DE2712980C2 - Galvanische Zelle mit einem Metall-Brom-Paar sowie Verfahren zum Betrieb dieser galvanischen Zelle - Google Patents

Galvanische Zelle mit einem Metall-Brom-Paar sowie Verfahren zum Betrieb dieser galvanischen Zelle

Info

Publication number
DE2712980C2
DE2712980C2 DE2712980A DE2712980A DE2712980C2 DE 2712980 C2 DE2712980 C2 DE 2712980C2 DE 2712980 A DE2712980 A DE 2712980A DE 2712980 A DE2712980 A DE 2712980A DE 2712980 C2 DE2712980 C2 DE 2712980C2
Authority
DE
Germany
Prior art keywords
galvanic cell
bromine
cell
metal
zinc
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE2712980A
Other languages
English (en)
Other versions
DE2712980A1 (de
Inventor
Augustin F. Berkeley Heights N.J. Venero
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of DE2712980A1 publication Critical patent/DE2712980A1/de
Application granted granted Critical
Publication of DE2712980C2 publication Critical patent/DE2712980C2/de
Expired legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
    • H01M10/365—Zinc-halogen accumulators
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hybrid Cells (AREA)
  • Inert Electrodes (AREA)

Description

Zn —· Zn" + 2e

Claims (1)

  1. Es wurden bereits galvanische Zellen vorgeschlagen, die eine Elektrode mit einem hohen positiven oxldlerenden Potential und eine weitere Elektrode mit einem stark negativen oder reduzierenden Potential besitzen.
    Typisch für derartige Zellen ist die Metall/Halogen-Zelle, deren Anodenmaterial üblicherweise aus Zink besteht.
    wahrend das Halogen der Kathode Brom Ist. Zu den Vorteilen dieser Zellen gehört Ihre hohe theoretische Ener gledlchte. Eine Zlnk/Brom-Zeüe besitzt beispielsweise eine theoretische Energiedichte von 440 Wh/kg und ein elektrisches Potential von etwa 1,85 Volt pro Zelle. In einer derartigen Zelle wird die Oberfläche der Metallanode, z. B. des Zinks, oxidiert, wobei die Wertigkeit zunimmt. Als Ergebnis werden die Zinkatome gemäß folgender Gleichung
DE2712980A 1976-04-07 1977-03-24 Galvanische Zelle mit einem Metall-Brom-Paar sowie Verfahren zum Betrieb dieser galvanischen Zelle Expired DE2712980C2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/674,583 US4105829A (en) 1976-04-07 1976-04-07 Metal halogen batteries and method of operating same

Publications (2)

Publication Number Publication Date
DE2712980A1 DE2712980A1 (de) 1977-10-20
DE2712980C2 true DE2712980C2 (de) 1985-05-09

Family

ID=24707172

Family Applications (1)

Application Number Title Priority Date Filing Date
DE2712980A Expired DE2712980C2 (de) 1976-04-07 1977-03-24 Galvanische Zelle mit einem Metall-Brom-Paar sowie Verfahren zum Betrieb dieser galvanischen Zelle

Country Status (7)

Country Link
US (1) US4105829A (de)
JP (1) JPS6059708B2 (de)
BE (1) BE853254A (de)
CA (1) CA1096937A (de)
DE (1) DE2712980C2 (de)
FR (1) FR2347787A1 (de)
GB (1) GB1569398A (de)

Families Citing this family (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1129945A (en) * 1977-09-30 1982-08-17 Henry F. Gibbard Complexing agents for zinc bromine storage systems
US4206269A (en) * 1978-12-06 1980-06-03 Electric Power Research Institute, Inc. Metal-halogen battery assembly and method of operation
US4631240A (en) * 1978-12-13 1986-12-23 Tracer Technologies, Inc. Electrochemical cell
US4592971A (en) * 1978-12-13 1986-06-03 Tracer Technologies, Inc. Metal halogen electrochemical cell
US4251568A (en) * 1979-08-27 1981-02-17 Energy Development Associates, Inc. Method of storing electrical energy
US4377623A (en) * 1980-07-29 1983-03-22 Anumin Pty. Ltd. Electro-chemical cells
CA1174729A (en) * 1981-06-01 1984-09-18 Patrick G. Grimes Electrochemical construction
US4346150A (en) * 1981-06-01 1982-08-24 Exxon Research & Engineering Co. Electrochemical construction
US4400448A (en) * 1981-06-01 1983-08-23 Exxon Research And Engineering Co. Electrochemical construction
US4469760A (en) * 1981-09-08 1984-09-04 Electric Power Research, Institute Redox battery including a bromine positive electrode and a chromium ion negative electrode, and method
US4521359A (en) * 1981-12-04 1985-06-04 Exxon Research & Engineering Co. Method of coextruding plastics to form a composite sheet
EP0091521B1 (de) * 1982-04-14 1986-12-03 Kabushiki Kaisha Meidensha Metall-Brom Sekundärelement
US4475282A (en) * 1982-04-30 1984-10-09 Exxon Research & Engineering Co. Method of constructing an improved electrochemical cell
US4534833A (en) * 1982-05-03 1985-08-13 Energy Development Associates, Inc. Zinc-chloride battery in a chlorine producing/consuming plant
EP0109223B1 (de) * 1982-11-02 1987-07-22 Kabushiki Kaisha Meidensha Meidensha Electric Mfg. Co., Ltd. Elektrolyt für Zink-Brom-Speicherbatterien
EP0116918A3 (de) * 1983-02-11 1986-03-19 Energy Research Corporation Metall-Halogen-Zellsystem
JPS59186280A (ja) * 1983-04-06 1984-10-23 Meidensha Electric Mfg Co Ltd 亜鉛−臭素電池の電解液中の臭素錯化剤の管理方法
JPS59214173A (ja) * 1983-05-20 1984-12-04 Meidensha Electric Mfg Co Ltd 亜鉛−臭素電池のセパレ−タ
CA1222281A (en) * 1983-06-17 1987-05-26 Yasuo Ando Secondary battery having the separator
US4491625A (en) * 1984-03-26 1985-01-01 Exxon Research & Engineering Co. Zinc-bromine batteries with improved electrolyte
CA1244078A (en) * 1984-06-06 1988-11-01 Takafumi Hashimoto Metal-halogen secondary battery
JPS60264061A (ja) * 1984-06-12 1985-12-27 Meidensha Electric Mfg Co Ltd 亜鉛一臭素電池
US4677039A (en) * 1984-12-27 1987-06-30 Toyota Jidosha Kabushiki Kaisha Zinc-bromine battery
JPS61156643A (ja) * 1984-12-27 1986-07-16 Toyota Motor Corp 亜鉛−臭素電池
JPS61156641A (ja) * 1984-12-27 1986-07-16 Toyota Motor Corp 亜鉛−臭素電池
US4818642A (en) * 1986-03-03 1989-04-04 Exxon Research And Engineering Company Electrolyte additive for improved battery performance
CA1278825C (en) * 1986-03-03 1991-01-08 Richard J. Bellows Metal halogen electrochemical cell
US4637968A (en) * 1986-03-07 1987-01-20 Exxon Research And Engineering Company Solid bromine complexers
US4748095A (en) * 1987-03-06 1988-05-31 Nagakazu Furuya Halogen cell
US5173362A (en) * 1991-02-01 1992-12-22 Globe-Union, Inc. Composite substrate for bipolar electrodes
AT398142B (de) * 1991-05-24 1994-09-26 Elin Energieanwendung Verfahren zur bestimmung des ladezustandes einer zink-brom-batterie sowie verfahren zum laden derselben
US5543243A (en) * 1993-12-01 1996-08-06 Trojan Battery Company Battery electrolyte circulation system
US5389459A (en) * 1994-01-14 1995-02-14 Hall; John C. Distributed energy system
US5952117A (en) * 1996-10-24 1999-09-14 Metallic Power, Inc. Method and apparatus for refueling an electrochemical power source
US5869200A (en) * 1997-08-12 1999-02-09 Sunsave, Inc. Magnetic slurry fueled battery system
FR2770339B1 (fr) 1997-10-27 2003-06-13 Commissariat Energie Atomique Structure munie de contacts electriques formes a travers le substrat de cette structure et procede d'obtention d'une telle structure
US20030035984A1 (en) 2001-08-15 2003-02-20 Colborn Jeffrey A. Metal fuel cell system for providing backup power to one or more loads
US6689711B2 (en) 2001-10-09 2004-02-10 Metallic Power, Inc. Methods of producing oxygen reduction catalyst
US6911274B1 (en) 2001-10-19 2005-06-28 Metallic Power, Inc. Fuel cell system
US6679280B1 (en) 2001-10-19 2004-01-20 Metallic Power, Inc. Manifold for fuel cell system
US6873157B2 (en) * 2002-04-04 2005-03-29 Metallic Power, Inc. Method of and system for determining the remaining energy in a metal fuel cell
US6764588B2 (en) * 2002-05-17 2004-07-20 Metallic Power, Inc. Method of and system for flushing one or more cells in a particle-based electrochemical power source in standby mode
US6942105B2 (en) * 2002-05-17 2005-09-13 Metallic Power, Inc. In-line filtration for a particle-based electrochemical power system
AU2004258144B2 (en) * 2003-07-09 2009-12-03 Largo Clean Energy Corp. Device for monitoring and charging of a selected group of battery cells
IL250456A0 (en) * 2014-08-20 2017-03-30 Albemarle Corp Quaternary ammonium halides with functional ether groups for use as battery electrolytes
WO2017132348A1 (en) 2016-01-27 2017-08-03 Ensync, Inc. Improved electrolyte system for rechargeable flow battery
WO2017132346A1 (en) * 2016-01-27 2017-08-03 Ensync, Inc. Zinc complex compounds for rechargeable flow battery
GB2616988B (en) 2023-03-01 2024-05-08 Offgrid Energy Labs Private Ltd Electrolyte for ultra efficient static zinc-based battery

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2566114A (en) * 1945-08-01 1951-08-28 Bloch Rudolf Electric cell
GB1083922A (en) * 1964-04-14 1967-09-20 Mifalei Yam Hamelah Electric cells
CH509672A (it) * 1969-04-23 1971-06-30 Consiglio Nazionale Ricerche Elettrodo per accumulatori elettrici a alogenuro di zinco in elettrolita acquoso del tipo a catodo solubile ed anodo disciolto
FR2079744A5 (en) * 1970-02-11 1971-11-12 Accumulateurs Fixes Non aqueous electrolyte for lithium halide cells - contg tetrachloraluminate and quaternary ammonium aluminate in thiony
US3935024A (en) * 1970-06-26 1976-01-27 Energy Development Associates Halogen hydrates
CH554078A (fr) * 1971-08-31 1974-09-13 Consiglio Nazionale Ricerche Accumulateur electrique.
US3816177A (en) * 1972-11-17 1974-06-11 Eco Control Secondary cells and batteries
US3929506A (en) * 1973-05-18 1975-12-30 Dow Chemical Co Zinc-bromide secondary cell
US4038460A (en) * 1976-03-17 1977-07-26 Eco-Control, Inc. Halogen complexing ethers
US4038459A (en) * 1976-03-17 1977-07-26 Eco-Control, Inc. Halogen complexing alcohols and nitriles

Also Published As

Publication number Publication date
CA1096937A (en) 1981-03-03
JPS6059708B2 (ja) 1985-12-26
DE2712980A1 (de) 1977-10-20
GB1569398A (en) 1980-06-11
JPS52122835A (en) 1977-10-15
FR2347787B1 (de) 1982-12-03
US4105829A (en) 1978-08-08
FR2347787A1 (fr) 1977-11-04
BE853254A (fr) 1977-10-05

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8110 Request for examination paragraph 44
8120 Willingness to grant licences paragraph 23
D2 Grant after examination
8364 No opposition during term of opposition