DE2240516A1 - Verfahren zur herstellung formbestaendiger formkoerper mit gleichmaessig eingefaerbter glatter oberflaeche - Google Patents
Verfahren zur herstellung formbestaendiger formkoerper mit gleichmaessig eingefaerbter glatter oberflaecheInfo
- Publication number
- DE2240516A1 DE2240516A1 DE2240516A DE2240516A DE2240516A1 DE 2240516 A1 DE2240516 A1 DE 2240516A1 DE 2240516 A DE2240516 A DE 2240516A DE 2240516 A DE2240516 A DE 2240516A DE 2240516 A1 DE2240516 A1 DE 2240516A1
- Authority
- DE
- Germany
- Prior art keywords
- colored
- thermoplastic polymer
- molding compound
- polyester
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 34
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 238000000465 moulding Methods 0.000 claims description 67
- 150000001875 compounds Chemical class 0.000 claims description 43
- 229920001169 thermoplastic Polymers 0.000 claims description 41
- 229920000728 polyester Polymers 0.000 claims description 30
- 239000000843 powder Substances 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 21
- 229920006305 unsaturated polyester Polymers 0.000 claims description 20
- 238000003825 pressing Methods 0.000 claims description 13
- 239000002131 composite material Substances 0.000 claims description 9
- 229920000642 polymer Polymers 0.000 claims description 9
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 8
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 7
- 239000002033 PVDF binder Substances 0.000 claims description 5
- 239000011888 foil Substances 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 5
- 239000004800 polyvinyl chloride Substances 0.000 claims description 5
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 5
- 239000012779 reinforcing material Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 230000002787 reinforcement Effects 0.000 claims description 4
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 4
- 229920000578 graft copolymer Polymers 0.000 claims description 3
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 2
- 239000003505 polymerization initiator Substances 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 229920001225 polyester resin Polymers 0.000 claims 1
- 239000004645 polyester resin Substances 0.000 claims 1
- 230000003014 reinforcing effect Effects 0.000 claims 1
- 239000002562 thickening agent Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 description 49
- 239000011347 resin Substances 0.000 description 49
- 239000010408 film Substances 0.000 description 41
- 238000000576 coating method Methods 0.000 description 14
- 239000004416 thermosoftening plastic Substances 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 11
- 239000000975 dye Substances 0.000 description 10
- 239000000654 additive Substances 0.000 description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 238000009472 formulation Methods 0.000 description 8
- 229920005992 thermoplastic resin Polymers 0.000 description 8
- 239000003677 Sheet moulding compound Substances 0.000 description 7
- 229920001187 thermosetting polymer Polymers 0.000 description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- -1 polyethylene Polymers 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 125000005907 alkyl ester group Chemical group 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 239000004412 Bulk moulding compound Substances 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000002015 acyclic group Chemical group 0.000 description 2
- 238000009500 colour coating Methods 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 239000004414 compression moulding compound Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000013039 cover film Substances 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000007888 film coating Substances 0.000 description 2
- 238000009501 film coating Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 235000019987 cider Nutrition 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000001056 green pigment Substances 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- LYDRKKWPKKEMNZ-UHFFFAOYSA-N tert-butyl benzoate Chemical compound CC(C)(C)OC(=O)C1=CC=CC=C1 LYDRKKWPKKEMNZ-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000003260 vortexing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
- B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
- B29C70/12—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of short length, e.g. in the form of a mat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Laminated Bodies (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US17846571A | 1971-09-07 | 1971-09-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2240516A1 true DE2240516A1 (de) | 1973-03-15 |
Family
ID=22652640
