DE60222919T2 - Eine anisotrope schmelze bildende polymere mit hoher streckbarkeit - Google Patents
Eine anisotrope schmelze bildende polymere mit hoher streckbarkeit Download PDFInfo
- Publication number
- DE60222919T2 DE60222919T2 DE2002622919 DE60222919T DE60222919T2 DE 60222919 T2 DE60222919 T2 DE 60222919T2 DE 2002622919 DE2002622919 DE 2002622919 DE 60222919 T DE60222919 T DE 60222919T DE 60222919 T2 DE60222919 T2 DE 60222919T2
- Authority
- DE
- Germany
- Prior art keywords
- polymer
- repeating unit
- amount
- mol
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000642 polymer Polymers 0.000 title claims description 151
- 238000002844 melting Methods 0.000 title description 8
- 230000008018 melting Effects 0.000 title description 8
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical group OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 41
- 239000000835 fiber Substances 0.000 claims description 20
- 239000010410 layer Substances 0.000 claims description 14
- 238000006467 substitution reaction Methods 0.000 claims description 8
- 229920000098 polyolefin Polymers 0.000 claims description 7
- 229920001169 thermoplastic Polymers 0.000 claims description 5
- 229920005992 thermoplastic resin Polymers 0.000 claims description 5
- 229920001283 Polyalkylene terephthalate Polymers 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 4
- 239000012790 adhesive layer Substances 0.000 claims description 3
- 230000004888 barrier function Effects 0.000 claims description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 52
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 37
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 34
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 28
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 26
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 23
- 125000003118 aryl group Chemical group 0.000 description 21
- -1 aromatic diol Chemical class 0.000 description 18
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 16
- KAUQJMHLAFIZDU-UHFFFAOYSA-N 6-Hydroxy-2-naphthoic acid Chemical compound C1=C(O)C=CC2=CC(C(=O)O)=CC=C21 KAUQJMHLAFIZDU-UHFFFAOYSA-N 0.000 description 14
- 229920000106 Liquid crystal polymer Polymers 0.000 description 13
- 238000006640 acetylation reaction Methods 0.000 description 12
- 238000006116 polymerization reaction Methods 0.000 description 12
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical compound C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 11
- 239000000155 melt Substances 0.000 description 11
- 230000021736 acetylation Effects 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 239000000463 material Substances 0.000 description 9
- 239000000376 reactant Substances 0.000 description 9
- 238000010992 reflux Methods 0.000 description 9
- 239000012808 vapor phase Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000006068 polycondensation reaction Methods 0.000 description 7
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 6
- 239000006227 byproduct Substances 0.000 description 5
- 239000002243 precursor Substances 0.000 description 5
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000004952 Polyamide Substances 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 239000011888 foil Substances 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 229920002647 polyamide Polymers 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 4
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 235000011056 potassium acetate Nutrition 0.000 description 3
- 229920001897 terpolymer Polymers 0.000 description 3
- DNUYOWCKBJFOGS-UHFFFAOYSA-N 2-[[10-(2,2-dicarboxyethyl)anthracen-9-yl]methyl]propanedioic acid Chemical compound C1=CC=C2C(CC(C(=O)O)C(O)=O)=C(C=CC=C3)C3=C(CC(C(O)=O)C(O)=O)C2=C1 DNUYOWCKBJFOGS-UHFFFAOYSA-N 0.000 description 2
- AULKDLUOQCUNOK-UHFFFAOYSA-N 3,5-dichloro-4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC(Cl)=C(O)C(Cl)=C1 AULKDLUOQCUNOK-UHFFFAOYSA-N 0.000 description 2
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 2
- QGNLHMKIGMZKJX-UHFFFAOYSA-N 3-chloro-4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C(Cl)=C1 QGNLHMKIGMZKJX-UHFFFAOYSA-N 0.000 description 2
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 2
- OMNHTTWQSSUZHO-UHFFFAOYSA-N 4-hydroxy-3,5-dimethylbenzoic acid Chemical compound CC1=CC(C(O)=O)=CC(C)=C1O OMNHTTWQSSUZHO-UHFFFAOYSA-N 0.000 description 2
- LTFHNKUKQYVHDX-UHFFFAOYSA-N 4-hydroxy-3-methylbenzoic acid Chemical compound CC1=CC(C(O)=O)=CC=C1O LTFHNKUKQYVHDX-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000000113 differential scanning calorimetry Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 229920006225 ethylene-methyl acrylate Polymers 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- IJFXRHURBJZNAO-UHFFFAOYSA-N meta--hydroxybenzoic acid Natural products OC(=O)C1=CC=CC(O)=C1 IJFXRHURBJZNAO-UHFFFAOYSA-N 0.000 description 2
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000012744 reinforcing agent Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- JMSVCTWVEWCHDZ-UHFFFAOYSA-N syringic acid Chemical compound COC1=CC(C(O)=O)=CC(OC)=C1O JMSVCTWVEWCHDZ-UHFFFAOYSA-N 0.000 description 2
- BYEAHWXPCBROCE-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropan-2-ol Chemical compound FC(F)(F)C(O)C(F)(F)F BYEAHWXPCBROCE-UHFFFAOYSA-N 0.000 description 1
- XBNGYFFABRKICK-UHFFFAOYSA-N 2,3,4,5,6-pentafluorophenol Chemical compound OC1=C(F)C(F)=C(F)C(F)=C1F XBNGYFFABRKICK-UHFFFAOYSA-N 0.000 description 1
- AUFZRCJENRSRLY-UHFFFAOYSA-N 2,3,5-trimethylhydroquinone Chemical compound CC1=CC(O)=C(C)C(C)=C1O AUFZRCJENRSRLY-UHFFFAOYSA-N 0.000 description 1
- CZAZXHQSSWRBHT-UHFFFAOYSA-N 2-(2-hydroxyphenyl)-3,4,5,6-tetramethylphenol Chemical compound OC1=C(C)C(C)=C(C)C(C)=C1C1=CC=CC=C1O CZAZXHQSSWRBHT-UHFFFAOYSA-N 0.000 description 1
- QLZJUIZVJLSNDD-UHFFFAOYSA-N 2-(2-methylidenebutanoyloxy)ethyl 2-methylidenebutanoate Chemical class CCC(=C)C(=O)OCCOC(=O)C(=C)CC QLZJUIZVJLSNDD-UHFFFAOYSA-N 0.000 description 1
- ZPXGNBIFHQKREO-UHFFFAOYSA-N 2-chloroterephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(Cl)=C1 ZPXGNBIFHQKREO-UHFFFAOYSA-N 0.000 description 1
- XCZKKZXWDBOGPA-UHFFFAOYSA-N 2-phenylbenzene-1,4-diol Chemical compound OC1=CC=C(O)C(C=2C=CC=CC=2)=C1 XCZKKZXWDBOGPA-UHFFFAOYSA-N 0.000 description 1
- 229940018563 3-aminophenol Drugs 0.000 description 1
- NEQFBGHQPUXOFH-UHFFFAOYSA-N 4-(4-carboxyphenyl)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C1=CC=C(C(O)=O)C=C1 NEQFBGHQPUXOFH-UHFFFAOYSA-N 0.000 description 1
- LPADJMFUBXMZNL-UHFFFAOYSA-N 4-hydroxy-3-phenylbenzoic acid Chemical compound OC(=O)C1=CC=C(O)C(C=2C=CC=CC=2)=C1 LPADJMFUBXMZNL-UHFFFAOYSA-N 0.000 description 1
- VARPGHCVZGMTLL-UHFFFAOYSA-N 5,7-dichloro-6-hydroxynaphthalene-2-carboxylic acid Chemical compound ClC1=C(O)C(Cl)=CC2=CC(C(=O)O)=CC=C21 VARPGHCVZGMTLL-UHFFFAOYSA-N 0.000 description 1
- MIBYFOLNIIUGNA-UHFFFAOYSA-N 5-chloro-6-hydroxynaphthalene-2-carboxylic acid Chemical compound ClC1=C(O)C=CC2=CC(C(=O)O)=CC=C21 MIBYFOLNIIUGNA-UHFFFAOYSA-N 0.000 description 1
