DE2948457A1 - Verfahren zur entmetallisierung von metallhaltigen kohlenwasserstoff- ausgangsprodukten - Google Patents
Verfahren zur entmetallisierung von metallhaltigen kohlenwasserstoff- ausgangsproduktenInfo
- Publication number
- DE2948457A1 DE2948457A1 DE19792948457 DE2948457A DE2948457A1 DE 2948457 A1 DE2948457 A1 DE 2948457A1 DE 19792948457 DE19792948457 DE 19792948457 DE 2948457 A DE2948457 A DE 2948457A DE 2948457 A1 DE2948457 A1 DE 2948457A1
- Authority
- DE
- Germany
- Prior art keywords
- demetallization
- less
- coke
- metal
- pores
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims description 22
- 229930195733 hydrocarbon Natural products 0.000 title claims description 21
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 21
- 239000004215 Carbon black (E152) Substances 0.000 title claims description 20
- 229910052751 metal Inorganic materials 0.000 claims description 33
- 239000002184 metal Substances 0.000 claims description 33
- 239000000571 coke Substances 0.000 claims description 32
- 239000000463 material Substances 0.000 claims description 25
- 239000011148 porous material Substances 0.000 claims description 25
- 150000002739 metals Chemical class 0.000 claims description 13
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
- 239000002010 green coke Substances 0.000 claims description 6
- 239000003208 petroleum Substances 0.000 claims description 5
- 239000011329 calcined coke Substances 0.000 claims description 3
- 238000004939 coking Methods 0.000 claims description 3
- 230000003111 delayed effect Effects 0.000 claims description 3
- 239000003079 shale oil Substances 0.000 claims description 3
- 239000010426 asphalt Substances 0.000 claims description 2
- 239000011294 coal tar pitch Substances 0.000 claims description 2
- 239000000446 fuel Substances 0.000 claims description 2
- 239000003921 oil Substances 0.000 claims description 2
- 238000005292 vacuum distillation Methods 0.000 claims description 2
- 150000002736 metal compounds Chemical class 0.000 claims 1
- 239000003209 petroleum derivative Substances 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 239000011275 tar sand Substances 0.000 claims 1
- 239000003054 catalyst Substances 0.000 description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 238000005984 hydrogenation reaction Methods 0.000 description 8
- 229910052720 vanadium Inorganic materials 0.000 description 8
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 8
- 239000007858 starting material Substances 0.000 description 6
- 238000011084 recovery Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000295 fuel oil Substances 0.000 description 3
- 238000001465 metallisation Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 229910052614 beryl Inorganic materials 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 229940011182 cobalt acetate Drugs 0.000 description 1
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- NLPVCCRZRNXTLT-UHFFFAOYSA-N dioxido(dioxo)molybdenum;nickel(2+) Chemical compound [Ni+2].[O-][Mo]([O-])(=O)=O NLPVCCRZRNXTLT-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- XOROUWAJDBBCRC-UHFFFAOYSA-N nickel;sulfanylidenetungsten Chemical compound [Ni].[W]=S XOROUWAJDBBCRC-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002006 petroleum coke Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 150000004763 sulfides Chemical group 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/612—Surface area less than 10 m2/g
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/966,901 US4227995A (en) | 1978-12-06 | 1978-12-06 | Demetallization of hydrocarbon feedstock |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2948457A1 true DE2948457A1 (de) | 1980-06-19 |
| DE2948457C2 DE2948457C2 (US07582779-20090901-C00044.png) | 1987-05-21 |
Family
ID=25512029
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19792948457 Granted DE2948457A1 (de) | 1978-12-06 | 1979-12-01 | Verfahren zur entmetallisierung von metallhaltigen kohlenwasserstoff- ausgangsprodukten |
