DE2553915C2 - Verfahren zum Vernetzen von Polyvinylalkohol, Gelatine oder einem Gelatinederivat - Google Patents
Verfahren zum Vernetzen von Polyvinylalkohol, Gelatine oder einem GelatinederivatInfo
- Publication number
- DE2553915C2 DE2553915C2 DE2553915A DE2553915A DE2553915C2 DE 2553915 C2 DE2553915 C2 DE 2553915C2 DE 2553915 A DE2553915 A DE 2553915A DE 2553915 A DE2553915 A DE 2553915A DE 2553915 C2 DE2553915 C2 DE 2553915C2
- Authority
- DE
- Germany
- Prior art keywords
- gelatin
- crosslinking
- polyvinyl alcohol
- compounds
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000008273 gelatin Substances 0.000 title claims description 31
- 229920000159 gelatin Polymers 0.000 title claims description 31
- 235000019322 gelatine Nutrition 0.000 title claims description 31
- 235000011852 gelatine desserts Nutrition 0.000 title claims description 31
- 108010010803 Gelatin Proteins 0.000 title claims description 30
- 238000000034 method Methods 0.000 title claims description 18
- 238000004132 cross linking Methods 0.000 title claims description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 title claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 title claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 9
- 239000010410 layer Substances 0.000 description 21
- 239000003431 cross linking reagent Substances 0.000 description 14
- 239000000243 solution Substances 0.000 description 13
- 150000003918 triazines Chemical class 0.000 description 11
- 239000007864 aqueous solution Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- 239000000084 colloidal system Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- -1 silver halide Chemical class 0.000 description 6
- 230000008961 swelling Effects 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000004332 silver Substances 0.000 description 5
- 229910052709 silver Inorganic materials 0.000 description 5
- 239000000975 dye Substances 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 239000004848 polyfunctional curative Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000012876 carrier material Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 241001233037 catfish Species 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 150000002433 hydrophilic molecules Chemical class 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical group 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/0052—Preparation of gels
- B01J13/0065—Preparation of gels containing an organic phase
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/30—Hardeners
- G03C1/305—Hardeners containing a diazine or triazine ring
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Colloid Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB52241/74A GB1502618A (en) | 1974-12-03 | 1974-12-03 | Triazine hardening agents |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2553915A1 DE2553915A1 (de) | 1976-06-10 |
| DE2553915C2 true DE2553915C2 (de) | 1985-11-28 |
Family
ID=10463162
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2553915A Expired DE2553915C2 (de) | 1974-12-03 | 1975-12-01 | Verfahren zum Vernetzen von Polyvinylalkohol, Gelatine oder einem Gelatinederivat |
Country Status (7)
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1594143A (en) * | 1977-05-10 | 1981-07-30 | Agfa Gevaert | Hardening solutions for proteinaceous materials |
| IL63638A0 (en) * | 1980-09-16 | 1981-11-30 | Aligena Ag | Semipermeable composite membranes,their manufacture and their use |
| AU588878B2 (en) | 1985-05-31 | 1989-09-28 | Konishiroku Photo Industry Co., Ltd. | Method for forming direct positive color image |
| DE4007668A1 (de) * | 1990-03-10 | 1991-09-12 | Beiersdorf Ag | Hydrogelschaeume und verfahren zu deren herstellung |
| CN107108530B (zh) * | 2014-12-23 | 2020-12-15 | 克洛星有限公司 | 2-卤素-4,6-二烷氧基-1,3,5-三嗪的工业生产方法以及其在胺存在下的用途 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1085334B (de) * | 1959-01-31 | 1960-07-14 | Goldschmidt Ag Th | Verfahren zur Vernetzung von Polyvinylalkohol |
| US3325287A (en) * | 1963-11-26 | 1967-06-13 | Fuji Photo Film Co Ltd | Photographic gelatin hardening composition |
| DE1284290B (de) * | 1963-11-26 | 1968-11-28 | Fuji Photo Film Co Ltd | Verfahren zur Haertung photographischer Gelatineschichten |
| CH494979A (de) * | 1968-02-09 | 1970-08-15 | Ciba Geigy | Verfahren zum Härten von gelatinehaltigen, lichtempfindlichen photographischen Schichten |
| JPS4910692B1 (US06368395-20020409-C00050.png) | 1969-09-22 | 1974-03-12 | ||
| GB1311736A (en) | 1970-07-30 | 1973-03-28 | Ciba Geigy | Gelatin hardening agents |
| CH574980A5 (US06368395-20020409-C00050.png) * | 1973-03-09 | 1976-04-30 | Ciba Geigy Ag |
-
1974
- 1974-12-03 GB GB52241/74A patent/GB1502618A/en not_active Expired
-
1975
- 1975-11-07 CH CH1443175A patent/CH613218A5/xx not_active IP Right Cessation
- 1975-11-13 US US05/631,566 patent/US4076538A/en not_active Expired - Lifetime
- 1975-11-20 JP JP50138780A patent/JPS6012903B2/ja not_active Expired
- 1975-12-01 DE DE2553915A patent/DE2553915C2/de not_active Expired
- 1975-12-01 FR FR7536710A patent/FR2293240A1/fr active Granted
- 1975-12-02 BE BE162363A patent/BE836177A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| GB1502618A (en) | 1978-03-01 |
| DE2553915A1 (de) | 1976-06-10 |
| FR2293240A1 (fr) | 1976-07-02 |
| FR2293240B1 (US06368395-20020409-C00050.png) | 1978-05-12 |
| JPS5178788A (en) | 1976-07-08 |
| CH613218A5 (US06368395-20020409-C00050.png) | 1979-09-14 |
| US4076538A (en) | 1978-02-28 |
| JPS6012903B2 (ja) | 1985-04-04 |
| BE836177A (fr) | 1976-06-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| 8125 | Change of the main classification |
Ipc: C08J 3/24 |
|
| 8128 | New person/name/address of the agent |
Representative=s name: SCHWABE, H., DIPL.-ING. SANDMAIR, K., DIPL.-CHEM. |
|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |