DE602004008217T2 - Einfach dispergierbare konzentrierte Esterquat Zusammensetzungen - Google Patents
Einfach dispergierbare konzentrierte Esterquat Zusammensetzungen Download PDFInfo
- Publication number
- DE602004008217T2 DE602004008217T2 DE602004008217T DE602004008217T DE602004008217T2 DE 602004008217 T2 DE602004008217 T2 DE 602004008217T2 DE 602004008217 T DE602004008217 T DE 602004008217T DE 602004008217 T DE602004008217 T DE 602004008217T DE 602004008217 T2 DE602004008217 T2 DE 602004008217T2
- Authority
- DE
- Germany
- Prior art keywords
- esterquat
- concentrated
- composition according
- weight
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims description 89
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 11
- 239000003960 organic solvent Substances 0.000 claims description 11
- 239000003002 pH adjusting agent Substances 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 9
- -1 ester quat compound Chemical class 0.000 claims description 8
- PUAQLLVFLMYYJJ-UHFFFAOYSA-N 2-aminopropiophenone Chemical compound CC(N)C(=O)C1=CC=CC=C1 PUAQLLVFLMYYJJ-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 125000006577 C1-C6 hydroxyalkyl group Chemical group 0.000 claims description 5
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 4
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 claims description 4
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 4
- 150000001298 alcohols Chemical class 0.000 claims description 4
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- 150000003973 alkyl amines Chemical class 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 150000001450 anions Chemical group 0.000 claims description 4
- 125000005265 dialkylamine group Chemical group 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 2
- 239000002671 adjuvant Substances 0.000 claims 1
- 238000003756 stirring Methods 0.000 description 22
- 239000012141 concentrate Substances 0.000 description 17
- 238000000034 method Methods 0.000 description 14
- 239000002562 thickening agent Substances 0.000 description 10
- 238000006460 hydrolysis reaction Methods 0.000 description 9
- 239000004480 active ingredient Substances 0.000 description 8
- 230000007062 hydrolysis Effects 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- 239000002979 fabric softener Substances 0.000 description 7
- 239000012768 molten material Substances 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 150000001767 cationic compounds Chemical class 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- JJLKTTCRRLHVGL-UHFFFAOYSA-L [acetyloxy(dibutyl)stannyl] acetate Chemical compound CC([O-])=O.CC([O-])=O.CCCC[Sn+2]CCCC JJLKTTCRRLHVGL-UHFFFAOYSA-L 0.000 description 2
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/645—Mixtures of compounds all of which are cationic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04007510A EP1584674B1 (en) | 2004-03-29 | 2004-03-29 | Easy-dispersible concentrate ester quat compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE602004008217D1 DE602004008217D1 (de) | 2007-09-27 |
| DE602004008217T2 true DE602004008217T2 (de) | 2008-05-15 |
Family
ID=34895968
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE602004008217T Expired - Lifetime DE602004008217T2 (de) | 2004-03-29 | 2004-03-29 | Einfach dispergierbare konzentrierte Esterquat Zusammensetzungen |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20070179080A1 (https=) |
| EP (1) | EP1584674B1 (https=) |
| JP (1) | JP2007537362A (https=) |
| CN (1) | CN100451093C (https=) |
| BR (1) | BRPI0509320B1 (https=) |
| DE (1) | DE602004008217T2 (https=) |
| ES (1) | ES2288646T3 (https=) |
| MX (1) | MXPA06011157A (https=) |
| WO (1) | WO2005095568A1 (https=) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE602006021410D1 (de) * | 2006-07-06 | 2011-06-01 | Clariant Brazil S A | Flüssige Weichspülerzusammensetzung |
| EP1876223B1 (en) * | 2006-07-06 | 2009-02-18 | Clariant (Brazil) S.A. | Concentrated esterquat composition |
| HUE033227T2 (en) | 2010-04-28 | 2017-11-28 | Evonik Degussa Gmbh | Textile softener composition |
| CN102758353B (zh) * | 2011-04-27 | 2016-08-17 | 赢创德固赛特种化学(上海)有限公司 | 柔软剂产品原料及制备柔软剂产品的方法 |
| WO2013113453A1 (en) | 2012-01-30 | 2013-08-08 | Evonik Industries Ag | Fabric softener active composition |
| EP2847307B1 (en) | 2012-05-07 | 2016-04-06 | Evonik Degussa GmbH | Fabric softener active composition and method for making it |