- PLPFTLXIQQYOMW-UHFFFAOYSA-N 5-chlorobenzene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=CC(Cl)=CC(C(O)=O)=C1 PLPFTLXIQQYOMW-UHFFFAOYSA-N 0.000 description 1
- PMZBHPUNQNKBOA-UHFFFAOYSA-N 5-methylbenzene-1,3-dicarboxylic acid Chemical compound CC1=CC(C(O)=O)=CC(C(O)=O)=C1 PMZBHPUNQNKBOA-UHFFFAOYSA-N 0.000 description 1
- JJUJLQXTYRRNJE-UHFFFAOYSA-N 5-phenylbenzene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C=2C=CC=CC=2)=C1 JJUJLQXTYRRNJE-UHFFFAOYSA-N 0.000 description 1
- VYRKAEUYLYEKFY-UHFFFAOYSA-N 5-sulfonylcyclohexa-1,3-diene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(=S(=O)=O)C1 VYRKAEUYLYEKFY-UHFFFAOYSA-N 0.000 description 1
- RHXQHKDRWDVLBY-UHFFFAOYSA-N 6-hydroxy-5-methoxynaphthalene-2-carboxylic acid Chemical compound OC(=O)C1=CC=C2C(OC)=C(O)C=CC2=C1 RHXQHKDRWDVLBY-UHFFFAOYSA-N 0.000 description 1
- XKFNZRZICQABOD-UHFFFAOYSA-N 6-hydroxy-5-methylnaphthalene-2-carboxylic acid Chemical compound OC(=O)C1=CC=C2C(C)=C(O)C=CC2=C1 XKFNZRZICQABOD-UHFFFAOYSA-N 0.000 description 1
- RAAPMEWYFAUSOB-UHFFFAOYSA-N 6-hydroxy-5-phenylnaphthalene-2-carboxylic acid Chemical compound OC=1C=CC2=CC(C(=O)O)=CC=C2C=1C1=CC=CC=C1 RAAPMEWYFAUSOB-UHFFFAOYSA-N 0.000 description 1
- JHXIMYHYJSQGGB-UHFFFAOYSA-N 7-chloro-6-hydroxynaphthalene-2-carboxylic acid Chemical compound C1=C(O)C(Cl)=CC2=CC(C(=O)O)=CC=C21 JHXIMYHYJSQGGB-UHFFFAOYSA-N 0.000 description 1
- LQQKHWUVRBYGOY-UHFFFAOYSA-N C[NH+](c(cc1)ccc1OC)[O-] Chemical compound C[NH+](c(cc1)ccc1OC)[O-] LQQKHWUVRBYGOY-UHFFFAOYSA-N 0.000 description 1
- DLCKABUEKRLQAJ-UHFFFAOYSA-N C[NH+](c1cc([NH+](C)[O-])ccc1)[O-] Chemical compound C[NH+](c1cc([NH+](C)[O-])ccc1)[O-] DLCKABUEKRLQAJ-UHFFFAOYSA-N 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229960004050 aminobenzoic acid Drugs 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 230000027455 binding Effects 0.000 description 1
- 238000009739 binding Methods 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- AJPXTSMULZANCB-UHFFFAOYSA-N chlorohydroquinone Chemical compound OC1=CC=C(O)C(Cl)=C1 AJPXTSMULZANCB-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000009820 dry lamination Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 1
- 238000010101 extrusion blow moulding Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N hydroquinone methyl ether Natural products COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000010103 injection stretch blow moulding Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 1
- 239000011654 magnesium acetate Substances 0.000 description 1
- 229940069446 magnesium acetate Drugs 0.000 description 1
- 235000011285 magnesium acetate Nutrition 0.000 description 1
- 229920001911 maleic anhydride grafted polypropylene Polymers 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachloro-phenol Natural products OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- WKOLLVMJNQIZCI-UHFFFAOYSA-N vanillic acid Chemical compound COC1=CC(C(O)=O)=CC=C1O WKOLLVMJNQIZCI-UHFFFAOYSA-N 0.000 description 1
- TUUBOHWZSQXCSW-UHFFFAOYSA-N vanillic acid Natural products COC1=CC(O)=CC(C(O)=O)=C1 TUUBOHWZSQXCSW-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/60—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds
- C08G63/605—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds the hydroxy and carboxylic groups being bound to aromatic rings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
- Y10T428/31797—Next to addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US933645 | 2001-08-21 | ||
