DE3019824C2 - Sauerstoffsonde - Google Patents
SauerstoffsondeInfo
- Publication number
- DE3019824C2 DE3019824C2 DE19803019824 DE3019824A DE3019824C2 DE 3019824 C2 DE3019824 C2 DE 3019824C2 DE 19803019824 DE19803019824 DE 19803019824 DE 3019824 A DE3019824 A DE 3019824A DE 3019824 C2 DE3019824 C2 DE 3019824C2
- Authority
- DE
- Germany
- Prior art keywords
- layer
- electrode layer
- oxygen
- probe
- solid electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000523 sample Substances 0.000 title claims description 138
- 239000001301 oxygen Substances 0.000 title claims description 118
- 229910052760 oxygen Inorganic materials 0.000 title claims description 118
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims description 107
- 239000007784 solid electrolyte Substances 0.000 claims description 50
- 239000011195 cermet Substances 0.000 claims description 28
- 239000003792 electrolyte Substances 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 19
- -1 oxygen ions Chemical class 0.000 claims description 14
- 239000012530 fluid Substances 0.000 claims description 3
- 239000010410 layer Substances 0.000 description 192
- 239000007789 gas Substances 0.000 description 35
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 31
- 229910052697 platinum Inorganic materials 0.000 description 15
- 238000002474 experimental method Methods 0.000 description 13
- 238000010438 heat treatment Methods 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 10
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 10
- 238000002485 combustion reaction Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 239000010409 thin film Substances 0.000 description 8
- 239000000292 calcium oxide Substances 0.000 description 7
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 7
- 229910010293 ceramic material Inorganic materials 0.000 description 6
- 230000001143 conditioned effect Effects 0.000 description 6
- 239000003973 paint Substances 0.000 description 6
- 239000011241 protective layer Substances 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 238000007639 printing Methods 0.000 description 5
- 230000004044 response Effects 0.000 description 5
- 238000011835 investigation Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000005245 sintering Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- DJOYTAUERRJRAT-UHFFFAOYSA-N 2-(n-methyl-4-nitroanilino)acetonitrile Chemical compound N#CCN(C)C1=CC=C([N+]([O-])=O)C=C1 DJOYTAUERRJRAT-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000032798 delamination Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 238000007750 plasma spraying Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229910052596 spinel Inorganic materials 0.000 description 2
- 239000011029 spinel Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- 229910015902 Bi 2 O 3 Inorganic materials 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 229910052839 forsterite Inorganic materials 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000004043 responsiveness Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4071—Cells and probes with solid electrolytes for investigating or analysing gases using sensor elements of laminated structure
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6404579A JPS55156858A (en) | 1979-05-25 | 1979-05-25 | Lamination-type film structure oxygen sensor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3019824A1 DE3019824A1 (de) | 1980-11-27 |
| DE3019824C2 true DE3019824C2 (de) | 1982-12-16 |
Family
ID=13246734
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19803019824 Expired DE3019824C2 (de) | 1979-05-25 | 1980-05-23 | Sauerstoffsonde |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS55156858A (enExample) |
| DE (1) | DE3019824C2 (enExample) |
| FR (1) | FR2457489A1 (enExample) |
| GB (1) | GB2050628B (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3343405A1 (de) * | 1982-12-01 | 1984-06-07 | Toyo Kogyo Co | Fuehler zum bestimmen des luft/brennstoff-verhaeltnisses im ansauggas einer brennkraftmaschine |
| DE3813930A1 (de) * | 1987-04-24 | 1988-11-03 | Ngk Insulators Ltd | Elektrodenstruktur eines sauerstoffmessfuehlerelements |
| DE3917710A1 (de) * | 1988-06-02 | 1990-01-04 | Ngk Insulators Ltd | Sauerstoffsensor mit eingebautem heizelement |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS564047A (en) * | 1979-06-26 | 1981-01-16 | Nissan Motor Co Ltd | Lamination type membrane-covered oxygen sensor |
| JPS57119250A (en) * | 1981-01-19 | 1982-07-24 | Nissan Motor Co Ltd | Oxygen sensor element holder |
| JPS57124761U (enExample) * | 1981-01-29 | 1982-08-03 | ||
| JPS57137849A (en) * | 1981-02-19 | 1982-08-25 | Nissan Motor Co Ltd | Element of film construction oxygen sensor |
| JPS57138053U (enExample) * | 1981-02-23 | 1982-08-28 | ||
| EP0062330A1 (de) * | 1981-04-03 | 1982-10-13 | Fuji Electric Co., Ltd. | Sauerstoffempfindlicher Sensor mit einem Sensorelement aus Zirkonoxyd, Verfahren zu dessen Herstellung und Nachbehandlung, Verwendung des Sensors zur Messung in schwefeloxydhaltiger Messgasatmosphäre |
| DE3635157A1 (de) * | 1986-10-16 | 1988-04-21 | Bosch Gmbh Robert | Gassensor mit cermet-elektroden |
| JPH01184457A (ja) * | 1988-01-18 | 1989-07-24 | Ngk Insulators Ltd | 酸素センサ素子 |
| GB9116385D0 (en) * | 1991-07-30 | 1991-09-11 | British Gas Plc | Oxygen sensor |
| CN106706743A (zh) * | 2016-12-30 | 2017-05-24 | 莱鼎电子材料科技有限公司 | 一种新型片式浓差型汽车氧传感器及其制备方法 |
| JP6804995B2 (ja) * | 2017-01-12 | 2020-12-23 | 日本特殊陶業株式会社 | ガスセンサ素子及びガスセンサ |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1926445A1 (de) * | 1969-05-23 | 1970-12-03 | Gen Electric | Elektrode fuer eine Zelle mit Sauerstoffionen-Festelektrolyt |
| US4040929A (en) * | 1975-09-15 | 1977-08-09 | Universal Oil Products Company | Oxygen sensor having thin film electrolyte |
| FR2350598A1 (fr) * | 1976-05-07 | 1977-12-02 | Thomson Csf | Senseur de concentration d'une espece dans un fluide |
| JPS5339791A (en) * | 1976-09-22 | 1978-04-11 | Nissan Motor | Oxygen sensor |
| JPS5348594A (en) * | 1976-10-14 | 1978-05-02 | Nissan Motor | Oxygen sensor |
| DE2718907C2 (de) * | 1977-04-28 | 1984-04-12 | Robert Bosch Gmbh, 7000 Stuttgart | Meßfühler zur Bestimmung des Sauerstoffgehalts in Abgasen |
| JPS584986B2 (ja) * | 1978-06-16 | 1983-01-28 | 日産自動車株式会社 | 酸素濃度測定装置 |
-
1979
- 1979-05-25 JP JP6404579A patent/JPS55156858A/ja active Pending
-
1980
- 1980-05-23 FR FR8011630A patent/FR2457489A1/fr active Granted
- 1980-05-23 DE DE19803019824 patent/DE3019824C2/de not_active Expired
- 1980-05-27 GB GB8017291A patent/GB2050628B/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3343405A1 (de) * | 1982-12-01 | 1984-06-07 | Toyo Kogyo Co | Fuehler zum bestimmen des luft/brennstoff-verhaeltnisses im ansauggas einer brennkraftmaschine |
| DE3813930A1 (de) * | 1987-04-24 | 1988-11-03 | Ngk Insulators Ltd | Elektrodenstruktur eines sauerstoffmessfuehlerelements |
| DE3917710A1 (de) * | 1988-06-02 | 1990-01-04 | Ngk Insulators Ltd | Sauerstoffsensor mit eingebautem heizelement |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2050628A (en) | 1981-01-07 |
| DE3019824A1 (de) | 1980-11-27 |
| GB2050628B (en) | 1983-05-11 |
| JPS55156858A (en) | 1980-12-06 |
| FR2457489A1 (fr) | 1980-12-19 |
| FR2457489B1 (enExample) | 1983-08-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OAP | Request for examination filed | ||
| OD | Request for examination | ||
| D2 | Grant after examination | ||
| 8363 | Opposition against the patent | ||
| 8330 | Complete disclaimer |