DE2261778C3 - Abbaubare Polyolefinfolien - Google Patents
Abbaubare PolyolefinfolienInfo
- Publication number
- DE2261778C3 DE2261778C3 DE2261778A DE2261778A DE2261778C3 DE 2261778 C3 DE2261778 C3 DE 2261778C3 DE 2261778 A DE2261778 A DE 2261778A DE 2261778 A DE2261778 A DE 2261778A DE 2261778 C3 DE2261778 C3 DE 2261778C3
- Authority
- DE
- Germany
- Prior art keywords
- oxide
- water
- weight
- polyolefin
- month
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000098 polyolefin Polymers 0.000 title claims description 25
- 239000003381 stabilizer Substances 0.000 claims description 15
- -1 polyethylene Polymers 0.000 claims description 12
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 11
- 239000004698 Polyethylene Substances 0.000 claims description 10
- 229920000573 polyethylene Polymers 0.000 claims description 10
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims description 9
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 230000001590 oxidative effect Effects 0.000 claims description 5
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 claims description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- 229920001748 polybutylene Polymers 0.000 claims description 2
- 230000005855 radiation Effects 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims 1
- 150000003077 polyols Chemical class 0.000 claims 1
- 239000011888 foil Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000000463 material Substances 0.000 description 8
- 239000010813 municipal solid waste Substances 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 230000015556 catabolic process Effects 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- 230000032683 aging Effects 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- JAEZSIYNWDWMMN-UHFFFAOYSA-N 1,1,3-trimethylthiourea Chemical compound CNC(=S)N(C)C JAEZSIYNWDWMMN-UHFFFAOYSA-N 0.000 description 3
- PDQAZBWRQCGBEV-UHFFFAOYSA-N Ethylenethiourea Chemical compound S=C1NCCN1 PDQAZBWRQCGBEV-UHFFFAOYSA-N 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000010525 oxidative degradation reaction Methods 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229920006238 degradable plastic Polymers 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- KFFQABQEJATQAT-UHFFFAOYSA-N N,N'-dibutylthiourea Chemical compound CCCCNC(=S)NCCCC KFFQABQEJATQAT-UHFFFAOYSA-N 0.000 description 1
- 241000009328 Perro Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 241000158147 Sator Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000006701 autoxidation reaction Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910003455 mixed metal oxide Inorganic materials 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003585 thioureas Chemical group 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0033—Additives activating the degradation of the macromolecular compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
- C08K5/405—Thioureas; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S220/00—Receptacles
- Y10S220/30—Biodegradable
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S260/00—Chemistry of carbon compounds
- Y10S260/43—Promoting degradability of polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US21015271A | 1971-12-20 | 1971-12-20 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2261778A1 DE2261778A1 (de) | 1973-07-19 |
| DE2261778B2 DE2261778B2 (de) | 1975-11-27 |
| DE2261778C3 true DE2261778C3 (de) | 1982-04-29 |
Family
ID=22781781
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2261778A Expired DE2261778C3 (de) | 1971-12-20 | 1972-12-16 | Abbaubare Polyolefinfolien |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US3795654A (OSRAM) |
| JP (1) | JPS512354B2 (OSRAM) |
| AR (1) | AR198644A1 (OSRAM) |
| AU (1) | AU470234B2 (OSRAM) |
| BE (1) | BE793006A (OSRAM) |
| BR (1) | BR7208917D0 (OSRAM) |
| CA (1) | CA987429A (OSRAM) |
| CH (1) | CH556363A (OSRAM) |
| DE (1) | DE2261778C3 (OSRAM) |
| DK (1) | DK135850B (OSRAM) |
| FR (1) | FR2165605A5 (OSRAM) |
| GB (1) | GB1365989A (OSRAM) |
| IE (1) | IE37021B1 (OSRAM) |
| IT (1) | IT972532B (OSRAM) |
| NL (1) | NL156422B (OSRAM) |
| SE (1) | SE392276B (OSRAM) |
| ZA (1) | ZA728962B (OSRAM) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3896585A (en) * | 1972-08-28 | 1975-07-29 | Princeton Chemical Res Inc | Furnace or thermal black in degradable agricultural mulch |
| US3984940A (en) * | 1973-05-08 | 1976-10-12 | Murray Reich | Degradable plastic |
