DE2754762C2 - Verfahren zur katalytischen Verbrennung von Schwefelwasserstoff enthaltendem Abgas und zur Durchführung des Verfahrens geeigneter Katalysator - Google Patents
Verfahren zur katalytischen Verbrennung von Schwefelwasserstoff enthaltendem Abgas und zur Durchführung des Verfahrens geeigneter KatalysatorInfo
- Publication number
- DE2754762C2 DE2754762C2 DE2754762A DE2754762A DE2754762C2 DE 2754762 C2 DE2754762 C2 DE 2754762C2 DE 2754762 A DE2754762 A DE 2754762A DE 2754762 A DE2754762 A DE 2754762A DE 2754762 C2 DE2754762 C2 DE 2754762C2
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- weight
- bismuth
- percent
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims description 73
- 239000007789 gas Substances 0.000 title claims description 54
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title claims description 42
- 238000000034 method Methods 0.000 title claims description 42
- 238000007084 catalytic combustion reaction Methods 0.000 title claims description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 36
- 229910052802 copper Inorganic materials 0.000 claims description 36
- 239000010949 copper Substances 0.000 claims description 36
- 229910052797 bismuth Inorganic materials 0.000 claims description 32
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 32
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 24
- 229910052760 oxygen Inorganic materials 0.000 claims description 24
- 239000001301 oxygen Substances 0.000 claims description 24
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 239000012876 carrier material Substances 0.000 claims description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 15
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 10
- 239000002245 particle Substances 0.000 description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 9
- 238000002485 combustion reaction Methods 0.000 description 6
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 235000010269 sulphur dioxide Nutrition 0.000 description 5
- 239000005864 Sulphur Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000004291 sulphur dioxide Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000003915 air pollution Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001341 alkaline earth metal compounds Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 150000001622 bismuth compounds Chemical class 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/843—Arsenic, antimony or bismuth
- B01J23/8437—Bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Biomedical Technology (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Incineration Of Waste (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US75753177A | 1977-01-07 | 1977-01-07 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2754762A1 DE2754762A1 (de) | 1978-07-13 |
| DE2754762C2 true DE2754762C2 (de) | 1987-02-05 |
Family
ID=25048172
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2754762A Expired DE2754762C2 (de) | 1977-01-07 | 1977-12-08 | Verfahren zur katalytischen Verbrennung von Schwefelwasserstoff enthaltendem Abgas und zur Durchführung des Verfahrens geeigneter Katalysator |
Country Status (13)
| Country | Link |
|---|---|
| JP (1) | JPS5377873A (no) |
| AR (1) | AR212728A1 (no) |
| AU (1) | AU510872B2 (no) |
| BE (1) | BE862443A (no) |
| BR (1) | BR7800064A (no) |
| CA (1) | CA1125731A (no) |
| DE (1) | DE2754762C2 (no) |
| FR (1) | FR2376686A1 (no) |
| GB (1) | GB1558656A (no) |
| MY (1) | MY8100349A (no) |
| NL (1) | NL190357C (no) |
| RO (1) | RO76367A (no) |
| ZA (1) | ZA7850B (no) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4576814A (en) * | 1979-04-04 | 1986-03-18 | Union Oil Company Of California | Catalyst and process for oxidizing hydrogen sulfide |
| DE3280104D1 (de) * | 1982-02-02 | 1990-03-15 | Union Oil Co | Katalysator und verfahren zum oxydieren von schwefelwasserstoff. |
| FR2631854A1 (fr) * | 1988-05-26 | 1989-12-01 | Norsolor Sa | Procede de purification catalytique d'un effluent aqueux |
| JP2000515807A (ja) * | 1996-07-26 | 2000-11-28 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 触媒組成物、その調製、及び接触灰化におけるその使用 |
| DE69705525T2 (de) * | 1996-07-26 | 2001-11-29 | Shell Internationale Research Maatschappij B.V., Den Haag | Verfahren zur katalytische verbrennung und dafür verwendbare katalysatorzusammensetzung |
| JP3847712B2 (ja) | 2000-10-18 | 2006-11-22 | 日揮株式会社 | 硫化水素、メルカプタン、炭酸ガス、芳香族炭化水素を含むガス中の硫黄化合物の除去方法およびその装置 |
| IT1403545B1 (it) * | 2011-02-02 | 2013-10-31 | Eonsudenergia Srl | Catalizzatore per la termolisi di rifiuti |
| EP3799854A1 (en) | 2019-10-01 | 2021-04-07 | Stefan Johannes Fellner | Extract of organic humified materials |
| CN113117517B (zh) * | 2019-12-31 | 2022-10-11 | 中国石油化工股份有限公司 | 一种高浓度含硫有机废气的处理方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1900751A (en) * | 1928-02-27 | 1933-03-07 | Ig Farbenindustrie Ag | Purification of gases |
| GB319396A (en) * | 1928-06-20 | 1929-09-20 | Ig Farbenindustrie Ag | Improvements relating to the purification of gas containing sulphuretted hydrogen |
| FR1070681A (fr) * | 1953-02-06 | 1954-08-05 | Bataafsche Petroleum | Procédé de préparation du soufre à partir de l'hydrogène sulfuré |
-
1977
- 1977-12-08 DE DE2754762A patent/DE2754762C2/de not_active Expired
- 1977-12-29 BE BE1008616A patent/BE862443A/xx not_active IP Right Cessation
-
1978
- 1978-01-05 JP JP5678A patent/JPS5377873A/ja active Granted
- 1978-01-05 ZA ZA00780050A patent/ZA7850B/xx unknown
- 1978-01-05 RO RO7892830A patent/RO76367A/ro unknown
- 1978-01-05 NL NLAANVRAGE7800126,A patent/NL190357C/xx not_active IP Right Cessation
- 1978-01-05 AU AU32198/78A patent/AU510872B2/en not_active Expired
- 1978-01-05 FR FR7800205A patent/FR2376686A1/fr active Granted
- 1978-01-05 GB GB368/78A patent/GB1558656A/en not_active Expired
- 1978-01-05 AR AR270636A patent/AR212728A1/es active
- 1978-01-05 BR BR7800064A patent/BR7800064A/pt unknown
- 1978-01-06 CA CA294,517A patent/CA1125731A/en not_active Expired
-
1981
- 1981-12-30 MY MY349/81A patent/MY8100349A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB1558656A (en) | 1980-01-09 |
| CA1125731A (en) | 1982-06-15 |
| FR2376686A1 (fr) | 1978-08-04 |
| AU3219878A (en) | 1979-07-12 |
| AR212728A1 (es) | 1978-09-15 |
| JPS6120342B2 (no) | 1986-05-21 |
| NL190357C (nl) | 1994-02-01 |
| BE862443A (nl) | 1978-06-29 |
| FR2376686B1 (no) | 1982-05-07 |
| NL190357B (nl) | 1993-09-01 |
| JPS5377873A (en) | 1978-07-10 |
| NL7800126A (nl) | 1978-07-11 |
| DE2754762A1 (de) | 1978-07-13 |
| AU510872B2 (en) | 1980-07-17 |
| RO76367A (ro) | 1981-11-04 |
| MY8100349A (en) | 1981-12-31 |
| ZA7850B (en) | 1978-12-27 |
| BR7800064A (pt) | 1979-01-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8128 | New person/name/address of the agent |
Representative=s name: JUNG, E., DIPL.-CHEM. DR.PHIL. SCHIRDEWAHN, J., DI |
|
| 8110 | Request for examination paragraph 44 | ||
| 8125 | Change of the main classification |
Ipc: B01D 53/36 |
|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition |