DE3908393C2 - - Google Patents
Info
- Publication number
- DE3908393C2 DE3908393C2 DE3908393A DE3908393A DE3908393C2 DE 3908393 C2 DE3908393 C2 DE 3908393C2 DE 3908393 A DE3908393 A DE 3908393A DE 3908393 A DE3908393 A DE 3908393A DE 3908393 C2 DE3908393 C2 DE 3908393C2
- Authority
- DE
- Germany
- Prior art keywords
- sensor element
- pump cell
- solid electrolyte
- diffusion
- element according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009792 diffusion process Methods 0.000 claims description 67
- 239000007789 gas Substances 0.000 claims description 33
- 239000007784 solid electrolyte Substances 0.000 claims description 29
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 24
- 239000004020 conductor Substances 0.000 claims description 14
- 230000004888 barrier function Effects 0.000 claims description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 8
- 229910052593 corundum Inorganic materials 0.000 claims description 8
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 238000009413 insulation Methods 0.000 claims description 6
- 150000001768 cations Chemical class 0.000 claims description 5
- 238000002485 combustion reaction Methods 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 238000005259 measurement Methods 0.000 claims description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 11
- 238000000034 method Methods 0.000 description 9
- 238000005086 pumping Methods 0.000 description 9
- 239000000523 sample Substances 0.000 description 9
- YAPQBXQYLJRXSA-UHFFFAOYSA-N theobromine Chemical compound CN1C(=O)NC(=O)C2=C1N=CN2C YAPQBXQYLJRXSA-UHFFFAOYSA-N 0.000 description 8
- 238000009826 distribution Methods 0.000 description 7
- 230000004044 response Effects 0.000 description 7
- 239000011888 foil Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 238000007650 screen-printing Methods 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- ZKATWMILCYLAPD-UHFFFAOYSA-N niobium pentoxide Chemical compound O=[Nb](=O)O[Nb](=O)=O ZKATWMILCYLAPD-UHFFFAOYSA-N 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 238000005245 sintering Methods 0.000 description 4
- 229960004559 theobromine Drugs 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 229910004369 ThO2 Inorganic materials 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 2
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 2
- 239000011195 cermet Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(IV) oxide Inorganic materials O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 230000007420 reactivation Effects 0.000 description 2
- 229910052596 spinel Inorganic materials 0.000 description 2
- 239000011029 spinel Substances 0.000 description 2
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 229910001260 Pt alloy Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 1
- 230000037427 ion transport Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4071—Cells and probes with solid electrolytes for investigating or analysing gases using sensor elements of laminated structure
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4071—Cells and probes with solid electrolytes for investigating or analysing gases using sensor elements of laminated structure
- G01N27/4072—Cells and probes with solid electrolytes for investigating or analysing gases using sensor elements of laminated structure characterized by the diffusion barrier
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3908393A DE3908393A1 (de) | 1989-03-15 | 1989-03-15 | Sensorelement fuer grenzstromsensoren zur bestimmung des (lambda)-wertes von gasgemischen |
| EP90903775A EP0462989B1 (de) | 1989-03-15 | 1990-03-08 | SENSORELEMENT FÜR GRENZSTROMSENSOREN ZUR BESTIMMUNG DES $g(l)-WERTES VON GASGEMISCHEN |
| JP2504105A JP2947929B2 (ja) | 1989-03-15 | 1990-03-08 | ガス混合物のλ値を測定するための限界電流センサ用のセンサ素子 |
| DE90903775T DE59003262D1 (de) | 1989-03-15 | 1990-03-08 | SENSORELEMENT FÜR GRENZSTROMSENSOREN ZUR BESTIMMUNG DES -g(l)-WERTES VON GASGEMISCHEN. |
| KR1019910701091A KR920701817A (ko) | 1989-03-15 | 1990-03-08 | 개스 혼합물의 λ값을 결정하기 위한 전류제한 센서용 센서 소자 |
| PCT/DE1990/000167 WO1990010862A1 (de) | 1989-03-15 | 1990-03-08 | SENSORELEMENT FÜR GRENZSTROMSENSOREN ZUR BESTIMMUNG DES μ-WERTES VON GASGEMISCHEN |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3908393A DE3908393A1 (de) | 1989-03-15 | 1989-03-15 | Sensorelement fuer grenzstromsensoren zur bestimmung des (lambda)-wertes von gasgemischen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3908393A1 DE3908393A1 (de) | 1990-09-27 |
| DE3908393C2 true DE3908393C2 (enrdf_load_stackoverflow) | 1991-01-24 |
Family
ID=6376369
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3908393A Granted DE3908393A1 (de) | 1989-03-15 | 1989-03-15 | Sensorelement fuer grenzstromsensoren zur bestimmung des (lambda)-wertes von gasgemischen |
| DE90903775T Expired - Fee Related DE59003262D1 (de) | 1989-03-15 | 1990-03-08 | SENSORELEMENT FÜR GRENZSTROMSENSOREN ZUR BESTIMMUNG DES -g(l)-WERTES VON GASGEMISCHEN. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE90903775T Expired - Fee Related DE59003262D1 (de) | 1989-03-15 | 1990-03-08 | SENSORELEMENT FÜR GRENZSTROMSENSOREN ZUR BESTIMMUNG DES -g(l)-WERTES VON GASGEMISCHEN. |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0462989B1 (enrdf_load_stackoverflow) |
| JP (1) | JP2947929B2 (enrdf_load_stackoverflow) |
| KR (1) | KR920701817A (enrdf_load_stackoverflow) |
| DE (2) | DE3908393A1 (enrdf_load_stackoverflow) |
| WO (1) | WO1990010862A1 (enrdf_load_stackoverflow) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4032436A1 (de) * | 1990-10-12 | 1992-04-16 | Bosch Gmbh Robert | Sensorelement fuer grenzstromsensoren zur bestimmung des (gamma)-wertes von gasgemischen |
| DE4226537C2 (de) * | 1992-08-11 | 2003-03-27 | Bosch Gmbh Robert | Polarographischer Sensor |
| DE4231966A1 (de) * | 1992-09-24 | 1994-03-31 | Bosch Gmbh Robert | Planare polarograhische Sonde zur Bestimmung des Lambda-Wertes von Gasgemischen |
| DE4243732A1 (de) * | 1992-12-23 | 1994-06-30 | Bosch Gmbh Robert | Sensoranordnung zur Bestimmung von Gaskomponenten und/oder Gaskonzentrationen von Gasgemischen |
| DE4333230B4 (de) * | 1993-09-30 | 2004-03-25 | Robert Bosch Gmbh | Elektrochemischer Meßfühler zur Bestimmung des Sauerstoffgehalts in Gasen |
| DE4340875A1 (de) * | 1993-12-01 | 1995-06-08 | Bosch Gmbh Robert | Sauerstoffmeßfühler |
| DE4341278B4 (de) * | 1993-12-03 | 2004-05-06 | Robert Bosch Gmbh | Grenzstromsensor zur Bestimmung des Lambdawertes in Gasgemischen |
| US5879526A (en) * | 1994-11-08 | 1999-03-09 | Robert Bosch Gmbh | Electrochemical measuring sensor for determining nitrogen oxides in gas mixtures |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1071709A (en) * | 1975-12-05 | 1980-02-12 | Arnold O. Isenberg | Gas analysis apparatus |
| DE3017947A1 (de) * | 1980-05-10 | 1981-11-12 | Bosch Gmbh Robert | Elektrochemischer messfuehler fuer die bestimmung des sauerstoffgehaltes in gasen und verfahren zum herstellen von sensorelementen fuer derartige messfuehler |
| DE3206903A1 (de) * | 1982-02-26 | 1983-09-15 | Bosch Gmbh Robert | Gassensor, insbesondere fuer abgase von brennkraftmaschinen |
| US4579643A (en) * | 1983-11-18 | 1986-04-01 | Ngk Insulators, Ltd. | Electrochemical device |
| DE3482745D1 (de) * | 1983-11-18 | 1990-08-23 | Ngk Insulators Ltd | Elektrochemische vorrichtung mit einem messfuehlelement. |
| JPH063429B2 (ja) * | 1984-10-18 | 1994-01-12 | 日本碍子株式会社 | 酸素センサ |
| JPS61138156A (ja) * | 1984-12-11 | 1986-06-25 | Ngk Spark Plug Co Ltd | 空燃比検出装置 |
| JPS61147155A (ja) * | 1984-12-20 | 1986-07-04 | Ngk Insulators Ltd | 電気化学的装置 |
| US4645572A (en) * | 1985-02-23 | 1987-02-24 | Ngk Insulators, Ltd. | Method of determining concentration of a component in gases and electrochemical device suitable for practicing the method |
| JPS62182645A (ja) * | 1985-12-26 | 1987-08-11 | Honda Motor Co Ltd | 酸素濃度センサの制御方法 |
| US4772376A (en) * | 1986-03-11 | 1988-09-20 | Nissan Motor Co., Ltd. | Air/fuel ratio sensor having oxygen sensor cell and oxygen pump cell |
| JPS6363962A (ja) * | 1986-09-04 | 1988-03-22 | Ngk Insulators Ltd | 工業用酸素濃度測定装置 |
| DE3726479C2 (de) * | 1987-08-08 | 1996-04-11 | Bosch Gmbh Robert | Verfahren zur Erzeugung von elektrisch-isolierenden Bereichen oder Schichten in oder auf O·2··-·-Ionen leitenden Festelektrolytsubstraten sowie Zusammensetzung zur Durchführung des Verfahrens |
| DE3728618C1 (de) * | 1987-08-27 | 1988-03-10 | Bosch Gmbh Robert | Sensorelement fuer Grenzstromsensoren zur Bestimmung des lambda-Wertes von Gasgemischen |
| DE3809154C1 (enrdf_load_stackoverflow) * | 1988-03-18 | 1988-12-08 | Robert Bosch Gmbh, 7000 Stuttgart, De | |
| DE3834987A1 (de) * | 1988-10-14 | 1990-04-19 | Bosch Gmbh Robert | Sensorelement fuer grenzstromsensoren zur bestimmung des (lambda)-wertes von gasgemischen |
-
1989
- 1989-03-15 DE DE3908393A patent/DE3908393A1/de active Granted
-
1990
- 1990-03-08 DE DE90903775T patent/DE59003262D1/de not_active Expired - Fee Related
- 1990-03-08 JP JP2504105A patent/JP2947929B2/ja not_active Expired - Lifetime
- 1990-03-08 WO PCT/DE1990/000167 patent/WO1990010862A1/de active IP Right Grant
- 1990-03-08 EP EP90903775A patent/EP0462989B1/de not_active Expired - Lifetime
- 1990-03-08 KR KR1019910701091A patent/KR920701817A/ko not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| JP2947929B2 (ja) | 1999-09-13 |
| KR920701817A (ko) | 1992-08-12 |
| WO1990010862A1 (de) | 1990-09-20 |
| DE59003262D1 (de) | 1993-12-02 |
| EP0462989B1 (de) | 1993-10-27 |
| EP0462989A1 (de) | 1992-01-02 |
| JPH04504170A (ja) | 1992-07-23 |
| DE3908393A1 (de) | 1990-09-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OP8 | Request for examination as to paragraph 44 patent law | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |