DE2259592A1 - Verfahren zum hydrierenden entschwefeln von asphaltischen oelen - Google Patents
Verfahren zum hydrierenden entschwefeln von asphaltischen oelenInfo
- Publication number
- DE2259592A1 DE2259592A1 DE2259592A DE2259592A DE2259592A1 DE 2259592 A1 DE2259592 A1 DE 2259592A1 DE 2259592 A DE2259592 A DE 2259592A DE 2259592 A DE2259592 A DE 2259592A DE 2259592 A1 DE2259592 A1 DE 2259592A1
- Authority
- DE
- Germany
- Prior art keywords
- oil
- zone
- line
- percent
- desulfurization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003921 oil Substances 0.000 title claims description 135
- 238000000034 method Methods 0.000 title claims description 77
- 230000008569 process Effects 0.000 title claims description 53
- 230000000887 hydrating effect Effects 0.000 title claims description 8
- 230000003009 desulfurizing effect Effects 0.000 title description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 107
- 239000011593 sulfur Substances 0.000 claims description 107
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 105
- 238000006477 desulfuration reaction Methods 0.000 claims description 91
- 230000023556 desulfurization Effects 0.000 claims description 91
- 238000009835 boiling Methods 0.000 claims description 74
- 239000001257 hydrogen Substances 0.000 claims description 64
- 229910052739 hydrogen Inorganic materials 0.000 claims description 64
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 57
- 239000011347 resin Substances 0.000 claims description 53
- 229920005989 resin Polymers 0.000 claims description 53
- 125000003118 aryl group Chemical group 0.000 claims description 49
- 239000003054 catalyst Substances 0.000 claims description 47
- 239000010779 crude oil Substances 0.000 claims description 39
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 34
- 239000007789 gas Substances 0.000 claims description 33
- 239000007858 starting material Substances 0.000 claims description 33
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 16
- 238000003776 cleavage reaction Methods 0.000 claims description 16
- 230000007017 scission Effects 0.000 claims description 16
- 229920006395 saturated elastomer Polymers 0.000 claims description 15
- 230000002829 reductive effect Effects 0.000 claims description 14
- 230000000694 effects Effects 0.000 claims description 13
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 11
- 238000005984 hydrogenation reaction Methods 0.000 claims description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- NINIDFKCEFEMDL-LZFNBGRKSA-N sulfur-38 atom Chemical compound [38S] NINIDFKCEFEMDL-LZFNBGRKSA-N 0.000 claims 1
- 239000010426 asphalt Substances 0.000 description 34
- 238000001704 evaporation Methods 0.000 description 29
- 230000008020 evaporation Effects 0.000 description 29
- 241000196324 Embryophyta Species 0.000 description 24
- 229930195733 hydrocarbon Natural products 0.000 description 24
- 150000002430 hydrocarbons Chemical class 0.000 description 24
- 238000004821 distillation Methods 0.000 description 23
- 238000006243 chemical reaction Methods 0.000 description 20
- 239000007788 liquid Substances 0.000 description 17
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 15
- 238000010438 heat treatment Methods 0.000 description 14
- 239000000295 fuel oil Substances 0.000 description 13
- 239000004215 Carbon black (E152) Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 9
- 230000007423 decrease Effects 0.000 description 9
- 238000002474 experimental method Methods 0.000 description 9
- 150000002739 metals Chemical class 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- 230000036961 partial effect Effects 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 230000002349 favourable effect Effects 0.000 description 7
- 239000010763 heavy fuel oil Substances 0.000 description 7
- 150000002431 hydrogen Chemical class 0.000 description 7
- 238000000926 separation method Methods 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 229910052720 vanadium Inorganic materials 0.000 description 6
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 6
- 150000002605 large molecules Chemical class 0.000 description 5
- 229920002521 macromolecule Polymers 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- -1 nickel and vanadium Chemical class 0.000 description 5
- 239000001294 propane Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 150000003464 sulfur compounds Chemical class 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 4
- 239000003085 diluting agent Substances 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000003849 aromatic solvent Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000012634 fragment Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 238000005292 vacuum distillation Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical group [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000003502 gasoline Substances 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 230000007928 solubilization Effects 0.000 description 2
- 238000005063 solubilization Methods 0.000 description 2
- FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical class C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 150000001934 cyclohexanes Chemical class 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- IYYZUPMFVPLQIF-UHFFFAOYSA-N dibenzothiophene Chemical class C1=CC=C2C3=CC=CC=C3SC2=C1 IYYZUPMFVPLQIF-UHFFFAOYSA-N 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 101150006844 groES gene Proteins 0.000 description 1
- 239000011874 heated mixture Substances 0.000 description 1
- 238000007327 hydrogenolysis reaction Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- VMWYVTOHEQQZHQ-UHFFFAOYSA-N methylidynenickel Chemical compound [Ni]#[C] VMWYVTOHEQQZHQ-UHFFFAOYSA-N 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007614 solvation Methods 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 150000003577 thiophenes Chemical class 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Liquid Carbonaceous Fuels (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US00206078A US3814681A (en) | 1971-12-08 | 1971-12-08 | Control of asphaltic oil hydrode-sulfurization process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2259592A1 true DE2259592A1 (de) | 1973-06-14 |
Family
ID=22764884
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2259592A Pending DE2259592A1 (de) | 1971-12-08 | 1972-12-06 | Verfahren zum hydrierenden entschwefeln von asphaltischen oelen |
Country Status (11)
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3775304A (en) * | 1971-12-08 | 1973-11-27 | Gulf Research Development Co | Increasing the ratio of aromatics to saturates in hydrodesulfurization of heavy asphaltic feed oil |
| FR2356244A1 (fr) * | 1976-06-23 | 1978-01-20 | Commissariat Energie Atomique | Procede et dispositif pour detecter et prelocaliser une rupture de gaine dans un reacteur nucleaire a neutrons rapides |
| US9028674B2 (en) * | 2013-01-17 | 2015-05-12 | Lummus Technology Inc. | Conversion of asphaltenic pitch within an ebullated bed residuum hydrocracking process |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3429801A (en) * | 1965-12-06 | 1969-02-25 | Universal Oil Prod Co | Two-stage hydrorefining of asphaltene-containing oils |
-
1971
- 1971-12-08 US US00206078A patent/US3814681A/en not_active Expired - Lifetime
-
1972
- 1972-08-02 CA CA148,602A patent/CA970312A/en not_active Expired
- 1972-12-06 NL NL7216550A patent/NL7216550A/xx unknown
- 1972-12-06 DE DE2259592A patent/DE2259592A1/de active Pending
- 1972-12-06 IT IT54530/72A patent/IT973937B/it active
- 1972-12-06 PL PL1972159342A patent/PL90890B1/pl unknown
- 1972-12-07 DD DD167447A patent/DD102725A5/xx unknown
- 1972-12-07 FR FR7243516A patent/FR2162522B1/fr not_active Expired
- 1972-12-07 SU SU1855987A patent/SU511867A3/ru active
- 1972-12-08 GB GB5678672A patent/GB1414495A/en not_active Expired
- 1972-12-08 JP JP12263472A patent/JPS5547076B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| SU511867A3 (ru) | 1976-04-25 |
| JPS5547076B2 (enrdf_load_stackoverflow) | 1980-11-27 |
| PL90890B1 (enrdf_load_stackoverflow) | 1977-02-28 |
| US3814681A (en) | 1974-06-04 |
| FR2162522A1 (enrdf_load_stackoverflow) | 1973-07-20 |
| GB1414495A (en) | 1975-11-19 |
| NL7216550A (enrdf_load_stackoverflow) | 1973-06-13 |
| IT973937B (it) | 1974-06-10 |
| CA970312A (en) | 1975-07-01 |
| JPS4866107A (enrdf_load_stackoverflow) | 1973-09-11 |
| DD102725A5 (enrdf_load_stackoverflow) | 1973-12-20 |
| FR2162522B1 (enrdf_load_stackoverflow) | 1976-08-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OHW | Rejection |