DE3148931C2 - - Google Patents
Info
- Publication number
- DE3148931C2 DE3148931C2 DE3148931A DE3148931A DE3148931C2 DE 3148931 C2 DE3148931 C2 DE 3148931C2 DE 3148931 A DE3148931 A DE 3148931A DE 3148931 A DE3148931 A DE 3148931A DE 3148931 C2 DE3148931 C2 DE 3148931C2
- Authority
- DE
- Germany
- Prior art keywords
- polyvinyl alcohol
- water
- soluble
- polyacrylic acid
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 54
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 52
- 229920002125 Sokalan® Polymers 0.000 claims description 25
- 239000004584 polyacrylic acid Substances 0.000 claims description 24
- 239000004014 plasticizer Substances 0.000 claims description 16
- 230000007062 hydrolysis Effects 0.000 claims description 13
- 238000006460 hydrolysis reaction Methods 0.000 claims description 13
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 7
- 239000011118 polyvinyl acetate Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 claims description 4
- 229920000223 polyglycerol Polymers 0.000 claims 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 47
- 239000010408 film Substances 0.000 description 37
- 239000000243 solution Substances 0.000 description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 26
- 238000005266 casting Methods 0.000 description 18
- 239000011888 foil Substances 0.000 description 15
- 229920000642 polymer Polymers 0.000 description 12
- 239000007787 solid Substances 0.000 description 12
- 239000002518 antifoaming agent Substances 0.000 description 11
- 238000004806 packaging method and process Methods 0.000 description 9
- 239000003139 biocide Substances 0.000 description 7
- 230000003115 biocidal effect Effects 0.000 description 6
- 229920002959 polymer blend Polymers 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 239000003599 detergent Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 230000032683 aging Effects 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- VUFOSBDICLTFMS-UHFFFAOYSA-M ethyl-hexadecyl-dimethylazanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)CC VUFOSBDICLTFMS-UHFFFAOYSA-M 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000005457 ice water Substances 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 229920006280 packaging film Polymers 0.000 description 3
- 239000012785 packaging film Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 229920013804 TRITON CF-32 Polymers 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- -1 aliphatic Alcohols Chemical class 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000003125 aqueous solvent Substances 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 229940096386 coconut alcohol Drugs 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000008240 homogeneous mixture Substances 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000002195 soluble material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 2
- 238000009463 water soluble packaging Methods 0.000 description 2
- ZYFORHCCOXYZKB-UHFFFAOYSA-M (2,6-dimethyl-4-phenylheptan-4-yl)-dimethyl-[2-(2-phenoxyethoxy)ethyl]azanium chloride hydrate Chemical compound O.[Cl-].C=1C=CC=CC=1OCCOCC[N+](C)(C)C(CC(C)C)(CC(C)C)C1=CC=CC=C1 ZYFORHCCOXYZKB-UHFFFAOYSA-M 0.000 description 1
- GKQHIYSTBXDYNQ-UHFFFAOYSA-M 1-dodecylpyridin-1-ium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+]1=CC=CC=C1 GKQHIYSTBXDYNQ-UHFFFAOYSA-M 0.000 description 1
- KBOMJGMOWUFNBI-UHFFFAOYSA-M 2-benzyl-1-ethyl-1-hydroxy-4-tridecyl-4,5-dihydroimidazol-1-ium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC1C[N+](O)(CC)C(CC=2C=CC=CC=2)=N1 KBOMJGMOWUFNBI-UHFFFAOYSA-M 0.000 description 1
- MSJLMQTXVKCUCD-UHFFFAOYSA-M 2-dodecylisoquinolin-2-ium;bromide Chemical compound [Br-].C1=CC=CC2=C[N+](CCCCCCCCCCCC)=CC=C21 MSJLMQTXVKCUCD-UHFFFAOYSA-M 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 239000005041 Mylar™ Substances 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 229920012485 Plasticized Polyvinyl chloride Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000013504 Triton X-100 Substances 0.000 description 1
- 229920004890 Triton X-100 Polymers 0.000 description 1
- 229920004897 Triton X-45 Polymers 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000000022 bacteriostatic agent Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 125000005501 benzalkonium group Chemical group 0.000 description 1
- WBYMVZZNNZJXQN-UHFFFAOYSA-N benzyl-dimethyl-(tetradecanoylamino)azanium chloride Chemical compound [Cl-].C(CCCCCCCCCCC)CC(=O)N[N+](CC1=CC=CC=C1)(C)C WBYMVZZNNZJXQN-UHFFFAOYSA-N 0.000 description 1
- JQQZCIIDNVIQKO-UHFFFAOYSA-N benzyl-dimethyl-[3-(tetradecanoylamino)propyl]azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC1=CC=CC=C1 JQQZCIIDNVIQKO-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 229940115457 cetyldimethylethylammonium bromide Drugs 0.000 description 1
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 description 1
- 229960001927 cetylpyridinium chloride Drugs 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- PGBHMTALBVVCIT-VCIWKGPPSA-N framycetin Chemical compound N[C@@H]1[C@@H](O)[C@H](O)[C@H](CN)O[C@@H]1O[C@H]1[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](N)C[C@@H](N)[C@@H]2O)O[C@@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CN)O2)N)O[C@@H]1CO PGBHMTALBVVCIT-VCIWKGPPSA-N 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- ACGUYXCXAPNIKK-UHFFFAOYSA-N hexachlorophene Chemical compound OC1=C(Cl)C=C(Cl)C(Cl)=C1CC1=C(O)C(Cl)=CC(Cl)=C1Cl ACGUYXCXAPNIKK-UHFFFAOYSA-N 0.000 description 1
- 229960004068 hexachlorophene Drugs 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000001069 nematicidal effect Effects 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 229940053050 neomycin sulfate Drugs 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- AOJFQRQNPXYVLM-UHFFFAOYSA-N pyridin-1-ium;chloride Chemical compound [Cl-].C1=CC=[NH+]C=C1 AOJFQRQNPXYVLM-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- UPCXAARSWVHVLY-UHFFFAOYSA-N tris(2-hydroxyethyl)azanium;acetate Chemical compound CC(O)=O.OCCN(CCO)CCO UPCXAARSWVHVLY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/02—Homopolymers or copolymers of unsaturated alcohols
- C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2329/02—Homopolymers or copolymers of unsaturated alcohols
- C08J2329/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Wrappers (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US21635880A | 1980-12-15 | 1980-12-15 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3148931A1 DE3148931A1 (de) | 1982-06-24 |
| DE3148931C2 true DE3148931C2 (enExample) | 1992-06-04 |
Family
ID=22806738
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19813148931 Granted DE3148931A1 (de) | 1980-12-15 | 1981-12-10 | Wasserloesliche folien aus polyvinylalkohol und polyacrylsaeure |
Country Status (15)
| Country | Link |
|---|---|
| JP (1) | JPS57125240A (enExample) |
| AU (1) | AU552603B2 (enExample) |
| BE (1) | BE891466A (enExample) |
| BR (1) | BR8108119A (enExample) |
| CA (1) | CA1197340A (enExample) |
| CH (1) | CH657108A5 (enExample) |
| DE (1) | DE3148931A1 (enExample) |
| DK (1) | DK161652C (enExample) |
| FR (1) | FR2496114B1 (enExample) |
| GB (1) | GB2090603B (enExample) |
| IT (1) | IT1144528B (enExample) |
| MX (1) | MX161147A (enExample) |
| NZ (1) | NZ199130A (enExample) |
| PH (1) | PH21825A (enExample) |
| ZA (1) | ZA818517B (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4205975C5 (de) * | 1992-02-27 | 2007-08-02 | Karg, Jörn E. | Verfahren zur Herstellung einer Kammer |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59219359A (ja) * | 1983-05-27 | 1984-12-10 | Kuraray Co Ltd | 流動性の改善された樹脂水性分散液 |
| US5362413A (en) * | 1984-03-23 | 1994-11-08 | The Clorox Company | Low-temperature-effective detergent compositions and delivery systems therefor |
| US4608187A (en) | 1984-04-02 | 1986-08-26 | The Clorox Company | Rubber toughened polyvinyl alcohol film compositions |
| JPS61204254A (ja) * | 1985-03-08 | 1986-09-10 | Kao Corp | ポリビニルアルコ−ルフイルム |
| US4797221A (en) * | 1985-09-12 | 1989-01-10 | S. C. Johnson & Son, Inc. | Polymer sheet for delivering laundry care additive and laundry care product formed from same |
| GB8612706D0 (en) * | 1986-05-23 | 1986-07-02 | Unilever Plc | Sealable container |
| US4972017A (en) * | 1987-03-24 | 1990-11-20 | The Clorox Company | Rinse soluble polymer film composition for wash additives |
| US4765916A (en) * | 1987-03-24 | 1988-08-23 | The Clorox Company | Polymer film composition for rinse release of wash additives |
| US4801636A (en) * | 1987-03-24 | 1989-01-31 | The Clorox Company | Rinse soluble polymer film composition for wash additives |
| US4747976A (en) * | 1987-05-14 | 1988-05-31 | The Clorox Company | PVA films with nonhydrolyzable anionic comonomers for packaging detergents |
| US4885105A (en) * | 1987-05-14 | 1989-12-05 | The Clorox Company | Films from PVA modified with nonhydrolyzable anionic comonomers |
| DE3806454A1 (de) * | 1988-02-29 | 1989-09-07 | Roesler Roland Oberflaechen | Schleifmittel fuer das gleitschleifverfahren und verfahren zu dessen herstellung |
| IL90584A (en) * | 1988-06-15 | 1994-12-29 | May & Baker Ltd | Package releasing its contents on contact with water |
| US5395616A (en) * | 1988-06-15 | 1995-03-07 | May & Baker Ltd. | Packaging for liquid products |
| SE465104B (sv) * | 1989-09-19 | 1991-07-29 | Anna Teurnell | Nedspolningsbar latrinpaase foer hundavfoering |
| DE4023909A1 (de) * | 1990-07-27 | 1992-01-30 | Wild Rudolf Gmbh & Co | Wiederverwendbarer behaelter aus kunststoff sowie seine herstellung und verwendung |
| FR2666349B1 (fr) * | 1990-08-28 | 1994-06-03 | Nln Sa | Detergent en sachet-dose pour le nettoyage de la vaisselle. |
| FR2666348B1 (fr) * | 1990-08-28 | 1994-06-03 | Nln Sa | Detergent en sachet-dose pour le nettoyage du linge. |
| US5256417A (en) * | 1992-01-31 | 1993-10-26 | Air Products And Chemicals, Inc. | Water dispersible towelette impregnated with non-aqueous lotion formulations |
| DE69521916T2 (de) * | 1992-04-01 | 2002-04-04 | Henkel Corp., Plymouth Meeting | Zusammensetzung und verfahren zur behandlung von metall |
| JPH05329276A (ja) * | 1992-05-20 | 1993-12-14 | Mitsui & Co Ltd | 水溶性有色バルーン |
| US5234140A (en) * | 1992-07-28 | 1993-08-10 | S. C. Johnson & Son, Inc. | Re-useable aerosol container |
| JP3340780B2 (ja) * | 1993-01-27 | 2002-11-05 | 呉羽化学工業株式会社 | ガスバリヤー性フィルム及びその製造方法 |
| JP3203287B2 (ja) * | 1994-01-26 | 2001-08-27 | 呉羽化学工業株式会社 | ガスバリヤー性積層体及びその製造方法 |
| GB9906176D0 (en) * | 1999-03-17 | 1999-05-12 | Unilever Plc | Process for producing a water soluble package |
| GB9906171D0 (en) | 1999-03-17 | 1999-05-12 | Unilever Plc | A process for producing a water soluble package |
| GB9906169D0 (en) | 1999-03-17 | 1999-05-12 | Unilever Plc | A process for producing a water soluble package |
| EP1272606A1 (en) | 2000-04-14 | 2003-01-08 | Unilever N.V. | Water soluble package and liquid contents thereof |
| DE60102582T2 (de) | 2000-05-15 | 2004-08-05 | Unilever N.V. | Flüssiges reinigungsmittel |
| DE10224420C1 (de) * | 2002-06-01 | 2003-12-04 | Beiersdorf Ag | Feucht klebender Wundverband |
| MXPA05001589A (es) * | 2002-08-09 | 2005-04-25 | Colgate Palmolive Co | Pano limpiador. |
| GB0222964D0 (en) | 2002-10-03 | 2002-11-13 | Unilever Plc | Polymeric film for water soluble package |
| US20040167256A1 (en) * | 2003-02-26 | 2004-08-26 | Verrall Andrew P. | Water soluble film for trigger spray bottle solution |
| DE102007026719B4 (de) | 2007-06-06 | 2014-05-15 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Formkörper hergerstellt durch Blasfolienextrusion aus einer biologisch abbaubaren polymeren Zusammensetzung, Verwendung des Formkörpers sowie Verfahren zur Herstellung des Formkörpers |
| DE102007042450B4 (de) | 2007-09-06 | 2009-12-31 | Andreas Siggelkow | Wasserlösliche Verpackung mit Funktionsdepot sowie Verfahren zu ihrer Herstellung und Verwendung der Verpackung |
| US8453653B2 (en) | 2007-12-20 | 2013-06-04 | Philip Morris Usa Inc. | Hollow/porous fibers and applications thereof |
| ES2609615T5 (es) | 2012-12-06 | 2020-08-03 | Mayr Melnhof Karton Ag | Método para la producción de un material de embalaje recubierto y material de embalaje con al menos una capa de bloqueo para compuestos hidrófobos |
| JP6122687B2 (ja) * | 2013-05-01 | 2017-04-26 | 積水化学工業株式会社 | ポリビニルアルコール溶液、ポリビニルアルコール溶液の製造方法、ポリビニルアルコールフィルムの製造方法及び積層フィルムの製造方法 |
| GB2552962A (en) * | 2016-08-15 | 2018-02-21 | Reckitt Benckiser Finish Bv | Composition for use in a machine dishwasher |
| WO2018183016A1 (en) * | 2017-03-30 | 2018-10-04 | Dow Global Technologies Llc | Free standing film |
| WO2020163546A1 (en) | 2019-02-06 | 2020-08-13 | Monosol, Llc | Water-soluble coatings for substrate surfaces |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR795872A (fr) * | 1934-11-10 | 1936-03-24 | Deutsch Celluloid Fabrik | Procédé de fabrication de feuilles très minces en produits polymérisés artificiels homogènes ou hétérogènes |
| US3634295A (en) * | 1968-07-24 | 1972-01-11 | Donald Thomas Dunlap | Textile sizing composition |
| IL37405A0 (en) * | 1970-08-12 | 1971-10-20 | Du Pont | Cold water soluble plastic films |
| JPS5514161B2 (enExample) * | 1972-01-14 | 1980-04-14 | ||
| US3736311A (en) * | 1972-03-02 | 1973-05-29 | Du Pont | Process for improving the thermal stability of polyvinyl alcohol with a polymeric polycarboxylic acid |
| DE2228159C3 (de) * | 1972-06-09 | 1975-05-22 | Conrad 8741 Saal Arbter | Einrichtung zum Führen und Verarbeiten von Stoffbahnen |
-
1981
- 1981-12-01 NZ NZ199130A patent/NZ199130A/xx unknown
- 1981-12-02 AU AU78184/81A patent/AU552603B2/en not_active Ceased
- 1981-12-08 ZA ZA818517A patent/ZA818517B/xx unknown
- 1981-12-10 DE DE19813148931 patent/DE3148931A1/de active Granted
- 1981-12-11 MX MX190562A patent/MX161147A/es unknown
- 1981-12-11 IT IT49887/81A patent/IT1144528B/it active
- 1981-12-14 CA CA000392178A patent/CA1197340A/en not_active Expired
- 1981-12-14 FR FR8123268A patent/FR2496114B1/fr not_active Expired
- 1981-12-14 BE BE0/206824A patent/BE891466A/fr not_active IP Right Cessation
- 1981-12-14 BR BR8108119A patent/BR8108119A/pt unknown
- 1981-12-14 PH PH26623A patent/PH21825A/en unknown
- 1981-12-15 DK DK555781A patent/DK161652C/da not_active IP Right Cessation
- 1981-12-15 JP JP56202366A patent/JPS57125240A/ja active Granted
- 1981-12-15 CH CH8008/81A patent/CH657108A5/de not_active IP Right Cessation
- 1981-12-15 GB GB8137743A patent/GB2090603B/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4205975C5 (de) * | 1992-02-27 | 2007-08-02 | Karg, Jörn E. | Verfahren zur Herstellung einer Kammer |
Also Published As
| Publication number | Publication date |
|---|---|
| IT8149887A0 (it) | 1981-12-11 |
| JPS57125240A (en) | 1982-08-04 |
| GB2090603B (en) | 1984-09-05 |
| DK161652B (da) | 1991-07-29 |
| FR2496114A1 (fr) | 1982-06-18 |
| PH21825A (en) | 1988-03-04 |
| JPH0214376B2 (enExample) | 1990-04-06 |
| CA1197340A (en) | 1985-11-26 |
| BR8108119A (pt) | 1982-09-28 |
| NZ199130A (en) | 1985-07-31 |
| DE3148931A1 (de) | 1982-06-24 |
| DK555781A (da) | 1982-06-16 |
| AU552603B2 (en) | 1986-06-12 |
| FR2496114B1 (fr) | 1987-08-14 |
| MX161147A (es) | 1990-08-08 |
| AU7818481A (en) | 1982-06-24 |
| BE891466A (fr) | 1982-06-14 |
| GB2090603A (en) | 1982-07-14 |
| CH657108A5 (de) | 1986-08-15 |
| DK161652C (da) | 1992-01-20 |
| IT1144528B (it) | 1986-10-29 |
| ZA818517B (en) | 1983-07-27 |
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| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8328 | Change in the person/name/address of the agent |
Free format text: STOLBERG-WERNIGERODE, GRAF ZU, U., DIPL.-CHEM. DR.RER.NAT. SUCHANTKE, J., DIPL.-ING. HUBER, A., DIPL.-ING. KAMEKE, VON, A., DIPL.-CHEM. DR.RER.NAT., 2000 HAMBURG SCHULMEYER, K., DIPL.-CHEM. DR.RER.NAT., PAT.-ANWAELTE, 2087 HASLOH |
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| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |