DE2739078A1 - Verfahren zur umwandlung von kohlenwasserstoffen - Google Patents
Verfahren zur umwandlung von kohlenwasserstoffenInfo
- Publication number
- DE2739078A1 DE2739078A1 DE19772739078 DE2739078A DE2739078A1 DE 2739078 A1 DE2739078 A1 DE 2739078A1 DE 19772739078 DE19772739078 DE 19772739078 DE 2739078 A DE2739078 A DE 2739078A DE 2739078 A1 DE2739078 A1 DE 2739078A1
- Authority
- DE
- Germany
- Prior art keywords
- hydrogen
- molten salt
- alkali metal
- products
- sulfur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229930195733 hydrocarbon Natural products 0.000 title claims description 51
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 51
- 238000000034 method Methods 0.000 title claims description 51
- 238000006243 chemical reaction Methods 0.000 title claims description 41
- 150000003839 salts Chemical class 0.000 claims description 43
- 239000004215 Carbon black (E152) Substances 0.000 claims description 40
- 239000001257 hydrogen Substances 0.000 claims description 38
- 229910052739 hydrogen Inorganic materials 0.000 claims description 38
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 35
- 239000003245 coal Substances 0.000 claims description 31
- 239000000463 material Substances 0.000 claims description 27
- 239000007787 solid Substances 0.000 claims description 26
- 229910052717 sulfur Inorganic materials 0.000 claims description 25
- 239000011593 sulfur Substances 0.000 claims description 24
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 22
- 239000007788 liquid Substances 0.000 claims description 21
- 239000002904 solvent Substances 0.000 claims description 21
- 239000012263 liquid product Substances 0.000 claims description 13
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 12
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 10
- 239000000852 hydrogen donor Substances 0.000 claims description 10
- 239000003208 petroleum Substances 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 7
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 6
- 150000008041 alkali metal carbonates Chemical class 0.000 claims description 6
- 229910052977 alkali metal sulfide Inorganic materials 0.000 claims description 5
- 239000007795 chemical reaction product Substances 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 239000000047 product Substances 0.000 description 42
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 27
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 20
- 239000003054 catalyst Substances 0.000 description 18
- 239000007858 starting material Substances 0.000 description 18
- 238000005984 hydrogenation reaction Methods 0.000 description 16
- 239000003610 charcoal Substances 0.000 description 14
- 239000007789 gas Substances 0.000 description 14
- 238000012360 testing method Methods 0.000 description 14
- 239000003921 oil Substances 0.000 description 13
- 239000000284 extract Substances 0.000 description 12
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 12
- 239000002956 ash Substances 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- 238000009835 boiling Methods 0.000 description 8
- 238000000926 separation method Methods 0.000 description 8
- 238000004821 distillation Methods 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000012074 organic phase Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000011592 zinc chloride Substances 0.000 description 6
- 235000005074 zinc chloride Nutrition 0.000 description 6
- 150000002431 hydrogen Chemical class 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 239000012265 solid product Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 4
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000003575 carbonaceous material Substances 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000011295 pitch Substances 0.000 description 4
- 230000000717 retained effect Effects 0.000 description 4
- 239000011269 tar Substances 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 239000010779 crude oil Substances 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000003502 gasoline Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- -1 zinc halide Chemical class 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 230000009969 flowable effect Effects 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910000000 metal hydroxide Inorganic materials 0.000 description 2
- 150000004692 metal hydroxides Chemical class 0.000 description 2
- 229910052976 metal sulfide Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- 238000005504 petroleum refining Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- HQDYNFWTFJFEPR-UHFFFAOYSA-N 1,2,3,3a-tetrahydropyrene Chemical class C1=C2CCCC(C=C3)C2=C2C3=CC=CC2=C1 HQDYNFWTFJFEPR-UHFFFAOYSA-N 0.000 description 1
- YMLBMIKSAYQNNI-UHFFFAOYSA-N 1,2,3,4-tetrahydrochrysene Chemical compound C1=CC2=CC=CC=C2C(C=C2)=C1C1=C2CCCC1 YMLBMIKSAYQNNI-UHFFFAOYSA-N 0.000 description 1
- TVOQZJIIVKIKQU-UHFFFAOYSA-N 1,2-dihydrochrysene Chemical compound C1=CC=C2C3=CC=C4CCC=CC4=C3C=CC2=C1 TVOQZJIIVKIKQU-UHFFFAOYSA-N 0.000 description 1
- NDVAMUMVOJRAJV-UHFFFAOYSA-N 10h-phenanthren-9-one Chemical compound C1=CC=C2C(=O)CC3=CC=CC=C3C2=C1 NDVAMUMVOJRAJV-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910001508 alkali metal halide Inorganic materials 0.000 description 1
- 150000008045 alkali metal halides Chemical class 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229960004217 benzyl alcohol Drugs 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000010883 coal ash Substances 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- INPLXZPZQSLHBR-UHFFFAOYSA-N cobalt(2+);sulfide Chemical compound [S-2].[Co+2] INPLXZPZQSLHBR-UHFFFAOYSA-N 0.000 description 1
- QUEGLSKBMHQYJU-UHFFFAOYSA-N cobalt;oxomolybdenum Chemical compound [Mo].[Co]=O QUEGLSKBMHQYJU-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000012084 conversion product Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- XXPBFNVKTVJZKF-UHFFFAOYSA-N dihydrophenanthrene Natural products C1=CC=C2CCC3=CC=CC=C3C2=C1 XXPBFNVKTVJZKF-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- XLNZHTHIPQGEMX-UHFFFAOYSA-N ethane propane Chemical compound CCC.CCC.CC.CC XLNZHTHIPQGEMX-UHFFFAOYSA-N 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000011339 hard pitch Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Substances OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 150000002816 nickel compounds Chemical class 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000004525 petroleum distillation Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 239000011338 soft pitch Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 1
- 238000005486 sulfidation Methods 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 229910001930 tungsten oxide Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
- C10G1/065—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation in the presence of a solvent
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
- C10G1/086—Characterised by the catalyst used
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/718,731 US4092236A (en) | 1976-08-30 | 1976-08-30 | Molten salt hydroconversion process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2739078A1 true DE2739078A1 (de) | 1978-03-02 |
Family
ID=24887270
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19772739078 Withdrawn DE2739078A1 (de) | 1976-08-30 | 1977-08-30 | Verfahren zur umwandlung von kohlenwasserstoffen |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4092236A (enExample) |
| JP (1) | JPS5329307A (enExample) |
| CA (1) | CA1089385A (enExample) |
| DE (1) | DE2739078A1 (enExample) |
| FR (1) | FR2362915A1 (enExample) |
| GB (1) | GB1589423A (enExample) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4191628A (en) * | 1978-10-12 | 1980-03-04 | The United States Of America As Represented By The United States Department Of Energy | Process for removal of mineral particulates from coal-derived liquids |
| DE3047050A1 (de) | 1980-12-13 | 1982-07-29 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe | Verfahren zur hydrierung von kohle |
| US5085764A (en) * | 1981-03-31 | 1992-02-04 | Trw Inc. | Process for upgrading coal |
| US4545891A (en) * | 1981-03-31 | 1985-10-08 | Trw Inc. | Extraction and upgrading of fossil fuels using fused caustic and acid solutions |
| US5059307A (en) * | 1981-03-31 | 1991-10-22 | Trw Inc. | Process for upgrading coal |
| US4421631A (en) * | 1981-10-02 | 1983-12-20 | Rockwell International Corporation | Hydrocarbon treatment process |
| US4437980A (en) | 1982-07-30 | 1984-03-20 | Rockwell International Corporation | Molten salt hydrotreatment process |
| US4671324A (en) * | 1982-09-01 | 1987-06-09 | Neill David C | Jack bolt assembly |
| US4540199A (en) * | 1982-09-01 | 1985-09-10 | Neill David C | Jack bolt assembly |
| JPH07108984B2 (ja) * | 1985-04-01 | 1995-11-22 | 三菱化学株式会社 | 重質石炭液化物の水素化分解方法 |
| ES2163873T3 (es) * | 1997-06-12 | 2002-02-01 | Pac Holding Sa | Procedimiento de eliminacion de desechos halogenados y/o que contienen hidrocarburos. |
| US5954949A (en) * | 1998-03-25 | 1999-09-21 | Unipure Corporation | Conversion of heavy petroleum oils to coke with a molten alkali metal hydroxide |
| US7520909B2 (en) * | 2004-06-03 | 2009-04-21 | Rogers Family Revocable Living Trust | Low temperature methods for hydrogen production |
| US8226816B2 (en) * | 2006-05-24 | 2012-07-24 | West Virginia University | Method of producing synthetic pitch |
| DE102006040662B3 (de) * | 2006-08-30 | 2008-03-27 | Pac Holding S.A. | Verfahren und Vorrichtung zur Verwertung von sauerstoffhaltigen Polymeren |
| US8512551B2 (en) | 2007-05-24 | 2013-08-20 | West Virginia University | Forming cement as a by-product of coal liquefaction |
| US8597382B2 (en) | 2007-05-24 | 2013-12-03 | West Virginia University | Rubber material in coal liquefaction |
| US8465561B2 (en) | 2007-05-24 | 2013-06-18 | West Virginia University | Hydrogenated vegetable oil in coal liquefaction |
| US8449632B2 (en) | 2007-05-24 | 2013-05-28 | West Virginia University | Sewage material in coal liquefaction |
| US9200213B2 (en) * | 2008-03-24 | 2015-12-01 | Baker Hughes Incorporated | Method for reducing acids in crude or refined hydrocarbons |
| US8309049B2 (en) | 2009-10-19 | 2012-11-13 | Battelle Energy Alliance, Llc | Molten metal reactor and method of forming hydrogen, carbon monoxide and carbon dioxide using the molten alkaline metal reactor |
| US9216401B2 (en) | 2011-07-21 | 2015-12-22 | Battelle Energy Alliance Llc | Bell column downtube, reactors utilizing same and related methods |
| US9187325B2 (en) | 2011-07-21 | 2015-11-17 | Battelle Energy Alliance Llc | Molten salt rolling bubble column, reactors utilizing same and related methods |
| US8685281B2 (en) | 2011-07-21 | 2014-04-01 | Battelle Energy Alliance Llc | System and process for the production of syngas and fuel gasses |
| US9114984B2 (en) * | 2012-06-25 | 2015-08-25 | Battelle Energy Alliance Llc | System and process for upgrading hydrocarbons |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2768935A (en) * | 1952-06-11 | 1956-10-30 | Universal Oil Prod Co | Process and apparatus for the conversion of hydrocarbonaceous substances in a molten medium |
| US3679577A (en) * | 1968-11-29 | 1972-07-25 | Shell Oil Co | Molten salt hydrofining process |
| US3745109A (en) * | 1970-10-01 | 1973-07-10 | North American Rockwell | Hydrocarbon conversion process |
| US3708270A (en) * | 1970-10-01 | 1973-01-02 | North American Rockwell | Pyrolysis method |
| US3677932A (en) * | 1971-03-12 | 1972-07-18 | Shell Oil Co | Molten salt hydroconversion process |
| US3779722A (en) * | 1972-02-23 | 1973-12-18 | D Tatum | Process for desulfurizing fuel |
| US3966582A (en) * | 1974-10-07 | 1976-06-29 | Clean Energy Corporation | Solubilization and reaction of coal and like carbonaceous feedstocks to hydrocarbons and apparatus therefor |
| US4003823A (en) * | 1975-04-28 | 1977-01-18 | Exxon Research And Engineering Company | Combined desulfurization and hydroconversion with alkali metal hydroxides |
-
1976
- 1976-08-30 US US05/718,731 patent/US4092236A/en not_active Expired - Lifetime
-
1977
- 1977-07-14 CA CA282,702A patent/CA1089385A/en not_active Expired
- 1977-08-09 GB GB33379/77A patent/GB1589423A/en not_active Expired
- 1977-08-29 JP JP10276977A patent/JPS5329307A/ja active Pending
- 1977-08-30 DE DE19772739078 patent/DE2739078A1/de not_active Withdrawn
- 1977-08-30 FR FR7726394A patent/FR2362915A1/fr active Granted
Non-Patent Citations (1)
| Title |
|---|
| NICHTS-ERMITTELT * |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2362915A1 (fr) | 1978-03-24 |
| FR2362915B1 (enExample) | 1984-05-25 |
| CA1089385A (en) | 1980-11-11 |
| JPS5329307A (en) | 1978-03-18 |
| GB1589423A (en) | 1981-05-13 |
| US4092236A (en) | 1978-05-30 |
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