| JPS5431854U (OSRAM) * | 1977-08-03 | 1979-03-02 | ||
| US4519161A (en) * | 1977-09-21 | 1985-05-28 | Dan Gilead | Agricultural process using controllably degradable polymer composition film |
| US4819374A (en) * | 1979-12-13 | 1989-04-11 | Mobil Oil Corporation | Thermoplastic films for soil treatment |
| US4417008A (en) * | 1981-06-30 | 1983-11-22 | Elkem Metals Company | Improved color pigment for solvent-base paint formulations |
| US4602664A (en) * | 1983-10-17 | 1986-07-29 | Hullen George W | Method and apparatus for collecting lawn debris and package for such apparatus |
| US4786550A (en) * | 1985-05-06 | 1988-11-22 | Kimberly-Clark Corporation | Meltblown and coform materials having application as seed beds |
| US5096940A (en) * | 1989-06-07 | 1992-03-17 | Techmer Pm | Degradable polymeric compositions |
| US5096939A (en) * | 1989-06-07 | 1992-03-17 | Techmer Pm | Degradable polymeric compositions |
| US5063111A (en) * | 1990-02-05 | 1991-11-05 | Owens-Illinois Plastic Products Inc. | Degradable bottle and can carrier coated with ultraviolet absorber |
| US5066686A (en) * | 1990-07-16 | 1991-11-19 | Phillips Petroleum Company | Deodorizing odorous polyolefins with low concentrations of inorganic oxidizing agents |
| US5111933A (en) * | 1991-04-16 | 1992-05-12 | Mobil Oil Corporation | Kit providing thermally degradable compost bag |
| US5518730A (en) * | 1992-06-03 | 1996-05-21 | Fuisz Technologies Ltd. | Biodegradable controlled release flash flow melt-spun delivery system |
| EP1765309B1 (en) * | 2004-07-02 | 2009-08-05 | Radi Medical Biodegradable AB | Smokeless toabacco product |
| US20070267415A1 (en) * | 2006-05-22 | 2007-11-22 | Valenti Debra S | Disposable liner for storing and/or dispensing cooking liquids |
| US20080302682A1 (en) * | 2007-06-11 | 2008-12-11 | Radi Medical Biodegradable Ab | Pouch for tobacco or tobacco substitute |
| US20090306452A1 (en) * | 2008-05-19 | 2009-12-10 | Payne Frederick C | Apparatus for treating a contaminated media with a sorbent |
| CN101665625B (zh) * | 2008-09-03 | 2012-07-25 | 王丽红 | 塑料降解用组合物及其用途及包含其的塑料和制品 |
| CN112549718B (zh) * | 2020-12-08 | 2022-11-25 | 中国农业科学院农产品加工研究所 | 叶菜昼夜滤波衍射诱抗抑菌调代谢保鲜膜 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL129982C (OSRAM) * | 1961-08-28 | 1900-01-01 | ||
| GB1052998A (OSRAM) * | 1963-11-12 | 1966-12-30 |
-
0
- BE BE793006D patent/BE793006A/xx not_active IP Right Cessation
-
1971
- 1971-12-20 US US00210152A patent/US3795654A/en not_active Expired - Lifetime
-
1972
- 1972-12-04 CA CA157,941A patent/CA987429A/en not_active Expired
- 1972-12-16 DE DE2261778A patent/DE2261778C3/de not_active Expired
- 1972-12-18 AU AU50197/72A patent/AU470234B2/en not_active Expired
- 1972-12-19 SE SE1665772A patent/SE392276B/xx unknown
- 1972-12-19 IE IE1770/72A patent/IE37021B1/xx unknown
- 1972-12-19 DK DK633172AA patent/DK135850B/da not_active IP Right Cessation
- 1972-12-19 IT IT33133/72A patent/IT972532B/it active
- 1972-12-19 JP JP47126846A patent/JPS512354B2/ja not_active Expired
- 1972-12-19 CH CH1849872A patent/CH556363A/fr not_active IP Right Cessation
- 1972-12-19 ZA ZA728962A patent/ZA728962B/xx unknown
- 1972-12-19 FR FR7245237A patent/FR2165605A5/fr not_active Expired
- 1972-12-19 NL NL7217300.A patent/NL156422B/xx not_active IP Right Cessation
- 1972-12-19 BR BR8917/72A patent/BR7208917D0/pt unknown
- 1972-12-19 GB GB5846572A patent/GB1365989A/en not_active Expired
- 1972-12-19 AR AR245721A patent/AR198644A1/es active
Also Published As
| Publication number | Publication date |
|---|---|
| IE37021L (en) | 1973-06-20 |
| DE2261778A1 (de) | 1973-07-19 |
| FR2165605A5 (OSRAM) | 1973-08-03 |
| DK135850B (da) | 1977-07-04 |
| AR198644A1 (es) | 1974-07-15 |
| BR7208917D0 (pt) | 1973-09-13 |
| AU470234B2 (en) | 1974-06-20 |
| US3795654A (en) | 1974-03-05 |
| IE37021B1 (en) | 1977-04-13 |
| BE793006A (fr) | 1973-06-19 |
| GB1365989A (en) | 1974-09-04 |
| JPS512354B2 (OSRAM) | 1976-01-24 |
| AU5019772A (en) | 1974-06-20 |
| SE392276B (sv) | 1977-03-21 |
| NL7217300A (OSRAM) | 1973-06-22 |
| DK135850C (OSRAM) | 1977-12-27 |
| DE2261778B2 (de) | 1975-11-27 |
| NL156422B (nl) | 1978-04-17 |
| ZA728962B (en) | 1974-04-24 |
| CH556363A (fr) | 1974-11-29 |
| CA987429A (en) | 1976-04-13 |
| JPS4869847A (OSRAM) | 1973-09-21 |
| IT972532B (it) | 1974-05-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8339 | Ceased/non-payment of the annual fee |