DE235631C - - Google Patents

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Publication number

DE235631C

DE235631C DENDAT235631D DE235631DA DE235631C DE 235631 C DE235631 C DE 235631C DE NDAT235631 D DENDAT235631 D DE NDAT235631D DE 235631D A DE235631D A DE 235631DA DE 235631 C DE235631 C DE 235631C

Authority

DE

Germany

Prior art keywords

parts

blue

halogen

indigo

dihaloindigo

Prior art date

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

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• 235000000177 Indigofera tinctoria Nutrition 0.000 claims description 11
• 229910052736 halogen Inorganic materials 0.000 claims description 5
• 150000002367 halogens Chemical class 0.000 claims description 4
• 238000000034 method Methods 0.000 claims description 3
• LSNNMFCWUKXFEE-UHFFFAOYSA-M bisulfite Chemical class OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 2
• 239000003085 diluting agent Substances 0.000 claims description 2
• 150000003839 salts Chemical class 0.000 claims description 2
• 239000011780 sodium chloride Substances 0.000 claims description 2
• 239000002904 solvent Substances 0.000 claims description 2
• 240000007871 Indigofera tinctoria Species 0.000 claims 1
• 239000003795 chemical substances by application Substances 0.000 claims 1
• 241001062009 Indigofera Species 0.000 description 10
• LQNUZADURLCDLV-UHFFFAOYSA-N Nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 10
• 229940097275 Indigo Drugs 0.000 description 7
• QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
• 238000009835 boiling Methods 0.000 description 4
• 150000001875 compounds Chemical class 0.000 description 4
• 239000000203 mixture Substances 0.000 description 4
• 229960000583 Acetic Acid Drugs 0.000 description 3
• QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
• GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
• WKBOTKDWSSQWDR-UHFFFAOYSA-N bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
• 239000012362 glacial acetic acid Substances 0.000 description 3
• 238000005658 halogenation reaction Methods 0.000 description 3
• 239000000047 product Substances 0.000 description 3
• HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
• 238000003756 stirring Methods 0.000 description 3
• 150000001447 alkali salts Chemical class 0.000 description 2
• 125000004429 atoms Chemical group 0.000 description 2
• 229910052801 chlorine Inorganic materials 0.000 description 2
• 239000000460 chlorine Substances 0.000 description 2
• ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
• GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 2
• CPELXLSAUQHCOX-UHFFFAOYSA-N hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 2
• 239000011541 reaction mixture Substances 0.000 description 2
• VMHLLURERBWHNL-UHFFFAOYSA-M sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
• XTHPWXDJESJLNJ-UHFFFAOYSA-N sulfurochloridic acid Chemical compound OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 2
• 239000000725 suspension Substances 0.000 description 2
• UPKAWFACSJWKND-ZXFFUEEESA-J tetrasodium;(6E)-4-amino-6-[[4-[4-[(2Z)-2-(8-amino-1-oxo-5,7-disulfonatonaphthalen-2-ylidene)hydrazinyl]-3-methoxyphenyl]-2-methoxyphenyl]hydrazinylidene]-5-oxonaphthalene-1,3-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].C\1=CC2=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C(N)=C2C(=O)C/1=N/NC(C(OC)=C1)=CC=C1C1=CC=C(N\N=C\2C(C3=C(N)C(=CC(=C3C=C/2)S([O-])(=O)=O)S([O-])(=O)=O)=O)C(OC)=C1 UPKAWFACSJWKND-ZXFFUEEESA-J 0.000 description 2
• RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
• 229940040526 Anhydrous Sodium Acetate Drugs 0.000 description 1
• 229920000742 Cotton Polymers 0.000 description 1
• 241000854350 Enicospilus group Species 0.000 description 1
• YBBRCQOCSYXUOC-UHFFFAOYSA-N Sulfuryl chloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 description 1
• -1 atoms Halogen Chemical class 0.000 description 1
• 230000015572 biosynthetic process Effects 0.000 description 1
• 238000007664 blowing Methods 0.000 description 1
• 238000001816 cooling Methods 0.000 description 1
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
• 238000005755 formation reaction Methods 0.000 description 1
• 229910000042 hydrogen bromide Inorganic materials 0.000 description 1
• 239000003973 paint Substances 0.000 description 1
• 239000002244 precipitate Substances 0.000 description 1
• 238000010992 reflux Methods 0.000 description 1
• 230000000717 retained Effects 0.000 description 1
• 239000000344 soap Substances 0.000 description 1
• 239000001632 sodium acetate Substances 0.000 description 1
• 235000017281 sodium acetate Nutrition 0.000 description 1
• CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
• 239000007858 starting material Substances 0.000 description 1
• 238000006467 substitution reaction Methods 0.000 description 1
• HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1