| US09/933,645 US6514611B1 (en) | 2001-08-21 | 2001-08-21 | Anisotropic melt-forming polymers having a high degree of stretchability |
| PCT/US2002/024970 WO2003018664A1 (en) | 2001-08-21 | 2002-08-07 | Anisotropic melt-forming polymers having a high degree of stretchability |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60222919D1 DE60222919D1 (de) | 2007-11-22 |
| DE60222919T2 true DE60222919T2 (de) | 2008-07-17 |
Family
ID=25464289
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2002622919 Expired - Lifetime DE60222919T2 (de) | 2001-08-21 | 2002-08-07 | Eine anisotrope schmelze bildende polymere mit hoher streckbarkeit |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6514611B1 (enExample) |
| EP (1) | EP1436340B1 (enExample) |
| JP (1) | JP4102300B2 (enExample) |
| CN (1) | CN1293117C (enExample) |
| DE (1) | DE60222919T2 (enExample) |
| TW (1) | TWI243832B (enExample) |
| WO (1) | WO2003018664A1 (enExample) |
Families Citing this family (76)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003021275A (ja) * | 2001-07-06 | 2003-01-24 | Toyoda Gosei Co Ltd | 樹脂パイプおよびその製造方法 |
| AU2003277557A1 (en) * | 2002-12-27 | 2004-07-29 | Polyplastics Co., Ltd. | Amorphous, wholly aromatic polyesteramide composition |
| JP4498810B2 (ja) * | 2004-04-16 | 2010-07-07 | ポリプラスチックス株式会社 | 液晶樹脂組成物 |
| JP2005306991A (ja) * | 2004-04-21 | 2005-11-04 | Polyplastics Co | ブロー成形用樹脂組成物及びブロー成形法 |
| JP2011093971A (ja) * | 2009-10-28 | 2011-05-12 | Sumitomo Chemical Co Ltd | 液晶樹脂の製造方法 |
| CN103764741B (zh) | 2011-08-29 | 2015-09-23 | 提克纳有限责任公司 | 低熔体粘度液晶聚合物的熔融聚合 |
| TWI554594B (zh) | 2011-08-29 | 2016-10-21 | 堤康那責任有限公司 | 高流量液晶聚合物組合物 |
| US20130053531A1 (en) | 2011-08-29 | 2013-02-28 | Ticona Llc | Method for Minimizing Process Disruptions During Formation of a Liquid Crystalline Polymer |
| US9045685B2 (en) | 2011-08-29 | 2015-06-02 | Ticona Llc | Cast molded parts formed from a liquid crystalline polymer |
| TW201319023A (zh) | 2011-08-29 | 2013-05-16 | Ticona Llc | 具改良低剪切黏度之熱向性液晶聚合物 |
| WO2013032970A1 (en) | 2011-08-29 | 2013-03-07 | Ticona Llc | Liquid crystalline polymer composition containing a fibrous filler |
| JP2014525499A (ja) | 2011-08-29 | 2014-09-29 | ティコナ・エルエルシー | 低い融解温度をもつ耐熱性液晶ポリマー組成物 |
| TW201319223A (zh) | 2011-08-29 | 2013-05-16 | Ticona Llc | 高流量液晶聚合物組合物 |
| TW201313884A (zh) | 2011-08-29 | 2013-04-01 | Ticona Llc | 液晶聚合物之固態聚合 |
| KR20140057629A (ko) | 2011-08-29 | 2014-05-13 | 티코나 엘엘씨 | 방향족 아마이드 화합물 |
| WO2013032971A1 (en) | 2011-08-29 | 2013-03-07 | Ticona Llc | Melt-extruded substrate for use in thermoformed articles |
| KR102087451B1 (ko) | 2011-09-30 | 2020-03-10 | 티코나 엘엘씨 | 액정 중합체를 위한 고상 중합 시스템 |
| WO2013051346A1 (ja) * | 2011-10-05 | 2013-04-11 | ポリプラスチックス株式会社 | 全芳香族ポリエステル、ポリエステル樹脂組成物、及びポリエステル成形品 |
| US9074070B2 (en) | 2011-10-31 | 2015-07-07 | Ticona Llc | Thermoplastic composition for use in forming a laser direct structured substrate |
| US8932483B2 (en) | 2011-11-15 | 2015-01-13 | Ticona Llc | Low naphthenic liquid crystalline polymer composition |
| KR101947215B1 (ko) | 2011-11-15 | 2019-02-12 | 티코나 엘엘씨 | 미세 피치 전기 커넥터 및 그에 사용하기 위한 열가소성 조성물 |
| WO2013074472A1 (en) | 2011-11-15 | 2013-05-23 | Ticona Llc | Method of forming a liquid crystalline thermoplastic composition |
| US20130123420A1 (en) | 2011-11-15 | 2013-05-16 | Ticona Llc | Liquid Crystalline Polymer Composition for High Voltage Electronic Components |
| WO2013074467A1 (en) | 2011-11-15 | 2013-05-23 | Ticona Llc | Low naphthenic liquid crystalline polymer composition for use in molded parts of a small dimensional tolerance |