Country Status (8)
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1174629A (en) * | 1980-05-29 | 1984-09-18 | Huno Van Der Eijk | Process for the demetallization of hydrocarbon oils |
| US4544479A (en) * | 1980-09-12 | 1985-10-01 | Mobil Oil Corporation | Recovery of metal values from petroleum residua and other fractions |
| DE3036504C2 (de) * | 1980-09-27 | 1983-08-18 | Rheinische Braunkohlenwerke Ag, 5000 Koeln | Verfahren zum Entfernen von fluor- und/oder schwefelreichen Schadstoffen aus gasförmigen und flüssigen Medien |
| US4439313A (en) * | 1980-12-05 | 1984-03-27 | The Lummus Company | Removal of arsenic impurity from hydrocarbons |
| FR2511389A1 (fr) * | 1981-08-11 | 1983-02-18 | Inst Francais Du Petrole | Procede d'hydroconversion catalytique d'hydrocarbures lourds en phase liquide et en presence d'un catalyseur disperse et de particules charbonneuses |
| US4585546A (en) * | 1983-04-29 | 1986-04-29 | Mobil Oil Corporation | Hydrotreating petroleum heavy ends in aromatic solvents with large pore size alumina |
| US4790929A (en) * | 1983-06-20 | 1988-12-13 | Engelhard Corporation | Hydrotreating process using porous mullite |
| US4587012A (en) * | 1983-10-31 | 1986-05-06 | Chevron Research Company | Process for upgrading hydrocarbonaceous feedstocks |
| US4800015A (en) * | 1986-04-04 | 1989-01-24 | Simmons John J | Utilization of low rank coal and peat |
| JPS62250913A (ja) * | 1986-04-23 | 1987-10-31 | Tonen Sekiyukagaku Kk | 石油留分中の砒素の除去方法 |
| ES2034626T3 (es) * | 1988-05-16 | 1993-04-01 | Mitsui Petrochemical Industries, Ltd. | Un metodo de eliminacion del mercurio y/o compuestos de mercurio de un aceite de hidrocarburos. |
| US5110779A (en) * | 1989-01-09 | 1992-05-05 | The Dow Chemical Company | Polymer hydrogenation catalysts |
| JP2730696B2 (ja) * | 1989-05-22 | 1998-03-25 | 日本ケッチェン株式会社 | 炭化水素油の脱スケール剤および水素化処理触媒 |
| US5358634A (en) * | 1991-07-11 | 1994-10-25 | Mobil Oil Corporation | Process for treating heavy oil |
| CN111375399B (zh) * | 2018-12-29 | 2022-04-08 | 中国石油化工股份有限公司 | 一种重油加氢处理催化剂及其制备方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2987470A (en) * | 1958-11-13 | 1961-06-06 | Hydrocarbon Research Inc | Demineralization of oils |
| JPS4817443B1 (US07582779-20090901-C00044.png) * | 1967-07-29 | 1973-05-29 | ||
| US3583902A (en) * | 1969-05-06 | 1971-06-08 | Atlantic Richfield Co | Two-stage conversion process |
| US3617481A (en) * | 1969-12-11 | 1971-11-02 | Exxon Research Engineering Co | Combination deasphalting-coking-hydrotreating process |
| US3947347A (en) * | 1972-10-04 | 1976-03-30 | Chevron Research Company | Process for removing metalliferous contaminants from hydrocarbons |
-
1978
- 1978-12-06 US US05/966,901 patent/US4227995A/en not_active Expired - Lifetime
-
1979
- 1979-11-08 CA CA000339438A patent/CA1121750A/en not_active Expired
- 1979-11-15 GB GB7939541A patent/GB2038354B/en not_active Expired
- 1979-11-28 IT IT50930/79A patent/IT1164913B/it active
- 1979-11-28 JP JP15414079A patent/JPS5578088A/ja active Pending
- 1979-12-01 DE DE19792948457 patent/DE2948457A1/de active Granted
- 1979-12-04 FR FR7929761A patent/FR2443492A1/fr active Granted
- 1979-12-05 NL NLAANVRAGE7908793,A patent/NL185093C/xx not_active IP Right Cessation
Non-Patent Citations (1)
| Title |
|---|
| NICHTS-ERMITTELT * |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2038354A (en) | 1980-07-23 |
| FR2443492A1 (fr) | 1980-07-04 |
| GB2038354B (en) | 1983-04-13 |
| DE2948457C2 (US07582779-20090901-C00044.png) | 1987-05-21 |
| IT7950930A0 (it) | 1979-11-28 |
| US4227995A (en) | 1980-10-14 |
| CA1121750A (en) | 1982-04-13 |
| NL185093B (nl) | 1989-08-16 |
| JPS5578088A (en) | 1980-06-12 |
| NL7908793A (nl) | 1980-06-10 |
| NL185093C (nl) | 1990-01-16 |
| IT1164913B (it) | 1987-04-15 |
| FR2443492B1 (US07582779-20090901-C00044.png) | 1984-04-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |