DE2226998C2 - Verfahren zum Herstellen einer ausgehärteten unschmelzbaren Phenolharzfaser - Google Patents
Verfahren zum Herstellen einer ausgehärteten unschmelzbaren PhenolharzfaserInfo
- Publication number
- DE2226998C2 DE2226998C2 DE19722226998 DE2226998A DE2226998C2 DE 2226998 C2 DE2226998 C2 DE 2226998C2 DE 19722226998 DE19722226998 DE 19722226998 DE 2226998 A DE2226998 A DE 2226998A DE 2226998 C2 DE2226998 C2 DE 2226998C2
- Authority
- DE
- Germany
- Prior art keywords
- fibers
- phenolic resin
- elongation
- fiber
- cured
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000835 fiber Substances 0.000 title claims description 112
- 229920001568 phenolic resin Polymers 0.000 title claims description 42
- 239000005011 phenolic resin Substances 0.000 title claims description 41
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 title claims description 38
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- 229920003986 novolac Polymers 0.000 claims description 14
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 14
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 8
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 15
- 239000007788 liquid Substances 0.000 description 12
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- 238000009835 boiling Methods 0.000 description 8
- -1 methylol groups Chemical group 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 230000008961 swelling Effects 0.000 description 7
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 5
- 229920003987 resole Polymers 0.000 description 5
- 229920006240 drawn fiber Polymers 0.000 description 4
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 4
- 229920003002 synthetic resin Polymers 0.000 description 4
- 239000000057 synthetic resin Substances 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000032050 esterification Effects 0.000 description 3
- 238000005886 esterification reaction Methods 0.000 description 3
- 238000006266 etherification reaction Methods 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229930040373 Paraformaldehyde Natural products 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000021736 acetylation Effects 0.000 description 2
- 238000006640 acetylation reaction Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000004312 hexamethylene tetramine Substances 0.000 description 2
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 2
- 229920002866 paraformaldehyde Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000004848 polyfunctional curative Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- AVQQQNCBBIEMEU-UHFFFAOYSA-N 1,1,3,3-tetramethylurea Chemical compound CN(C)C(=O)N(C)C AVQQQNCBBIEMEU-UHFFFAOYSA-N 0.000 description 1
- 239000004953 Aliphatic polyamide Substances 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 241000251730 Chondrichthyes Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- WETWJCDKMRHUPV-UHFFFAOYSA-N acetyl chloride Chemical compound CC(Cl)=O WETWJCDKMRHUPV-UHFFFAOYSA-N 0.000 description 1
- 239000012346 acetyl chloride Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000010933 acylation Effects 0.000 description 1
- 238000005917 acylation reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229920003231 aliphatic polyamide Polymers 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- DENRZWYUOJLTMF-UHFFFAOYSA-N diethyl sulfate Chemical compound CCOS(=O)(=O)OCC DENRZWYUOJLTMF-UHFFFAOYSA-N 0.000 description 1
- 229940008406 diethyl sulfate Drugs 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/76—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from other polycondensation products
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14904571A | 1971-06-01 | 1971-06-01 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2226998A1 DE2226998A1 (de) | 1973-01-04 |
| DE2226998C2 true DE2226998C2 (de) | 1985-02-21 |
Family
ID=22528557
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19722226998 Expired DE2226998C2 (de) | 1971-06-01 | 1972-06-02 | Verfahren zum Herstellen einer ausgehärteten unschmelzbaren Phenolharzfaser |
Country Status (5)
| Country | Link |
|---|---|
| JP (2) | JPS519408B1 (enExample) |