| CN103930464B (zh) | 2011-11-15 | 2016-02-10 | 提克纳有限责任公司 | 紧凑型相机模块 |
| WO2013074477A1 (en) | 2011-11-15 | 2013-05-23 | Ticona Llc | Naphthenic-rich liquid crystalline polymer composition with improved flammability performance |
| US20140004328A1 (en) | 2012-06-27 | 2014-01-02 | Ticona Llc | Ultralow Viscosity Liquid Crystalline Polymer Composition |
| JP5753143B2 (ja) * | 2012-09-21 | 2015-07-22 | ポリプラスチックス株式会社 | 全芳香族ポリエステル及びポリエステル樹脂組成物、並びにポリエステル成形品 |
| US8822628B2 (en) | 2012-09-24 | 2014-09-02 | Ticona Llc | Crosslinkable liquid crystalline polymer |
| WO2014047015A1 (en) | 2012-09-24 | 2014-03-27 | Ticona Llc | Crosslinkable aromatic polyester |
| US8853342B2 (en) | 2012-09-24 | 2014-10-07 | Ticona Llc | Crosslinkable liquid crystalline polymer |
| WO2014052052A1 (en) | 2012-09-27 | 2014-04-03 | Ticona Llc | Thermotropic liquid crystalline powder |
| US20140087149A1 (en) | 2012-09-27 | 2014-03-27 | Ticona Llc | Soluble aromatic polymer |
| US9145469B2 (en) | 2012-09-27 | 2015-09-29 | Ticona Llc | Aromatic polyester containing a biphenyl chain disruptor |
| US20140099458A1 (en) | 2012-10-05 | 2014-04-10 | Ticona Llc | Liquid Crystalline Composition with a Metallic Appearance |
| US9284435B2 (en) | 2012-10-16 | 2016-03-15 | Ticona Llc | Antistatic liquid crystalline polymer composition |
| WO2014070875A1 (en) | 2012-11-01 | 2014-05-08 | Ticona Llc | Multi-layered co-injection molded article |
| WO2014074228A1 (en) | 2012-11-09 | 2014-05-15 | Ticona Llc | Liquid crystalline polymer composition for melt-extruded sheets |
| WO2014074227A1 (en) | 2012-11-09 | 2014-05-15 | Ticona Llc | Liquid crystalline polymer composition for films |
| WO2014081650A1 (en) | 2012-11-21 | 2014-05-30 | Ticona Llc | Liquid crystalline polymer composition for melt-extruded substrates |
| WO2014088700A1 (en) | 2012-12-05 | 2014-06-12 | Ticona Llc | Conductive liquid crystalline polymer composition |
| EP2935515B1 (en) | 2012-12-19 | 2020-04-15 | Ticona LLC | Liquid crystalline composition having a dark black color |
| US20140178705A1 (en) | 2012-12-20 | 2014-06-26 | Ticona Llc | Aromatic Polyester Coatings and Laminates |
| CN111732821A (zh) | 2013-03-13 | 2020-10-02 | 提克纳有限责任公司 | 抗静电液晶聚合物组合物 |
| US9206300B2 (en) | 2013-06-07 | 2015-12-08 | Ticona Llc | High strength thermotropic liquid crystalline polymer |
| EP3029395B1 (en) * | 2013-07-29 | 2024-11-27 | Mitsubishi Electric Corporation | Heat pump device |
| US20150104165A1 (en) | 2013-10-16 | 2015-04-16 | Ticona Llc | Polymer Composition for Use in a Compact Camera Module |
| US20150111794A1 (en) | 2013-10-21 | 2015-04-23 | Ticona Gmbh | Two Component Polyoxymethylene Based Systems |
| WO2015059598A1 (en) | 2013-10-21 | 2015-04-30 | Ticona Gmbh | Intrinsic low friction polyoxymethylene |
| WO2015094486A1 (en) | 2013-12-19 | 2015-06-25 | Ticona Llc | Liquid crystalline composition having a pearly luster |
| US20150175805A1 (en) | 2013-12-19 | 2015-06-25 | Ticona Llc | Polyarylene Sulfide Composition for Use in Forming a Laser Direct Structured Substrate |
| WO2015095035A1 (en) | 2013-12-20 | 2015-06-25 | Ticona Llc | Metal detectable liquid crystalline polymer composition |
| CN106164172B (zh) | 2014-04-09 | 2019-07-26 | 提克纳有限责任公司 | 摄像模组 |
| KR102305241B1 (ko) | 2014-04-09 | 2021-09-24 | 티코나 엘엘씨 | 대전방지 중합체 조성물 |
| WO2016003588A1 (en) | 2014-07-01 | 2016-01-07 | Ticona Llc | Laser activatable polymer composition |
| WO2016028614A1 (en) | 2014-08-21 | 2016-02-25 | Ticona Llc | Composition containing a polyaryletherketone and low naphthenic liquid crystalline polymer |
| WO2016028613A1 (en) | 2014-08-21 | 2016-02-25 | Ticona Llc | Polyaryletherketone composition |
| US10196577B2 (en) | 2015-09-30 | 2019-02-05 | Celanese Sales Germany Gmbh | Low friction squeak free assembly |
| CN105837805A (zh) * | 2016-02-01 | 2016-08-10 | 金发科技股份有限公司 | 一种液晶聚酯以及由其组成的模塑组合物和其应用 |
| US11352480B2 (en) | 2016-03-18 | 2022-06-07 | Ticona Llc | Polyaryletherketone composition |
| WO2018139393A1 (ja) * | 2017-01-26 | 2018-08-02 | ポリプラスチックス株式会社 | 全芳香族ポリエステル及びポリエステル樹脂組成物 |
| US10633535B2 (en) | 2017-02-06 | 2020-04-28 | Ticona Llc | Polyester polymer compositions |
| WO2018163098A1 (en) | 2017-03-10 | 2018-09-13 | Celanese Sales Germany Gmbh | Polyester polymer compositions |
| KR102627886B1 (ko) | 2017-12-05 | 2024-01-19 | 티코나 엘엘씨 | 카메라 모듈에 사용하기 위한 방향족 중합체 조성물 |
| US11384238B2 (en) | 2018-02-08 | 2022-07-12 | Celanese Sales Germany Gmbh | Polymer composite containing recycled carbon fibers |
| CN109651607B (zh) * | 2018-12-03 | 2021-05-14 | 成都博斐特新材料有限公司 | 一种树脂聚合物材料及其制备方法和应用 |
| CN112175174B (zh) | 2019-07-02 | 2023-03-28 | 财团法人工业技术研究院 | 液晶聚合物、积层材料、液晶聚合物溶液与液晶聚合物薄膜的形成方法 |
| EP3998952B1 (en) | 2019-07-17 | 2024-10-09 | Ticona LLC | Ultrasonic probe |
| US12209164B2 (en) | 2019-09-10 | 2025-01-28 | Ticona Llc | Polymer composition and film for use in 5G applications |
| US12142820B2 (en) | 2019-09-10 | 2024-11-12 | Ticona Llc | 5G system containing a polymer composition |
| US11917753B2 (en) | 2019-09-23 | 2024-02-27 | Ticona Llc | Circuit board for use at 5G frequencies |
| US11646760B2 (en) | 2019-09-23 | 2023-05-09 | Ticona Llc | RF filter for use at 5G frequencies |
| CN115151403A (zh) | 2019-12-17 | 2022-10-04 | 提克纳有限责任公司 | 采用热致液晶聚合物的三维打印系统 |
| CN115734798A (zh) | 2020-04-28 | 2023-03-03 | 提克纳有限责任公司 | 微针组件 |
| US12428543B2 (en) | 2021-05-18 | 2025-09-30 | Ticona Llc | Connected medical device containing a liquid crystalline polymer composition having a low dielectric constant |
| CN118613966A (zh) | 2021-12-01 | 2024-09-06 | 提克纳有限责任公司 | 天线模块 |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4351918A (en) | 1981-04-06 | 1982-09-28 | Celanese Corporation | Poly(ester-amide) capable of forming an anisotropic melt phase derived from 6-hydroxy-2-naphthoic acid, other aromatic hydroxyacid, carbocyclic dicarboxylic acid, and aromatic monomer capable of forming an amide linkage |
| US4370466A (en) | 1981-09-28 | 1983-01-25 | E. I. Du Pont De Nemours And Company | Optically anisotropic melt forming polyesters |
| US4522974A (en) | 1982-07-26 | 1985-06-11 | Celanese Corporation | Melt processable polyester capable of forming an anisotropic melt comprising a relatively low concentration of 6-oxy-2-naphthoyl moiety-4-benzoyl moiety, 1,4-dioxyphenylene moiety, isophthaloyl moiety and terephthaloyl moiety |
| JPS5943021A (ja) | 1982-09-02 | 1984-03-09 | Ueno Seiyaku Oyo Kenkyusho:Kk | 芳香族（コ）ポリエステルの製法 |
| JP2664406B2 (ja) | 1988-04-13 | 1997-10-15 | ポリプラスチックス 株式会社 | 溶融時に光学的異方性を示すポリエステル樹脂及び樹脂組成物 |
| US4563508A (en) | 1984-05-18 | 1986-01-07 | Dart Industries, Inc. | Injection moldable aromatic polyesters compositions and method of preparation |
| DE3542856A1 (de) | 1985-12-04 | 1987-06-11 | Basf Ag | Vollaromatische mesomorphe polyesteramide, deren herstellung und verwendung |
| US4664972A (en) * | 1986-04-23 | 1987-05-12 | E. I. Du Pont De Nemours And Company | Optically anisotropic melt forming aromatic copolyesters based on t-butylhydroquinone |
| DE3736991A1 (de) | 1987-10-31 | 1989-05-11 | Bayer Ag | Thermotrope aromatische polyester mit hoher waermeformbestaendigkeit, verfahren zu ihrer herstellung und ihre verwendung zur herstellung von formkoerpern, filamenten, fasern und folien |
| JP2664404B2 (ja) | 1988-04-13 | 1997-10-15 | ポリプラスチックス 株式会社 | 溶融時に光学的異方性を示すポリエステル樹脂及び樹脂組成物 |
| JP2664405B2 (ja) | 1988-04-13 | 1997-10-15 | ポリプラスチックス 株式会社 | 溶融時に光学的異方性を示すポリエステル樹脂及び樹脂組成物 |
| JPH0216120A (ja) | 1988-07-05 | 1990-01-19 | Polyplastics Co | 溶融時に光学的異方性を示すポリエステル樹脂及び樹脂組成物 |
| ES2010297A6 (es) | 1988-07-27 | 1989-11-01 | Cables Comunicaciones | Un procedimiento para la preparacion de nuevas copoliesteramidas termotropas aromaticas. |
| US5025082A (en) | 1988-08-24 | 1991-06-18 | Mitsubishi Kasei Corporation | Aromatic polyester, aromatic polyester-amide and processes for producing the same |
| US5089594A (en) | 1988-10-11 | 1992-02-18 | Amoco Corporation | Wholly aromatic polyester of isophthalic acid, terephthalic acid, p-hydroxybenzoic acid, hydroquinone and an arylene diol |
| US5066767A (en) | 1989-03-01 | 1991-11-19 | Amoco Corporation | Wholly aromatic polyesters comprising isophthalic acid, terephthalic acid, p-hydroxybenzoic acid, hydroquinone and an arylene diol |
| DE3923294A1 (de) | 1989-07-14 | 1991-01-24 | Bayer Ag | Hochwaermeformbestaendige thermotrope polyester mit guter schlagzaehigkeit, verfahren zu ihrer herstellung sowie ihrer verwendung zur herstellung von formkoerpern, filamenten und folien |
| EP0503063B1 (en) * | 1990-09-28 | 1999-06-02 | Daicel Chemical Industries, Ltd. | Composite film |
| JP3099455B2 (ja) | 1990-10-08 | 2000-10-16 | 住友化学工業株式会社 | 芳香族ポリエステルおよびその製造方法 |
| US5204443A (en) | 1991-04-19 | 1993-04-20 | Hoechst Celanese Corp. | Melt processable poly(ester-amide) capable of forming an anisotropic melt containing an aromatic moiety capable of forming an amide linkage |
| WO1994029365A1 (en) | 1993-06-15 | 1994-12-22 | Nippon Petrochemicals Company, Limited | Wholly aromatic polyester, composition thereof, and molded article made therefrom |
| US5656714A (en) | 1995-06-02 | 1997-08-12 | Hoechst Celanese Corp. | Polyester from terephthalic acid, 6-hydroxy-2-naphthoic acid, 4-hydroxybenzoic acid, 4,4'-biphenol and resorcinol |
| US6022491A (en) * | 1996-01-05 | 2000-02-08 | E. I. Du Pont De Nemours And Company | Liquid crystalline polymer composition |
| US5798432A (en) | 1996-03-22 | 1998-08-25 | Hoechst Celanese Corp. | Method of making thermotropic liquid crystalline polymers containing hydroquinone |
| US6093787A (en) * | 1997-06-06 | 2000-07-25 | Eastman Chemical Company | Liquid crystalline polyesters and molding compositions prepared therefrom |
| US6268026B1 (en) * | 1997-10-20 | 2001-07-31 | Hoechst Celanese Corporation | Multilayer laminate formed from a substantially stretched non-molten wholly aromatic liquid crystalline polymer and non-liquid crystalline polyester and method for forming same |
| US6312772B1 (en) | 1997-10-20 | 2001-11-06 | Hoechst Celanese Corporation | Multilayer laminate formed from a substantially stretched non-molten wholly aromatic liquid crystalline polymer and non-polyester thermoplastic polymer |
| US6426128B1 (en) | 1998-01-06 | 2002-07-30 | Hna Holdings, Inc. | Co-processable multi-layer laminates for forming high strength, haze-free, transparent articles and methods of producing same |
| FI991006L (fi) | 1999-05-03 | 2000-11-04 | Optatech Oy | Uudet nestekiteiset polymeerit |
| US6132884A (en) | 2000-01-14 | 2000-10-17 | Ticona Llc | Process for producing amorphous anisotrophic melt-forming polymers having a high degree of stretchability and polymers produced by same |
| US6207790B1 (en) | 2000-01-14 | 2001-03-27 | Ticona Llc | Process for producing amorphous anisotropic melt-forming polymers having a high degree of stretchability and polymers produced by same |
| US6222000B1 (en) | 2000-01-14 | 2001-04-24 | Ticona Llc | Process for producing amorphous anisotropic melt-forming polymers having a high degree of stretchability |
-
2001
- 2001-08-21 US US09/933,645 patent/US6514611B1/en not_active Expired - Lifetime
-
2002
- 2002-07-30 TW TW91117027A patent/TWI243832B/zh not_active IP Right Cessation
- 2002-08-07 JP JP2003523521A patent/JP4102300B2/ja not_active Expired - Fee Related
- 2002-08-07 WO PCT/US2002/024970 patent/WO2003018664A1/en not_active Ceased
- 2002-08-07 DE DE2002622919 patent/DE60222919T2/de not_active Expired - Lifetime
- 2002-08-07 EP EP02768441A patent/EP1436340B1/en not_active Expired - Lifetime
- 2002-08-07 CN CNB028163168A patent/CN1293117C/zh not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP1436340B1 (en) | 2007-10-10 |
| DE60222919D1 (de) | 2007-11-22 |
| CN1556823A (zh) | 2004-12-22 |
| US6514611B1 (en) | 2003-02-04 |
| JP2005501150A (ja) | 2005-01-13 |
| CN1293117C (zh) | 2007-01-03 |
| EP1436340A1 (en) | 2004-07-14 |
| JP4102300B2 (ja) | 2008-06-18 |
| WO2003018664A1 (en) | 2003-03-06 |
| TWI243832B (en) | 2005-11-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE60222919T2 (de) | Eine anisotrope schmelze bildende polymere mit hoher streckbarkeit | |
| DE60020206T2 (de) | Zusammensetzung und Verfahren zur Herstellung von dehnbaren Polymeren und dadurch geformte Gegenstände | |
| DE69215749T2 (de) | In der Schmelze verarbeitbares Polyester-Amid das eine anisotrope Schmelze bilden kann | |
| DE60026835T2 (de) | Flüssigkristalline polymere | |
| DE69317768T2 (de) | Vollaromatische flüssigkristalline polymere, die ionische monomereinheiten enthalten und verbundstoffe daraus | |
| DE69409113T2 (de) | Flüssigkristalline polymerzusammensetzungen | |
| DE3014925A1 (de) | Aus der schmelze verarbeitbare, vollaromatische polyester und ihre verwendung | |
| DE60017068T2 (de) | Verfahren zur Herstellung von amorphen anisotrope Schmelzen bildenden Polymeren mit hoher Dehnbarkeit und nach diesem Verfahren hergestellte Polymere | |
| DE3542814A1 (de) | Vollaromatische mesomorphe polyester, deren herstellung sowie verwendung | |
| DE68904709T2 (de) | Verfahren zur herstellung aromatischer thermotroper copolyesteramide sowie entsprechende copolyesteramide. | |
| EP1390423B1 (en) | Stretchable liquid crystal polymer composition | |
| DE60017069T2 (de) | Verfahren zur Herstellung von amorphen anisotrope Schmelzen bildendenden Polymeren mit hoher Dehnbarkeit und nach diesem Verfahren hergestellte Polymere | |
| US6222000B1 (en) | Process for producing amorphous anisotropic melt-forming polymers having a high degree of stretchability | |
| DE68927929T2 (de) | Wärmebeständige polymere und mischung von hydroquinonpoly(isoterephthalaten), enthaltend reste von p-hydroxybenzoesäure | |
| EP0232777B1 (de) | Verfahren zur Herstellung von Teilen aus thermotropen flüssigkristallinen Kunststoffen mit definierter Orientierung der LC-Polymer-Moleküle sowie die so hergestellten Teile | |
| DE69129050T2 (de) | Thermotrope flüssigkristalline Polyester | |
| DE3542832A1 (de) | Vollaromatische fluessigkristalline polykondensate, deren herstellung und verwendung |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| R082 | Change of representative |
Ref document number: 1436340 Country of ref document: EP Representative=s name: ZIMMERMANN & PARTNER, DE |