| BR102014025172B1 (pt) | 2013-11-05 | 2020-03-03 | Evonik Degussa Gmbh | Método para fabricação de um éster de ácido graxo de metisulfato de tris-(2-hidroxietil)-metilamônio, e composição ativa de amaciante de roupa |
| UA119182C2 (uk) | 2014-10-08 | 2019-05-10 | Евонік Дегусса Гмбх | Активна композиція для пом'якшувача тканини |
| EP3208315A1 (en) | 2016-02-16 | 2017-08-23 | Omya International AG | Process for manufacturing white pigment containing products |
| EP3208314B1 (en) | 2016-02-16 | 2018-08-15 | Omya International AG | Process for manufacturing white pigment containing products |
| EP3444036A1 (en) | 2017-08-16 | 2019-02-20 | Omya International AG | Indirect flotation process for manufacturing white pigment containing products |
| AU2021306216B2 (en) | 2020-07-09 | 2023-12-21 | Advansix Resins & Chemicals Llc | Branched amino acid surfactants |
| WO2022015604A1 (en) | 2020-07-13 | 2022-01-20 | Advansix Resins & Chemicals Llc | Branched amino acid surfactants for personal care and cosmetic products |
| AU2021307397B2 (en) | 2020-07-13 | 2024-06-13 | Advansix Resins & Chemicals Llc | Branched amino acid surfactants for use in healthcare products |
| CN116075582B (zh) | 2020-07-13 | 2025-08-19 | 艾德凡斯化学公司 | 用于清洁产品的支链氨基酸表面活性剂 |
| CA3298099A1 (en) | 2020-07-13 | 2026-03-02 | Advansix Resins & Chemicals Llc | Branched amino acid surfactants for electronics products |
| EP4179038A1 (en) | 2020-07-13 | 2023-05-17 | AdvanSix Resins & Chemicals LLC | Branched amino acid surfactants for oil and gas production |
| CN116057130B (zh) | 2020-07-13 | 2024-05-28 | 艾德凡斯化学公司 | 用于油墨、涂料和胶粘剂的支链氨基酸表面活性剂 |
| CN116348582B (zh) * | 2020-11-11 | 2024-12-13 | 联合利华知识产权控股有限公司 | 浓缩的非水性织物调理剂 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3608093A1 (de) * | 1986-03-12 | 1987-09-17 | Henkel Kgaa | Konfektioniertes textilweichmacher-konzentrat |
| DE4405702A1 (de) * | 1994-02-23 | 1995-08-24 | Witco Surfactants Gmbh | Hochkonzentrierte wäßrige Weichspülmittel mit verbesserter Lagerstabilität |
| DE19616482A1 (de) * | 1996-04-25 | 1997-10-30 | Hoechst Ag | Hochkonzentrierte wäßrige Esterquat-Lösungen |
| CN1251608A (zh) * | 1996-08-30 | 2000-04-26 | 普罗格特-甘布尔公司 | 用于制备织物柔软组合物的具有降低可燃性的浓缩预混合物 |
| US5961966A (en) * | 1996-12-09 | 1999-10-05 | Croda, Inc. | Quaternary fatty diesters of hydroxypropyl diethanol amine |
| JPH10251972A (ja) * | 1997-03-11 | 1998-09-22 | Lion Corp | カチオン界面活性剤の加水分解抑制剤、及びカチオン界面活性剤組成物 |
| WO1998052907A1 (en) * | 1997-05-19 | 1998-11-26 | The Procter & Gamble Company | Quaternary fatty acid triethanolamine ester salts and their use as fabric softeners |
| GB9810656D0 (en) * | 1998-05-18 | 1998-07-15 | Unilever Plc | Stable ammonium compositions |
| US6995131B1 (en) * | 1999-05-10 | 2006-02-07 | The Procter & Gamble Company | Clear or translucent aqueous fabric softener compositions containing high electrolyte and optional phase stabilizer |
| JP3947644B2 (ja) * | 1999-12-27 | 2007-07-25 | ライオン株式会社 | 液体柔軟剤組成物 |
| JP3984401B2 (ja) * | 1999-12-27 | 2007-10-03 | ライオン株式会社 | エステル結合を含むカチオン界面活性剤組成物及びその製造方法 |
| GB0002877D0 (en) * | 2000-02-08 | 2000-03-29 | Unilever Plc | Fabric conditioning composition |
| US20030139312A1 (en) * | 2000-05-11 | 2003-07-24 | Caswell Debra Sue | Highly concentrated fabric softener compositions and articles containing such compositions |
-
2004
- 2004-03-29 EP EP04007510A patent/EP1584674B1/en not_active Expired - Lifetime
- 2004-03-29 ES ES04007510T patent/ES2288646T3/es not_active Expired - Lifetime
- 2004-03-29 DE DE602004008217T patent/DE602004008217T2/de not_active Expired - Lifetime
-
2005
- 2005-03-22 JP JP2007505443A patent/JP2007537362A/ja active Pending
- 2005-03-22 US US10/594,210 patent/US20070179080A1/en not_active Abandoned
- 2005-03-22 BR BRPI0509320-1A patent/BRPI0509320B1/pt not_active IP Right Cessation
- 2005-03-22 WO PCT/EP2005/003004 patent/WO2005095568A1/en not_active Ceased
- 2005-03-22 MX MXPA06011157A patent/MXPA06011157A/es unknown
- 2005-03-22 CN CNB2005800100155A patent/CN100451093C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1942570A (zh) | 2007-04-04 |
| EP1584674B1 (en) | 2007-08-15 |
| WO2005095568A8 (en) | 2006-11-16 |
| BRPI0509320A (pt) | 2007-09-04 |
| CN100451093C (zh) | 2009-01-14 |
| ES2288646T3 (es) | 2008-01-16 |
| MXPA06011157A (es) | 2007-04-16 |
| JP2007537362A (ja) | 2007-12-20 |
| WO2005095568A1 (en) | 2005-10-13 |
| DE602004008217D1 (de) | 2007-09-27 |
| EP1584674A1 (en) | 2005-10-12 |
| US20070179080A1 (en) | 2007-08-02 |
| BRPI0509320B1 (pt) | 2015-08-11 |
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