DE2524274C3 - Verfahren zur Herstellung von Mischpolymerisaten des Äthylens - Google Patents
Verfahren zur Herstellung von Mischpolymerisaten des ÄthylensInfo
- Publication number
- DE2524274C3 DE2524274C3 DE2524274A DE2524274A DE2524274C3 DE 2524274 C3 DE2524274 C3 DE 2524274C3 DE 2524274 A DE2524274 A DE 2524274A DE 2524274 A DE2524274 A DE 2524274A DE 2524274 C3 DE2524274 C3 DE 2524274C3
- Authority
- DE
- Germany
- Prior art keywords
- ethylene
- tert
- temperature
- percent
- atm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 24
- 239000005977 Ethylene Substances 0.000 title claims description 24
- 238000000034 method Methods 0.000 title claims description 17
- 229920001577 copolymer Polymers 0.000 title claims description 11
- 238000002360 preparation method Methods 0.000 title claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 22
- 239000011541 reaction mixture Substances 0.000 claims description 20
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 claims description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 13
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 11
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 claims description 9
- 238000000926 separation method Methods 0.000 claims description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 20
- 239000010408 film Substances 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 12
- 239000000203 mixture Substances 0.000 description 11
- 239000004831 Hot glue Substances 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 239000000155 melt Substances 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 239000002253 acid Substances 0.000 description 5
- 238000003776 cleavage reaction Methods 0.000 description 5
- 150000002978 peroxides Chemical class 0.000 description 5
- 230000007017 scission Effects 0.000 description 5
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 150000002432 hydroperoxides Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 101100117236 Drosophila melanogaster speck gene Proteins 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000012442 inert solvent Substances 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 239000007870 radical polymerization initiator Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- HGXJDMCMYLEZMJ-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOOC(=O)C(C)(C)C HGXJDMCMYLEZMJ-UHFFFAOYSA-N 0.000 description 1
- KYCWTPHGKBURHV-UHFFFAOYSA-N 2-n-tert-butyl-1,3,5-triazine-2,4,6-triamine Chemical group CC(C)(C)NC1=NC(N)=NC(N)=N1 KYCWTPHGKBURHV-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical class O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- 238000006887 Ullmann reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 150000008028 secondary esters Chemical class 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 150000008027 tertiary esters Chemical group 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polymerisation Methods In General (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2524274A DE2524274C3 (de) | 1975-05-31 | 1975-05-31 | Verfahren zur Herstellung von Mischpolymerisaten des Äthylens |
| CA252,152A CA1061942A (en) | 1975-05-31 | 1976-05-10 | Manufacture of copolymers of ethylene |
| JP51058003A JPS6011725B2 (ja) | 1975-05-31 | 1976-05-21 | エチレンの共重合体の製法 |
| GB22031/76A GB1538894A (en) | 1975-05-31 | 1976-05-27 | Manufacture of copolymers of ethylene |
| NL7605786A NL7605786A (nl) | 1975-05-31 | 1976-05-28 | Werkwijze voor de bereiding van copolymeren van etheen. |
| FR7616211A FR2313406A1 (fr) | 1975-05-31 | 1976-05-28 | Procede de preparation de copolymerisats d'ethylene |
| AT393676A AT343353B (de) | 1975-05-31 | 1976-05-28 | Verfahren zur herstellung von mischpolymerisaten des athylens |
| BE167479A BE842394A (fr) | 1975-05-31 | 1976-05-31 | Procede de preparation de copolymerisats d'ethylene |
| US05/737,719 US4122248A (en) | 1975-05-31 | 1976-11-01 | Manufacture of homogeneous ethylene/tert-butyl acrylate/acrylic acid terpolymers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2524274A DE2524274C3 (de) | 1975-05-31 | 1975-05-31 | Verfahren zur Herstellung von Mischpolymerisaten des Äthylens |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2524274A1 DE2524274A1 (de) | 1976-12-09 |
| DE2524274B2 DE2524274B2 (de) | 1980-03-13 |
| DE2524274C3 true DE2524274C3 (de) | 1987-09-10 |
Family
ID=5947971
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2524274A Expired DE2524274C3 (de) | 1975-05-31 | 1975-05-31 | Verfahren zur Herstellung von Mischpolymerisaten des Äthylens |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS6011725B2 (is) |
| AT (1) | AT343353B (is) |
| BE (1) | BE842394A (is) |
| CA (1) | CA1061942A (is) |
| DE (1) | DE2524274C3 (is) |
| FR (1) | FR2313406A1 (is) |
| GB (1) | GB1538894A (is) |
| NL (1) | NL7605786A (is) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4599392A (en) * | 1983-06-13 | 1986-07-08 | The Dow Chemical Company | Interpolymers of ethylene and unsaturated carboxylic acids |
| SE453622B (sv) * | 1983-12-08 | 1988-02-15 | Asea Ab | Halvledarkomponent for generering av optisk stralning |
| DE3404743A1 (de) * | 1984-02-10 | 1985-08-14 | Basf Ag, 6700 Ludwigshafen | Copolymerisate des ethylens mit carboxylgruppenhaltigen comonomeren |
| JPS61127709A (ja) * | 1984-11-27 | 1986-06-16 | Sumitomo Chem Co Ltd | エチレン共重合体の製造方法 |
| US5945083A (en) * | 1995-03-10 | 1999-08-31 | Kawasaki Jukogyo Kabushiki Kaisha | Process for producing iron carbide and equipment therefor |
| DE10008931A1 (de) * | 2000-02-25 | 2001-08-30 | Basf Ag | Verfahren zur Herstellung von emulgierbaren Ethylenpolymerisaten |
| JP2008050148A (ja) * | 2006-08-28 | 2008-03-06 | Kansai Kanaami Kk | 搬送ベルトおよび搬送装置 |
| US7943709B2 (en) * | 2007-03-30 | 2011-05-17 | Lg Chem, Ltd. | Copolymer comprising alkene, acrylate and unsaturated organic acid, and method for preparing the same |
| EP3181599A1 (en) * | 2015-12-18 | 2017-06-21 | Borealis AG | Novel process for producing a polar ethylene copolymer with low melt flow rate |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE591916A (is) * | 1959-06-23 | |||
| US3132120A (en) * | 1961-02-03 | 1964-05-05 | Du Pont | Method for the preparation of ethylene copolymers |
| DE1720335C3 (de) * | 1967-12-21 | 1985-01-03 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Mischpolymerisaten des Äthylens |
| DE1770777A1 (de) * | 1968-07-03 | 1971-12-02 | Basf Ag | Verfahren zum Herstellen von wachsartigen Mischpolymerisaten des AEthylens |
| DE2119047C3 (de) * | 1971-04-20 | 1978-09-14 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Mischpolymerisaten des Äthylens |
-
1975
- 1975-05-31 DE DE2524274A patent/DE2524274C3/de not_active Expired
-
1976
- 1976-05-10 CA CA252,152A patent/CA1061942A/en not_active Expired
- 1976-05-21 JP JP51058003A patent/JPS6011725B2/ja not_active Expired
- 1976-05-27 GB GB22031/76A patent/GB1538894A/en not_active Expired
- 1976-05-28 AT AT393676A patent/AT343353B/de not_active IP Right Cessation
- 1976-05-28 FR FR7616211A patent/FR2313406A1/fr active Granted
- 1976-05-28 NL NL7605786A patent/NL7605786A/xx not_active Application Discontinuation
- 1976-05-31 BE BE167479A patent/BE842394A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| NL7605786A (nl) | 1976-12-02 |
| GB1538894A (en) | 1979-01-24 |
| BE842394A (fr) | 1976-12-01 |
| DE2524274B2 (de) | 1980-03-13 |
| DE2524274A1 (de) | 1976-12-09 |
| FR2313406B1 (is) | 1980-12-19 |
| CA1061942A (en) | 1979-09-04 |
| JPS52886A (en) | 1977-01-06 |
| ATA393676A (de) | 1977-09-15 |
| FR2313406A1 (fr) | 1976-12-31 |
| JPS6011725B2 (ja) | 1985-03-27 |
| AT343353B (de) | 1978-05-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AG | Has addition no. |
Ref country code: DE Ref document number: 2617411 Format of ref document f/p: P |
|
| C3 | Grant after two publication steps (3rd publication) | ||
| AG | Has addition no. |
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