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2240516A Pending DE2240516A1 (de) | 1971-09-07 | 1972-08-17 | Verfahren zur herstellung formbestaendiger formkoerper mit gleichmaessig eingefaerbter glatter oberflaeche |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3801693A (cg-RX-API-DMAC7.html) |
| JP (1) | JPS4834290A (cg-RX-API-DMAC7.html) |
| AU (1) | AU4224472A (cg-RX-API-DMAC7.html) |
| CA (1) | CA974722A (cg-RX-API-DMAC7.html) |
| DE (1) | DE2240516A1 (cg-RX-API-DMAC7.html) |
| FR (1) | FR2152516B3 (cg-RX-API-DMAC7.html) |
| IT (1) | IT952650B (cg-RX-API-DMAC7.html) |
| NL (1) | NL7208948A (cg-RX-API-DMAC7.html) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2441025C3 (de) * | 1973-08-29 | 1978-10-26 | Mitsubishi Rayon Co. Ltd., Tokio | Schwundarm härtbare ungesättigte Polyesterharzgemische und deren Verwendung für Formkörper mit verbesserter Haftfähigkeit für Überzüge |
| US4009225A (en) * | 1973-10-05 | 1977-02-22 | Armco Steel Corporation | Low profile pigmented sheet molding process and product |
| US4003368A (en) * | 1974-06-27 | 1977-01-18 | Armco Steel Corporation | Article transparent to microwaves and process for making same |
| FR2280492A1 (fr) * | 1974-07-31 | 1976-02-27 | Emery Guy | Procede et installation permettant de recuperer des matieres plastiques melangees, de toutes provenances |
| US4141929A (en) * | 1974-11-07 | 1979-02-27 | Armco Inc. | Unidirectional sheet molding composition and process of preparing same |
| US4144305A (en) * | 1975-03-14 | 1979-03-13 | Owens-Corning Fiberglas Corporation | Method of obtaining interface adhesion between thermosetting layers which contain mold release agents |
| US4043988A (en) * | 1976-01-02 | 1977-08-23 | Hooker Chemicals & Plastics Corporation | Low profile polyester molding composition |
| US4258106A (en) * | 1976-08-02 | 1981-03-24 | Owens-Corning Fiberglas Corporation | Method of obtaining interface adhesion and articles produced thereby |
| NL7803224A (nl) * | 1978-03-25 | 1979-09-27 | Stamicarbon | Sierlaag op voorwerpen uit minerale vulstoffen en een thermohardend hars. |
| EP0011132A1 (de) * | 1978-10-13 | 1980-05-28 | Metzeler Schaum Gmbh | Verfahren zur Herstellung von Formkörpern aus kaschierten Polyurethan-Hartschaumstoffplatten |
| US4568505A (en) * | 1979-10-10 | 1986-02-04 | Allied Corporation | Process to produce sheet molding compound using a polyamide release film |
| NL8203904A (nl) * | 1982-10-08 | 1984-05-01 | Synres Internationaal Nv | Bekledingspoeder. |
| US4647418A (en) * | 1982-11-12 | 1987-03-03 | Mcdougal John R | Process for the manufacture of products from reinforced polyester |
| US4624814A (en) * | 1982-11-12 | 1986-11-25 | Mcdougal John R | Process for the manufacture of products from reinforced polyester resins |
| JPS59122602U (ja) * | 1983-01-31 | 1984-08-18 | 日新電機株式会社 | 抵抗出力回路 |
| DE3819916C2 (de) * | 1988-06-11 | 1996-12-19 | Erfurt Umformtechnik Gmbh | Verfahren zur Dosierung der Materialmenge bei der Herstellung von Formteilen aus härtbaren Formmassen |
| JPH03269055A (ja) * | 1989-03-31 | 1991-11-29 | Union Carbide Chem & Plast Co Inc | 収縮抑制剤としてポリ（ビニルエーテル） |
| DE3931998A1 (de) * | 1989-09-26 | 1991-04-04 | Basf Ag | Verfahren zur herstellung von schwarz eingefaerbten, haertbaren polyesterformmassen |
| US5326516A (en) * | 1989-10-03 | 1994-07-05 | Plasticolors, Inc. | Method of preparing a cured pigmented thermosetting polymer composition exhibiting improved color values and reduced haze |
| US5443775A (en) * | 1992-05-08 | 1995-08-22 | Plasticolors, Inc. | Process for preparing pigmented thermoplastic polymer compositions and low shrinking thermosetting resin molding composition |
| GB9825066D0 (en) * | 1998-11-17 | 1999-01-13 | Ici Plc | Moulded article and moulding composition |
| EP4190844A4 (en) * | 2020-07-27 | 2024-08-21 | Toray Industries, Inc. | Fiber-reinforced plastic and production method for fiber-reinforced plastic |
-
1971
- 1971-09-07 US US00178465A patent/US3801693A/en not_active Expired - Lifetime
-
1972
- 1972-03-09 CA CA136,652A patent/CA974722A/en not_active Expired
- 1972-04-11 FR FR7212636A patent/FR2152516B3/fr not_active Expired
- 1972-04-14 IT IT49634/72A patent/IT952650B/it active
- 1972-05-12 AU AU42244/72A patent/AU4224472A/en not_active Expired
- 1972-06-28 NL NL7208948A patent/NL7208948A/xx unknown
- 1972-06-28 JP JP47064138A patent/JPS4834290A/ja active Pending
- 1972-08-17 DE DE2240516A patent/DE2240516A1/de active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| AU4224472A (en) | 1973-11-15 |
| FR2152516B3 (cg-RX-API-DMAC7.html) | 1975-06-20 |
| NL7208948A (cg-RX-API-DMAC7.html) | 1973-03-09 |
| FR2152516A1 (cg-RX-API-DMAC7.html) | 1973-04-27 |
| CA974722A (en) | 1975-09-23 |
| JPS4834290A (cg-RX-API-DMAC7.html) | 1973-05-17 |
| IT952650B (it) | 1973-07-30 |
| US3801693A (en) | 1974-04-02 |
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