DE60026319D1 - Fluorchemische wasser- und ölabweisende zusammensetzung - Google Patents
Fluorchemische wasser- und ölabweisende zusammensetzungInfo
- Publication number
- DE60026319D1 DE60026319D1 DE60026319T DE60026319T DE60026319D1 DE 60026319 D1 DE60026319 D1 DE 60026319D1 DE 60026319 T DE60026319 T DE 60026319T DE 60026319 T DE60026319 T DE 60026319T DE 60026319 D1 DE60026319 D1 DE 60026319D1
- Authority
- DE
- Germany
- Prior art keywords
- fluorocarbon
- oil repellent
- repellent composition
- alcohol
- thiol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0828—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing sulfonate groups or groups forming them
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3802—Low-molecular-weight compounds having heteroatoms other than oxygen having halogens
- C08G18/3804—Polyhydroxy compounds
- C08G18/3812—Polyhydroxy compounds having fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31558—Next to animal skin or membrane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31562—Next to polyamide [nylon, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31565—Next to polyester [polyethylene terephthalate, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31598—Next to silicon-containing [silicone, cement, etc.] layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2164—Coating or impregnation specified as water repellent
- Y10T442/2172—Also specified as oil repellent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2164—Coating or impregnation specified as water repellent
- Y10T442/2189—Fluorocarbon containing
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14802599P | 1999-08-10 | 1999-08-10 | |
US148025P | 1999-08-10 | ||
US09/596,322 US6479612B1 (en) | 1999-08-10 | 2000-06-19 | Fluorochemical water and oil repellents |
US596322 | 2000-06-19 | ||
PCT/US2000/021719 WO2001010921A1 (en) | 1999-08-10 | 2000-08-09 | Fluorochemical water and oil repellents |
Publications (2)
Publication Number | Publication Date |
---|---|
DE60026319D1 true DE60026319D1 (de) | 2006-04-27 |
DE60026319T2 DE60026319T2 (de) | 2006-11-30 |
Family
ID=26845445
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE2000626319 Expired - Lifetime DE60026319T2 (de) | 1999-08-10 | 2000-08-09 | Fluorchemische wasser- und ölabweisende zusammensetzung |
Country Status (12)
Country | Link |
---|---|
US (1) | US6479612B1 (de) |
EP (1) | EP1203037B1 (de) |
JP (1) | JP4790951B2 (de) |
KR (1) | KR100624633B1 (de) |
CN (1) | CN1157430C (de) |
AT (1) | ATE318849T1 (de) |
AU (1) | AU764359B2 (de) |
BR (1) | BR0013329A (de) |
CA (1) | CA2378229C (de) |
DE (1) | DE60026319T2 (de) |
TW (1) | TWI231818B (de) |
WO (1) | WO2001010921A1 (de) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10208567A1 (de) * | 2002-02-27 | 2003-09-11 | Degussa Construction Chem Gmbh | Wässriges fluormodifiziertes Polyurethansystem für Anti-Graffiti- und Anti-Soiling-Beschichtungen |
US6740251B2 (en) * | 2002-07-29 | 2004-05-25 | E. I. Du Pont De Nemours And Company | Fluorinated treatment for soil resistance |
US6824854B2 (en) * | 2002-07-29 | 2004-11-30 | E. I. Du Pont De Nemours And Company | Carpets treated for soil resistance |
DE602005004645T2 (de) * | 2005-02-04 | 2009-01-29 | E.I. Dupont De Nemours And Co., Wilmington | Zusammensetzungen Fluorkohlenstoff-gepfropfte Polysiloxane aufweisend |
US20060188729A1 (en) * | 2005-02-22 | 2006-08-24 | Kai-Volker Schubert | Washable leather with repellency |
US7160480B2 (en) * | 2005-02-22 | 2007-01-09 | E. I. Du Pont De Nemours And Company | Leather treated with fluorochemicals |
WO2006116424A2 (en) * | 2005-04-26 | 2006-11-02 | Nanosys, Inc. | Paintable nanofiber coatings |
US20070066785A1 (en) * | 2005-09-22 | 2007-03-22 | Acosta Erick J | Triazole-containing fluorinated urethanes and ureas |
US7494511B2 (en) * | 2006-05-08 | 2009-02-24 | E.I. Du Pont De Nemours And Company | Hydrophilic stain release agents |
EP2263990B1 (de) | 2006-11-03 | 2012-12-26 | E. I. du Pont de Nemours and Company | Flüssigkeitsabweisendes und fleckenresistentes Zementprodukt |
US7470745B2 (en) * | 2006-11-13 | 2008-12-30 | E. I. Du Pont De Nemours And Company | Perfluoroether based polymers |
US8048953B2 (en) * | 2006-11-13 | 2011-11-01 | E. I. Du Pont De Nemours And Company | Fluororpolymer compositions and treated substrates |
EP2188858A1 (de) * | 2007-10-23 | 2010-05-26 | E. I. du Pont de Nemours and Company | Ternäre emissionsschichten für lumineszenzanwendungen |
WO2009055628A1 (en) * | 2007-10-26 | 2009-04-30 | E. I. Du Pont De Nemours And Company | Process and materials for making contained layers and devices made with same |
US8040048B2 (en) * | 2007-12-12 | 2011-10-18 | Lang Charles D | Process for forming an organic electronic device including an organic device layer |
EP2231738A1 (de) * | 2007-12-20 | 2010-09-29 | DSM IP Assets B.V. | Ionomere für verbesserten druckverformungsrest bei bestimmten copolymeren |
US8286561B2 (en) | 2008-06-27 | 2012-10-16 | Ssw Holding Company, Inc. | Spill containing refrigerator shelf assembly |
US11786036B2 (en) | 2008-06-27 | 2023-10-17 | Ssw Advanced Technologies, Llc | Spill containing refrigerator shelf assembly |
WO2010042668A1 (en) | 2008-10-07 | 2010-04-15 | Ross Technology Corporation | Spill resistant surfaces having hydrophobic and oleophobic borders |
MX2012003537A (es) | 2009-09-28 | 2012-04-30 | Du Pont | Agente fluorado de control de desprendimiento y uso de este. |
GB0919014D0 (en) * | 2009-10-30 | 2009-12-16 | 3M Innovative Properties Co | Soll and stain resistant coating composition for finished leather substrates |
US9074778B2 (en) | 2009-11-04 | 2015-07-07 | Ssw Holding Company, Inc. | Cooking appliance surfaces having spill containment pattern |
BR112012023312A2 (pt) | 2010-03-15 | 2019-09-24 | Ross Tech Corporation | desentupidor e métodos de produção de superfícies hidrofóbicas |
JP2014512417A (ja) | 2011-02-21 | 2014-05-22 | ロス テクノロジー コーポレーション. | 低voc結合剤系を含む超疎水性および疎油性被覆物 |
DE102011085428A1 (de) | 2011-10-28 | 2013-05-02 | Schott Ag | Einlegeboden |
EP2791255B1 (de) | 2011-12-15 | 2017-11-01 | Ross Technology Corporation | Zusammensetzung und beschichtung für superhydrophobe leistung |
BR112014032676A2 (pt) | 2012-06-25 | 2017-06-27 | Ross Tech Corporation | revestimentos elastoméricos que têm propriedades hidrofóbicas e/ou oleofóbicas |