| CA (1) | CA1020720A (enExample) |
| DE (1) | DE2226998C2 (enExample) |
| FR (1) | FR2140128B1 (enExample) |
| GB (1) | GB1385503A (enExample) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109610045B (zh) * | 2018-08-23 | 2021-09-21 | 成都市宏智达科技有限公司 | 一种耐高温、高强度碳化硅纤维的制备方法 |
| WO2021153178A1 (ja) * | 2020-01-30 | 2021-08-05 | 株式会社クラレ | 非晶性エポキシ系繊維、繊維構造体および成形体 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2376511A (en) * | 1941-05-23 | 1945-05-22 | Chrysler Corp | Method of making synthetic resin yarn |
| US3412862A (en) * | 1967-09-07 | 1968-11-26 | Merle P. Chaplin | Method and apparatus for cleaning areas overlain by a water body |
| US3650102A (en) * | 1968-03-04 | 1972-03-21 | Carborundum Co | Fibers from novolacs |
-
1971
- 1971-12-07 JP JP46098384A patent/JPS519408B1/ja active Pending
-
1972
- 1972-05-16 CA CA142,332A patent/CA1020720A/en not_active Expired
- 1972-05-23 GB GB2409872A patent/GB1385503A/en not_active Expired
- 1972-05-31 FR FR7219503A patent/FR2140128B1/fr not_active Expired
- 1972-06-02 DE DE19722226998 patent/DE2226998C2/de not_active Expired
-
1974
- 1974-12-11 JP JP14162774A patent/JPS5130164B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2140128B1 (enExample) | 1977-12-23 |
| JPS5130164B2 (enExample) | 1976-08-30 |
| JPS50142815A (enExample) | 1975-11-17 |
| GB1385503A (en) | 1975-02-26 |
| FR2140128A1 (enExample) | 1973-01-12 |
| JPS519408B1 (enExample) | 1976-03-26 |
| CA1020720A (en) | 1977-11-15 |
| DE2226998A1 (de) | 1973-01-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE1910419C3 (de) | Novolak-Fasern und Verfahren zu ihrer Herstellung | |
| DE3023726C2 (de) | Verfahren zur Herstellung von Filamenten | |
| DE2839167C2 (de) | Kohlenstoff-Kohlenstoff-Verbundmaterial und Verfahren zu seiner Herstellung | |
| DE69025789T2 (de) | Polyvinylalkoholfaser und Verfahren zu deren Herstellung | |
| DE2214281C3 (de) | Phenolharzfaser mit verbesserten Beständigkeiten und Verfahren zu ihrer Herstellung | |
| US7445834B2 (en) | Polypropylene fiber for reinforcement of matrix materials | |
| DE68917190T2 (de) | Polyvinylalkoholfaser mit ausgezeichnetem Widerstand gegen heisses Wasser und Verfahren zur Herstellung derselben. | |
| DE2227003C3 (de) | Verfahren zur Herstellung einer unschmelzbaren gehärteten Faser aus modifizierten Phenolharz | |
| DE2226998C2 (de) | Verfahren zum Herstellen einer ausgehärteten unschmelzbaren Phenolharzfaser | |
| DE2211437C3 (de) | Flammfester Endlosfaden und Verfahren zu seiner Herstellung | |
| DE2524609A1 (de) | Temperaturbestaendiges gewebe | |
| EP1705269B1 (de) | Aus einem Polyhydroxyether enthaltenden Rohstoff gesponnenes thermoplastisches Fasermaterial, Verfahren zu seiner Herstellung und Verwendungen dafür | |
| DE69300989T2 (de) | Vinylalkoholeinheiten enthaltende Polymerfaser mit Widerstandsfähigkeit gegenüber heissem Wasser und heisser Feuchtigkeit sowie Verfahren zu ihrer Herstellung | |
| DE2246572C2 (de) | Verfahren zum Herstellen einer Kohlenstoffaser | |
| DE2308827A1 (de) | Hohlfaden und verfahren zu seiner herstellung | |
| DE3854253T2 (de) | Polyvinylalkoholfasern mit dünnem Querschnitt und Anwendung für verstärkte Artikel. | |
| DE1809758A1 (de) | Verfahren zur Behandlung von Kohlenstoffasern zur Verbesserung ihrer Verarbeitbarkeit insbesondere zu kohlefaserverstaerkten Kunststoffen | |
| US4207408A (en) | High tenacity phenolic resin fibers | |
| DE68918002T2 (de) | Siliciumcarbidfaser und Verfahren zu ihrer Herstellung. | |
| EP1403405A2 (de) | Endlosfäden mit hoher Dimensionssabilität, Hydrolysebeständigkeit und Flammfestigkeit | |
| DE2446751A1 (de) | Verfahren zur herstellung verbesserter celluloseacetat-fasern | |
| DD255957B5 (de) | Verfahren zur herstellung von acrylfasern fuer den einsatz in hydraulischen bindern | |
| DE2308828B2 (de) | Verfahren zur Herstellung von gehärteten Phenolharzfäden mit verbesserter Verstreckbarkeit | |
| DE1494637A1 (de) | Verfahren zur Herstellung von Polyvinylalkoholsynthesefaeden | |
| WO1992012287A1 (de) | Verfahren zur herstellung eines präadhärisierten polyesterfilaments und reifenkord aus diesem polyesterfilament |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |