DE2420358B2 - Formmassen - Google Patents
FormmassenInfo
- Publication number
- DE2420358B2 DE2420358B2 DE2420358A DE2420358A DE2420358B2 DE 2420358 B2 DE2420358 B2 DE 2420358B2 DE 2420358 A DE2420358 A DE 2420358A DE 2420358 A DE2420358 A DE 2420358A DE 2420358 B2 DE2420358 B2 DE 2420358B2
- Authority
- DE
- Germany
- Prior art keywords
- weight
- parts
- graft
- styrene
- acrylonitrile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000000465 moulding Methods 0.000 title claims description 34
- 150000001875 compounds Chemical class 0.000 title claims description 19
- 229920000578 graft copolymer Polymers 0.000 claims description 96
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 76
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 62
- 239000002245 particle Substances 0.000 claims description 40
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 39
- 239000000203 mixture Substances 0.000 claims description 38
- 229920001577 copolymer Polymers 0.000 claims description 28
- 238000006116 polymerization reaction Methods 0.000 claims description 13
- 239000005062 Polybutadiene Substances 0.000 claims description 7
- 229920002857 polybutadiene Polymers 0.000 claims description 7
- 239000002585 base Substances 0.000 description 45
- 239000000178 monomer Substances 0.000 description 39
- 229920000638 styrene acrylonitrile Polymers 0.000 description 35
- 229920005989 resin Polymers 0.000 description 24
- 239000011347 resin Substances 0.000 description 24
- 238000006243 chemical reaction Methods 0.000 description 22
- 238000007720 emulsion polymerization reaction Methods 0.000 description 21
- 229920000126 latex Polymers 0.000 description 20
- 239000004816 latex Substances 0.000 description 16
- 238000012545 processing Methods 0.000 description 15
- 239000003995 emulsifying agent Substances 0.000 description 14
- 238000005259 measurement Methods 0.000 description 14
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 11
- 239000011159 matrix material Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 229920001971 elastomer Polymers 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 239000005060 rubber Substances 0.000 description 9
- 239000007787 solid Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 238000012662 bulk polymerization Methods 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 238000010557 suspension polymerization reaction Methods 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000012190 activator Substances 0.000 description 5
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 5
- 239000008187 granular material Substances 0.000 description 5
- 238000007373 indentation Methods 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 229920001897 terpolymer Polymers 0.000 description 4
- 238000010626 work up procedure Methods 0.000 description 4
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 3
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 description 3
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001447 alkali salts Chemical class 0.000 description 3
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 3
- 150000008052 alkyl sulfonates Chemical class 0.000 description 3
- 239000008384 inner phase Substances 0.000 description 3
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 3
- 230000000379 polymerizing effect Effects 0.000 description 3
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 2
- 238000001493 electron microscopy Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- 241000237858 Gastropoda Species 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical group CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910001869 inorganic persulfate Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- HKUFIYBZNQSHQS-UHFFFAOYSA-N n-octadecyloctadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCNCCCCCCCCCCCCCCCCCC HKUFIYBZNQSHQS-UHFFFAOYSA-N 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 150000003440 styrenes Chemical group 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003508 terpinolene derivatives Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000009757 thermoplastic moulding Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/942—Polymer derived from nitrile, conjugated diene and aromatic co-monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Priority Applications (14)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2420358A DE2420358B2 (de) | 1974-04-26 | 1974-04-26 | Formmassen |
| IN707/CAL/1975A IN143199B (enExample) | 1974-04-26 | 1975-04-08 | |
| US05/570,350 US4009226A (en) | 1974-04-26 | 1975-04-22 | Abs moulding compositions |
| GB16797/75A GB1501256A (en) | 1974-04-26 | 1975-04-23 | Moulding compositions |
| BE155710A BE828319A (fr) | 1974-04-26 | 1975-04-24 | Compositions pour moulage |
| AT315875A AT335174B (de) | 1974-04-26 | 1975-04-24 | Formmassen |
| IT49274/75A IT1035448B (it) | 1974-04-26 | 1975-04-24 | Composizioni da stampaggio |
| CA75225573A CA1049188A (en) | 1974-04-26 | 1975-04-24 | Thermoplastic moulding compositions based on abs-graft polymers |
| JP50049228A JPS50144748A (enExample) | 1974-04-26 | 1975-04-24 | |
| BR3227/75A BR7502543A (pt) | 1974-04-26 | 1975-04-25 | Composicoes para moldagem |
| ES436997A ES436997A1 (es) | 1974-04-26 | 1975-04-25 | Procedimiento para la obtencion de compuestos de moldeo. |
| NL7504969A NL7504969A (nl) | 1974-04-26 | 1975-04-25 | Werkwijze ter bereiding van vervormbare poly- meersamenstellingen, alsmede gevormde voort- brengsels, welke daaruit bestaan. |
| FR7513114A FR2268833B1 (enExample) | 1974-04-26 | 1975-04-25 | |
| CH531875A CH597306A5 (enExample) | 1974-04-26 | 1975-04-25 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2420358A DE2420358B2 (de) | 1974-04-26 | 1974-04-26 | Formmassen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2420358A1 DE2420358A1 (de) | 1975-12-11 |
| DE2420358B2 true DE2420358B2 (de) | 1980-02-07 |
Family
ID=5914096
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2420358A Ceased DE2420358B2 (de) | 1974-04-26 | 1974-04-26 | Formmassen |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US4009226A (enExample) |
| JP (1) | JPS50144748A (enExample) |
| AT (1) | AT335174B (enExample) |
| BE (1) | BE828319A (enExample) |
| BR (1) | BR7502543A (enExample) |
| CA (1) | CA1049188A (enExample) |
| CH (1) | CH597306A5 (enExample) |
| DE (1) | DE2420358B2 (enExample) |
| ES (1) | ES436997A1 (enExample) |
| FR (1) | FR2268833B1 (enExample) |
| GB (1) | GB1501256A (enExample) |
| IN (1) | IN143199B (enExample) |
| IT (1) | IT1035448B (enExample) |
| NL (1) | NL7504969A (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2420357A1 (de) * | 1974-04-26 | 1975-12-11 | Bayer Ag | Formmassen |
| DE3304544A1 (de) * | 1983-02-10 | 1984-08-16 | Bayer Ag, 5090 Leverkusen | Abs-formmassen |
Families Citing this family (73)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4243765A (en) * | 1976-12-29 | 1981-01-06 | The Dow Chemical Company | Impact-resistant polymers and rubber concentrates therefor |
| DE2818679A1 (de) * | 1978-04-27 | 1979-10-31 | Bayer Ag | Thermoplastische formmassen |
| DE2846754A1 (de) * | 1978-10-27 | 1980-05-08 | Basf Ag | Schlagzaehe thermoplastische kunststoffmassen |
| DE2901576C2 (de) * | 1979-01-17 | 1987-02-26 | Basf Ag, 6700 Ludwigshafen | Schlagzähe thermoplastische Kunststoffmassen |
| DK397681A (da) * | 1980-09-11 | 1982-03-12 | Stamicarbon | Polymert materiale |
| DE3036969A1 (de) * | 1980-10-01 | 1982-05-13 | Hoechst Ag, 6000 Frankfurt | Schutzkolloidfreie kunststoffdispersionen mit bimodaler partikelgroessenverteilung |
| JPS5817144A (ja) * | 1981-07-23 | 1983-02-01 | Mitsubishi Monsanto Chem Co | 耐衝撃性樹脂組成物 |
| US4713420A (en) * | 1982-05-21 | 1987-12-15 | The Dow Chemical Company | ABS compositions having trimodal rubber particle distributions |
| JPH068374B2 (ja) * | 1983-07-19 | 1994-02-02 | 電気化学工業株式会社 | 熱可塑性樹脂組成物 |
| DE3337940A1 (de) * | 1983-10-19 | 1985-05-09 | Bayer Ag, 5090 Leverkusen | Polymerlegierungen mit matter oberflaeche |
| US4785051A (en) * | 1983-11-21 | 1988-11-15 | The Dow Chemical Company | Rubber-modified monovinylidene aromatic polymer compositions |
| BR8407190A (pt) * | 1983-11-21 | 1985-11-05 | Dow Chemical Co | Composicoes de polimeros aromaticos de monovinilideno modificados com borracha,contendo tres tipos diferentes de particulas de borracha |
| AU584945B2 (en) * | 1984-11-30 | 1989-06-08 | Dow Chemical Company, The | Improved impact resistant polymeric compositions |
| US5210135A (en) * | 1989-08-09 | 1993-05-11 | Bayer Aktiengesellschaft | ABS moulding compounds with improved yield stress |
| US5041498A (en) * | 1990-01-02 | 1991-08-20 | The Dow Chemical Company | Trimodal ABS compositions having good gloss and reduced gloss sensitivity |
| US5574099A (en) * | 1991-03-18 | 1996-11-12 | Japan Synthetic Rubber Co., Ltd. | Rubber-reinforced styrene resin composition and process for producing the same |
| AU1836095A (en) * | 1994-02-22 | 1995-09-04 | Dow Chemical Company, The | Process for the preparation of multimodal abs polymers |
| DE4414123A1 (de) * | 1994-04-22 | 1995-10-26 | Bayer Ag | Thermoplastische Formmassen vom ABS-Typ |
| DE4441846A1 (de) | 1994-11-24 | 1996-05-30 | Bayer Ag | ABS-Formmassen mit neuartiger Morphologie |
| DE19711022A1 (de) * | 1997-03-17 | 1998-09-24 | Basf Ag | Verwendung eines Mehrstufenrührers zur Herstellung von Polymerisaten |
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| DE19941491A1 (de) | 1999-09-01 | 2001-03-15 | Bayer Ag | Thermoplastische Formmassen auf Basis bestimmter Pfropfkautschukkomponenten |
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| DE10008418A1 (de) * | 2000-02-23 | 2001-08-30 | Bayer Ag | ABS-Formmassen mit verbesserter Verarbeitbarkeit und hohem Glanz |
| DE10008420A1 (de) * | 2000-02-23 | 2001-08-30 | Bayer Ag | Polymerzusammensetzungen mit verbesserter Eigenschaftskonstanz |
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| KR100409071B1 (ko) † | 2000-07-03 | 2003-12-11 | 주식회사 엘지화학 | 열안정성이 우수한 내열성 열가소성 수지의 제조방법 |
| DE10060410A1 (de) | 2000-12-05 | 2002-06-06 | Bayer Ag | Thermoplastische Formmassen |
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| DE102005060827A1 (de) * | 2005-12-20 | 2007-06-28 | Lanxess Deutschland Gmbh | Pfropfkautschuke mit verbesserter Beständigkeit gegen thermooxidativen Abbau |
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| KR20140087879A (ko) * | 2012-12-31 | 2014-07-09 | 제일모직주식회사 | 투명 열가소성 수지 조성물 및 이로부터 형성된 성형품 |
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| KR20220003152A (ko) | 2016-09-27 | 2022-01-07 | 이네오스 스티롤루션 그룹 게엠베하 | Asa 플라스틱을 생산하는 개선된 방법 |
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| WO2019020688A1 (en) | 2017-07-26 | 2019-01-31 | Ineos Styrolution Group Gmbh | STYRENE COPOLYMER COMPOSITION HAVING ENHANCED RESIDUAL GLOSS |
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| US20230203293A1 (en) | 2020-05-29 | 2023-06-29 | Ineos Styrolution Group Gmbh | Low-density abs composites |
| WO2022074101A1 (en) | 2020-10-08 | 2022-04-14 | Ineos Styrolution Group Gmbh | Preparation of diene polymer latex of high gel content and controlled cross linking |
| ES3009096T3 (en) | 2021-02-16 | 2025-03-26 | Ineos Styrolution Group Gmbh | Process for producing a thermoplastic moulding compound comprising a thermoplastic copolymer and a graft copolymer |
| US20240174853A1 (en) | 2021-03-16 | 2024-05-30 | Ineos Styrolutjion Group Gmbh | Abs molding composition with improved surface quality for plating applications |
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| CN119403875A (zh) | 2022-04-29 | 2025-02-07 | 英力士苯领集团股份公司 | 抗紫外线性能改进的丙烯腈苯乙烯丙烯酸酯共聚物组合物 |
| EP4565632A1 (de) | 2022-08-04 | 2025-06-11 | INEOS Styrolution Group GmbH | Thermoplastische abs-formmassen mit einer guten eigenschaftskombination von verarbeitbarkeit und oberflächenqualität |
| EP4565654A1 (de) | 2022-08-04 | 2025-06-11 | INEOS Styrolution Group GmbH | Thermoplastische abs-formmasse mit guter eigenschaftskombination von verarbeitbarkeit und oberflächenqualität |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3509238A (en) * | 1966-03-21 | 1970-04-28 | Monsanto Co | Abs graft polyblends containing two graft polymers with different degrees of grafting |
| US3509237A (en) * | 1966-03-21 | 1970-04-28 | Monsanto Co | Abs graft polyblends containing two graft polymers having different particle sizes |
| JPS5522507B2 (enExample) * | 1972-09-19 | 1980-06-17 | ||
| JPS5414669B2 (enExample) * | 1973-09-03 | 1979-06-08 |
-
1974
- 1974-04-26 DE DE2420358A patent/DE2420358B2/de not_active Ceased
-
1975
- 1975-04-08 IN IN707/CAL/1975A patent/IN143199B/en unknown
- 1975-04-22 US US05/570,350 patent/US4009226A/en not_active Expired - Lifetime
- 1975-04-23 GB GB16797/75A patent/GB1501256A/en not_active Expired
- 1975-04-24 BE BE155710A patent/BE828319A/xx not_active IP Right Cessation
- 1975-04-24 AT AT315875A patent/AT335174B/de not_active IP Right Cessation
- 1975-04-24 IT IT49274/75A patent/IT1035448B/it active
- 1975-04-24 CA CA75225573A patent/CA1049188A/en not_active Expired
- 1975-04-24 JP JP50049228A patent/JPS50144748A/ja active Pending
- 1975-04-25 NL NL7504969A patent/NL7504969A/xx not_active Application Discontinuation
- 1975-04-25 FR FR7513114A patent/FR2268833B1/fr not_active Expired
- 1975-04-25 CH CH531875A patent/CH597306A5/xx not_active IP Right Cessation
- 1975-04-25 BR BR3227/75A patent/BR7502543A/pt unknown
- 1975-04-25 ES ES436997A patent/ES436997A1/es not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2420357A1 (de) * | 1974-04-26 | 1975-12-11 | Bayer Ag | Formmassen |
| DE3304544A1 (de) * | 1983-02-10 | 1984-08-16 | Bayer Ag, 5090 Leverkusen | Abs-formmassen |
Also Published As
| Publication number | Publication date |
|---|---|
| AT335174B (de) | 1977-02-25 |
| ES436997A1 (es) | 1977-01-16 |
| CH597306A5 (enExample) | 1978-03-31 |
| FR2268833A1 (enExample) | 1975-11-21 |
| US4009226A (en) | 1977-02-22 |
| IN143199B (enExample) | 1977-10-15 |
| DE2420358A1 (de) | 1975-12-11 |
| IT1035448B (it) | 1979-10-20 |
| GB1501256A (en) | 1978-02-15 |
| BE828319A (fr) | 1975-10-24 |
| ATA315875A (de) | 1976-06-15 |
| JPS50144748A (enExample) | 1975-11-20 |
| CA1049188A (en) | 1979-02-20 |
| NL7504969A (nl) | 1975-10-28 |
| FR2268833B1 (enExample) | 1979-03-16 |
| BR7502543A (pt) | 1976-03-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8235 | Patent refused |