DE3311449C2 - - Google Patents
Info
- Publication number
- DE3311449C2 DE3311449C2 DE3311449A DE3311449A DE3311449C2 DE 3311449 C2 DE3311449 C2 DE 3311449C2 DE 3311449 A DE3311449 A DE 3311449A DE 3311449 A DE3311449 A DE 3311449A DE 3311449 C2 DE3311449 C2 DE 3311449C2
- Authority
- DE
- Germany
- Prior art keywords
- rubber
- styrene
- methylstyrene
- nucleus
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001971 elastomer Polymers 0.000 claims description 45
- 239000005060 rubber Substances 0.000 claims description 45
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 39
- 239000000203 mixture Substances 0.000 claims description 18
- 229920001577 copolymer Polymers 0.000 claims description 16
- 229920000642 polymer Polymers 0.000 claims description 16
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 14
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 12
- 239000000178 monomer Substances 0.000 claims description 9
- 230000009477 glass transition Effects 0.000 claims description 8
- 229920001519 homopolymer Polymers 0.000 claims description 7
- 229920002857 polybutadiene Polymers 0.000 claims description 7
- 150000003440 styrenes Chemical class 0.000 claims description 5
- 150000001993 dienes Chemical class 0.000 claims description 4
- 229920005555 halobutyl Polymers 0.000 claims description 3
- 229920001195 polyisoprene Polymers 0.000 claims description 3
- 244000043261 Hevea brasiliensis Species 0.000 claims description 2
- 229920003052 natural elastomer Polymers 0.000 claims description 2
- 229920001194 natural rubber Polymers 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 description 13
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 8
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- 239000002174 Styrene-butadiene Substances 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 238000007720 emulsion polymerization reaction Methods 0.000 description 4
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 229920000126 latex Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000004071 soot Substances 0.000 description 3
- 229940126062 Compound A Drugs 0.000 description 2
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 229920005549 butyl rubber Polymers 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- 125000002897 diene group Chemical group 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- OJOWICOBYCXEKR-UHFFFAOYSA-N 5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=CC)CC1C=C2 OJOWICOBYCXEKR-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- MDBBOVGSTVJQCA-UHFFFAOYSA-N buta-1,3-diene;prop-1-en-2-ylbenzene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.CC(=C)C1=CC=CC=C1 MDBBOVGSTVJQCA-UHFFFAOYSA-N 0.000 description 1
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- ZAKVZVDDGSFVRG-UHFFFAOYSA-N prop-1-en-2-ylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CC(=C)C1=CC=CC=C1 ZAKVZVDDGSFVRG-UHFFFAOYSA-N 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 229920006301 statistical copolymer Polymers 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57049998A JPS58167632A (ja) | 1982-03-30 | 1982-03-30 | タイヤ用ゴム配合組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3311449A1 DE3311449A1 (de) | 1983-10-13 |
| DE3311449C2 true DE3311449C2 (en, 2012) | 1987-12-17 |
Family
ID=12846669
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3311449A Granted DE3311449A1 (de) | 1982-03-30 | 1983-03-29 | Kautschukmischung fuer kraftfahrzeugreifen |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4487892A (en, 2012) |
| JP (1) | JPS58167632A (en, 2012) |
| DE (1) | DE3311449A1 (en, 2012) |
| FR (1) | FR2524472B1 (en, 2012) |
| GB (1) | GB2119388B (en, 2012) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4791173A (en) * | 1985-09-13 | 1988-12-13 | The B F Goodrich Company | Tire tread rubber compositions |
| GB8606808D0 (en) * | 1986-03-19 | 1986-04-23 | Malaysian Rubber Producers | Elastoplastic compositions |
| US4754793A (en) * | 1987-06-23 | 1988-07-05 | Polysar Limited | Butyl elastomeric compositions having reduced permeability to gases |
| US5063268A (en) * | 1990-06-08 | 1991-11-05 | Exxon Chemical Patents Inc. | Composition for tire treads (E-235) |
| WO1992011138A1 (fr) * | 1990-12-24 | 1992-07-09 | Tsukihoshi Kasei Kabushiki Kaisha | Stratifie de resine pour recouvrir du verre |
| ES2089271T3 (es) * | 1991-04-04 | 1996-10-01 | Bridgestone Firestone Inc | Compuesto de goma de alto modulo y baja histeresis para cubiertas de neumaticos. |
| JP3553707B2 (ja) * | 1994-11-30 | 2004-08-11 | 株式会社ブリヂストン | 空気入りタイヤ |
| IT1275534B (it) * | 1995-07-14 | 1997-08-07 | Pirelli | Mescola di gomma vulcanizzabile per fasce battistrada di pneumatici di veicoli |
| CA2168697A1 (en) * | 1995-09-22 | 1997-03-23 | Jean-Paul Lambotte | Tire with tread having silica reinforcement |
| CA2315830A1 (en) * | 2000-07-27 | 2002-01-27 | Bayer Inc. | Butylpolymer composition having improved cold flow properties |
| US6672350B2 (en) * | 2001-09-06 | 2004-01-06 | The Goodyear Tire & Rubber Company | Tire with shock absorbing configured rubber tread |
| EP1456042B1 (en) * | 2001-12-21 | 2009-02-18 | Pirelli Tyre S.p.A. | Tyre comprising a cycloolefin polymer, tread band and elastomeric composition used therein |
| AU2002368306A1 (en) * | 2002-10-31 | 2004-05-25 | Pirelli Pneumatici S.P.A. | Method for preparing a crosslinkable elastomeric composition |
| US20040182486A1 (en) * | 2003-01-30 | 2004-09-23 | Carlo Bernard | Agricultural or industrial tire with reinforced rubber composition |
| US20050103415A1 (en) * | 2003-11-18 | 2005-05-19 | Lukich Lewis T. | Tire with shock absorbing closed cell rubber tread of spaced apart lugs |
| US20050171267A1 (en) * | 2004-01-29 | 2005-08-04 | Zanzig David J. | Tire with component of rubber composition comprised of functionalized styrene/butadiene elastomer, silica and styrene/alpha methylstyrene resin |
| EP1748052B1 (en) * | 2004-05-17 | 2012-05-09 | Bridgestone Corporation | Styrene polymer, styrene copolymer, rubber composition, and pneumatic tire |
| EP1913075B1 (en) * | 2005-08-09 | 2014-12-17 | Arizona Chemical Company | Rubber compositions containing improved tackifiers |
| JP5082571B2 (ja) * | 2007-05-02 | 2012-11-28 | 横浜ゴム株式会社 | タイヤトレッド用ゴム組成物 |
| JP5503159B2 (ja) * | 2008-02-15 | 2014-05-28 | 株式会社ブリヂストン | ゴム組成物及びそれを用いたタイヤ |
| US8722806B2 (en) | 2008-02-15 | 2014-05-13 | Bridgestone Corporation | Rubber composition and tire using the same |
| WO2013042130A1 (en) | 2011-09-19 | 2013-03-28 | Pathi Viraj Kumar | A smart hub and the method of operating thereof |
| US9764594B2 (en) | 2014-12-09 | 2017-09-19 | The Goodyear Tire & Rubber Company | Pneumatic tire |
| US9757987B2 (en) | 2014-12-09 | 2017-09-12 | The Goodyear Tire & Rubber Company | Pneumatic tire |
| US10563050B2 (en) | 2015-12-15 | 2020-02-18 | The Goodyear Tire & Rubber Company | Pneumatic tire |
| US10730985B2 (en) | 2016-12-19 | 2020-08-04 | Bridgestone Corporation | Functionalized polymer, process for preparing and rubber compositions containing the functionalized polymer |
| JP7019818B2 (ja) | 2017-12-15 | 2022-02-15 | 株式会社ブリヂストン | 官能化ポリマー、官能化ポリマーの調製プロセス、及び官能化ポリマーを含有するゴム組成物 |
| US10947368B2 (en) | 2019-03-04 | 2021-03-16 | The Goodyear Tire & Rubber Company | Pneumatic tire |
| JP7238154B2 (ja) | 2019-03-10 | 2023-03-13 | 株式会社ブリヂストン | 変性高シスポリジエンポリマー、関連する方法及びゴム組成物 |
| US11440350B2 (en) | 2020-05-13 | 2022-09-13 | The Goodyear Tire & Rubber Company | Pneumatic tire |
| JP6800435B1 (ja) * | 2020-07-28 | 2020-12-16 | 住友ゴム工業株式会社 | 空気入りタイヤ |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1167677B (de) * | 1964-04-09 | Phoenix Gummiwerke Ag | Reifen-Laufstreifen fuer Kraftfahrzeuge | |
| FR933593A (fr) * | 1945-10-02 | 1948-04-26 | Wingfoot Corp | Nouvelle composition chimique à base de caoutchouc |
| GB744258A (en) * | 1953-05-11 | 1956-02-01 | Ici Ltd | Thermoplastic compositions |
| GB763645A (en) * | 1954-05-07 | 1956-12-12 | Distillers Co Yeast Ltd | Improved rubber composition |
| US3103498A (en) * | 1957-04-20 | 1963-09-10 | Composition of modified elastomeric | |
| GB907799A (en) * | 1958-02-20 | 1962-10-10 | Polymer Corp | Blends of hard polymers and rubbery polymers |
| FR1405661A (fr) * | 1963-08-14 | 1965-07-09 | Bayer Ag | Procédé de préparation de polybutadiènes présentant des propriétés de transformation améliorées |
| GB1139267A (en) * | 1966-08-10 | 1969-01-08 | Texas Us Chem Co | Resin reinforced elastomer compositions |
| GB1437786A (en) * | 1972-12-12 | 1976-06-03 | Chamberlain Phipps Ltd | Randing |
| US3932332A (en) * | 1973-02-16 | 1976-01-13 | Hercules Incorporated | Copolymers of alpha-methylstyrene and styrene and uses thereof |
| US4104334A (en) * | 1975-10-09 | 1978-08-01 | Phillips Petroleum Company | Rubber composition |
| JPS5937014B2 (ja) * | 1978-07-11 | 1984-09-07 | 日本ゼオン株式会社 | タイヤ・トレツド用ゴム組成物 |
| JPS5590538A (en) * | 1978-12-28 | 1980-07-09 | Yokohama Rubber Co Ltd:The | Tread composition for low-turning resistance tire |
| JPS5813641A (ja) * | 1981-07-16 | 1983-01-26 | Japan Synthetic Rubber Co Ltd | ゴム配合組成物 |
-
1982
- 1982-03-30 JP JP57049998A patent/JPS58167632A/ja active Pending
-
1983
- 1983-03-29 GB GB08308559A patent/GB2119388B/en not_active Expired
- 1983-03-29 FR FR8305156A patent/FR2524472B1/fr not_active Expired
- 1983-03-29 DE DE3311449A patent/DE3311449A1/de active Granted
- 1983-03-30 US US06/480,617 patent/US4487892A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| GB2119388A (en) | 1983-11-16 |
| GB2119388B (en) | 1985-09-11 |
| US4487892A (en) | 1984-12-11 |
| JPS58167632A (ja) | 1983-10-03 |
| GB8308559D0 (en) | 1983-05-05 |
| FR2524472B1 (fr) | 1987-02-27 |
| DE3311449A1 (de) | 1983-10-13 |
| FR2524472A1 (fr) | 1983-10-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OP8 | Request for examination as to paragraph 44 patent law | ||
| 8125 | Change of the main classification |
Ipc: C08L 9/06 |
|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |