FR2079744A5 - Non aqueous electrolyte for lithium halide cells - contg tetrachloraluminate and quaternary ammonium aluminate in thiony - Google Patents

Non aqueous electrolyte for lithium halide cells - contg tetrachloraluminate and quaternary ammonium aluminate in thiony

Info

Publication number
FR2079744A5
FR2079744A5 FR7004833A FR7004833A FR2079744A5 FR 2079744 A5 FR2079744 A5 FR 2079744A5 FR 7004833 A FR7004833 A FR 7004833A FR 7004833 A FR7004833 A FR 7004833A FR 2079744 A5 FR2079744 A5 FR 2079744A5
Authority
FR
France
Prior art keywords
aqueous electrolyte
tetrachloraluminate
thiony
contg
non aqueous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR7004833A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SAFT Societe des Accumulateurs Fixes et de Traction SA
Original Assignee
SAFT Societe des Accumulateurs Fixes et de Traction SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SAFT Societe des Accumulateurs Fixes et de Traction SA filed Critical SAFT Societe des Accumulateurs Fixes et de Traction SA
Priority to FR7004833A priority Critical patent/FR2079744A5/en
Application granted granted Critical
Publication of FR2079744A5 publication Critical patent/FR2079744A5/en
Expired legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0563—Liquid materials, e.g. for Li-SOCl2 cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/388—Halogens
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Primary Cells (AREA)

Abstract

Non aqueous electrolyte for Li anode cells comprising LiAlCl4 and NR4Cl where R = Me, Et, Pr, Bu pref. Et. dissolved in SOCl2. The concn. of LiAlCl4 plus up to 5 mol % NR4Cl is 1-2 mole/litre. The cathode is pref. sintered nickel and the separator polypropylene felt. The addition of NR4Cl neutralises any excess AlCl3 which otherwise attacks the Li anode. The electrolyte is prepared by adding AlCl3 then LiCl to SOCl2. Addition of NR4Cl may precipitate some LiCl which is filtered off.
FR7004833A 1970-02-11 1970-02-11 Non aqueous electrolyte for lithium halide cells - contg tetrachloraluminate and quaternary ammonium aluminate in thiony Expired FR2079744A5 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7004833A FR2079744A5 (en) 1970-02-11 1970-02-11 Non aqueous electrolyte for lithium halide cells - contg tetrachloraluminate and quaternary ammonium aluminate in thiony

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7004833A FR2079744A5 (en) 1970-02-11 1970-02-11 Non aqueous electrolyte for lithium halide cells - contg tetrachloraluminate and quaternary ammonium aluminate in thiony

Publications (1)

Publication Number Publication Date
FR2079744A5 true FR2079744A5 (en) 1971-11-12

Family

ID=9050456

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7004833A Expired FR2079744A5 (en) 1970-02-11 1970-02-11 Non aqueous electrolyte for lithium halide cells - contg tetrachloraluminate and quaternary ammonium aluminate in thiony

Country Status (1)

Country Link
FR (1) FR2079744A5 (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2262256A1 (en) * 1971-12-27 1973-07-26 Union Carbide Corp NON-Aqueous ELECTROCHEMICAL CELL
FR2306537A1 (en) * 1975-03-31 1976-10-29 Union Carbide Corp COIL-UP NON-AQUEOUS ELECTROCHEMICAL BATTERY
FR2347787A1 (en) * 1976-04-07 1977-11-04 Exxon Research Engineering Co HALOGEN ELECTRIC ACCUMULATOR
DE2902526A1 (en) * 1978-01-31 1979-08-02 Accumulateurs Fixes GALVANIC LITHIUM CELL WITH THIONYL CHLORIDE
FR2466106A1 (en) * 1979-09-24 1981-03-27 Duracell Int FLUID DEPOLARIZER BATTERY
EP0027029A2 (en) * 1979-10-01 1981-04-15 Medtronic, Inc. High energy-density electrochemical cell
USRE30661E (en) 1977-03-23 1981-06-30 Electrochimica Corporation Electric current producing galvanic cell
DE3114962A1 (en) * 1980-04-14 1982-02-04 Honeywell Inc., Minneapolis, Minn. ELECTROCHEMICAL CELL WITH A LITHIUM ANODE
EP0118292A2 (en) * 1983-03-02 1984-09-12 Amoco Corporation Non-aqueous electrochemical cell and electrolyte
EP0130073A2 (en) * 1983-06-27 1985-01-02 Amoco Corporation A method of enhancing and controlling the solubility of lithium salts in liquid sulfur dioxide
EP0164254A2 (en) * 1984-06-07 1985-12-11 Amoco Corporation Porous lithium electrodes and their use in nonaqueous electrochemical cells
EP0164969A2 (en) * 1984-06-07 1985-12-18 Amoco Corporation Etched metal electrodes and their use in nonaqueous electrochemical cells
US4891281A (en) * 1982-08-09 1990-01-02 Duracell Inc. Electrochemical cells having low vapor pressure complexed SO2 electrolytes
CN114497539A (en) * 2022-01-13 2022-05-13 常州大学 Water-based rechargeable battery based on copper ferrocyanide anode and phenazine organic matter cathode

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2262256A1 (en) * 1971-12-27 1973-07-26 Union Carbide Corp NON-Aqueous ELECTROCHEMICAL CELL
FR2306537A1 (en) * 1975-03-31 1976-10-29 Union Carbide Corp COIL-UP NON-AQUEOUS ELECTROCHEMICAL BATTERY
FR2347787A1 (en) * 1976-04-07 1977-11-04 Exxon Research Engineering Co HALOGEN ELECTRIC ACCUMULATOR
USRE30661E (en) 1977-03-23 1981-06-30 Electrochimica Corporation Electric current producing galvanic cell
DE2902526A1 (en) * 1978-01-31 1979-08-02 Accumulateurs Fixes GALVANIC LITHIUM CELL WITH THIONYL CHLORIDE
FR2466106A1 (en) * 1979-09-24 1981-03-27 Duracell Int FLUID DEPOLARIZER BATTERY
EP0027029A2 (en) * 1979-10-01 1981-04-15 Medtronic, Inc. High energy-density electrochemical cell
EP0027029A3 (en) * 1979-10-01 1981-04-29 Medtronic, Inc. High energy-density electrochemical cell
DE3114962A1 (en) * 1980-04-14 1982-02-04 Honeywell Inc., Minneapolis, Minn. ELECTROCHEMICAL CELL WITH A LITHIUM ANODE
US4891281A (en) * 1982-08-09 1990-01-02 Duracell Inc. Electrochemical cells having low vapor pressure complexed SO2 electrolytes
EP0118292A3 (en) * 1983-03-02 1985-12-27 Amoco Corporation Non-aqueous electrochemical cell and electrolyte
EP0118292A2 (en) * 1983-03-02 1984-09-12 Amoco Corporation Non-aqueous electrochemical cell and electrolyte
EP0130073A2 (en) * 1983-06-27 1985-01-02 Amoco Corporation A method of enhancing and controlling the solubility of lithium salts in liquid sulfur dioxide
EP0130073A3 (en) * 1983-06-27 1986-01-15 Amoco Corporation A method of enhancing and controlling the solubility of lithium salts in liquid sulfur dioxide
EP0164969A2 (en) * 1984-06-07 1985-12-18 Amoco Corporation Etched metal electrodes and their use in nonaqueous electrochemical cells
EP0164254A3 (en) * 1984-06-07 1986-12-17 Amoco Corporation Porous lithium electrodes and their use in nonaqueous electrochemical cells
EP0164969A3 (en) * 1984-06-07 1986-12-30 Amoco Corporation Etched metal electrodes and their use in nonaqueous electrochemical cells
EP0164254A2 (en) * 1984-06-07 1985-12-11 Amoco Corporation Porous lithium electrodes and their use in nonaqueous electrochemical cells
CN114497539A (en) * 2022-01-13 2022-05-13 常州大学 Water-based rechargeable battery based on copper ferrocyanide anode and phenazine organic matter cathode
CN114497539B (en) * 2022-01-13 2024-01-23 常州大学 Aqueous rechargeable battery based on copper ferrocyanide anode and phenazine organic matter cathode

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