US20140170917A1 (en) * | 2012-12-19 | 2014-06-19 | 3M Innovative Properties Company | Polyurethane polymer, synthetic leather, and method |
US10442935B2 (en) * | 2016-08-06 | 2019-10-15 | Hrl Laboratories, Llc | Coatings combining oil-absorbing and oil-repelling components for increased smudge resistance |
CN111635804B (zh) * | 2019-11-22 | 2021-05-18 | 中国科学院兰州化学物理研究所 | 一种全氟聚醚超分子凝胶复合纳米颗粒润滑剂及其制备方法和应用 |
Family Cites Families (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3019133A (en) | 1956-05-14 | 1962-01-30 | Bohme Fettchemie Gmbh | Process for waterproofing leather |
NL268543A (de) | 1962-06-22 | 1900-01-01 | ||
US3236372A (en) | 1964-10-21 | 1966-02-22 | Master Lock Co | Bicycle lock sleeves |
US3573952A (en) | 1968-10-21 | 1971-04-06 | Minnesota Mining & Mfg | Process for imparting oil repellency to suede leather |
US3951762A (en) | 1972-01-14 | 1976-04-20 | Bayer Aktiengesellschaft | Preparation of perfluorinated organic sulfonyl fluorides |
DE3304120A1 (de) | 1983-02-08 | 1984-08-09 | Henkel KGaA, 4000 Düsseldorf | Verfahren zur herstellung wasserdichter leder und pelze |
JPS6040182A (ja) | 1983-08-16 | 1985-03-02 | Asahi Glass Co Ltd | 高引火点を有する撥水撥油剤 |
AU582346B2 (en) | 1983-09-13 | 1989-03-23 | Minnesota Mining And Manufacturing Company | Fluorohydrocarbon sulfonamide compounds and use thereof in treatment of leather, textiles and cellusosic materials |
US4668406A (en) * | 1984-04-02 | 1987-05-26 | Minnesota Mining And Manufacturing Company | Fluorochemical biuret compositions and fibrous substrates treated therewith |
FR2588555B1 (fr) | 1985-10-16 | 1987-12-11 | Atochem | Monomeres acryliques fluores, polymeres en derivant et leur application au traitement hydrofuge et oleofuge de substrats divers |
DE3607773C2 (de) | 1986-03-08 | 1995-06-22 | Cassella Ag | Fluoralkylliganden enthaltende Polyurethane, Verfahren zu ihrer Herstellung und ihre Zubereitungen und ihre Verwendung |
DE3727665A1 (de) | 1987-08-19 | 1989-03-02 | Cassella Ag | Methylolierte und gegebenenfalls veretherte fluoralkylliganden enthaltende urethane |
GB8809864D0 (en) | 1988-04-26 | 1988-06-02 | Ici Plc | Polyurethanes |
DE3943127A1 (de) | 1989-12-28 | 1991-07-04 | Hoechst Ag | Urethane als aliphatischen fluoralkoholen, isocyanaten und carbonsaeuren, verfahren zu ihrer herstellung und ihre verwendung |
JPH03265700A (ja) | 1990-03-16 | 1991-11-26 | Asahi Glass Co Ltd | 皮革用撥水撥油剤 |
US5276175A (en) | 1991-04-02 | 1994-01-04 | Minnesota Mining And Manufacturing Company | Isocyanate derivatives comprising flourochemical oligomers |
CA2110488A1 (en) | 1991-07-10 | 1993-01-21 | Franceska Fieuws | Fluorochemical water- and oil-repellent treating compositions |
JP3297071B2 (ja) | 1992-02-05 | 2002-07-02 | 旭硝子株式会社 | 撥水撥油剤組成物 |
JPH0617034A (ja) | 1992-07-03 | 1994-01-25 | Asahi Glass Co Ltd | 撥水撥油剤組成物およびその製造方法 |
JPH0625377A (ja) * | 1992-07-07 | 1994-02-01 | Dainippon Ink & Chem Inc | ポリウレタン樹脂水性分散体の製造方法 |
DE4223110A1 (de) | 1992-07-14 | 1994-01-20 | Henkel Kgaa | Neue Lederfettungsmittel und ihre Verwendung (II) |
JP3629753B2 (ja) | 1994-05-16 | 2005-03-16 | 旭硝子株式会社 | 水分散型防汚加工剤 |
US5491261A (en) | 1994-07-01 | 1996-02-13 | Ciba-Geigy Corporation | Poly-perfluoroalkyl-substituted alcohols and acids, and derivatives thereof |
DE69517252T2 (de) | 1994-07-01 | 2001-01-25 | Ciba Specialty Chemicals Holding Inc., Basel | Perfluoroalkylsulfid-,-sulfon-, -polysulfon- und -polysulfiddiole |
DE4423352A1 (de) | 1994-07-04 | 1996-01-11 | Henkel Kgaa | Verwendung Carboxylgruppen-terminierter Di-, Oligo- und/oder Polyester zur fettenden Ausrüstung von Leder |
CA2163611A1 (en) | 1994-12-15 | 1996-06-16 | Wayne K. Larson | Low surface energy sulfo-polyurethane or sulfo-polyurea compositions |
JP3564805B2 (ja) | 1995-02-16 | 2004-09-15 | 松下電器産業株式会社 | フロロアルキルカルボン酸とその誘導体 |
US5714082A (en) | 1995-06-02 | 1998-02-03 | Minnesota Mining And Manufacturing Company | Aqueous anti-soiling composition |
WO1997000995A1 (en) | 1995-06-23 | 1997-01-09 | Minnesota Mining And Manufacturing Company | Composition and process for imparting durable repellency to substrates |
US5672651A (en) * | 1995-10-20 | 1997-09-30 | Minnesota Mining And Manufacturing Company | Durable repellent fluorochemical compositions |
DE69705399T2 (de) | 1996-05-17 | 2002-05-02 | Minnesota Mining And Mfg. Co., Saint Paul | Eine gute leistung beider lufttrocknung von wäsche versorgende fluorochemische polyurethane |
FR2749309A1 (fr) | 1996-05-29 | 1997-12-05 | Atochem Elf Sa | Oligomeres urethanes fluores et leur application au traitement hydrofuge et oleofuge de substrats divers |
-
2000
- 2000-06-19 US US09/596,322 patent/US6479612B1/en not_active Expired - Fee Related
- 2000-07-21 TW TW89114611A patent/TWI231818B/zh not_active IP Right Cessation
- 2000-08-09 CA CA 2378229 patent/CA2378229C/en not_active Expired - Fee Related
- 2000-08-09 EP EP00952672A patent/EP1203037B1/de not_active Expired - Lifetime
- 2000-08-09 AU AU65327/00A patent/AU764359B2/en not_active Ceased
- 2000-08-09 DE DE2000626319 patent/DE60026319T2/de not_active Expired - Lifetime
- 2000-08-09 WO PCT/US2000/021719 patent/WO2001010921A1/en active IP Right Grant
- 2000-08-09 JP JP2001515726A patent/JP4790951B2/ja not_active Expired - Fee Related
- 2000-08-09 KR KR1020027001763A patent/KR100624633B1/ko not_active IP Right Cessation
- 2000-08-09 CN CNB00811692XA patent/CN1157430C/zh not_active Expired - Fee Related
- 2000-08-09 BR BR0013329A patent/BR0013329A/pt not_active Application Discontinuation
- 2000-08-09 AT AT00952672T patent/ATE318849T1/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
US6479612B1 (en) | 2002-11-12 |
EP1203037A1 (de) | 2002-05-08 |
DE60026319T2 (de) | 2006-11-30 |
BR0013329A (pt) | 2002-04-16 |
KR20020030092A (ko) | 2002-04-22 |
CA2378229C (en) | 2009-10-06 |
TWI231818B (en) | 2005-05-01 |
CA2378229A1 (en) | 2001-02-15 |
CN1370184A (zh) | 2002-09-18 |
AU764359B2 (en) | 2003-08-14 |
EP1203037B1 (de) | 2006-03-01 |
AU6532700A (en) | 2001-03-05 |
CN1157430C (zh) | 2004-07-14 |
WO2001010921A1 (en) | 2001-02-15 |
JP4790951B2 (ja) | 2011-10-12 |
KR100624633B1 (ko) | 2006-09-19 |
ATE318849T1 (de) | 2006-03-15 |
JP2003506537A (ja) | 2003-02-18 |
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