur Herstellung einer wässerigen Dispersion, wässerige Dispersion und Zusammensetzung von wässerigen Überzügen | |
| JP5086812B2 (ja) | フッ化ビニルインターポリマー | |
| DE2822116A1 (de) | Terpolymeres von tetrafluoraethylen und aethylen sowie verfahrensherstellung desselben | |
| DD262433A5 (de) | Verfahren zur polymerisation und copolymerisation fluorhaltiger monomerer in waessriger dispersion | |
| DE69604782T2 (de) | Copolymerisationsverfahren für fluormonomere und funktionalisierte kohlenwasserstoffmonomere und danach hergestelltes copolymer | |
| DE69610813T2 (de) | Tetrafluorethylen-Terpolymer | |
| DE2021069A1 (de) | AEthylen-Monochlortrifluoraethylen-Mischpolymerisat | |
| DD259629A5 (de) | Verfahren zur polymerisation und copolymerisation fluorierter monomerer | |
| EP0043499A1 (de) | Verfahren zur Herstellung von wässrigen, kolloidalen Dispersionen von Copolymerisaten des Typs Tetrafluorethylen-Ethylen | |
| DE2052495A1 (de) | Verfahren zum Mischpolymensieren von monomerem Tetrafluorethylen und monomerem Fluorvinylather | |
| DE2706783A1 (de) | Verfahren zur herstellung von tetrafluoraethylen/hexafluorpropylen-copolymeren | |
| CA1248287A (en) | Melt-processible tetrafluoroethylene copolymers and process for preparing them | |
| DE1645010C3 (de) | Verfahren zur Copolymerisation von Vinylidenfluorid mit cis-1-H-Pentafluorpropen oder Hexafluorpropen | |
| US20020028895A1 (en) | Process for manufacture of a copolymer of tetrafluoroethylene and perfluoro (alkyl vinyl ether) | |
| DE3486415T2 (de) | Polymer enthaltendes dielektrisches Material. | |
| DE1795078A1 (de) | Pastenextrudierbare Tetrafluoraethylen-Dispersionspolymerisate | |
| EP1165632B2 (de) | Tetrafluor ethylen / hexafluor propylen copolymere mit besserer ausziehbarkeit | |
| DE69601335T2 (de) | Tetrafluorethylen-Terpolymer | |
| DE60114959T2 (de) | Verfahren zur Herstellung von Polyvinylester-Harzzusammensetzungen | |
| DE69501296T2 (de) | Verfahren zur Herstellung von wasserstoff-enthaltenden Fluorpolymeren durch Suspensions(co)polymerisation |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition |