DE3602710A1 - Verfahren zum regenerieren von mit schwefelsaeure und mit ammoniumsulfaten beladenem koernigem kohlenstoffhaltigem adsorptionsmittel - Google Patents

Verfahren zum regenerieren von mit schwefelsaeure und mit ammoniumsulfaten beladenem koernigem kohlenstoffhaltigem adsorptionsmittel

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Publication number
DE3602710A1
DE3602710A1 DE19863602710 DE3602710A DE3602710A1 DE 3602710 A1 DE3602710 A1 DE 3602710A1 DE 19863602710 DE19863602710 DE 19863602710 DE 3602710 A DE3602710 A DE 3602710A DE 3602710 A1 DE3602710 A1 DE 3602710A1
Authority
DE
Germany
Prior art keywords
adsorbent
gas
reduction zone
heated
regeneration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19863602710
Other languages
German (de)
English (en)
Other versions
DE3602710C2 (xx
Inventor
Herbert Dr Widulle
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WIDULLE, HERBERT, DR., 2000 HAMBURG, DE
Original Assignee
PETERSEN HUGO VERFAHRENSTECH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PETERSEN HUGO VERFAHRENSTECH filed Critical PETERSEN HUGO VERFAHRENSTECH
Priority to DE19863602710 priority Critical patent/DE3602710A1/de
Publication of DE3602710A1 publication Critical patent/DE3602710A1/de
Application granted granted Critical
Publication of DE3602710C2 publication Critical patent/DE3602710C2/de
Granted legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • B01D53/08—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds according to the "moving bed" method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3416—Regenerating or reactivating of sorbents or filter aids comprising free carbon, e.g. activated carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3458—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3483—Regenerating or reactivating by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/30—Active carbon
    • C01B32/354—After-treatment
    • C01B32/36—Reactivation or regeneration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/202—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2062—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/302—Sulfur oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/404—Nitrogen oxides other than dinitrogen oxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40043—Purging
    • B01D2259/4005—Nature of purge gas
    • B01D2259/40052—Recycled product or process gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40077—Direction of flow
    • B01D2259/40081—Counter-current
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
    • B01D2259/4009—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating using hot gas

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Thermal Sciences (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Treating Waste Gases (AREA)
DE19863602710 1986-01-30 1986-01-30 Verfahren zum regenerieren von mit schwefelsaeure und mit ammoniumsulfaten beladenem koernigem kohlenstoffhaltigem adsorptionsmittel Granted DE3602710A1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE19863602710 DE3602710A1 (de) 1986-01-30 1986-01-30 Verfahren zum regenerieren von mit schwefelsaeure und mit ammoniumsulfaten beladenem koernigem kohlenstoffhaltigem adsorptionsmittel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19863602710 DE3602710A1 (de) 1986-01-30 1986-01-30 Verfahren zum regenerieren von mit schwefelsaeure und mit ammoniumsulfaten beladenem koernigem kohlenstoffhaltigem adsorptionsmittel

Publications (2)

Publication Number Publication Date
DE3602710A1 true DE3602710A1 (de) 1987-08-06
DE3602710C2 DE3602710C2 (xx) 1990-02-08

Family

ID=6292918

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19863602710 Granted DE3602710A1 (de) 1986-01-30 1986-01-30 Verfahren zum regenerieren von mit schwefelsaeure und mit ammoniumsulfaten beladenem koernigem kohlenstoffhaltigem adsorptionsmittel

Country Status (1)

Country Link
DE (1) DE3602710A1 (xx)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1992001502A1 (en) * 1990-07-26 1992-02-06 Qutherm Kav B.V. Method for the regeneration of an adsorption filter which contains (halogeno) hydrocarbons and for the removal of (halogeno) hydrocarbons from gases
WO1992003224A1 (de) * 1990-08-17 1992-03-05 Steag Aktiengesellschaft Verfahren und anordnung zum reinigen von kohlenstoffhaltigem adsorptionsmittel
WO1993019835A1 (de) * 1992-03-27 1993-10-14 Bergwerksverband Gmbh Verfahren zur regeneration von mit stickoxiden adsorptiv beladenem kohlenstoffhaltigem material
WO1996002315A1 (de) * 1994-07-19 1996-02-01 Fpr Holding Ag Verfahren zum reinigen von abgasen
CN101592449B (zh) * 2008-05-29 2012-01-25 中国石油化工股份有限公司 一种烟气脱硫脱氮吸附剂再生过程中的换热方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4113597C2 (de) * 1990-04-28 1996-10-17 Babcock Anlagen Gmbh Verfahren zur Reinigung von Abgasen

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3423761A1 (de) * 1984-06-28 1986-01-09 Bergwerksverband Gmbh, 4300 Essen Verfahren zur abscheidung von so(pfeil abwaerts)2(pfeil abwaerts) und no(pfeil abwaerts)x(pfeil abwaerts)

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3423761A1 (de) * 1984-06-28 1986-01-09 Bergwerksverband Gmbh, 4300 Essen Verfahren zur abscheidung von so(pfeil abwaerts)2(pfeil abwaerts) und no(pfeil abwaerts)x(pfeil abwaerts)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1992001502A1 (en) * 1990-07-26 1992-02-06 Qutherm Kav B.V. Method for the regeneration of an adsorption filter which contains (halogeno) hydrocarbons and for the removal of (halogeno) hydrocarbons from gases
WO1992003224A1 (de) * 1990-08-17 1992-03-05 Steag Aktiengesellschaft Verfahren und anordnung zum reinigen von kohlenstoffhaltigem adsorptionsmittel
US5405812A (en) * 1990-08-17 1995-04-11 Steag Aktiengesellschaft Method and arrangement for purifying a carbon-containing adsorption medium
WO1993019835A1 (de) * 1992-03-27 1993-10-14 Bergwerksverband Gmbh Verfahren zur regeneration von mit stickoxiden adsorptiv beladenem kohlenstoffhaltigem material
WO1996002315A1 (de) * 1994-07-19 1996-02-01 Fpr Holding Ag Verfahren zum reinigen von abgasen
CN101592449B (zh) * 2008-05-29 2012-01-25 中国石油化工股份有限公司 一种烟气脱硫脱氮吸附剂再生过程中的换热方法

Also Published As

Publication number Publication date
DE3602710C2 (xx) 1990-02-08

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Legal Events

Date Code Title Description
OP8 Request for examination as to paragraph 44 patent law
D2 Grant after examination
8327 Change in the person/name/address of the patent owner

Owner name: WIDULLE, HERBERT, DR., 2000 HAMBURG, DE

8363 Opposition against the patent
8339 Ceased/non-payment of the annual fee