DE2200210C3 - Verfahren zur Entfernung von Stickstoffoxiden aus Gasgemischen - Google Patents

Verfahren zur Entfernung von Stickstoffoxiden aus Gasgemischen

Info

Publication number
DE2200210C3
DE2200210C3 DE2200210A DE2200210A DE2200210C3 DE 2200210 C3 DE2200210 C3 DE 2200210C3 DE 2200210 A DE2200210 A DE 2200210A DE 2200210 A DE2200210 A DE 2200210A DE 2200210 C3 DE2200210 C3 DE 2200210C3
Authority
DE
Germany
Prior art keywords
gas
bed
molecular sieve
silica gel
passed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE2200210A
Other languages
German (de)
English (en)
Other versions
DE2200210B2 (de
DE2200210A1 (de
Inventor
John Joseph Katonah N.Y. Collins (V.St.A.)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of DE2200210A1 publication Critical patent/DE2200210A1/de
Publication of DE2200210B2 publication Critical patent/DE2200210B2/de
Application granted granted Critical
Publication of DE2200210C3 publication Critical patent/DE2200210C3/de
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9481Catalyst preceded by an adsorption device without catalytic function for temporary storage of contaminants, e.g. during cold start
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/52Hydrogen sulfide
    • B01D53/523Mixtures of hydrogen sulfide and sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/52Hydrogen sulfide
    • B01D53/526Mixtures of hydrogen sulfide and carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00Nitrogen; Compounds thereof
    • C01B21/20Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
    • C01B21/36Nitrogen dioxide (NO2, N2O4)
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G5/00Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas
    • C10G5/04Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas with liquid absorbents
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/08Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/16Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with non-aqueous liquids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • B01D2253/108Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/10Single element gases other than halogens
    • B01D2257/102Nitrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/10Single element gases other than halogens
    • B01D2257/104Oxygen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/404Nitrogen oxides other than dinitrogen oxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/401Further details for adsorption processes and devices using a single bed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/414Further details for adsorption processes and devices using different types of adsorbents
    • B01D2259/4141Further details for adsorption processes and devices using different types of adsorbents within a single bed
    • B01D2259/4145Further details for adsorption processes and devices using different types of adsorbents within a single bed arranged in series
    • B01D2259/4146Contiguous multilayered adsorbents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)
DE2200210A 1971-01-06 1972-01-04 Verfahren zur Entfernung von Stickstoffoxiden aus Gasgemischen Expired DE2200210C3 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10426271A 1971-01-06 1971-01-06

Publications (3)

Publication Number Publication Date
DE2200210A1 DE2200210A1 (de) 1972-07-27
DE2200210B2 DE2200210B2 (de) 1977-11-24
DE2200210C3 true DE2200210C3 (de) 1978-07-13

Family

ID=22299503

Family Applications (1)

Application Number Title Priority Date Filing Date
DE2200210A Expired DE2200210C3 (de) 1971-01-06 1972-01-04 Verfahren zur Entfernung von Stickstoffoxiden aus Gasgemischen

Country Status (11)

Country Link
US (1) US3674429A (enExample)
JP (1) JPS5123959B1 (enExample)
AU (1) AU458612B2 (enExample)
BE (1) BE777726A (enExample)
CA (1) CA961239A (enExample)
DE (1) DE2200210C3 (enExample)
FR (1) FR2121599B1 (enExample)
GB (1) GB1357701A (enExample)
IT (1) IT948802B (enExample)
NL (1) NL170838C (enExample)
SE (1) SE382803B (enExample)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2055425B2 (de) * 1970-11-11 1979-09-06 Bayer Ag, 5090 Leverkusen Adsorptionsverfahren zum Zerlegen von Gasgemischen
GB1460595A (en) * 1974-02-22 1977-01-06 Cjb Developments Ltd Process for the removal of carbon dioxide from gases
US4220632A (en) * 1974-09-10 1980-09-02 The United States Of America As Represented By The United States Department Of Energy Reduction of nitrogen oxides with catalytic acid resistant aluminosilicate molecular sieves and ammonia
GB1545635A (en) * 1975-12-19 1979-05-10 Mitsubishi Electric Corp Ozone-generating apparatus
US4146372A (en) * 1976-03-29 1979-03-27 Mittex Aktiengesellschaft Process and system for recovering water from the atmosphere
US4367204A (en) * 1979-05-04 1983-01-04 Budapesti Muszaki Egyetem Process for the recirculation of nitrogen oxides
FR2464744A1 (fr) * 1979-09-12 1981-03-20 Ceag Verfahrenstechnik Gmbh Procede et installation pour la regeneration thermique de produits adsorbants charges
US4398927A (en) * 1980-07-30 1983-08-16 Exxon Research And Engineering Co. Cyclic adsorption process
DE3149672C2 (de) * 1981-12-15 1986-11-13 Didier-Werke Ag, 6200 Wiesbaden Verfahren zum Klimatisieren unter Anwendung von mittels Wassersorption arbeitenden Speichermedien
DE3201390A1 (de) * 1982-01-19 1983-07-28 CEAG Verfahrenstechnik GmbH, 4714 Selm Verfahren zur rueckgewinnung eines im wesentlichen wasserfreien desorbats sowie vorrichtung zum durchfuehren des verfahrens
DE3226840A1 (de) * 1982-07-17 1984-02-16 Kernforschungsanlage Jülich GmbH, 5170 Jülich Verfahren zur abtrennung und rezyklierung von no(pfeil abwaerts)x(pfeil abwaerts)-gasanteilen durch ad- und desorption an molsieb
US4472178A (en) * 1983-07-05 1984-09-18 Air Products And Chemicals, Inc. Adsorptive process for the removal of carbon dioxide from a gas
AT380092B (de) * 1983-09-29 1986-04-10 Simmering Graz Pauker Ag Verfahren und vorrichtung zur gewinnung von waerme aus wasserdampfhaeltigen gasen durch absorption oder adsorption
DE3336427A1 (de) * 1983-10-06 1985-04-18 Linde Ag, 6200 Wiesbaden Verfahren und vorrichtung zum regenerieren von adsorbern
JPS60173592U (ja) * 1984-04-27 1985-11-16 三和テッキ株式会社 電界検知型ブ−ム
JP2575874B2 (ja) * 1989-04-21 1997-01-29 三菱重工業株式会社 自己再生型脱硝方法
US5264198A (en) * 1991-03-29 1993-11-23 Mainstream Engineering Corporation Method for production of spacecraft-grade N2 O4
US5169413A (en) * 1991-10-07 1992-12-08 Praxair Technology Inc. Low temperature pressure swing adsorption with refrigeration
US5670125A (en) * 1993-09-30 1997-09-23 The Boc Group, Inc. Process for the purification of nitric oxide
US5417950A (en) * 1994-07-07 1995-05-23 The Boc Group, Inc. Process for the purification of nitric oxide
US5580369A (en) * 1995-01-30 1996-12-03 Laroche Industries, Inc. Adsorption air conditioning system
US5614000A (en) * 1995-10-04 1997-03-25 Air Products And Chemicals, Inc. Purification of gases using solid adsorbents
US5919286A (en) * 1997-03-06 1999-07-06 Air Products And Chemicals, Inc. PSA process for removel of nitrogen oxides from gas
US6106593A (en) * 1998-10-08 2000-08-22 Air Products And Chemicals, Inc. Purification of air
US6576044B1 (en) 1999-02-25 2003-06-10 The Boc Group, Inc. Process for the purification of nitric oxide
US6231824B1 (en) 1999-08-10 2001-05-15 The Boc Group, Inc. Removal of nitric oxide from gas streams
CA2737695C (en) 2008-09-22 2018-10-23 Geno Llc Conversion of nitrogen dioxide (no2) to nitric oxide (no)
WO2021242717A1 (en) 2020-05-26 2021-12-02 Stuckert Nicholas Combined thermal energy storage and contaminant removal

Also Published As

Publication number Publication date
DE2200210B2 (de) 1977-11-24
AU458612B2 (en) 1975-03-06
NL170838B (nl) 1982-08-02
FR2121599A1 (enExample) 1972-08-25
GB1357701A (en) 1974-06-26
DE2200210A1 (de) 1972-07-27
US3674429A (en) 1972-07-04
AU3759472A (en) 1973-07-12
JPS5123959B1 (enExample) 1976-07-20
CA961239A (en) 1975-01-21
NL7200138A (enExample) 1972-07-10
NL170838C (nl) 1983-01-03
BE777726A (fr) 1972-07-05
FR2121599B1 (enExample) 1974-10-18
IT948802B (it) 1973-06-11
SE382803B (sv) 1976-02-16

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Legal Events

Date Code Title Description
C3 Grant after two publication steps (3rd publication)
8339 Ceased/non-payment of the annual fee